Importance of Chemical Composition of Ice Nuclei on the Formation of Arctic Ice Clouds     

Setigui Aboubacar Keita  Eric Girard 《Pure and Applied Geophysics》2016,173(9):3141-3163

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Element partitioning between magnesium silicate perovskite and ferropericlase: New insights into bulk lower-mantle geochemistry     

Anne-Line Auzende  James Badro  Frederick J. Ryerson  Peter K. Weber  Stewart J. Fallon  Ahmed Addad  Julien Siebert  Guillaume Fiquet   《Earth and Planetary Science Letters》2008,269(1-2):164-174

In this study, we investigated iron–magnesium exchange and transition-metal trace-element partitioning between magnesium silicate perovskite (Mg,Fe)SiO₃ and ferropericlase (Mg,Fe)O synthetised under lower-mantle conditions (up to 115 GPa and 2200 K) in a laser-heated diamond anvil cell. Recovered samples were thinned to electron transparency by focused ion beam and characterized by analytical transmission electron microscopy (ATEM) and nanometer-scale secondary ion mass spectroscopy (nanoSIMS). Iron concentrations in both phases were obtained from X-ray energy dispersive spectroscopy measurements and nanoSIMS. Our results are the first to show that recently reported spin-state and phase transitions in the lower mantle directly affect the evolution of Fe–Mg exchange between both phases. Mg-perovskite becomes increasingly iron-depleted above 70–80 GPa possibly due to the high spin–low spin transition of iron in ferropericlase. Conversely, the perovskite to post-perovskite transition is accompanied by a strong iron enrichment of the silicate phase, ferropericlase remaining in the Fe-rich phase though. Nanoparticles of metallic iron were observed in the perovskite-bearing runs, suggesting the disproportionation of ferrous iron oxide, but were not observed when the post-perovskite phase was present. Implications on the oxidation state of the Earth and core segregation will be discussed. Transition trace-element (Ni, Mn) concentrations (determined with the nanoSIMS) show similar trends and could thus be used to trace the origin of diamonds generated at depth. This study provides new results likely to improve the geochemical and geophysical models of the Earth's deep interiors.  相似文献   

No significant post-Eocene rotation of the Moesian Platform and Rhodope (Bulgaria): Implications for the kinematic evolution of the Carpathian and Aegean arcs     

Douwe J.J. van Hinsbergen  Guillaume Dupont-Nivet  Radoslav Nakov  Karen Oud  Christian Panaiotu 《Earth and Planetary Science Letters》2008,273(3-4):345-358

The region located between the Carpathian–Balkan and Aegean arcs, the Moesian Platform and Bulgarian Rhodope, is generally assumed to have been stably attached to the East European craton during the Cenozoic evolution of these arcs. The kinematic evolution of this region is, however, poorly constrained by paleomagnetic analysis. In this paper we provide new paleomagnetic data (800 volcanic and sedimentary samples from 12 localities) showing no significant post-Eocene rotation of the Moesian platform and Rhodope with respect to Eurasia, therefore confirming the stability of this region. We compare this result to a provided review of paleomagnetic data from the South Carpathians (Tisza block) and the Aegean region. The Tisza block underwent 68.4 ± 16.7° of middle Miocene ( 15–10 Ma) clockwise rotation with respect to the Moesian Platform, in line with previous rotation estimates based on structural geology. The stability of the Moesian platform during middle Miocene eastward emplacement of the Tisza block into the Carpathian back-arc supports dextral shear along the Southern Carpathians recorded by 13–6 Ma clockwise strike-slip related rotations in foreland deposits. The new reference direction for the Moesian platform and Rhodope allows accurate quantification of the rotation difference with the west Aegean domain at 38.0 ± 7.2° occurring between 15 and 8 Ma. To accommodate this rotation, we propose that the pivot point of the west-Aegean rotation was located approximately in the middle of the rotating domain rather than at the northern tip as previously proposed. This new scenario predicts less extension southeast of the pivot point, in good agreement with estimates from Aegean structural geology. Northwest of the pivot point, the model requires contraction or extrusion that can be accommodated by the coeval motion of the Tisza Block around the northwestern edge of the Moesian platform.  相似文献   

Numerical study of the variations of magnetic resonance signals caused by surface slope   总被引：1，自引：0，他引：1  

J.-F. Girard  A. Legchenko  M. Boucher  J.-M. Baltassat 《Journal of Applied Geophysics》2008,66(3-4):94

When performing forward modelling and inversion of Magnetic Resonance Sounding (MRS) data, the water-content distribution is typically assumed to be horizontal (1D case). This assumption is fully justified because MRS is often used for characterizing continuous aquifers in a nearly flat environment. However, MRS can also be used in areas with sharp topographical variations. Following a review of the standard MRS equations when using a coincident transmitter/receiver loop, the mathematical terms potentially affected by tilting of the loop are discussed. We present the results of a numerical modelling exercise, studying a case where the surface is not horizontal and the loop cannot be considered to be parallel to the top of the aquifer. This shows that maximum variations in the MRS-signal amplitude are caused mainly by north- or south-dipping slopes. Slope effects depend on the loop size (a larger loop produces a larger error) especially in the presence of shallow water. With a geomagnetic-field inclination of 65° and a slope angle ≤ 10°, the topography causes a maximum variation in amplitude of less than 10%. Near magnetic poles and equator, the slope effect is lower and undetectable in most cases. It was found that within a 10% range of variation in the amplitude, errors introduced into inversions are within the typical uncertainty for MRS inversion and hence no topographic corrections are necessary. Thus, a significant effect from non-horizontal topography might be expected only when data uncertainty is lower than the slope effect (the slope effect is lower than equivalence when data quality is poor). Today, most field data sets are inverted using the modulus of the MRS signal, but some new developments consider the complex signal (both modulus and phase). However, inversion of complex MRS signals, which would provide a higher sensitivity to groundwater distribution, may be affected by slope effect. Thus, the slope orientation and dip angle should be accurately measured in the field when the phase of MRS signals is inverted too.  相似文献   

Automatic correction and simplification of geological maps and cross-sections for numerical simulations     

Pierre Anquez  Jeanne Pellerin  Modeste Irakarama  Paul Cupillard  Bruno Lévy  Guillaume Caumon 《Comptes Rendus Geoscience》2019,351(1):48-58

Incorporating prior geological knowledge in geophysical process models often meets practical meshing challenges and raises the question of how much detail is to be included in the geometric model. We introduce a strategy to automatically repair and simplify geological maps, geological cross-sections and the associated meshes while preserving elementary consistency rules. To identify features breaking validity and/or the thin features potentially problematic when generating a mesh, we associate an exclusion zone with each model feature (horizon, fault). When these zones overlap, both the connectivity and the geometry of the geological layers are automatically modified. The output model enforces specific practical quality criteria on the model topology and geometry that facilitates the generation of a mesh with lower bounds on minimum angles and minimum local entity sizes. Our strategy is demonstrated on an invalid geological cross-section from a real-case study in the Lorraine coal basin. We further explore the impacts of the model modifications on wave propagation simulation. We show that the differences on the seismograms due to model simplifications are relatively small if the magnitude of simplifications is adapted to the physical problem parameters.  相似文献   

H2O Content Measurement in Phengite by Secondary Ion Mass Spectrometry: A New Set of Reference Materials     

Cindy Luisier  Lukas Baumgartner  Guillaume Siron  Torsten Vennemann  Martin Robyr 《Geostandards and Geoanalytical Research》2019,43(4):635-646

Five new natural white mica reference materials (RMs) were developed for in situ H₂O content analyses by secondary ion mass spectrometry at the SwissSIMS laboratory of Lausanne University, Switzerland. The white mica reference materials cover a large part of the natural muscovite–phengite compositional range and are therefore suitable as reference materials for the analysis of natural rocks as well as individual minerals. The independent H₂O content of the reference materials UNIL_WM1 to UNIL_WM5 was obtained by thermal conversion elemental analyser and corresponds to 4.35 ± 0.02, 4.33 ± 0.03, 4.30 ± 0.07, 4.50 ± 0.02 and 4.42 ± 0.11 (% m/m, ± 1s), respectively. SIMS determinations of H₂O content revealed a matrix effect correlated to the FeO content of white mica. The compositional range in FeO of the reference materials that were calibrated for H₂O determination is from 1.13% to 3.67% m/m. No crystallographic orientation dependency was observed at the level of homogeneity of these reference materials. An analytical precision of 0.02% to 0.08% m/m (1SE) is expected for the final uncertainty on measurements of unknown white micas in natural samples.  相似文献   

Diagenetic controls on the isotopic composition of carbonate‐associated sulphate in the Permian Capitan Reef Complex,West Texas     

Theodore M. Present  Melissa Gutierrez  Guillaume Paris  Charles Kerans  John P. Grotzinger  Jess F. Adkins 《Sedimentology》2019,66(7):2605-2626

Late Palaeozoic‐age strata from the Capitan Reef in west Texas show facies‐dependent heterogeneity in the sulphur isotopic composition of carbonate‐associated sulphate, which is trace sulphate incorporated into carbonate minerals that is often used to reconstruct the sulphur isotopic composition of ancient seawater. However, diagenetic pore fluid processes may influence the sulphur isotopic composition of carbonate‐associated sulphate. These processes variously modify the sulphur isotopic composition of incorporated sulphate from syndepositional seawater in shelf crest, outer shelf, shelf margin and slope depositional settings. This study used a new multicollector inductively‐coupled plasma mass spectrometry technique to determine the sulphur isotopic composition of samples of individual depositional and diagenetic textures. Carbonate rocks representing peritidal facies in the Yates and Tansill formations preserve the sulphur isotopic composition of Guadalupian seawater sulphate despite alteration of the carbon and oxygen isotopic compositions by meteoric and dolomitizing diagenetic processes. However, sulphur isotopic data indicate that limestones deposited in reef and slope facies in the Capitan and Bell Canyon formations largely incorporate sulphate from anoxic marine‐phreatic pore fluids isotopically modified from seawater by microbial sulphate reduction, despite generally preserving the carbon and oxygen isotopic compositions of Permian seawater. Some early and all late meteoric calcite cements have carbonate‐associated sulphate with a sulphur isotopic composition distinct from that of Permian seawater. Detailed petrographic and sedimentary context for carbonate‐associated sulphate analyses will allow for improved reconstructions of ancient seawater composition and diagenetic conditions in ancient carbonate platforms. The results of this study indicate that carbonate rocks that diagenetically stabilize in high‐energy environments without pore fluid sulphate gradients can provide a robust archive of ancient seawater's sulphur isotopic composition.  相似文献   

The Planeterrella,a pedagogic experiment in planetology and plasma physics     

Jean Lilensten  Mathieu Barthélemy  Cyril Simon  Philippe Jeanjacquot  Guillaume Gronoff 《Acta Geophysica》2009,57(1):220-235

We present here a plasma physics experiment which makes it possible to simulate, in a naive yet useful way, the formation of polar lights. It involves shooting electrons at a magnetized sphere placed in a vacuum chamber. This experiment, inspired by K. Birkeland’s Terrella, built at the turn of 19th century, allows the visualization of very many geophysical and astrophysical situations. Although delicate, it is feasible at undergraduate level.  相似文献   

Reconstruction of Channelized Systems Through a Conditioned Reverse Migration Method     

Marion N. Parquer  Pauline Collon  Guillaume Caumon 《Mathematical Geosciences》2017,49(8):965-994

Geological heterogeneities directly control underground flow. In channelized sedimentary environments, their determination is often underconstrained: it may be possible to observe the most recent channel path and the abandoned meanders on seismic or satellite images, but smaller-scale structures are generally below image resolution. In this paper, reconstruction of channelized systems is proposed with a stochastic inverse simulation reproducing the reverse migration of the system. Maps of the recent trajectories of the Mississippi river were studied to define appropriate relationships between simulation parameters. Measurements of curvature and migration vectors showed (i) no significant correlation between curvature and migration offset and (ii) correlation trends of downstream and lateral migration offsets versus the curvature at half-meander scale. The proposed reverse migration method uses these trends to build possible paleo-trajectories of the river starting from the last stage of the sequence observed from present-day (satellite or seismic) data. As abandoned meanders provide clues about the paleo-locations of the river, they are integrated time step by time step during the reverse simulation process. We applied the method to a satellite image of a fluvial system. Each of the different resulting geometries of the system honored most of the available observations and presented meandering patterns similar to the observed ones.  相似文献   

The importance of chemical data for the study of interstellar shocks     

Evelyne Roueff  Guillaume Pineau Des Forêts  David R. Flower 《Astrophysics and Space Science》1995,233(1-2):125-137

Shock waves perturb the chemical state of the interstellar gas. We consider the effects of C-shocks on the composition of molecular clouds, for a range of values of the pre-shock gas density and magnetic induction. The time required to re-establish equilibrium in the post-shock gas depends on the initial conditions and can become very large. The significance of the two known chemical phases of dark clouds and of bistability is considered in this context.  相似文献