An integrated methodology for salt damage assessment and remediation: the case of San Jerónimo Monastery (Granada, Spain)     

E. Ruiz-Agudo  B. Lubelli  A. Sawdy  R. van Hees  C. Price  C. Rodriguez-Navarro 《Environmental Earth Sciences》2011,63(7-8):1475-1486

San Jerónimo Monastery (Granada, Spain) was selected as a case study for the investigation of the effect of indoor environmental conditions on salt weathering and for on-site testing of a remediation treatment using crystallization inhibitors on account of the extreme salt damage affecting both the building stone, a biomicritic limestone, calcarenite and wall paintings. A methodology combining several analysis techniques, phenomenological observations, salt and moisture analysis, environmental monitoring and thermodynamic simulations, was adopted in order to study the salt damage problems affecting this building. Within the collected samples, the majority of salts were found to be magnesium sulphate in the form of either hexahydrite or epsomite, depending on the climate conditions, together with minor amounts of gypsum, nitrates and chlorides. Comparison of empirical observations with thermodynamic simulations of the salt mixture behaviour clearly showed that salt-induced damage events take place during the seasonal changes from spring to summer and winter to spring. An aqueous solution of an organic phosphonate, which in laboratory experiments was found to be an effective inhibitor of magnesium sulphate crystallization, was sprayed over a selected test area of unpainted stonework at the site. Preliminary results seem to indicate that after the application of the treatment both the amount of efflorescence and ongoing damage to the stone support is reduced. However, long-term monitoring of the future condition of the test area is needed to confirm whether indeed this treatment is appropriate and effective in reducing salt damage at this case study site. The outcome of this study extends beyond the particular problems at San Jerónimo Monastery, as it demonstrates a methodological approach for the study and evaluation of salt weathering problems affecting cultural heritage.  相似文献   

Origin of freshwater and polynya water in the Arctic Ocean halocline in summer 2007     

Dorothea Bauch  Michiel Rutgers van der Loeff  Nils Andersen  Sinhue Torres-Valdes  Karel Bakker  E. Povl Abrahamsen 《Progress in Oceanography》2011,91(4):482-495

Extremely low summer sea-ice coverage in the Arctic Ocean in 2007 allowed extensive sampling and a wide quasi-synoptic hydrographic and δ¹⁸O dataset could be collected in the Eurasian Basin and the Makarov Basin up to the Alpha Ridge and the East Siberian continental margin. With the aim of determining the origin of freshwater in the halocline, fractions of river water and sea-ice meltwater in the upper 150 m were quantified by a combination of salinity and δ¹⁸O in the Eurasian Basin. Two methods, applying the preformed phosphate concentration (PO^*) and the nitrate-to-phosphate ratio (N/P), were compared to further differentiate the marine fraction into Atlantic and Pacific-derived contributions. While PO^*-based assessments systematically underestimate the contribution of Pacific-derived waters, N/P-based calculations overestimate Pacific-derived waters within the Transpolar Drift due to denitrification in bottom sediments at the Laptev Sea continental margin.Within the Eurasian Basin a west to east oriented front between net melting and production of sea-ice is observed. Outside the Atlantic regime dominated by net sea-ice melting, a pronounced layer influenced by brines released during sea-ice formation is present at about 30–50 m water depth with a maximum over the Lomonosov Ridge. The geographically distinct definition of this maximum demonstrates the rapid release and transport of signals from the shelf regions in discrete pulses within the Transpolar Drift.The ratio of sea-ice derived brine influence and river water is roughly constant within each layer of the Arctic Ocean halocline. The correlation between brine influence and river water reveals two clusters that can be assigned to the two main mechanisms of sea-ice formation within the Arctic Ocean. Over the open ocean or in polynyas at the continental slope where relatively small amounts of river water are found, sea-ice formation results in a linear correlation between brine influence and river water at salinities of about 32–34. In coastal polynyas in the shallow regions of the Laptev Sea and southern Kara Sea, sea-ice formation transports river water into the shelf’s bottom layer due to the close proximity to the river mouths. This process therefore results in waters that form a second linear correlation between brine influence and river water at salinities of about 30–32. Our study indicates which layers of the Arctic Ocean halocline are primarily influenced by sea-ice formation in coastal polynyas and which layers are primarily influenced by sea-ice formation over the open ocean. Accordingly we use the ratio of sea-ice derived brine influence and river water to link the maximum in brine influence within the Transpolar Drift with a pulse of shelf waters from the Laptev Sea that was likely released in summer 2005.  相似文献   

Source-rock maturation characteristics of symmetric and asymmetric grabens inferred from integrated analogue and numerical modeling: The southern Viking Graben (North Sea)     

Maarten P. Corver  Harry DoustJan-Diederik van Wees  Sierd Cloetingh 《Marine and Petroleum Geology》2011,28(4):921-935

We present the results of an integrated analogue and numerical modeling study with a focus on structural, stratigraphic and thermal differences between symmetric and asymmetric grabens. These models enable fault interpretation and subsidence analyses in studies of active rifting and graben migration. We imported the surface topography and crustal thinning factors from the analogue models into tectono-stratigraphic forward models which allowed an assessment of the relative importance of sediment stacking in the generation of symmetric and asymmetric grabens. Effects on source-rock maturation zones were calculated through 1D-thermal modeling for different graben types. Combined analogue-numerical modeling appears to be a useful method to simulate natural examples, as shown in this study of the southern Viking Graben in the northern North Sea. This area was formed by Early Permian-Late Jurassic extension, with rifting most intense during the Late Jurassic. The thermal structure of the model, constrained by lithospheric and sedimentary parameters for this region, compares well with actual source-rock maturation data on the southern Viking Graben.  相似文献   

Early-stage transformation of coastal marine governance in Vietnam?   总被引：1，自引：0，他引：1  

Derek Armitage  Melissa Marschke  Truong van Tuyen 《Marine Policy》2011

This paper examines an apparent ‘early stage’ governance transformation in the Tam Giang Lagoon, Vietnam. In this context, the role of key policy windows for innovative governance practice is assessed (e.g., changes to Land and Fisheries Laws). Also examined is the emergence of recent initiatives to catalyze a wider shift in governance practice in the region, including the formation of co-management institutional networks that contribute to trust building and learning, and the allocation of collective territorial use rights for fisheries. While these changes are consistent with experiences in other coastal marine contexts, the paper shows that place-based and longitudinal research is necessary to explain and predict the conditions and incentives that catalyze governance shifts. Differences between a governance change and more fundamental transformation are difficult to discern using point-in-time analysis. Moreover, the results show that current declines in ecological conditions in the lagoon may not be reversed by changes to access rights or the emergence of co-management. Rather, these governance changes may simply help to stabilize the situation and buy time until other livelihood opportunities arise. Assessments of governance transformation thus need to be linked to ecological outcomes (i.e., reversing degradation of coastal marine systems, avoiding biophysical tipping points) which may not be easily identified in the short-term. Despite uncertainty, the emergence of policy windows, evidence of institutional innovation, and small-scale rights allocation experiments, all suggest important shifts in the trajectory of governance are underway in the Tam Giang Lagoon.  相似文献   

Coastal erosion and control   总被引：2，自引：0，他引：2  

L.C. van Rijn 《Ocean & Coastal Management》2011,54(12):867-887

Coastal erosion is a problem at many coastal sites caused by natural effects as well as human activities. This paper explores the coastal cell concept to deal with coastal erosion by identifying and analysingthe sediment volumes accumulated in large-scale and small-scale coastal cells at various sites. Mechanisms causing chronic erosion and episodic erosion related to coastal variability are identified and discussed. The effectiveness of soft and hard remedial measures for sandy beaches are assessed based on laboratory, field and modelling experiences.  相似文献   

Ecosystem-based marine spatial management: Review of concepts, policies, tools, and critical issues   总被引：1，自引：0，他引：1  

Stelios Katsanevakis  Vanessa Stelzenmüller  Andy South  Thomas Kirk Sørensen  Peter J.S. Jones  Sandy Kerr  Fabio Badalamenti  Christos Anagnostou  Patricia Breen  Guillem Chust  Giovanni D’Anna  Mike Duijn  Tatiana Filatova  Fabio Fiorentino  Helena Hulsman  Kate Johnson  Aristomenis P. Karageorgis  Ingrid Kröncke  Simone Mirto  Carlo Pipitone  Susan Portelli  Wanfei Qiu  Henning Reiss  Dimitris Sakellariou  Maria Salomidi  Luc van Hoof  Vassiliki Vassilopoulou  Tomás Vega Fernández  Sandra Vöge  Anke Weber  Argyro Zenetos  Remment ter Hofstede 《Ocean & Coastal Management》2011,54(11):807-820

Conventional sectoral management and piecemeal governance are considered less and less appropriate in pursuit of sustainable development. Ecosystem based marine spatial management (EB-MSM) is an approach that recognizes the full array of interactions within an ecosystem, including human uses, rather than considering single issues, species, or ecosystem services in isolation. Marine spatial planning and ocean zoning are emerging concepts that can support EB-MSM. EB-MSM is driven by high-level goals that managers aim to achieve through the implementation of measures. High-level goals and objectives need to be translated into more operational objectives before specific targets, limits and measures can be elaborated.Monitoring, evaluation and adaptation are necessary to ensure that marine management measures are both effective and efficient. Solid monitoring frameworks are the foundation of adaptive management, as they provide the necessary information to evaluate performance and the effectiveness of management actions. Marine protected areas (MPAs) - possibly set up in networks - constitute a key component in EB-MSM policies and practises and have been applied as a cornerstone in conservation of marine biodiversity, management of fish populations, development of coastal tourism, etc. Moreover, MPA experiences have provided methods and concepts (such as zoning) to a wider EB-MSM context. The assignment of values to biophysical features of the marine environment allows the direct assessment of related management choices and may assist EB-MSM.A range of monetary valuation techniques have been proposed to reduce attributes of goods and services to a single metric. However, in the marine environment such an approach is often over simplistic, and thus less reductive techniques may be necessary. Rather than producing a single metric, the results of non-monetary assessments guide policy allowing weight to be given as necessary to potential areas of conflict and consensus.Strategies to take into account climate change effects and geohazard risks in EB-MSM have been applied or proposed worldwide. EB-MSM regimes must be alert to such risks and flexible to account for changes.  相似文献   

The response of phytoplankton to iron enrichment in Sub-Antarctic HNLCLSi waters: Results from the SAGE experiment     

Jill Peloquin  Julie HallKarl Safi  Walker O. Smith Jr.Simon Wright  Rick van den Enden 《Deep Sea Research Part II: Topical Studies in Oceanography》2011,58(6):808-823

Areas of high nutrients and low chlorophyll a comprise nearly a third of the world’s oceans, including the equatorial Pacific, the Southern Ocean and the Sub-Arctic Pacific. The SOLAS Sea-Air Gas Exchange (SAGE) experiment was conducted in late summer, 2004, off the east coast of the South Island of New Zealand. The objective was to assess the response of phytoplankton in waters with low iron and silicic acid concentrations to iron enrichment. We monitored the quantum yield of photochemistry (F_v/F_m) with pulse amplitude modulated fluorometry, chlorophyll a, primary productivity, and taxonomic composition. Measurements of F_v/F_m indicated that the phytoplankton within the amended patch were relieved from iron stress (F_v/F_m approached 0.65). Although there was no significant difference between IN and OUT stations at points during the experiment, the eventual enhancement in chlorophyll a and primary productivity was twofold by the end of the 15-day patch occupation. However, no change in particulate carbon or nitrogen pools was detected. Enhancement in primary productivity and chlorophyll a were approximately equal for all phytoplankton size classes, resulting in a stable phytoplankton size distribution. Initial seed stocks of diatoms were extremely low, <1% of the assemblage based on HPLC pigment analysis, and did not respond to iron enrichment. The most dominant groups before and after iron enrichment were type 8 haptophytes and prasinophytes that were associated with ∼75% of chlorophyll a. Twofold enhancement of biomass estimated by flow cytometry was detected only in eukaryotic picoplankton, likely prasinophytes, type 8 haptophytes and/or pelagophytes. These results suggest that factors other than iron, such as silicic acid, light or physical disturbance limited the phytoplankton assemblage during the SAGE experiment. Furthermore, these results suggest that additional iron supply to the Sub-Antarctic under similar seasonal conditions and seed stock will most likely favor phytoplankton <2 ??m. This implies that any iron-mediated gain of fixed carbon will most likely be remineralized in shallow water rather than sink and be sequestered in the deep ocean.  相似文献   

Implications of alternative metrics for global mitigation costs and greenhouse gas emissions from agriculture     

A. Reisinger  P. Havlik  K. Riahi  O. van Vliet  M. Obersteiner  M. Herrero 《Climatic change》2013,117(4):677-690

100-year Global Warming Potentials (GWPs) are used almost universally to compare emissions of greenhouse gases in national inventories and reduction targets. GWPs have been criticised on several grounds, but little work has been done to determine global mitigation costs under alternative physics-based metrics . We used the integrated assessment model MESSAGE to compare emission pathways and abatement costs for fixed and time-dependent variants of the Global Temperature Change Potential (GTP) with those based on GWPs, for a policy goal of limiting the radiative forcing to a specified level in the year 2100. We find that fixed 100-year GTPs would increase global abatement costs (discounted and aggregated over the 21^st century) under this policy goal by 5–20 % relative to 100-year GWPs, whereas time-varying GTPs would reduce costs by about 5 %. These cost differences are smaller than differences arising from alternative assumptions regarding agricultural mitigation potential and much smaller than those arising from alternative radiative forcing targets. Using the land-use model GLOBIOM, we show that alternative metrics affect food production differently in different world regions depending on regional characteristics of future land-use change to meet growing food demand. We conclude that under scenarios of complete participation, the choice of metric has a limited impact on global abatement costs but could be important for the political economy of regional and sectoral participation in collective mitigation efforts, in particular changing costs and gains over time for agriculture and energy-intensive sectors.  相似文献   

Climate impact of transportation A model comparison     

Bastien Girod  Detlef P. van Vuuren  Maria Grahn  Alban Kitous  Son H Kim  Page Kyle 《Climatic change》2013,118(3-4):595-608

Transportation contributes to a significant and rising share of global energy use and GHG emissions. Therefore modeling future travel demand, its fuel use, and resulting CO₂ emission is highly relevant for climate change mitigation. In this study we compare the baseline projections for global service demand (passenger-kilometers, ton-kilometers), fuel use, and CO₂ emissions of five different global transport models using harmonized input assumptions on income and population. For four models we also evaluate the impact of a carbon tax. All models project a steep increase in service demand over the century. Technology change is important for limiting energy consumption and CO₂ emissions, the study also shows that in order to stabilise or even decrease emissions radical changes would be required. While all models project liquid fossil fuels dominating up to 2050, they differ regarding the use of alternative fuels (natural gas, hydrogen, biofuels, and electricity), because of different fuel price projections. The carbon tax of 200 USD/tCO₂ in 2050 stabilizes or reverses global emission growth in all models. Besides common findings many differences in the model assumptions and projections indicate room for further understanding long-term trends and uncertainty in future transport systems.  相似文献   

Future surface mass balance of the Antarctic ice sheet and its influence on sea level change, simulated by a regional atmospheric climate model   总被引：1，自引：1，他引：0  

S. R. M. Ligtenberg  W. J. van de Berg  M. R. van den Broeke  J. G. L. Rae  E. van Meijgaard 《Climate Dynamics》2013,41(3-4):867-884

A regional atmospheric climate model with multi-layer snow module (RACMO2) is forced at the lateral boundaries by global climate model (GCM) data to assess the future climate and surface mass balance (SMB) of the Antarctic ice sheet (AIS). Two different GCMs (ECHAM5 until 2100 and HadCM3 until 2200) and two different emission scenarios (A1B and E1) are used as forcing to capture a realistic range in future climate states. Simulated ice sheet averaged 2 m air temperature (T_2m) increases (1.8–3.0 K in 2100 and 2.4–5.3 K in 2200), simultaneously and with the same magnitude as GCM simulated T_2m. The SMB and its components increase in magnitude, as they are directly influenced by the temperature increase. Changes in atmospheric circulation around Antarctica play a minor role in future SMB changes. During the next two centuries, the projected increase in liquid water flux from rainfall and snowmelt, together 60–200 Gt year^?1, will mostly refreeze in the snow pack, so runoff remains small (10–40 Gt year^?1). Sublimation increases by 25–50 %, but remains an order of magnitude smaller than snowfall. The increase in snowfall mainly determines future changes in SMB on the AIS: 6–16 % in 2100 and 8–25 % in 2200. Without any ice dynamical response, this would result in an eustatic sea level drop of 20–43 mm in 2100 and 73–163 mm in 2200, compared to the twentieth century. Averaged over the AIS, a strong relation between $\Updelta$ SMB and $\Updelta\hbox{T}_{2{\rm m}}$ of 98 ± 5 Gt w.e. year^?1 K^?1 is found.  相似文献