Impact of Changes in Redox Conditions on Leaching of Some Elements from MSW Fly Ash     

Lallan Prasad Gupta    Hodaka Kawahata    Mio Ltakeuchi  Hidekazu Ohta  Yoshiro Ono 《Resource Geology》2006,56(2):191-196

Abstract. Oxidation and reduction processes can influence extent of leaching of elements from solid waste. Three samples of municipal solid waste combustion fly ash were subjected to oxidizing and reducing conditions in order to evaluate leaching of elements in the Milli-Q water and fly ash (liquid to solid ratio, 100) mixtures. Although the oxidizing and reducing conditions were applied for 6 hours only, elements like Cs, Li, Mg, Sb, Tl and V leached more under oxidizing condition than under reducing condition in the case of all three ash samples. Cadmium, Pb and Zn leached more from all samples under reducing condition than under oxidizing condition. Leaching of other elements like Al, Ba, Cr, Cu, Ni and Rb was inconsistent with oxidizing or reducing conditions and varied from sample to sample, suggesting that factors other than redox may be more important in controlling leaching of these elements. Strong acid neutralization capacity of the fly ash samples let the pH vary within a narrow range, and thus severely limited the extent of leaching during the course of the experiment. Lead and Zn were the most sensitive while K and Na were the least sensitive to changes in redox conditions.  相似文献   

Heavy metals in freshly deposited sediments of the river Subernarekha, India: an example of lithogenic and anthropogenic effects   总被引：1，自引：0，他引：1  

A. K. Upadhyay  K. K. Gupta  J. K. Sircar  M. K. Deb  G. L. Mundhara 《Environmental Geology》2006,50(3):397-403

Heavy metal distribution patterns in river sediments aid in understanding the exogenic cycling of elements as well as in assessing the effect of anthropogenic influences. In India, the Subernarekha river flows over the Precambrian terrain of the Singhbhum craton in eastern India. The rocks are of an iron ore series and the primary rock types are schist and quartzite. One main tributary, the Kharkhai, flows through granite rocks and subsequently flows through the schist and quartzite layers. The Subernarekha flows through the East Singhbhum district, which is one of India’s industrialised areas known for ore mining, steel production, power generation, cement production and other related activities. Freshly deposited river sediments were collected upstream and downstream the industrial zone. Samples were collected from four locations and analysed in <63-μm sediment fraction for heavy metals including Zn, Pb, Cd and Cu by anodic stripping voltammetry. Enrichment of these elements over and above the local natural concentration level has been calculated and reported. Sediments of the present study are classified by Muller’s geo-accumulation index (I _geo) and vary from element to element and with climatic seasons. During pre-monsoon period the maximum I _geo value for Zn is moderately to highly polluted and for Cu and Pb is moderately polluted, respectively, based on the Muller’s standard. Anthropogenic, lithogenic or cumulative effects of both components are the main reasons for such variations in I _geo values. The basic igneous rock layer through which the river flows or a seasonal rivulet that joins with the main river may be the primary source for lithogenic components.  相似文献   

Real Time Analysis and Forecasting of Strata Caving Behaviour during Longwall Operations     

S. Tadisetty  K. Matsui  H. Shimada  R. N. Gupta 《Rock Mechanics and Rock Engineering》2006,39(4):383-393

Summary. Discontinuous manual observations and irregular caving characteristics of roof rocks often lead to improper decisions resulting in accidents and production loss. Hence, systematic monitoring of the hanging roof behind the chock shields is necessary for safe and productive mining operations. A real-time application was successfully implemented in an Indian mine for forecasting of hanging roof behaviour to enhance safety and productivity. This paper reports the functioning of real-time TWAP (time weighted average pressure) analysis in the forecasting of hanging roof behaviour in real time.  相似文献   

Fast computation of Hankel Transform using orthonormal exponential approximation of complex kernel function     

Pravin K. Gupta  Sri Niwas  Neeta Chaudhary 《Journal of Earth System Science》2006,115(3):267-276

The computation of electromagnetic (EM) fields, for 1-D layered earth model, requires evaluation of Hankel Transform (HT) of the EM kernel function. The digital filtering is the most widely used technique to evaluate HT integrals. However, it has some obvious shortcomings. We present an alternative scheme, based on an orthonormal exponential approximation of the kernel function, for evaluating HT integrals. This approximation of the kernel function was chosen because the analytical solution of HT of an exponential function is readily available in literature. This expansion reduces the integral to a simple algebraic sum. The implementation of such a scheme requires that the weights and the exponents of the exponential function be estimated. The exponents were estimated through a guided search algorithm while the weights were obtained using Marquardt matrix inversion method. The algorithm was tested on analytical HT pairs available in literature. The results are compared with those obtained using the digital filtering technique with Anderson filters. The field curves for four types (A-, K-, H-and Q-type) of 3-layer earth models are generated using the present scheme and compared with the corresponding curves obtained using the Anderson sc heme. It is concluded that the present scheme is more accurate than the Anderson scheme  相似文献   

A GIS numerical framework to study the process basis of scaling statistics in river networks   总被引：1，自引：0，他引：1  

Mantilla  R. Gupta  V.K. 《Geoscience and Remote Sensing Letters, IEEE》2005,2(4):404-408

A new geographic information system (GIS) numerical framework (NF), called CUENCAS, for flows in river networks is presented. The networks are extracted from digital elevation models (DEMs). The program automatically partitions a basin into hillslopes and channel links that are required to correspond to these features in an actual terrain. To investigate the appropriate DEM resolution for this correspondence, we take a high-resolution DEM at 10-m pixel size, and create DEMs at eight different resolutions in increments of 10 m by averaging. The extracted networks from 10-30 m remain about the same, even though there is a tenfold reduction in the number of pixels. By contrast, the extracted networks show increasing distortions of the original network from 40-90 m DEMs. We show the presence of statistical self-similarity (scaling) in the probability distributions of drainage areas in a Horton-Strahler framework using CUENCAS. The NF for flows takes advantage of the hillslope-link decomposition of an actual terrain and specifies mass and momentum balance equations and physical parameterizations at this scale. These equations are numerically solved. An application of NF is given to test different physical assumptions that produce statistical self-similarity in spatial peak flow statistics in a Horton-Strahler framework.  相似文献   

Atmospheric Surface-Layer Processes During the Total Solar Eclipse Of 11 August 1999     

Prakash M. Ramchandran  Radhika Ramchandran  K. Sen Gupta  S. M. Patil  P. N. Jadhav 《Boundary-Layer Meteorology》2002,104(3):445-461

The central path of the total solar eclipse (TSE) of 11 August 1999 mostly passedthrough a region of active monsoon in India, with the eclipse ending around localsunset. Measurements in the surface layer (SL) were carried out close to the eclipseaxis at Akola (20°42' N, 77°2' E) in central India. The globalradiation flux reaching the surface vanishes around totality at 1803:24 (LT), followedby a small recovery before again dipping to zero at sunset. The temperatures in the SL, and subsoil at 50-mm depth, show a local minimum with a lag of about 10 min after the second contact, whereas the lag appears to vanish when the temperature series is detrended. The SL exhibits near-neutral, though generally stable, conditions from about 1500 hr itself due to heavy cloud cover followed by the eclipse-induced cooling of the surface. The wind component across the eclipse axis vanishes at totality, the wind vector aligning with the azimuth of the traversing moon shadow. The deceleration of the mean flow can be due to the combined effect of the colder surface and downward heat flux, where the locally altered horizontal temperature gradients may cause, as in this instance, the cessation of the cross flow.The oscillations in temperature and wind that show significant peaks, around 90–100 min as well as the semi-period of the eclipse near 60 min, persist for several hours past the eclipse event. A fresh analysis of the published data on the TSE of 7 March 1970 shows spectral peaks in the temperature nearly coincident with those already reported from the surface pressure records. The oscillations in the SL fields during the two TSE events are very similar implying that the source mechanism is also likely to be the same in both the cases.  相似文献   

A response‐based decoupling criterion for multiply‐supported secondary systems     

Samit Ray Chaudhuri  Vinay K. Gupta 《地震工程与结构动力学》2002,31(8):1541-1562

It is often infeasible to carry out coupled analyses of multiply‐supported secondary systems for earthquake excitations. ‘Approximate’ decoupled analyses are then resorted to, unless the response errors due to those are significantly high. This study proposes a decoupling criterion to identify such cases where these errors are likely to be larger than an acceptable level. The proposed criterion is based on the errors in the primary system response due to decoupling and has been obtained by assuming (i) the input excitation to be an ideal white noise process, (ii) cross‐modal correlation to be negligible, and (iii) the combined system to be classically damped. It uses the modal properties of the undamped combined system, and therefore, a perturbation approach has been formulated to determine the combined system properties in case of light to moderately heavy secondary systems. A numerical study has been carried out to illustrate the accuracy achieved with the proposed perturbation formulation. The proposed decoupling criterion has been validated with the help of two example primary‐secondary systems and four example excitation processes. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

Prediction of Ground Vibrations due to Construction Blasts in Different Types of Rock   总被引：1，自引：1，他引：1  

G. R. Tripathy  I. D. Gupta 《Rock Mechanics and Rock Engineering》2002,35(3):195-204

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Geoindicators for tropical urbanization   总被引：4，自引：0，他引：4  

Avijit Gupta 《Environmental Geology》2002,42(7):736-742

The urban population of the developing countries, which are almost entirely within the tropics and subtropics, increased from 286 to 1,515 million between 1950 and 1990. This figure is expected to reach 4 billion by 2025. Certain major cities (Mexico City, Bombay, São Paulo, etc.) are expected to grow to extremely large sizes. The major physical changes that occur with urbanization can be summarized as changes in hydrology, geomorphology, climate, vegetation, and air and water quality. The intensity and rapidity of such changes require a careful, but urgent assessment of the environmental modification. The tropical environment tends to magnify the environmental impact of urbanization. Geoindicators can be used for the measurement of a number of changes of this nature. This paper presents a selection of geoindicators that could be used to measure such impacts. The geoindicators have been selected according to (1) their effectiveness in measuring environmental impacts and (2) the type of data that is required for their use. Shortage of quantitative information is a common problem for tropical cities. In addition, certain types of geoindicators need to be highlighted for cities in specific types of location such as deltas or coastal plains, steep slopes, or in proximity to convergent or transverse plate margins. The projection, that in another 50 years about half of the population of tropical countries will be urban, adds urgency to this venture.  相似文献   

Aftershock activity of Bhuj earthquake of january 26th, 2001     

Ashwani Kumar  S. C. Gupta  A. K. Jindal  Sanjay Jain  Vandana 《Journal of Earth System Science》2003,112(3):391-395

Following a large-sized Bhuj earthquake (M _s = 7.6) of January 26th, 2001, a small aperture 4-station temporary local network was deployed, in the epicentral area, for a period of about three weeks and resulted in the recording of more than 1800 aftershocks (-0.07 ≤M _L <5.0). Preliminary locations of epicenters of 297 aftershocks (2.0 ≤M _L <5.0) have brought out a dense cluster of aftershock activity, the center of which falls 20 km NW of Bhachau. Epicentral locations of after-shocks encompass a surface area of about 50 × 40 km² that seems to indicate the surface projection of the rupture area associated with the earthquake. The distribution of aftershock activity above magnitude 3, shows that aftershocks are nonuniformly distributed and are aligned in the north, northwest and northeast directions. The epicenter of the mainshock falls on the southern edge of the delineated zone of aftershock activity and the maximum clustering of activity occurs in close proximity of the mainshock. Well-constrained focal depths of 122 aftershocks show that 89% of the aftershocks occurred at depths ranging between 6 and 25 km and only 7% and 4% aftershocks occur at depths less than 5 and more than 25 km respectively. The Gutenberg-Richter (GR) relationship, logN = 4.52 - 0.89M_L, is fitted to the aftershock data (1.0<-M _L<5.0) and theb-value of 0.89 has been estimated for the aftershock activity.  相似文献