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1.
Abstract. Oxidation and reduction processes can influence extent of leaching of elements from solid waste. Three samples of municipal solid waste combustion fly ash were subjected to oxidizing and reducing conditions in order to evaluate leaching of elements in the Milli-Q water and fly ash (liquid to solid ratio, 100) mixtures. Although the oxidizing and reducing conditions were applied for 6 hours only, elements like Cs, Li, Mg, Sb, Tl and V leached more under oxidizing condition than under reducing condition in the case of all three ash samples. Cadmium, Pb and Zn leached more from all samples under reducing condition than under oxidizing condition. Leaching of other elements like Al, Ba, Cr, Cu, Ni and Rb was inconsistent with oxidizing or reducing conditions and varied from sample to sample, suggesting that factors other than redox may be more important in controlling leaching of these elements. Strong acid neutralization capacity of the fly ash samples let the pH vary within a narrow range, and thus severely limited the extent of leaching during the course of the experiment. Lead and Zn were the most sensitive while K and Na were the least sensitive to changes in redox conditions.  相似文献   
2.
Abstract. Municipal solid waste combustion leads to concentration of various metals in the solid residue (fly ash) remaining after combustion. These metals pose serious environmental hazard and require proper handling and monitoring in order to control their harmful effects. Leachability of some metals from fly ash was examined in fly ash and Milli-Q water mixture (liquid-to-solid ratio, 100) under various temperature and pH conditions in the laboratory. The leaching experiments conducted for 24 hours showed that pH was generally more important than temperature in controlling the amount of metals leached out of the fly ash. However, at a given pH, rise in temperature led to different degree of (usually one to two fold) enhanced or reduced leaching of metals. Owing to amphoteric nature of oxides of Al, Cr, Pb and Zn, these metals often yielded typical pattern of increase and decrease in their concentrations with change in pH. The extent of leaching of Cr and Pb in our experiments suggests that decrease of pH to acidic range in the case of Pb and to neutral to acidic range for Cr over a long period of storage of fly ash at solid waste dumping site may facilitate leaching of these metals from fly ash, leading to contamination of groundwater to the level that exceeds beyond the level permitted by the environmental laws.  相似文献   
3.
The future regional sea level (RSL) rise in the western North Pacific is investigated by dynamical downscaling with the Regional Ocean Modeling System (ROMS) with an eddy-permitting resolution based on three global climate models—MIROC-ESM, CSIRO-Mk3.6.0, and GFDL-CM3—under the highest greenhouse-gas emission scenario. The historical run is forced by the air-sea fluxes calculated from Coordinated Ocean Reference Experiment version 2 (COREv2) data. Three future runs—ROMS-MIROC, ROMS-CSIRO, and ROMS-GFDL—are forced with an atmospheric field constructed by adding the difference between the climate model parameters for the twenty-first and twentieth century to fields in the historical run. In all downscaling, the RSL rise along the eastern coast of Japan is generally half or less of the RSL rise maxima off the eastern coast. The projected regional (total) sea level rises along the Honshu coast during 2081–2100 relative to 1981–2000 are 19–25 (98–104), 6–15 (71–80), and 8–14 (80–86) cm in ROMS-MIROC, ROMS-CSIRO, and ROMS-GFDL, respectively. The discrepancies of the RSL rise along the Honshu coast between the climate models and downscaling are less than 10 cm. The RSL changes in the Kuroshio Extension (KE) region in all downscaling simulations are related to the changes of KE (northward shift or intensification) with climate change.  相似文献   
4.
Although much is known about overall sediment delivery ratios for catchments as components of sediment production and sediment yield, little is known about the component of temporary sediment storage. Sediment delivery ratios focused on the influence of storm-related sediment storage are measured at Matakonekone and Oil Springs tributaries of the Waipaoa River basin, east coast of New Zealand. The terrace deposits of both tributaries show abundant evidence of storm-related sedimentation, especially sediment delivered from Cyclone Bola, a 50 year return rainfall event which occurred in 1988. The sediment delivery ratio is calculated by dividing the volume of sediment transported from a tributary to the main stream by the volume of sediment generated at erosion sites in the tributary catchment. Because the sediment delivery volume is unknown, it can be calculated as the difference between sediment generation volume and sediment storage volume in the channel reach of the tributary. The volume of sediment generated from erosion sites in each tributary catchment was calculated from measurements made on aerial photographs dating from 1960 (1:44 000) and 1988 (1:27 000). The volume of sediment stored in the tributary can be calculated from measurements of cross-sections located along the tributary channel, which are accompanied by terrace deposits dated by counting annual growth rings of trees on terrace surfaces. Sediment delivery ratios are 0·93 for both Matakonekone catchment and Oil Springs catchment. Results indicate that Oil Springs catchment has contributed more than twice the volume of sediment to the Waipaoa River than the Matakonekone catchment (2·75 × 106 m3 vs 1·22 × 106 m3). Although large volumes of sediment are initially deposited during floods, subsequent smaller flows scour away much of these deposits. The sediment scouring rate from storage is 1·25 × 104 m3 a−1 for Matakonekone stream and 0·83 × 104 m3 a−1 for Oil Springs stream. Matakonekone and Oil Springs channels respond to extreme storms by instantaneously aggrading, then gradually excavating the temporarily stored sediment. Results from Matakonekone and Oil Springs streams suggest a mechanism by which event recurrence interval can strongly influence the magnitude of a geomorphic change. Matakonekone stream with its higher stream power is expected to excavate sediment deposits more rapidly and allow more rapid re-establishment of storage capacity. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   
5.
Mio Kasai   《Geomorphology》2006,81(3-4):421-439
In headwater streams in steep land settings, narrow and steep valley floors provide closely coupled relationships between geomorphic components including hillslopes, tributary fans, and channel reaches. These relationships together with small catchment sizes result in episodic changes to the amount of stored sediment in channels. Major sediment inputs follow high magnitude events. Subsequent exponential losses via removal of material can be represented by a relaxation curve. The influence of hillslope and tributary processes on relaxation curves, and that of altered coupling relations between components, were investigated along a 1.3 km reach of a degrading channel in the 4.8 km2 Weraamaia Catchment, New Zealand. Extensive deforestation in the late 19th and early 20th centuries, followed by invasion of scrubs and reforestation, induced changes to major erosion types from gully complexes to shallow landslides. Changes in the size and pattern of sediment slugs from 1938 to 2002 were analysed from air photographs tied to detailed field measurement. The rate and calibre of sediment flux changed progressively following substantive hillslope input in a storm in 1938. Subsequently, the channel narrowed and incised, decoupling tributary fans from the main stem, thereby scaling down the size of sediment slugs. As a consequence, the dominant influence on the behaviour of sediment slugs and associated relaxation processes, changed from tributary fans to the type and distribution of bedrock outcrops along the reach.  相似文献   
6.
A six‐year monitoring programme characterized the migration/dispersion patterns of sediment slugs generated following typhoon‐induced disturbances in 1993 and 1997 along a single‐thread gravel‐bed stream, Oyabu Creek, on Kyushu Island, Japan. This laterally con?ned creek comprises rif?e–pool sequences with intervening bedrock outcrops. The passage of sediment pulses associated with sediment slug processes re?ected, and was controlled by, the rif?e–pool structures which provided channel bed roughness, the volume of sediment stored along valley ?oors, and the distribution of bedrock outcrops. Changes to bed material size following major sediment inputs during the disturbance events also exerted an in?uence on subsequent sediment slug processes. The sequence of rainfall events, together with changes to channel bed structure, induced different phases in the sediment slug processes. The capacity of a reach to store or trap sediment, as recorded by the longitudinal structure of the channel, varied during these differing phases. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   
7.
本文在对岚皋县柳家坡滑坡群进行野外调研的基础上,论述和分析了该滑坡群的自然地质环境、工程地质特征及形成滑坡的主要因素。文章认为,因有构成河流阶地基座的软弱的千枚糜棱岩充当滑床和在滑床与滑体间有充分起润滑作用的水的供给,是柳家坡滑坡产生的根本原因。本章最后还对滑坡群的防护和治理措施提出了看法和意见。  相似文献   
8.
A typhoon in 1993 induced major aggradation along Oyabu Creek, a steep, gravel bed mountain stream in Kyushu, Japan. Processes of sediment reworking are inferred from a 7-year monitoring program that measured adjustments to channel cross-sections, the longitudinal profile, and the extent/distribution of bedrock outcrops along a 3-km study reach. Over time, the reach adopted a riffle and pool structure, with notable increase in the area of exposed bedrock on the bed. This adjustment process was characterised by progressive reduction in sediment storage change per unit flow. The relaxation pathway following disturbance induced by the typhoon was shaped by the magnitude and frequency of subsequent rainfall events, the capacity of these events to transport available sediments, and physical linkages between reaches. Adjacent subreaches demonstrated differing relaxation pathways in response to these influences, induced by spatial and temporal variability in threshold conditions along the channel. Longer-term evidence indicates that responses to major disturbance, such as the 1993 typhoon, occur as ‘cycles’ of around 20-year duration. A relaxation period of 7 years is required to attain a quasi-equilibrium bed configuration and rate of sediment flux. The timeframe of cycles is considered to reflect changes to hillslope–channel bed coupling, marking the period required to generate sufficient sediment stores to reactivate phases of aggradation and subsequent degradation.  相似文献   
9.
The sediment delivery ratio was estimated for two periods (28 years and eight years) following reforestation of seven tributary catchments (0·33 to 0·49 km2) in the headwaters of the Waipaoa River basin, North Island, New Zealand. In these catchments, gully erosion, which largely resulted from clearance of the natural forest between 1880 and 1920, is the main source of sediment to streams. Reforestation commenced in the early 1960s in an attempt to stabilize hillslopes and reduce sediment supply. Efforts have been partially successful and channels are now degrading, though gully erosion continues to supply sediment at accelerated rates in parts of the catchment. Data from the area indicate that the sediment delivery ratio (SDR) can be estimated as a function of two variables, ψ (the product of catchment area and channel slope) and A g (the temporally averaged gully area for the period). Sediment input from gullies was determined from a well defined relationship between sediment yield and gully area. Sediment scoured from channels was estimated from dated terrace remnants and the current channel bed. Terrace remnants represent aggradation during major floods. This technique provides estimates of SDR averaged over periods between large magnitude terrace‐forming events and with the present channel bed. The technique averages out short‐term variability in sediment flux. Comparison of gully area and sediment transport between two periods (1960–1988 and 1988–1996) indicates that the annual rate of sediment yield from gullies for the later period has decreased by 77 per cent, sediment scouring in channels has increased by 124 per cent, and sediment delivered from catchments has decreased by 78 per cent. However, average SDR for the tributaries was found to be not significantly different between these periods. This may reflect the small number of catchments examined. It is also due to the fact that the volume of sediment scoured from channels was very small relative to that produced by gullies. According to the equation for SDR determined for the Waipaoa headwaters, SDR increases with increasing catchment area in the case where A g and channel slope are fixed. This is because the amount of sediment produced from a channel by scouring increases with increasing catchment area. However, this relationship does not hold for the main stem of the study catchments, because sediment delivered from its tributaries still continues to accumulate in the channel. Higher order channels are, in effect, at a different stage in the aggradation/degradation cycle and it will take some time until a main channel reflects the effects of reforestation and its bed adjusts to net degradation. Results demonstrate significant differences among even low order catchments, and such differences will need to be taken into consideration when using SDR to estimate sediment yields. Copyright © 2001 John Wiley & Sons, Ltd.  相似文献   
10.
Due to the political boundaries between the Central European countries, on one hand, and the thick Tertiary cover in the Pannonian Basin, on the other, the eastward continuation of the Alpine and Dinaridic units has been ambiguous and poorly documented. Based on comparative analyses, the aim of the present paper is to define the pre-Tertiary structural units in the junction area of the Alpine, Dinaridic, and Pannonian regions, in the SW part of the Pannonian Basin, and to draw conclusions on the continuation of the Alpine and Dinaridic units. According to diagnostic characteristics of the Periadriatic Lineament system, the Balaton Lineament system may be considered as its direct eastern continuation. North of the Periadriatic–Balaton Lineament system, the Transdanubian Range Unit, due to its pre-Tertiary paleogeographic setting, shows mainly South Alpine facies relations; however, its present structural position is identical to that of the Upper Austroalpine nappes. Between the Periadriatic–Balaton and Zagreb–Zemplin Lineament systems heterogeneous structural units are juxtaposed, forming the Sava Composite Unit. In the northern part of this composite unit non-metamorphosed nappes occur which can be considered the eastern continuation of the South Alpine units. These nappes are overthrust onto Internal Dinaridic units in the Tertiary. The Zagreb–Zemplin (Mid-Hungarian) Lineament separates the Sava Unit from the Tisza Unit showing close affinity to the Tethyan margin of the Eurasian plate during the early stage of the Alpine evolution. Received: 1 June 1999 / Accepted: 14 March 2000  相似文献   
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