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31.
Regions of freshwater influence (ROFIs) are dynamic areas within the coastal seas that experience cycles of stability driven by density gradients and the spring-neap tidal cycle. As a result, pulses of biological production may occur on a more frequent timescale than the classic seasonal cycle. Net community production (NCP) rates and chlorophyll a concentration are presented from a site within the ROFI of Liverpool Bay and compared to similar measurements made at a site outside the ROFI during 2009. The influence of water column stability on biological production in the ROFI was also investigated using high-frequency observations from a Cefas Smartbuoy. Both sites were autotrophic from spring to autumn before becoming heterotrophic over winter. NCP at the inshore site was estimated to range from 30.8 to 50.4 gC m−2 year−1. A linear relationship detected between chlorophyll a and NCP from both sites was used to estimate metabolic balance over 1 year at the ROFI site using high-resolution chlorophyll a concentrations from the Smartbuoy but was found to poorly replicate NCP rates compared to those derived from dissolved oxygen fluxes. There was no clear biological response to periods of stratification within the ROFI, and it is proposed that changes in light attenuation in the Liverpool Bay ROFI, driven not only by stratification but also by fluctuations in riverine sediment load, most likely play an important role in controlling phytoplankton growth in this region.  相似文献   
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Zircon is a key mineral in geochemical and geochronological studies in a range of geological settings as it is mechanically and chemically robust. However, distortion of its crystal lattice can facilitate enhanced diffusion of key elements such as U and Pb. Electron backscatter diffraction (EBSD) analysis of ninety-nine zircons from the Lewisian Gneiss Complex (LGC) of northwest Scotland has revealed five zircons with lattice distortion. The distortion can take the form of gradual bending of the lattice or division of the crystal into subgrains. Zircon lattices are distorted because of either post-crystallisation plastic distortion or growth defects. Three of the five distorted zircons, along with many of the undistorted zircons in the population, were analysed by ion microprobe to measure U and Pb isotopes, Ti and REEs. Comparison of Th/U ratio, 207Pb/206Pb age, REE profile and Ti concentration between zircons with and without lattice distortion suggests that the distortion is variably affecting the concentration of these trace elements and isotopes within single crystals, within samples and between localities. REE patterns vary heterogeneously, sometimes relatively depleted in heavy REEs or lacking a Eu anomaly. Ti-in-zircon thermometry records temperatures that were either low (~700 °C) or high (>900 °C) relative to undistorted zircons. One distorted zircon records apparent 207Pb/206Pb isotopic ages (?3.0 to +0.3 % discordance) in the range of ~2,420–2,450 Ma but this does not correlate with any previously dated tectonothermal event in the LGC. Two other distorted zircons give discordant ages of 2,331 ± 22 and 2,266 ± 40 Ma, defining a discordia lower intercept within error of a late amphibolite-facies tectonothermal event. This illustrates that Pb may be mobilised in distorted zircons at lower metamorphic grade than in undistorted zircons. These differences in trace element abundances and isotope systematics in distorted zircons relative to undistorted zircons are generally interpreted to have been facilitated by subgrain walls. Trace elements and isotopes would have moved from undistorted lattice into these subgrain walls as their chemical potential is modified due to the presence of the dislocations which make up the subgrain wall. Subgrain walls provided pathways for chemical exchange between crystal and surroundings. Only five per cent of zircons in this population have lattice distortion suggesting it will not have a major impact on zircon geochronology studies, particularly as three of the five distorted zircons are from strongly deformed rocks not normally sampled in such studies. However, this does suggest there may be a case for EBSD analysis of zircons prior to geochemical analysis when zircons from highly deformed rocks are to be investigated.  相似文献   
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We investigate the impact of 1/8°, 1/16°, 1/32°, and 1/64° ocean model resolution on model–data comparisons for the Gulf Stream system mainly between the Florida Straits and the Grand Banks. This includes mean flow and variability, the Gulf Stream pathway, the associated nonlinear recirculation gyres, the large-scale C-shape of the subtropical gyre and the abyssal circulation. A nonlinear isopycnal, free surface model covering the Atlantic from 9°N to 47°N or 51°N, including the Caribbean and Gulf of Mexico, and a similar 1/16° global model are used. The models are forced by winds and by a global thermohaline component via ports in the model boundaries. When calculated using realistic wind forcing and Atlantic model boundaries, linear simulations with Munk western boundary layers and a Sverdrup interior show two unrealistic mean Gulf Stream pathways between Cape Hatteras and the Grand Banks, one proceeding due east from Cape Hatteras and a second one continuing northward along the western boundary until forced eastward by the regional northern boundary. The northern pathway is augmented when a linear version of the upper ocean global thermohaline contribution to the Gulf Stream is added as a Munk western boundary layer. A major change is required to obtain a realistic pathway in nonlinear models. Resolution of 1/8° is eddy-resolving but mainly gives a wiggly version of the linear model Gulf Stream pathway and weak abyssal flows except for the deep western boundary current (DWBC) forced by ports in the model boundaries. All of the higher resolution simulations show major improvement over the linear and 1/8° nonlinear simulations. Additional major improvement is seen with the increase from 1/16° to 1/32° resolution and modest improvement with a further increase to 1/64°. The improvements include (1) realistic separation of the Gulf Stream from the coast at Cape Hatteras and a realistic Gulf Stream pathway between Cape Hatteras and the Grand Banks based on comparisons with Gulf Stream pathways from satellite IR and from GEOSAT and TOPEX/Poseidon altimetry (but 1/32° resolution was required for robust results), (2) realistic eastern and western nonlinear recirculation gyres (which contribute to the large-scale C-shape of the subtropical gyre) based on comparisons with mean surface dynamic height from the generalized digital environmental model (GDEM) oceanic climatology and from the pattern and amplitude of sea surface height (SSH) variability surrounding the eastern gyre as seen in TOPEX/Poseidon altimetry, (3) realistic upper ocean and DWBC transports based on several types of measurements, (4) patterns and amplitude of SSH variability which are generally realistic compared to TOPEX/Poseidon altimetry, but which vary from simulation to simulation for specific features and which are most realistic overall in the 1/64° simulation, (5) a basin wide explosion in the number and strength of mesoscale eddies (with warm core rings (WCRs) north of the Gulf Stream, the regional eddy features best observed by satellite IR), (6) realistic statistics for WCRs north of the Gulf Stream based on comparison to IR analyses (low at 1/16° resolution and most realistic at 1/64° resolution for mean population and rings generated/year; realistic ring diameters at all resolutions), and (7) realistic patterns and amplitude of abyssal eddy kinetic energy (EKE) in comparison to historical measurements from current meters.  相似文献   
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In studies of large-scale ocean dynamics, often quoted values of Sverdrup transport are computed using the Hellerman–Rosenstein wind stress climatology. The Sverdrup solution varies, however, depending on the wind set used. We examine the differences in the large-scale upper ocean response to different surface momentum forcing fields for the North Atlantic Ocean by comparing the different Sverdrup interior/Munk western boundary layer solutions produced by a 1/16° linear numerical ocean model forced by 11 different wind stress climatologies. Significant differences in the results underscore the importance of careful selection of a wind set for Sverdrup transport calculation and for driving nonlinear models. This high-resolution modeling approach to solving the linear wind-driven ocean circulation problem is a convenient way to discern details of the Sverdrup flow and Munk western boundary layers in areas of complicated geometry such as the Caribbean and Bahamas. In addition, the linear solutions from a large number of wind sets provide a well-understood baseline oceanic response to wind stress forcing and thus, (1) insight into the dynamics of observed circulation features, by themselves and in conjunction with nonlinear models, and (2) insight into nonlinear model sensitivity to the choice of wind-forcing product.The wind stress products are evaluated and insight into the linear dynamics of specific ocean features is obtained by examining wind stress curl patterns in relation to the corresponding high-resolution linear solutions in conjunction with observational knowledge of the ocean circulation. In the Sverdrup/Munk solutions, the Gulf Stream pathway consists of two branches. One separates from the coast at the observed separation point, but penetrates due east in an unrealistic manner. The other, which overshoots the separation point at Cape Hatteras and continues to flow northward along the continental boundary, is required to balance the Sverdrup interior transport. A similar depiction of the Gulf Stream is commonly seen in the mean flow of nonlinear, eddy-resolving basin-scale models of the North Atlantic Ocean. An O(1) change from linear dynamics is required for realistic simulation of the Gulf Stream pathway. Nine of the eleven Sverdrup solutions have a C-shaped subtropical gyre, similar to what is seen in dynamic height contours derived from observations. Three mechanisms are identified that can contribute to this pattern in the Sverdrup transport contours. Along 27°N, several wind sets drive realistic total western boundary current transport (within 10% of observed) when a 14 Sv global thermohaline contribution is added (COADS, ECMWF 10 m re-analysis and operational, Hellerman–Rosenstein and National Centers for Environmental Prediction (NCEP) surface stress re-analysis), a few drive transport that is substantially too high (ECMWF 1000 mb re-analysis and operational and Isemer–Hasse) and Fleet Numerical Meteorology and Oceanography Center (FNMOC) surface stresses give linear transport that is slightly weaker than observed. However, higher order dynamics are required to explain the partitioning of this transport between the Florida Straits and just east of the Bahamas (minimal in the linear solutions vs. 5 Sv observed east of the Bahamas). Part of the Azores Current transport is explained by Sverdrup dynamics. So are the basic path of the North Atlantic Current (NAC) and the circulation features within the Intra-Americas Sea (IAS), when a linear rendition of the northward upper ocean return flow of the global thermohaline circulation is added in the form of a Munk western boundary layer.  相似文献   
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As described by [Csanady, G.T., Hamilton, P., 1988. Circulation of slope water. Continental Shelf Research 8, 565–624], the flow regime over the slope of the southern Middle Atlantic Bight (MAB) includes a current reversal in which southwestward flow over the upper and middle slope becomes entrained in the northeastward current adjacent to the Gulf Stream. In this paper we use satellite-derived data to quantify how lateral motions of the Gulf Stream impact this current system. In our analysis, the Gulf Stream’s thermal front is delineated using a two-year time series of sea surface temperature derived from NOAA/AVHRR satellite data. Lateral motions of the Gulf Stream are represented in terms of temporal variations of the area, east of 73°W, between the Gulf Stream thermal front and the shelf edge. Variations of slope water flow within this area are represented by anomalies of geostrophic velocity as derived from the time series of the sea level anomaly determined from TOPEX/POSEIDON satellite altimeter data. A strong statistical relationship is found between Gulf Stream displacements and parabathic flow over the continental slope. It is such that the southwestward flow over the slope is accelerated when the Gulf Stream is relatively far from the shelf edge, and is decelerated (and perhaps even reversed) when the Gulf Stream is close to the shelf edge. This relationship between Gulf Stream displacements and parabathic flow is also observed in numerical simulations produced by the Miami Isopycnic Coordinate Model. In qualitative terms, it is consistent with the notion that when the Gulf Stream is closer to the 200-m isobath, it is capable of entraining a larger fraction of shelf water masses. Alternatively, when the Gulf Stream is far from the shelf-break, more water is advected into the MAB slope region from the northeast. Analysis of the diabathic flow indicates that much of the cross-slope transport by which the southwestward flow entering the study region is transferred to the northeastward flow exiting the region occurs in a narrow band roughly centered at 36.75°N, order 150 km north of Cape Hatteras. This transport, and thus the cyclonic circulation of the southern MAB, strengthens when the Gulf Stream is relatively close to the shelf edge, and weakens when the Gulf Stream is far from the shelf edge.  相似文献   
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