Geochemical processes controlling arsenic mobility in groundwater: A case study of arsenic mobilization and natural attenuation     

Y. Thomas He  Arthur G. Fitzmaurice  Azra Bilgin  Sunkyung Choi  Peggy O’Day  John Horst  James Harrington  H. James Reisinger  David R. Burris  Janet G. Hering 《Applied Geochemistry》2010

The behavior of As in the subsurface environment was examined along a transect of groundwater monitoring wells at a Superfund site, where enhanced reductive dechlorination (ERD) is being used for the remediation of groundwater contaminated with chlorinated solvents. The transect was installed parallel to the groundwater flow direction through the treatment area. The ERD technology involves the injection of organic C (OC) to stimulate in situ microbial dechlorination processes. A secondary effect of the ERD treatment at this site, however, is the mobilization of As, as well as Fe and Mn. The concentrations of these elements are low in groundwater collected upgradient of the ERD treatment area, indicating that, in the absence of the injected OC, the As that occurs naturally in the sediment is relatively immobile. Batch experiments conducted using sediments from the site inoculated with an Fe(III)- and As(V)-reducing bacterium and amended with lactate resulted in mobilization of As, Fe and Mn, suggesting that As mobilization in the field is due to microbial processes.  相似文献   

Mineralogy,petrology, chronology,and exposure history of the Chelyabinsk meteorite and parent body          下载免费PDF全文

K. Righter  P. Abell  D. Agresti  E. L. Berger  A. S. Burton  J. S. Delaney  M. D. Fries  E. K. Gibson  M. K. Haba  R. Harrington  G. F. Herzog  L. P. Keller  D. Locke  F. N. Lindsay  T. J. McCoy  R. V. Morris  K. Nagao  K. Nakamura‐Messenger  P. B. Niles  L. E. Nyquist  J. Park  Z. X. Peng  C.‐Y. Shih  J. I. Simon  C. C. Swisher III  M. J. Tappa  B. D. Turrin  R. A. Zeigler 《Meteoritics & planetary science》2015,50(10):1790-1819

Three masses of the Chelyabinsk meteorite have been studied with a wide range of analytical techniques to understand the mineralogical variation and thermal history of the Chelyabinsk parent body. The samples exhibit little to no postentry oxidation via Mössbauer and Raman spectroscopy indicating their fresh character, but despite the rapid collection and care of handling some low levels of terrestrial contamination did nonetheless result. Detailed studies show three distinct lithologies, indicative of a genomict breccia. A light‐colored lithology is LL5 material that has experienced thermal metamorphism and subsequent shock at levels near S4. The second lithology is a shock‐darkened LL5 material in which the darkening is caused by melt and metal‐troilite veins along grain boundaries. The third lithology is an impact melt breccia that formed at high temperatures (~1600 °C), and it experienced rapid cooling and degassing of S₂ gas. Portions of light and dark lithologies from Chel‐101, and the impact melt breccias (Chel‐102 and Chel‐103) were prepared and analyzed for Rb‐Sr, Sm‐Nd, and Ar‐Ar dating. When combined with results from other studies and chronometers, at least eight impact events (e.g., ~4.53 Ga, ~4.45 Ga, ~3.73 Ga, ~2.81 Ga, ~1.46 Ga, ~852 Ma, ~312 Ma, and ~27 Ma) are clearly identified for Chelyabinsk, indicating a complex history of impacts and heating events. Finally, noble gases yield young cosmic ray exposure ages, near 1 Ma. These young ages, together with the absence of measurable cosmogenic derived Sm and Cr, indicate that Chelyabinsk may have been derived from a recent breakup event on an NEO of LL chondrite composition.  相似文献   

3.8-μm photometry during the secondary eclipse of the extrasolar planet HD 209458b     

Drake Deming †  L. Jeremy Richardson  Joseph Harrington 《Monthly notices of the Royal Astronomical Society》2007,378(1):148-152

We report infrared photometry of the extrasolar planet HD 209458b during the time of secondary eclipse (planet passing behind the star). Observations were acquired during two secondary eclipses at the NASA Infrared Telescope Facility (IRTF) in 2003 September. We used a circular variable filter (1.5 per cent bandpass) centred at 3.8 μm to isolate the predicted flux peak of the planet at this wavelength. Residual telluric absorption and instrument variations were removed by offsetting the telescope to nearby bright comparison stars at a high temporal cadence. Our results give a secondary eclipse depth of 0.0013 ± 0.0011, not yet sufficient precision to detect the eclipse, whose expected depth is  ∼0.002 –0.003  . We here elucidate the current observational limitations to this technique, and discuss the approach needed to achieve detections of hot Jupiter secondary eclipses at 3.8 μm from the ground.  相似文献   

TritonX-100－5-Br-PADAP光度法测定铜和镍   总被引：2，自引：0，他引：2  

萨木嘎  刘颖  嘎日迪 《岩矿测试》1999,18(4):5

研究了非离子型表面活性剂Ｔｒｉｔｏｎ Ｘ－ １００ 存在下,用５ － Ｂｒ － ＰＡＤＡＰ 光度法测定铜、镍的方法。结果表明：在ｐＨ９ ．０ 的硼砂缓冲介质中,５ － Ｂｒ － ＰＡＤＡＰ 与铜和镍生成紫红色络合物,λＣｕｍ ａｘ ＝ ５７５ ｎｍ ,εＣｕ ＝ １ ．０４ ×１０５ Ｌ·ｍｏｌ－ １·ｃｍ － １ ;λＮｉｍ ａｘ ＝ ５７５ ｎｍ ,εＮｉ ＝ １ ．１４ ×１０５ Ｌ·ｍｏｌ－ １·ｃｍ － １ 。铜和镍的质量浓度分别在０ ～５６０ μｇ／ Ｌ和０ ～４４０ μｇ／ Ｌ符合比尔定律。加入六偏磷酸钠后,由于偏磷酸镍的形成,镍不再与５ － Ｂｒ － ＰＡＤＡＰ 显色,可通过铜及铜镍总量的测定,计算出镍的含量。用该方法实测了钢样中铜和镍的含量,结果与推荐值相符,对铜和镍５ 次测定的ＲＳＤ均小于５ ％ 。  相似文献   

Influence of Groundwater Hydraulic Gradient on Bank Storage Metrics          下载免费PDF全文

Chani Welch  Glenn A. Harrington  Peter G. Cook 《Ground water》2015,53(5):782-793

The hydraulic gradient between aquifers and rivers is one of the most variable properties in a river/aquifer system. Detailed process understanding of bank storage under hydraulic gradients is obtained from a two‐dimensional numerical model of a variably saturated aquifer slice perpendicular to a river. Exchange between the river and the aquifer occurs first at the interface with the unsaturated zone. The proportion of total water exchanged through the river bank compared to the river bed is a function of aquifer hydraulic conductivity, partial penetration, and hydraulic gradient. Total exchange may be estimated to within 50% using existing analytical solutions provided that unsaturated zone processes do not strongly influence exchange. Model‐calculated bank storage is at a maximum when no hydraulic gradient is present and increases as the hydraulic conductivity increases. However, in the presence of a hydraulic gradient, the largest exchange flux or distance of penetration does not necessarily correspond to the highest hydraulic conductivity, as high hydraulic conductivity increases the components of exchange both into and out of an aquifer. Flood wave characteristics do not influence ambient groundwater discharge, and so in large floods, hydraulic gradients must be high to reduce the volume of bank storage. Practical measurement of bank storage metrics is problematic due to the limitations of available measurement technologies and the nested processes of exchange that occur at the river‐aquifer interface. Proxies, such as time series concentration data in rivers and groundwater, require further development to be representative and quantitative.  相似文献   

IMPACT OF THE SOUTHERN OSCILLATION ON THE NORTH AMERICAN SOUTHWEST MONSOON     

John A. Harrington Jr.  Randall S. Cerveny  Robert C. Balling Jr. 《自然地理学》2013,34(4):318-330

The intensity and spatial variations in the North American Southwest Monsoon are examined to determine the influence of the Southern Oscillation. Sixty-five years (1920–1984) of July and August monthly precipitation data from Arizona and New Mexico are normalized using a square root transformation, converted into z-scores, and stratified according to onset and following years for Warm Events and Cold Events of the Southern Oscillation. The results for July reveal different spatial patterns in the monsoonal precipitation for the extremes of the Southern Oscillation. Warm-Event onset years are associated with positive precipitation anomalies that decline along a northeast-to-southwest gradient across the study area whereas the Cold-Event onset years produce highest positive values in west-central Arizona and negative values throughout the eastern two-thirds of the study area. Spatial patterns for the August precipitation data do not appear to be influenced by the extremes of the Southern Oscillation. [Key words: Southwest Monsoon, Southern Oscillation, Arizona, New Mexico.]  相似文献   

Stratigraphic and structural synthesis of the New England Orogen     

R. J. Korsch  H. J. Harrington 《Australian Journal of Earth Sciences》2013,60(1-2):205-226

The Spring Well volcanic complex in the Eastern Goldfields Province of Western Australia, is a relatively fresh and well exposed Archaean felsic volcanic centre that is preserved in a synclinal structure at the top of the local greenstone succession. Subaerial acid pyroclastic deposits and subordinate lava flows, intruded by anastomosing intermediate‐acid dykes and sills, comprise the near‐vent facies. In the distal regions of the centre, subaqueous crystal tuff and other tuff units are intercalated with epiclastic sediments.

Geochemical modelling indicates that the acid rocks are unlikely to have been derived by batch partial melting of probable crustal sources. However, differentiation from intermediate parents is compatible with the available geochemical data. The intermediate rocks, in turn, have critical geochemical characteristics comparable with all other studied intermediate calc‐alkaline rocks in the Yilgarn Block. Since it can be demonstrated that many of these rocks have an ultimate mantle source (through differentiation of LIL element enriched mafic primary magmas) it follows that such an origin is applicable in the Spring Well rocks. Therefore, it is concluded that the Spring Well volcanic complex represents a mantle‐derived, calc‐alkaline differentiation series, in which the more silicic members of the suite predominate. Apart from the diagnostic geochemical characteristics of these acid volcanic rocks, their spatial association with intermediate rocks distinguishes them from anatectic acid volcanic rocks that also occur in the greenstone sequences of the Yilgarn Block.  相似文献   

自适应转换波炮域偏移方法的研究与应用          下载免费PDF全文

李大卫  何艳  高宏亮  钟萍 《地球物理学进展》2009,24(6):2122-2127

抛开常规的转换点位置估计及极性校正,把检波点作为虚拟震源,利用单程波方程实现转换波记录的炮域偏移处理.由于该方法具有无需寻找转换点位置和进行极性校正的自适应特性,尤其适合于复杂构造转换波记录成像,并且在整个偏移处理流程中减少了估算转换点位置这一环节,有利于偏移精度的进一步提高,同时提高了运算效率.理论模型及实际资料的处理效果论证了该方法的正确性和有效性.  相似文献   

基于陆海统筹的海岸带空间功能分区——以宁波市为例     

安太天  高金柱  李晋  朱庆林  沈佳纹  丁健 《海洋通报》2022,(3):315-324

海岸带空间功能分区是优化海岸带开发与保护的基础性工作,在国土空间规划体系中具有重要作用。当前我国海陆功能分区在分区层级、分区方法等方面并不一致,导致海岸带保护与开发利用失衡。本文在梳理国内外海岸带空间功能分区研究的基础上,从陆海统筹角度出发,构建海岸带空间功能分区体系,并以宁波市为例进行验证,在优先划定生态保护区基础上,对海陆空间进行适宜性评价,根据评价结果确定功能分区。结果表明：（1）宁波市海岸带功能区中生态保护区面积占比约为60%,海陆一体发展区占比约为22.3%,海洋发展区占比约为12.5%,陆地发展区占比约为5.2%;(2)宁波市开发利用功能区空间分布与以临港产业、海洋服务业和海洋渔业为基础的海洋经济发展导向相符。海岸带空间功能分区要以生态保护为底线,以优化空间布局为导向,为优化海岸带开发与保护提供有力支撑。  相似文献   

Implications of the observed distributions of very long period comet orbits     

R.S. Harrington 《Icarus》1985,61(1):60-62

With allowance for galactic perturbations and observational error, the observed distributions of sizes an orientations of very long period comets are consistent with a uniform distribution of comets within the Oort Cloud.  相似文献