Synthesis and characterisation of a multifunctional oil-based drilling fluid additive     

Wu-Juan Sun  Guo-Qing Tian  Hang-Juan Huang  Guo-Min Lu  Cong-Yu Ke  Jun-Feng Hui  Xun-Li Zhang 《Environmental Earth Sciences》2018,77(24):793

An oil-based drilling fluid additive H-DEA (or humic acid-cocamide diethanolamine) was synthesised using humic acid and cocamide diethanolamine as raw materials. The rheological behaviors of H-DEA showed that the synthesised product has the good properties in both decreasing the filtrate loss and improving rheology property of oil-based drilling fluids compared with other commercially available additives. Under the optimal additive amount of 3%, both API filtrate loss and yield point changed remarkably from 5.40 to 0.41 mL and 9.0 to 25.6 Pa, respectively. Furthermore, differential scanning calorimetry (DSC) showed that H-DEA has good thermal stability in a wide temperature range up to 170 °C. Infrared spectroscopy (IR) and rheological analysis revealed that the possible mechanism of the multifunctional effects may be attributed to the existing of high density of strong polar groups, hydrogen bonds, electrostatic forces, and intermolecular association on H-DEA molecular structure. The results of the study showed that the synthesised H-DEA can be potentially used as a multifunctional oil-based drilling fluid additive in oil-drilling excavation.  相似文献   

Effects of vegetation restoration on soil physical properties of abandoned farmland on the Loess Plateau,China   总被引：1，自引：0，他引：1  

Jing Li  Zhanbin Li  Mengjing Guo  Peng Li  Shengdong Cheng  Bo Yuan 《Environmental Earth Sciences》2018,77(5):205

To improve the ecological environment in China, the Chinese government implemented a country-wide ecological protection and reforestation project (namely the “Grain for Green Project”) in 1999 to return cultivated land with slopes of 25° or more to perennial vegetation. Vegetation restoration reduces soil erosion mainly by changing the soil physical properties. Different vegetation restoration methods might produce different impacts on soil physical properties. In this study, two vegetation restoration methods (i.e., natural restoration and artificial restoration) were compared on abandoned farmland in the typically hilly and gullied areas of the Loess Plateau of Northwest China. In the natural restoration method, the farmland was abandoned to natural vegetation succession without irrigation, fertilization or other artificial disturbances. In the artificial restoration method, the farmland was planted with black locust (Robinia pseudoacacia L.) and watered and cultivated for the first two years. Three soil physical properties (i.e., soil moisture, bulk density and aggregation) were investigated under the two vegetation restoration methods. The results showed that the soil moisture and soil bulk density were higher under artificial restoration than under natural restoration within the first three years of vegetation restoration. By the fourth year, the soil moisture and soil bulk density were higher under natural restoration than under artificial restoration. For the stability of soil aggregates?>?0.25 mm, the soil aggregates in the 0-20 cm soil layer were more stable under artificial restoration than under natural restoration, while the results were the opposite for the 40-60 cm soil layer. Overall, the soil physical properties were continuously improved during the restoration of vegetation on abandoned farmland. In choosing between vegetation restoration methods, natural restoration is preferable to artificial restoration, but artificial intervention is needed during the first three years.  相似文献   

Laboratory investigations of inert gas flow behaviors in compact sandstone     

Chaojun Jia  Weiya Xu  Huanling Wang  Wei Wang  Jun Yu  Zhinan Lin 《Environmental Earth Sciences》2018,77(6):245

The seepage evolution behavior of compact rock is significant for the stability and safety of many engineering applications. In this research, both hydrostatic and triaxial compression tests were conducted on compact sandstone using an inert gas, namely argon. A triaxial compression test with a water permeability measurement was carried out to study the difference between the gas permeability and water permeability evolutions during the complete stress–strain process. Based on the experimental data, the hydrostatic stress-dependent gas permeability was discussed firstly. A second-order function was proposed to predict and explain the gas slippage effect. The mechanical properties and crack development of the sandstone samples were discussed to better understand the permeability evolution with crack growth during the complete stress–strain process. The results show that the gas permeability evolution can be divided into five stages according to the different crack growth stages. Then, the permeability changes in the crack closure stress \( \sigma_{\text{cc}} \), crack initiation stress \( \sigma_{\text{ci}} \), crack damage stress \( \sigma_{\text{cd}} \) and peak stress \( \sigma_{\text{p}} \) with confining pressures were analyzed. Finally, we found that the difference between the corrected gas permeability and water permeability can be attributed to the interaction between the water and sandstone grains.  相似文献   

Land use change assessment in coastal mangrove forests of Iran utilizing satellite imagery and CA–Markov algorithms to monitor and predict future change     

Hana Etemadi  Joseph M. Smoak  Jalal Karami 《Environmental Earth Sciences》2018,77(5):208

Mangrove forest stores large organic carbon stocks in a setting that is highly vulnerable to climate change and direct anthropogenic influences. As such there is a need to elucidate the causes and consequences of land use change on these ecosystems that have high value in terms of ecosystem services. We examine the areal pattern of land types in a coastal region located in southern Iran over a period of 14 years to predict future loss and gain in land types to the year 2025. We applied a CA–Markov model to simulate and predict mangrove forest change. Landsat satellite images from 2000 to 2014 were used to analyze the land cover changes between soil, open water and mangroves. Major changes during this period were observed in soil and water which could be attributed to rising sea level. Furthermore, the mangrove area in the more seaward position was converted to open water due to sea-level rise. A cellular automata model was then used to predict the land cover changes that would occur by the year 2025. Results demonstrated that approximately 21 ha of mangrove area will be converted to open water, while mangroves are projected to expand by approximately 28 ha in landward direction. These changes need to be delineated to better inform precise mitigation and adaptation measures.  相似文献   

Land use change modeling and the effect of compact city paradigms: integration of GIS-based cellular automata and weights-of-evidence techniques     

Saleh Abdullahi  Biswajeet Pradhan 《Environmental Earth Sciences》2018,77(6):251

In recent decades, attaining urban sustainability is the primary goal for urban planners and decision makers. Among various aspects of urban sustainability, environmental protection such as agricultural and forest conservations is very important in tropical countries like Malaysia. In this regard, compact urban development due to high density, rural development containment is known as the most sustainable urban forms. This paper attempts to propose an integrated modeling approach to predict the future land use changes by considering city compactness paradigms. First, the cellular automata (CA) were applied for calculating land use conversion. Next, weights-of-evidence (WoE) which is based on Bayes theory was utilized to calibrate CA model and to support the transitional rule assessment. Several urban-related parameters as well as compact city indicators were utilized to estimate the future land use maps. The results showed how compact development parameters and site characteristics can be combined using the WoE model to predict the probability of land use changes. The modeling approach supports the essential logic of probabilistic methods and indicates that spatial autocorrelation of various land use types and accessibility is the main drivers of urban land use changes.  相似文献   

Long-term seasonal rainfall forecasting: efficiency of linear modelling technique     

Iqbal Hossain  H. M. Rasel  Monzur Alam Imteaz  Fatemeh Mekanik 《Environmental Earth Sciences》2018,77(7):280

Using the lagged (past) climate indices, including El Nino–Southern Oscillation (ENSO) and Indian Ocean Dipole (IOD) as input parameters and long-term spring rainfall as outputs, calibration and validation of the linear multiple regression (MR) models have been performed. Since Australian rainfall varies both temporally and spatially, the analysis on the linear MR models was performed on regional scale. These models show the capability of linear MR technique for long-term predictions of Western Australian spring rainfall. The emphasis was given to assess the statistical correlations between Western Australian spring rainfall and dominating large-scale climate modes. The efficiency of linear modelling technique was evaluated to predict seasonal rainfall forecasting. At the same time, the Pearson correlation (R), mean absolute error, root-mean-square error and Willmott index agreement (d) were used to assess the capability of MR models. The models which fulfilled the limits of statistical significances were used for the prediction of future spring rainfall using independent data set. The results indicate that during calibration periods maximum achievable correlations varied from 0.47 to 0.53 for the selected stations. In regard to predict peaks and troughs of rainfall time series, it was found that correlations between predicted and actual peaks varied from 0.82 to 0.94 and between predicted and actual troughs varied from 0.53 to 0.91.  相似文献   

Traces of ancient geysers preserved in the travertine of Siwaqa,Jordan: conditions of their formation     

Ikhlas Alhejoj  Klaus Bandel  Elias Salameh  Khitam Alzughoul 《Environmental Earth Sciences》2018,77(7):281

A Pleistocene travertine quarrying on a hill in Siwaqa area, central Jordan, excavated solid, well-stratified travertine beds of about 12 m in thickness. The fabric and composition of the travertine indicate original deposition from hot spring water. At present, the area and its surrounding are devoid of any perennial water, except for periodic flood flows that collect at Siwaqa dam 4–5 km to the west of the quarry area, joining the catchment of the River Mujib. The travertine overlies combusted oil shale. The exposed hot spring travertine consists predominantly of well-bedded limestone, interrupted by horizons of chaotic angular debris, indicating ejection from below such as those produced by geysers. The article discusses the origins of the mottled and angular rock fragments, their transportation due to explosive geyser, the conditions and possible causes that produced the pressures leading to steam outbreaks and are responsible for the observed redistribution of travertine layers.  相似文献   

Water resource development and protection in loess areas of the world: a summary to the thematic issue of water in loess     

Peiyue Li  Hui Qian 《Environmental Earth Sciences》2018,77(24):796

Loess is mainly distributed in arid and semiarid areas of the world, and water is essential and precious in the loess areas. Water is also an important factor inducing various geohazards and soil erosion in the loess areas. The thematic issue of Environmental Earth Sciences was edited to reflect the latest research on water and water-related themes in the loess areas of the world, especially on the Chinese Loess Plateau. This editorial introduced the background and initiative of editing this thematic issue, and it also introduced briefly the water environment projects currently underway on the Chinese Loess Plateau such as the grain for green project, the huge land creation project, and the sponge city project. The papers included in the thematic issue were also introduced to give readers a general understanding of their main research points. Finally, some suggestions to boost further water environment research in the loess areas were put forward. All the papers included in the thematic issue will scientifically support the sustainable socio-economic development in the loess areas of the world.  相似文献   

Hydrogeochemical investigation of geothermal springs in Erzurum,East Anatolia (Turkey)     

Mine Alacali 《Environmental Earth Sciences》2018,77(24):802

Geothermal water sources located within The Erzurum province were identified and hot water samples were taken from four different geothermal areas. The results of in situ and hydrogeochemical analyses of these hot water samples were interpreted and the properties of hot water, water–rock associations, estimated reservoir temperature and hot water usage areas were determined. The temperatures of the samples collected from the study area vary between 26.2 and 57.7 °C, while pH values change from 6.09 to 7.33, EC values obtained from in situ measurements are between 1829 and 9480 µS/cm and Eh values are (??190) to (26.3) mV. Total dissolved solids of the hot waters have a range from 838.7 to 3914.1 mg/l. The maximum estimated reservoir temperature is calculated as 250 °C by applying chemical geothermometers. However, considering the actual temperatures of Pasinler, Köprüköy, Horasan and Il?ca thermal waters and wells, the most reliable temperature range depending on the applied geothermometers’ results indicate minimum and maximum reservoir temperatures 85–158.9 °C, respectively, taking in account the errors. According to the isotope analysis, the waters circulating within the geothermal system are of meteoric origin and modern waters. In addition, two samples taken from clayey levels observed in the field were analyzed and the mineralogy of the clays was evaluated.  相似文献   

Quantifying land use influences on event-based flow frequency,timing, magnitude,and rate of change in an urbanizing watershed of the central USA     

Sean J. Zeiger  Jason A. Hubbart 《Environmental Earth Sciences》2018,77(3):107

There is a need for research that advances understanding of flow alterations in contemporary watersheds where natural and anthropogenic interactions can confound mitigation efforts. Event-based flow frequency, timing, magnitude, and rate of change were quantified at five-site nested gauging sites in a representative mixed-land-use watershed of the central USA. Statistically independent storms were paired by site (n = 111 × 5 sites) to test for significant differences in event-based rainfall and flow response variables (n = 17) between gauging sites. Increased frequency of small peak flow events (i.e., 64 more events less than 4.0 m³ s^?1) was observed at the rural–urban interface of the watershed. Differences in flow response were apparent during drier periods when small rainfall events resulted in increased flow response at urban sites in the lower reaches. Relationships between rainfall and peak flow were stronger with decreased pasture/crop land use and increased urban land use by approximately 20%. Event-based total rainfall explained 40–68% of the variance in peak flow (p < 0.001). Coefficients of determination (r²) were negatively correlated with pasture/crop land use (r² = 0.92; p = 0.007; n = 5) and positively correlated with urban land use (r² = 0.90; p = 0.008; n = 5). Significant differences in flow metrics were observed between rural and urban sites (p < 0.05; n = 111) that were not explained by differences in rainfall variables and drainage area. An urban influence on flow timing was observed using median time lag to peak centroid and time of maximum precipitation to peak flow. Results highlight the need to establish manageable flow targets in rapidly urbanizing mixed-land-use watersheds.  相似文献