Synthesis of highly dense and fine-grained aggregates of mantle composites by vacuum sintering of nano-sized mineral powders     

Sanae Koizumi  Takehiko Hiraga  Chihiro Tachibana  Miki Tasaka  Tomonori Miyazaki  Tamio Kobayashi  Asako Takamasa  Naoki Ohashi  Satoru Sano 《Physics and Chemistry of Minerals》2010,37(8):505-518

Synthesized mineral powders with particle size of <100 nm are vacuum sintered to obtain highly dense and fine-grained polycrystalline mantle composites: single phase aggregates of forsterite (iron-free), olivine (iron containing), enstatite and diopside; two-phase composites of forsterite + spinel and forsterite + periclase; and, three-phase composites of forsterite + enstatite + diopside. Nano-sized powders of colloidal SiO₂ and highly dispersed Mg(OH)₂ with particle size of ≤50 nm are used as chemical sources for MgO and SiO₂, which are common components for all of the aggregates. These powders are mixed with powders of CaCO₃, MgAl₂O_4, and Fe(CO₂CH₃)₂ to introduce mineral phases of diopside, spinel, and olivine to the aggregates, respectively. To synthesize highly dense composites through pressureless sintering, we find that calcined powders should be composed of particles that have: (1) fully or partially reacted to the desired minerals, (2) a size of <100 nm and (3) less propensity to coalesce. Such calcined powders are cold isostatically pressed and then vacuum sintered. The temperature and duration of the sintering process are tuned to achieve a balance between high density and fine grain size. Highly dense (i.e., porosity ≤1 vol%) polycrystalline mantle mineral composites with grain size of 0.3–1.1 μm are successfully synthesized with this method.  相似文献   

High-resolution observations of dissolved isoprene in surface seawater in the Southern Ocean during austral summer 2010–2011     

Sohiko Kameyama  Satoshi Yoshida  Hiroshi Tanimoto  Satoshi Inomata  Koji Suzuki  Hisayuki Yoshikawa-Inoue 《Journal of Oceanography》2014,70(3):225-239

We measured dissolved isoprene (2-methyl-1,3-butadiene; C₅H₈) concentrations in a broad area of the southern Indian Ocean and in the Indian sector of the Southern Ocean from 35°S to 64°S and from 37°E to 111°E during austral summer 2010–2011. Isoprene concentrations were continuously measured by use of a proton-transfer-reaction mass spectrometer combined with a bubbling-type equilibrator. Concentrations of isoprene and its emission flux throughout the study period ranged from 0.2 to 395 pmol L^?1 and from 181 to 313 nmol m^?2 day^?1, respectively, the averages being generally higher than those of previous studies. Although we found a significant linear positive relationship between isoprene and chlorophyll-a concentrations (r ² = 0.37, n = 36, P < 0.001), the correlation coefficient was lower than previously reported. In contrast, in the high-latitude area (>53°S) we identified a significant negative correlation (r ² = 0.59, n = 1263, P < 0.001) between isoprene and the temperature-normalized partial pressure of carbon dioxide (n-pCO₂), used as an indicator of net community production in this study. This suggests that residence times and factors controlling variations in isoprene and n-pCO₂ are similar within a physically stable water column.  相似文献   

Impact of tropical and subtropical SSTs on mid-latitude tropospheric warming in the northern summer of 2010     

Chiaki Kobayashi 《Climate Dynamics》2014,43(7-8):1871-1882

The relationship between mid-latitude tropospheric warming (MLTW) and the tropical sea surface temperatures (SSTs) in June–August (JJA) of 2010 has been investigated using an atmospheric general circulation model forced with the evolving observed SSTs. The simulation results indicate that the SST anomalies (SSTAs) in the equatorial Pacific in JJA 2010, indicating La Niña condition, did not contribute simultaneously to produce the MLTW in JJA 2010, and, instead, the SSTAs in the northern subtropics (the whole latitudinal band between 10°N and 30°N) contributed. However, it is shown by the results that enough magnitude of the atmospheric height anomalies over the northern mid-latitude was not reproduced by the SSTAs over the northern subtropical Indo-western Pacific (IWP) alone or over the northern subtropical Atlantic alone. It implies that both the SSTA over the northern subtropics of IWP and Atlantic were necessary to reproduce the MLTW. The possible role of convective activity for the MLTW is also discussed.  相似文献   

Large-Eddy Simulation of Pollutant Removal from a Three-Dimensional Street Canyon   总被引：3，自引：3，他引：0  

Takenobu Michioka  Hiroshi Takimoto  Ayumu Sato 《Boundary-Layer Meteorology》2014,150(2):259-275

Large-eddy simulations were conducted to investigate the mechanism of pollutant removal from a three-dimensional street canyon. Five block configurations with aspect ratios (building height to length) of 1, 2, 4, 8 and $\infty $ were used to create an urban-like array. A pollutant was released from a ground-level line source at the centre of the target canyon floor. For smaller aspect ratios, the relative contribution of the turbulent mass flux to net mass flux at the roof level, which was spatially averaged along the roof-level ventilation area, was closer to unity, indicating that turbulent motions mainly affected pollutant removal from the top of the canyon. As aspect ratio increased, the relative contribution became smaller, owing to strong upwind motions. However, the relative contribution again reached near unity for the infinite aspect ratio (i.e. a two-dimensional street canyon) because of lowered lateral flow convergence. At least 75 % of total emissions from the three-dimensional street canyon were attributable to turbulent motions. Pollutant removal by turbulent motions was related to the coherent structures of low-momentum fluid above the canyons. Though the coherent structure size of the low-momentum fluid differed, the positions of low-momentum fluid largely corresponded to instantaneous high concentrations of pollutant above the target canyon, irrespective of canyon geometry.  相似文献   

Solid‐state 13C NMR characterization of insoluble organic matter from Antarctic CM2 chondrites: Evaluation of the meteoritic alteration level     

Hikaru YABUTA  Hiroshi NARAOKA  Kinya SAKANISHI  Hiroyuki KAWASHIMA 《Meteoritics & planetary science》2005,40(5):779-787

Abstract— Chemical structures of the insoluble organic matter (IOM) from the Antarctic CM2 chondrites (Yamato [Y‐] 791198, 793321; Belgica [B‐] 7904; Asuka [A‐] 881280, 881334) and the Murchison meteorite were analyzed by solid‐state ¹³C nuclear magnetic resonance (NMR) spectroscopy. Different types of carbons were characterized, such as aliphatic carbon (Ali‐C), aliphatic carbon linked to hetero atom (Hetero‐Ali‐C), aromatic carbon (Aro‐C), carboxyls (COOR), and carbonyls (C=O). The spectra of the IOM from Murchison and Y‐791198 showed two major peaks: Ali‐C and Aro‐C, while the spectra from the other meteorites showed only one major peak of Aro‐C. Carbon distribution was determined both by manual integration and deconvolution. For most IOM, the Aro‐C was the most abundant (49.8–67.8%) of all carbon types. When the ratios of Ali‐C to Aro‐C (Ali/Aro) were plotted with the atomic hydrogen to carbon ratio (H/C), a correlation was observed. If we use the H/C as a parameter for the thermal alteration event on the meteorite parent body, this result shows a different extent of thermal alteration. In addition, IOM with a lower Ali/Aro showed a lower ratio of Ali‐C to COOR plus C=O (Ali / (COOR + C=O)). This result suggests that the ratio of CO moieties to aliphatic carbon in IOM might reflect chemical oxidation that was involved in hydrothermal alteration.  相似文献   

Textural variations and impact history of the Millbillillie eucrite     

Akira Yamaguchi  Hiroshi Takeda  Donald D. Bogard  Daniel Garrison 《Meteoritics & planetary science》1994,29(2):237-245

Abstract— We have investigated 10 new specimens of the Millbillillie eucrite to study its textures and mineral compositions by electron probe microanalyser and scanning electron microscope. Although originally described as having fine-grained texture, the new specimens show diversity of texture. The compositions (Mg/Fe ratios) of the host pigeonites and augite lamellae are homogeneous, respectively, in spite of the textural variation. In addition to their chemical homogeneity, pyroxenes in coarse and fine-grained clasts are partly inverted to orthopyroxene. Chemical zoning of plagioclase during crystal growth is preserved. This eucrite includes areas of granulitic breccias and impact melts. Large scale textures show a subparallel layering suggesting incomplete mixing and deposition of impact melt and lithic fragments. An ³⁹Ar-⁴⁰Ar age determination for a coarse-grained clast indicates a strong degassing event at 3.55 ± 0.02 Ga. We conclude that Millbillillie is among the most equilibrated eucrites produced by thermal annealing after impact brecciation. According to the classification of impact breccias, Millbillillie can be classified as a mixture of granulitic breccias and impact melts. The last significant thermal event is characterized by network-like glassy veins that run through clasts and matrices. Consideration of textural observations and requirements for Ar-degassing suggests that the ³⁹Ar-⁴⁰Ar age could in principle date either the earilier brecciation and annealing event or the event which produced the veins.  相似文献   

Laboratory Enrichment of Radioactive Assemblages and Estimation of Thorium and Uranium Radioactivity in Fractions Separated from Placer Sands in Southeast Bangladesh     

Takayuki Sasaki  Mohammad Rajib  Masafumi Akiyoshi  Taishi Kobayashi  Ikuji Takagi  Toshiyuki Fujii  Md. Mashrur Zaman 《Natural Resources Research》2015,24(2):209-220

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The High-Resolution Coronal Imager (Hi-C)     

Ken Kobayashi  Jonathan Cirtain  Amy R. Winebarger  Kelly Korreck  Leon Golub  Robert W. Walsh  Bart De Pontieu  Craig DeForest  Alan Title  Sergey Kuzin  Sabrina Savage  Dyana Beabout  Brent Beabout  William Podgorski  David Caldwell  Kenneth McCracken  Mark Ordway  Henry Bergner  Richard Gates  Sean McKillop  Peter Cheimets  Simon Platt  Nick Mitchell  David Windt 《Solar physics》2014,289(11):4393-4412

The High-Resolution Coronal Imager (Hi-C) was flown on a NASA sounding rocket on 11 July 2012. The goal of the Hi-C mission was to obtain high-resolution (≈?0.3?–?0.4′′), high-cadence (≈?5 seconds) images of a solar active region to investigate the dynamics of solar coronal structures at small spatial scales. The instrument consists of a normal-incidence telescope with the optics coated with multilayers to reflect a narrow wavelength range around 19.3 nm (including the Fe xii 19.5-nm spectral line) and a 4096×4096 camera with a plate scale of 0.1′′?pixel^?1. The target of the Hi-C rocket flight was Active Region 11520. Hi-C obtained 37 full-frame images and 86 partial-frame images during the rocket flight. Analysis of the Hi-C data indicates the corona is structured on scales smaller than currently resolved by existing satellite missions.  相似文献   

Infrared polarimetry of the stars in the inner galaxy     

Y. Kobayashi  J. Jugaku  H. Okuda  S. Sato  T. Nagata 《Astrophysics and Space Science》1986,119(1):135-139

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A study of Mg and K isotopes in Allende CAIs: Implications to the time scale for the multiple heating processes     

Motoo Ito  Hiroshi Nagasawa  Hisayoshi Yurimoto 《Meteoritics & planetary science》2006,41(12):1871-1881

Abstract— The measurements of magnesium and potassium isotopic compositions of refractory minerals in Allende calcium‐aluminum‐rich inclusions (CAIs), 7R‐19–1, HN3–1, and EGG3 were taken by secondary ion mass spectrometry (SIMS). The 7R‐19–1 contains ¹⁶O‐rich and ¹⁶O‐poor melilite grains and define a single isochron corresponding to an initial ²⁶Al/²⁷Al ratio of (6.6 ± 1.3) × 10^?5. The Al‐Mg isochron, O isotope measurements and petrography of melilite in 7R‐19–1 indicate that ¹⁶O‐poor melilite crystallized within 0.4 Myr after crystallization of ¹⁶O‐rich melilite, suggesting that oxygen isotopic composition of the CAI‐forming region changed from ¹⁶O‐rich to ¹⁶O‐poor within this time interval. The ¹⁶O‐poor melilite is highly depleted in K compared to the adjacent ¹⁶O‐rich melilite, indicating evaporation during remelting of 7R‐19–1. We determined the isochron for ⁴¹Ca‐⁴¹K isotopic systematics in EGG3 pyroxene with (4.1 ± 2.0) × 10^?9 (2s?) as an initial ratio of ⁴¹Ca/⁴⁰Ca, which is at least two times smaller than the previous result (Sahijipal et al. 2000). The ratio of ⁴¹Ca/⁴⁰Ca in the EGG3 pyroxene grain agrees within error with the value obtained by Hutcheon et al. (1984). No evidence for the presence of ⁴¹K excess (decay product of a short‐lived radionuclide ⁴¹Ca) was found in 7R‐19–1 and HN3–1. We infer that the CAI had at least an order of magnitude lower than canonical ⁴¹Ca/⁴⁰Ca ratio at the time of the CAI formation.  相似文献