Trace element in igneous petrology | C.J. Allègre and S.R. Hart (Editors), 1978. A Volume in Memory of Paul W. Gast. Developments in Petrology, 5. Elsevier,Amsterdam, 272 pp., Dfl. 121.00, $ 49.95     

Hiroshi Nagasawa 《Earth》1979,15(1):79-80

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Resonance capacity method for earthquake response analysis of hysteretic structures     

Minoru Yamada  Hiroshi Kawamura 《地震工程与结构动力学》1980,8(4):299-313

The Resonance Capacity Method is proposed for the earthquake response analysis of hysteretic structures. Resonance Capacity is a physical quantity of structures which is related to the hysteretic energy absorbed by structures in one cycle and is equated to the acceleration, velocity and displacement amplitudes α₀, d₀ and d₀ of earthquake ground motions at resonance.¹ According to the idealized trapezoidal approximation of earthquake ground motions in the logarithmic period–velocity plane as proposed by Veletsos and Newmark,⁸ the Resonance Capacity property applies in each period range, short, medium and long, where α₀, v₀ and d₀ respectively are approximately constant. In the medium range of periods, the energy dissipated in hysteretic loops and the deformation amplitudes of a single-degree system with elasto–plastic force–deformation relationships are calculated for the case of El Centro 1940, 18 May earthquake, by this Resonance Capacity Method. The result is compared with results from conventional numerical response analyses obtained by Berg and Thomaides,¹⁴ Kato and Akiyama¹² and Veletsos and Newmark,⁸ and the general agreement is seen to be good. Therefore, it may be possible to apply this Resonance Capacity Method over the entire range of periods. By means of this method the earthquake response analysis of hysteretic systems can be performed easily, and the hysteretic energy and fatigue characteristics of structures may be taken into account directly, up to the point of fracture.  相似文献   

Fast Oxidation Reaction of Nitrite by Dissolved Oxygen in the Freezing Process in the Tropospheric Aqueous Phase     

Norimichi Takenaka  Tohru Daimon  Akihiro Ueda  Keiichi Sato  Masaru Kitano  Hiroshi Bandow  Yasuaki Maeda 《Journal of Atmospheric Chemistry》1998,29(2):135-150

Nitrite oxidation in the tropospheric aqueous phase by freezing was evaluated by freezing a field sample. Nitrite oxidation by dissolved oxygen in the freezing process is much faster than by other oxidation processes, such as reactions with ozone, hydrogen peroxide or dissolved oxygen in an aqueous solution at pHs 3 to –6. At pH 4.5 and 25°C, the lifetime of nitrite in the aqueous phase is ca. 1 hr in oxidation by ozone (6×10^-10 mol dm^-3), ca. 10 hr in oxidation by H₂O₂ (2×10^-4 mol dm^-3), and 7.5 hr (Fischer and Warneck, 1996) in photodissociation at midday in summer. Under the same conditions at a temperature below 0°C, the lifetime of nitrite in the freezing process is estimated as ca. 2 sec when the droplets are frozen within a second. The reaction by freezing is affected by the presence of salts, such as NaCl or KCl, or orgnaic compounds, such as methanol or acetone. The results of freezing a field rain or fog sample showed that nitrite oxidation proceeds below pH 6, and the conversion ratio of nitrate from nitrite increases with decreasing pH. The oxidation of nitrite by freezing was also observed in freezing fog particles generated by an ultrasonic humidifier. The ratios of the concentrations of ions in the winter sample to those in the summer sample (or those in the fog sample) were almost the same values. However, the concentration of nitrite in the winter sample was lower than that estimated by the ratios of other ions. From the present study, it seems that the freezing process plays an important role in the nitrite sink process in the tropospheric aqueous phase.  相似文献   

Trace element distribution in mineral separates of the Allende inclusions and their genetic implications     

Hiroshi Nagasawa  Douglas P Blanchard  Jeffrey W Jacobs  Joyce C Brannon  John A Philpotts  Naoki Onuma 《Geochimica et cosmochimica acta》1977,41(11):1587-1600

Concentrations of the REE, Sc, Co, Fe, Zn, Ir, Na and Cr were determined by instrumental neutron activation and mass spectrometric isotope dilution analysis for mineral separates of the coarseand fine-grained types (group I and II of Martin and Mason's classification) of the Allende inclusions.These data, combined with data on mineral/liquid partition coefficients, oxygen isotope distributions and diffusion calculations, suggest the following: (1) Minerals in the coarse-grained inclusions (group I) crystallized in a closed system with respect to refractory elements. On the other hand, differences in oxygen isotope distributions among minerals preclude a totally molten stage in the history of the inclusion. Group I inclusions were formed by rapid condensation (either to liquid or solid) in a supercooled solar nebula; extrasolar pyroxene and spinel dust were included but not melted in the condensing inclusions, thus preserving their extrasolar oxygen isotope composition. REE were distributed by diffusion during the subsequent heating at subsolidus temperatures; because oxygen diffuses much more slowly at these temperatures, the oxygen isotope anomalies were preserved. (2) The fine-grained (group II) inclusions were also formed by condensation from a super-cooled nebular gas; however, REE-rich clinopyroxene and spinel were formed early and REE-poor sodalite and nepheline were formed later and mechanically mixed with clinopyroxene and spinel to form the inclusions. The REE patterns of the bulk inclusions and the mineral separates are fractionated, indicating that REE abundances in the gaseous phase were already fractionated at the time of condensation of the minerals. (3) Pre-existing Mg isotope anomalies in the coarse-grained inclusions must have been erased during the heating stage thus resetting the ²⁶Al-²⁶Mg chronometer.  相似文献   

ESR diagram: a method to distinguish vitrinite macerals     

Hiroshi Morishima  Hideki Matsubayashi 《Geochimica et cosmochimica acta》1978,42(5):537-540

It has been found that samples consisting of a homogeneous vitrinite show a good ESR correlation of spin concentration with geothermal parameters and that a graph of ESR line width vs g-value can be useful in the identification of the maceral and the determination of the coalification rank.  相似文献   

The theory of the nutation for the rigid earth model at the second order   总被引：6，自引：0，他引：6  

Hiroshi Kinoshita  Jean Souchay 《Celestial Mechanics and Dynamical Astronomy》1990,48(3):187-265

We perform a complete reconstruction of the series of the nutation for a rigid Earth model with the use of the very accurate theories ELP2000 and VSOP82 for the motion of the Moon and the planets respectively, in such a way that all the individual contributions up to 0.005 mas should be taken. This implies the introduction of the planetary effects, of the influence of second-order parts of the potential of the Earth (J3, triaxiality), and some improvements due to an extension of the theory at the second order. All this increase notably the number of coefficients to be taken in account, and modifies also in a significant way the value of some of them.  相似文献   

Lithospheric drift on early Mars: Evidence in the magnetic field     

Daisuke Kobayashi 《Icarus》2010,210(1):37-42

The crustal magnetic anomalies on Mars may represent hot spot tracks resulting from lithospheric drift on ancient Mars. As evidence, an analysis of lineation patterns derived from the ΔBr magnetic map is presented. The ΔBr map, largely free of external magnetic field effects, allows excellent detail of the magnetic anomaly pattern, particularly in areas of Mars where the field is relatively weak. Using cluster analysis, we show that the elongated anomalies in the martian magnetic field form concentric small circles (parallels of latitude) about two distinct north pole locations. If these pole locations represent ancient spin axes, then tidal force on the early lithosphere by former satellites in retrograde orbits may have pulled the lithosphere in an east-west direction over hot mantle plumes. With an active martian core dynamo, this may have resulted in the observed magnetic anomaly pattern of concentric small circles. As further evidence, we observe that, of the 15 martian giant impact basins that were possibly formed while the core dynamo was active, seven lie along the equators of our two proposed paleopoles. We also find that four other re-magnetized giant impact basins lie along a great circle about the mean magnetic paleopole of Mars. These 11 impact basins, likely the result of fallen retrograde satellite fragments, indicate that Mars once had moons large enough to cause tidal drag on the early martian lithosphere. The results of this study suggest that the magnetic signatures of this tidal interaction have been preserved to the present day.  相似文献   

From an initial transient-state to a steady-state in metamorphic reactions: An experimental approach in the system dolomite-quartz-H₂O     

Tadao  Nishiyama  Aiko  Tominaga  Hiroshi  Isobe 《Island Arc》2007,16(1):16-27

Abstract We carried out hydrothermal experiments in the system dolomite‐quartz‐H₂O to track the temporal change in reaction rates of simultaneous reactions during the development of reaction zones. Two types of configurations for the starting materials were prepared: dolomite single crystals + quartz powder + water and quartz single crystals + dolomite powder + water, both sealed separately in gold capsules. Runs at 0.1GPa and 600°C with cold seal pressure vessels gave the following results. (i) In short duration (45–71 h) runs metastable layer sequences involving wollastonite and talc occur in the reaction zone, whereas they disappear in longer duration (168–336 h) runs. (ii) The layer sequence of the reaction zones in short duration runs differs from place to place on the dolomite crystal even in the same run. (iii) The diversity of layer sequences in the short duration runs merges into a unique layer sequence in the longer duration runs. (iv) The reaction zone develops locally on the dolomite crystal, but no reaction zone was observed on the quartz crystal in any of the runs. The lines of evidence (i)–(iii) show that the system evolves from an initial transient‐ to a steady‐state and that the kinetic effect is important in the development of reaction zones. A steady diffusion model for the unique layer sequence Qtz/Di/Fo + Cal/Dol + Cal/Dol shows that the Dol + Cal layer cannot be formed by diffusion‐controlled process and that the stability of the layer sequence Qtz/Di/Fo + Cal/Dol depends not only on L‐ratios (a = /L_CaOCaO and b = /L_MgOMgO) but also on the relative rate P = (−2ξ₁ − ξ₂)/(–ξ₁ − 2ξ₂) of competing reactions: Dol + 2Qtz = Di + 2CO₂ (ξ₁) and 2Dol + Qtz = Fo + 2Cal + 2CO₂ (ξ₂). For smaller P the stability field will shift to higher values of a and b. The steady diffusion model also shows that the apparent‐non‐reactivity on the quartz surface can be attributed to void formation in a large volume fraction in the diopside layer.  相似文献   

Synthesis of highly dense and fine-grained aggregates of mantle composites by vacuum sintering of nano-sized mineral powders     

Sanae Koizumi  Takehiko Hiraga  Chihiro Tachibana  Miki Tasaka  Tomonori Miyazaki  Tamio Kobayashi  Asako Takamasa  Naoki Ohashi  Satoru Sano 《Physics and Chemistry of Minerals》2010,37(8):505-518

Synthesized mineral powders with particle size of <100 nm are vacuum sintered to obtain highly dense and fine-grained polycrystalline mantle composites: single phase aggregates of forsterite (iron-free), olivine (iron containing), enstatite and diopside; two-phase composites of forsterite + spinel and forsterite + periclase; and, three-phase composites of forsterite + enstatite + diopside. Nano-sized powders of colloidal SiO₂ and highly dispersed Mg(OH)₂ with particle size of ≤50 nm are used as chemical sources for MgO and SiO₂, which are common components for all of the aggregates. These powders are mixed with powders of CaCO₃, MgAl₂O_4, and Fe(CO₂CH₃)₂ to introduce mineral phases of diopside, spinel, and olivine to the aggregates, respectively. To synthesize highly dense composites through pressureless sintering, we find that calcined powders should be composed of particles that have: (1) fully or partially reacted to the desired minerals, (2) a size of <100 nm and (3) less propensity to coalesce. Such calcined powders are cold isostatically pressed and then vacuum sintered. The temperature and duration of the sintering process are tuned to achieve a balance between high density and fine grain size. Highly dense (i.e., porosity ≤1 vol%) polycrystalline mantle mineral composites with grain size of 0.3–1.1 μm are successfully synthesized with this method.  相似文献   

High-resolution observations of dissolved isoprene in surface seawater in the Southern Ocean during austral summer 2010–2011     

Sohiko Kameyama  Satoshi Yoshida  Hiroshi Tanimoto  Satoshi Inomata  Koji Suzuki  Hisayuki Yoshikawa-Inoue 《Journal of Oceanography》2014,70(3):225-239

We measured dissolved isoprene (2-methyl-1,3-butadiene; C₅H₈) concentrations in a broad area of the southern Indian Ocean and in the Indian sector of the Southern Ocean from 35°S to 64°S and from 37°E to 111°E during austral summer 2010–2011. Isoprene concentrations were continuously measured by use of a proton-transfer-reaction mass spectrometer combined with a bubbling-type equilibrator. Concentrations of isoprene and its emission flux throughout the study period ranged from 0.2 to 395 pmol L^?1 and from 181 to 313 nmol m^?2 day^?1, respectively, the averages being generally higher than those of previous studies. Although we found a significant linear positive relationship between isoprene and chlorophyll-a concentrations (r ² = 0.37, n = 36, P < 0.001), the correlation coefficient was lower than previously reported. In contrast, in the high-latitude area (>53°S) we identified a significant negative correlation (r ² = 0.59, n = 1263, P < 0.001) between isoprene and the temperature-normalized partial pressure of carbon dioxide (n-pCO₂), used as an indicator of net community production in this study. This suggests that residence times and factors controlling variations in isoprene and n-pCO₂ are similar within a physically stable water column.  相似文献