Methane-dominated thermochemical sulphate reduction in the Triassic Feixianguan Formation East Sichuan Basin, China: towards prediction of fatal H₂S concentrations   总被引：2，自引：0，他引：2  

Chunfang Cai  Zengye Xie  Richard H. Worden  Guoyi Hu  Lansheng Wang  Hong He 《Marine and Petroleum Geology》2004,21(10):1265-1279

New sour pools have recently found in the Lower Triassic Feixianguan Fm carbonate reservoirs in the East Sichuan Basin in China with H₂S up to 17.4% by volume. A recent blowout from a well drilled into this formation killed hundreds of people as a result of the percentage concentrations of H₂S. In order to assess the origin of fatal H₂S as well as the cause of petroleum alteration, H₂S concentrations and the isotopes, δ³⁴S and δ¹³C have been collected and measured in gas samples from reservoirs. Anhydrite, pyrite and elemental sulphur δ³⁴S values have been measured for comparison. The high concentrations of H₂S gas are found to occur at depths >3000 m (temperature now at 100 °C) in evaporated platform facies oolitic dolomite or limestone that contains anhydrite nodule occurrence within the reservoirs. Where H₂S concentrations are greater than 10% its δ³⁴S values lie between +12.0 and +13.2‰ CDT. This is within the range of anhydrite δ³⁴S values found within the Feixianguan Fm (+11.0 to +21.7‰; average 15.5±3.5‰ CDT). Thus H₂S must have been generated by thermochemical sulphate reduction (TSR) locally within the reservoirs. Burial history analysis and fluid inclusion data reveal that the temperature at which TSR occurred was greater than about 130–140 °C, suggesting that the present depth-temperature minimum is an artifact of post-TSR uplift. Both methane and ethane were actively involved in TSR since the petroleum became almost totally dry (no alkanes except methane) and methane δ¹³C values become significantly heavier as TSR proceeded. Methane δ¹³C difference thus reflects the extent of TSR. While it is tempting to use a present-day depth control (>3000 m) to predict the distribution of H₂S in the Feixianguan Fm, this is an invalid approach since TSR occurred when the formation was buried some 1000–2000 m deeper than it is at present. The likelihood of differential uplift across the basin means that it is important to develop a basinal understanding of the thermal history of the Feixianguan Fm so that it is possible to determine which parts of the basin have been hotter than 130–140 °C.  相似文献   

虾蟹海产品香味的前体物质的加热变化     

薛长湖  汪贻生  林洪  楼伟凤 《中国海洋大学学报(自然科学版)》1994,(4)

本文研究了虾蟹海产品香味的前体物质在加热前后的变化。实验结果表明：对虾和蟹肌肉中的糖原和不饱和脂肪酸在加热前后含量下降，糖原是Ｍａｉｌｌａｒｄ反应的基础物质．不饱和脂肪酸是虾蟹肌肉香味中羰基化合物的前体物质。虾蟹肌肉中主要积累的核苷酸成分ＡＭＰ在加热后减少，而肌肉提取物中的游离氨基酸和结合氨基酸，特别是疏水氨基酸含量均增加。  相似文献   

可编程序控制器的多机联用     

洪忠渝 《中国海洋大学学报(自然科学版)》1992,(3)

多台可编程序控制器通过输入、输出点的直接连接,传递命令、状态和数据,实现多机联用系统。  相似文献   

环胶州湾公路海上段汽车尾气的环境影响     

杨三才  徐静琦  竺维丽  洪光  吴玉坤 《中国海洋大学学报(自然科学版)》1993,(1)

对类比路段进行连续模拟试验,进行现场调查,给出汽车尾气主要污染物的排污强度,预测了汽车尾气中CO、C_nH_m和NO_x的扩散范围。  相似文献   

Refraction-Diffraction Mathematical Model for Waves With Lateral Energy Transmission Mechanism and Its Verification     

Xu Shikai  Wang Hongchuan Hong Guangwen Engineer  Nanjing Hydraulic Research Institute  Nanjing  . Professor  Research Institute of Coastal  Ocean Engineering  Hohai University  Nanjing 《中国海洋工程》1996,(4)

To solve problems concerning wave elements and wave propagation, an effective way is the wave energy balance equation, which is widely applied in oceanography and ocean dynamics for its simple computation. The present papaer advances wave energy balance equations considering lateral energy transmission and energy loss as the governing equation for the study of wave refraction-diffraction. For the mathematical model, numerical simulation is made by means of difference method, and the result is verified with two examples.  相似文献   

钝顶螺旋藻部分原生质体及单细胞的制备与培养   总被引：21，自引：0，他引：21  

秦松  王希华  童顺  曾呈奎 《海洋与湖沼》1995,26(1):109-112

于1992年1月-1994年4月，进行超声波处理方法制备钝顶螺旋藻部分原生质体以作为基因工程受体，以及制备单细胞用于固体平板克隆化培养的研究。研究结果表明：超声波以20kHz频率、15W功率作用30s，可使藻丝体断裂成15．0±1．6个细胞长度；延长作用时间，至2－6个细胞长度时，细胞壁结构遭到破坏，形成部分原生质体；继续作用，可形成少量原生质体和大量单细胞。断裂藻丝体、部分原生质体、单细胞以及原生质体均可涂布于固体培养基上再生或生长。以一定密度涂布单细胞与原生质体，能够形成彼此分开的单个克隆，可用于筛选及遗传分析。本文提供了一种节省溶菌酶的制备螺旋藻透性体的方法，超声波作用利于外源基因的导入，而涂布培养利于进一步的筛选和形成克隆。  相似文献   

伶仃洋L＿2和L＿（16）孔第四纪有孔虫群与孢粉化石带特征及其地质意义   总被引：5，自引：0，他引：5  

陈木宏  赵焕庭  温孝胜  张乔民  宋朝景 《海洋地质与第四纪地质》1994,(1)

本文所依据的分析样品是取自珠江最大的一个河口湾伶仃洋中部的水下钻孔岩芯，其底部到达花岗岩基底。通过对第四纪有孔虫群与孢粉化石带特征的分析，阐明在相同的钻孔岩芯中，有孔虫分布变化所反映的古沉积环境特征与孢粉分析的古气候特征较为吻合，并与相应的沉积相对应，结合￣（１４）Ｃ和￣（２３０）Ｔｈ／￣（２３２）Ｔｈ比值法测年数据，从而较好地重塑本区晚更新世中期以来的地质历史。  相似文献   

流形上的空间密度聚类算法研究     

刘峰  刘希玉  刘弘 《中国海洋大学学报(自然科学版)》2007,37(4):681-684,626

研究流形上的聚类分析，针对基于密度的空间聚类引入了流形概念，提出1种基于流形的密度聚类算法，该方法将流形的概念与聚类相结合，可以适用于样本为复杂分布的聚类。文中通过实例证明此算法的有效性。  相似文献   

Evaluation of bending moments and shear forces at unit connections of very large floating structures using hydroelastic and rigid body analyses   总被引：1，自引：0，他引：1  

Byoung Wan Kim  Sa Young Hong  Jo Hyun Kyoung  Seok Kyu Cho 《Ocean Engineering》2007,34(11-12):1668-1679

This paper investigates the characteristics of bending moments, shear forces and stresses at unit connections of very large floating structures (VLFS) under wave loads. The responses of VLFS are calculated by solving multi-body motion equation considering hydroelasticity and connection stiffness. Hydroelastic responses are calculated by the direct method. Higher-order boundary element method (HOBEM) is used for fluid analysis and finite element method (FEM) is introduced for structural analysis. The equation of motion is modified to describe the unit connections by employing spring elements. Bending moments and shear forces at the connections are obtained from the dynamic equilibrium condition for pressures and inertia forces. Two types of VLFS units such as tandem arranged units and side-by-side arranged units are considered in the numerical examples. The influences of connection stiffness, wave frequency and heading angle on responses of VLFS are investigated through the numerical examples. Rigid body analysis along with hydroelastic analysis is also carried out in the numerical analysis and comparison of those two approaches is discussed.  相似文献   

Parabolic Wave Propagation Modelling in Orthogonal Coordinate Systems     

袁德奎  林斌良肖鸿 《中国海洋工程》2004,18(3):445-456

This paper presents a numerical model study of the propagation of water waves using the parabolic approximation of the mild-slope equation in the orthogonal coordinate system. Two types of coordinate systems are studied: (a) a general form of orthogonal coordinate system and (b) the conformal system, a special form of orthogonal coordinate system. Two typical examples, namely, expanded breakwaters and a circular channel, are studied to validate the model. First, the examples are studied by use of the general orthogonal coordinates. Then the same examples are computed by use of the confonnal system. The computational results show that the confonnal coordinate system generally gives better predictions than the general orthogonal system. A numerical technique for generating the conformal grid is combined with the numerical model to improve the practicability of the model. The comparison between the result from the numerical grid system and that from the analytical grid system shows that reliable computational results can be obtained by use of the numerical confonnal grid system.  相似文献