微量硫化物、硫酸盐硫同位素EA-IRMS在线测试分析     

武晓珮  范昌福  胡斌  高建飞  李延河 《地球学报》2020,41(5):605-612

常规EA-IRMS硫同位素测试中, 硫化银(Ag2S)的需样量为0.2~1.0 mg, 硫酸钡(BaSO4)的需样量为0.35~1.5 mg, 较大的需样量已难以满足珍贵样品及微区样品的分析要求, 因此如何减少测试样品量已成为EA-IRMS测试分析工作中急需解决的问题。通过对EA-IRMS测试系统的研究发现, 在采用常规方法测试样品时, 由于初始He载气流速(100 mL/min)、进入分流接口时的流速(10 mL/min)与进入离子源时流速 (0.3 mL/min)的差异导致样品燃烧产生的目标气体中99.7%的气体被浪费, 样品的总体利用率仅有0.3%。因此如何减少样品在测试过程中的损耗, 提高样品的利用率, 从而减少需样量的关键在于缩小载气流速的差距。本实验在常规EA-IRMS测试技术基础上进行了关键改进,在元素分析仪和分流接口之间设计增加一个由六通阀和自动加热冷阱构成的装置, 自动加热冷阱可在Load模式时收集SO2气体, 六通阀在Load-Inject模式之间切换时可改变He载气流速, 通过与分流接口匹配的反吹He载气(10 mL/min)将冷阱中富集的SO2气体送入分流接口, 从而保证进入分流接口前样品燃烧产生的SO2气体全部收集。这一改进, 理论上可以将样品的利用率提高10倍, 该系统需硫量降至3~13 μg, 并且可以提高反应管的寿命, 降低清灰的频率, 提高工作效率。同时有效避免了拖尾的产生, 提高分析结果的精密度。本次微量样品实验获得的硫同位素数据与常规方法一致, 分析精度优于0.15‰(1SD), 测量值与真值的差异在0.4‰以内, 达到国际同类实验室先进水平。此外, 该方法可为微量有机碳、氮同位素EA-IRMS测试分析工作的开展提供参考经验。  相似文献   

High‐Precision,High‐Accuracy Oxygen Isotope Measurements of Zircon Reference Materials with the SHRIMP‐SI     

Janaína N. vila  Trevor R. Ireland  Peter Holden  Peter Lanc  Andrew Latimore  Norm Schram  John Foster  Ian S. Williams  Liane Loiselle  Bin Fu 《Geostandards and Geoanalytical Research》2020,44(1):85-102

Analytical protocols for SHRIMP‐SI oxygen isotope analysis (δ¹⁸O) of a suite of zircon reference materials (RMs) are presented. Data reduction involved a robust estimate of uncertainties associated with the individual spot as well as for groups where the spot data are combined. The repeatability of δ¹⁸O measurements is dependent on both the analytical conditions and the choice of the primary reference material. Under optimised conditions, repeatability was often better than 0.4‰ (2s) allowing sample uncertainties to be obtained to better than 0.2‰ (at 95% confidence limit). Single spot uncertainty combined the within‐spot precision with the scatter associated with repeated measurements of the primary zircon reference material during a measurement session. The uncertainty for individual spots measured under optimised conditions was between 0.3 and 0.4‰ (at 95% confidence). The analytical protocols described were used to assess a variety of zircon RMs that have been used for geochronology and for which laser fluorination oxygen isotope data are available (Temora 2, FC1, R33, QGNG and Ple?ovice), as well as zircons that have been used as RMs for trace element or other types of determination (Mud Tank, Monastery, 91500, AS57, AS3, KIM‐5, OG1, SL13, CZ3 and several other Sri Lankan zircons). Repeated analyses over nine sessions and seven different mounts show agreement within analytical uncertainty for Temora 2, FC1, R33, QGNG, Ple?ovice and 91500, when normalised to Mud Tank. For existing ion microprobe mounts with these materials, an appropriate δ¹⁸O can be determined. However, care should be taken when using zircons from the Duluth Complex (i.e., FC1, AS57 and AS3) as reference materials as our data indicated an excess scatter on δ¹⁸O values associated with low‐U zircon grains.  相似文献   

黑龙江黑宝山-罕达气盆地早白垩世九峰山组年代地层划分     

杨雅军  江斌  王筱筝  庞雪娇  石国明 《地质与资源》2020,29(5):403-410

为了确定黑龙江黑宝山-罕达气盆地九峰山组形成的气候环境及时代,对九峰山组生物地层特征进行了系统的总结与对比.植物及其孢粉化石反映了典型的亚热带潮湿气候环境,时代为早白垩世.对九峰山组下部所夹流纹质凝灰岩进行了LA-ICP-MS锆石U-Pb同位素测年,获得了119±0.89 Ma成岩年龄.综合古生物和同位素年龄确定九峰山组形成于早白垩世阿普特阶中晚期,这一研究成果可为东北地区晚中生代区域性地层、成煤时代、含煤盆地对比提供精确的年代依据.  相似文献   

Cu–Mo Differential Mineralization Mechanism of the Dabate Polymetallic Deposit in Western Tianshan,NW China: Evidence from Geology,Fluid Inclusions,and Oxygen Isotope Systematics     

Rui Cao  Shengchao Yan  Bin Chen  Keke Sun  Qinglin Zhang  Haodong Gu 《Resource Geology》2020,70(1):50-69

Classic porphyry Cu–Mo deposits are mostly characterized by close temporal and spatial relationships between Cu and Mo mineralization. The northern Dabate Cu–Mo deposit is a newly discovered porphyry Cu–Mo polymetallic deposit in western Tianshan, northwest China. The Cu mineralization postdates the Mo mineralization and is located in shallower levels in the deposit, which is different from most classic porphyry Cu–Mo deposits. Detailed field investigations, together with microthermometry, laser Raman spectroscopy, and O‐isotope studies of fluid inclusions, were conducted to investigate the origin and evolution of ore‐forming fluids from the main Mo to main Cu stage of mineralization in the deposit. The results show that the ore‐forming fluids of the main Mo stage belonged to an NaCl + H₂O system of medium to high temperatures (280–310°C) and low salinities (2–4 wt% NaCl equivalent (eq.)), whereas that of the main Cu stage belonged to an F‐rich NaCl + CO₂ + H₂O system of medium to high temperatures (230–260°C) and medium to low salinities (4–10 wt% NaCl eq.). The δ¹⁸O values of the ore‐forming fluids decrease from 3.7–7.8‰ in the main Mo stage to ?7.5 to ?2.9‰ in the main Cu stage. These data indicate that the separation of Cu and Mo was closely related to a large‐scale vapor–brine separation of the early ore‐forming fluids, which produced the Mo‐bearing and Cu‐bearing fluids. Subsequently, the relatively reducing (CH₄‐rich) Mo‐bearing, ore‐forming fluids, dominantly of magmatic origin, caused mineralization in the rhyolite porphyry due to fluid boiling, whereas the relatively oxidizing (CO₂‐rich) Cu‐bearing, ore‐forming fluids mixed with meteoric water and precipitated chalcopyrite within the crushed zone at the contact between rhyolite porphyry and wall rock. We suggest that the separation of Cu and Mo in the deposit may be attributed to differences in the chemical properties of Cu and Mo, large‐scale vapor–brine separation of early ore‐forming fluids, and changes in oxygen fugacity.  相似文献   

河北滦县－滦南县段滦河冲积平原水文地质特征分析     

杨庆洪  左文喆  祝彬 《地质与资源》2020,29(4):374

滦县－滦南县段滦河冲积平原铁矿群司家营铁矿区、马城铁矿区、坎上铁矿区、常裕铁矿、高官营铁矿总储量达几十亿吨,均覆盖有巨厚的第四系含水体,水文地质条件复杂,一直未能开采,成为“大水呆滞金属矿”,被视为开发过程中可能对区域水文地质环境造成较大影响的大水矿区,列为限制开采区,至本世纪初才相继解限投产.通过对司家营铁矿北区、司家营铁矿南区、马城铁矿区、坎上铁矿区、常裕铁矿、高官营铁矿等6处矿山的水文地质条件的分析,论述了滦县－滦南县段滦河冲积平原的水文地质特征.  相似文献   

西昆仑穆呼锰矿床地质特征、控矿因素及成矿模式     

董志国  张连昌  董飞羽  张帮禄  谢月桥  查斌  彭自栋  王长乐 《吉林大学学报(地球科学版)》2020,50(5):1358-1372

穆呼锰矿床位于西昆仑造山带玛尔坎苏锰矿带东段,研究程度相对薄弱。穆呼锰矿床的含矿地层为上石炭统喀拉阿特河组,自下而上可分为角砾灰岩、钙质杂砂岩和含炭质泥灰岩3个岩性段,具有完整的海侵层序特征,反映了由逐步断陷到稳定沉积的盆地演化过程。锰矿层赋存于第三岩性段炭质泥灰岩中,矿石矿物主要为化学组分纯净的泥晶菱锰矿。根据详细的矿相学观察并综合前人研究成果,笔者认为菱锰矿是初始沉淀的锰（氢）氧化物与有机质通过成岩反应形成的。这种成矿机制需要3个基本条件：丰富的锰质来源、氧化还原分层的海水和有机质的大量埋藏。在穆呼一带,有利于满足以上条件的主要控矿因素包括：伸展拉张的构造背景、强烈的海底热液活动、海侵事件和温暖潮湿的古气候。笔者根据w（Ba）-w（P₂O₅）图解并结合区域对比分析,初步认为穆呼锰矿床的成矿模式可能属于最小含氧量带扩张型。  相似文献   

新疆东天山觉罗塔格带中康古尔金矿床成因的再认识     

杜尚泽  张元厚  杨万志  文斌  王鹏 《矿床地质》2020,39(6):1103-1121

东天山觉罗塔格构造带中康古尔金矿因其独特的成矿地质特征,成因一直备受争议。文章立足于康古尔金矿地质特征,结合前人的研究资料,通过探讨觉罗塔格带的构造演化,重新审视康古尔金矿的成因。笔者总结了觉罗塔格构造带晚古生代地层时代及火山-沉积建造特征,认为晚古生代早期大洋板块向北俯冲,发育奥陶纪-泥盆纪弧火山岩及火山-沉积岩系,石炭纪康古尔洋发生双向洋-陆俯冲,在两侧形成对称岛弧带,局部平稳拉张环境为铜-铅-锌-金成矿的有利环境。野外地质观察及室内研究结果表明其成因不仅仅与韧性剪切作用有关。康古尔金矿体位于海相安山岩、凝灰岩的交替部位,上部富金-中部铅锌-下部富铜的金属分带特征,与VMS矿床特征一致。矿体呈板状且与围岩截然接触,明显受挤压变形的网脉状矿化表明矿体形成早于韧性剪切作用。矿床地球化学特征表明,康古尔金矿成矿作用具有多期多阶段性。通过详细对比康古尔金矿和造山型金矿、小热泉子VMS铜矿的特征,笔者认为康古尔金矿具有原生VMS矿床的特征,并且被二叠纪韧性变形所改造,为喷流沉积-变质热液改造型富金多金属矿床。  相似文献   

洪水预报自回归实时校正多步外延方法研究     

张娟  钟平安  徐斌  王凯  姚超宇 《水文》2019,39(6):41-45

自回归模型在洪水预报实时校正中应用广泛。针对自回归模型进行连续多时段校正时中间误差系列缺失问题,提出一种基于历史洪水预报误差系列的样本重组自回归外延方法,以淮河流域王家坝断面为背景,选用洪量相对误差、洪峰相对误差、峰滞时间和确定性系数四个指标开展校正效果评估,并与时程递推外延方法对比。结果表明:样本重组外延方法可以提升洪水预报精度,延长洪水预报有效预见期,特别在降低洪量误差和提高洪水过程的拟合精度上优势更为显著。同时,该方法泛化能力较强,具有实用价值。  相似文献   

中小河流防洪特征水位与雨量预警阈值分析方法研究     

胡余忠  汪朝霞  周斌  江世启 《水文》2019,39(1):27-32

以新建的中小河流水文站点如何快速有效发挥减灾预警作用为切入点,采用山洪灾害调查评价的技术路线,以安徽省皖南山区石台县中心城区新建水文站点为例,调查了预警河段历史洪水信息,采集了沿河两岸居住地房屋基础高程,建立预警站点与影响人口的关联关系,并基此确定水文站点的特征水位以及基于现状防洪能力的雨量预警指标体系,确定警戒水位54.0m、保证水位55.3m。1h流域平均净雨强度70mm/hr,或6h面平均雨量110mm为致灾临界雨量阈值。  相似文献   

西藏甲玛铜多金属矿床磁黄铁矿标型矿物学特征及其地质意义   总被引：2，自引：0，他引：2  

杨阳  唐菊兴  吴纯能  林彬  唐攀  张泽斌  何亮  祁婧  李怡萱 《矿床地质》2020,39(2):337-350

甲玛矿床位于冈底斯成矿带东段,是西藏地区最大的铜多金属矿床之一。磁黄铁矿是甲玛矿床最常见的金属矿物之一,其标型特征不仅反映其自身形成环境,对其形成机制和矿床成因也具有指示意义。文章选取产于不同岩性中的磁黄铁矿矿石样品,利用矿相学、X射线衍射和电子探针分析等手段对磁黄铁矿的形态、成分和结构进行了分析研究。研究表明,甲玛矿床的磁黄铁矿主要分布在距离岩体中心较远的矿区远端矽卡岩和角岩中。磁黄铁矿的晶胞参数和粉晶X射线衍射曲线显示矽卡岩中的磁黄铁矿主要为高温六方磁黄铁矿,角岩中的磁黄铁矿为高温六方磁黄铁矿和低温单斜磁黄铁矿的交生体,但主要以低温单斜磁黄铁矿为主。通过对矽卡岩和角岩中的磁黄铁矿进行电子探针测试,结果显示:矽卡岩中的磁黄铁矿中w(Fe)为60.09%～60.71%,平均为60.38%,w(S)为38.18%～38.69%,平均38.35%,化学分子式为Fe_8S_9～Fe_(10)S_(11);角岩中的磁黄铁矿中w(Fe)为59.05%～59.57%,平均为59.10%,w(S)为39.28%～39.95%,平均39.59%,化学分子式为Fe_5S_6～Fe_7S_8。根据以上矿物学特征,笔者进一步探讨了该矿床磁黄铁矿的沉淀机制:炽热的岩浆热液上涌,与碳酸盐岩地层和碎屑岩地层接触发生相互作用,并有大气水的加入,使得成矿流体在角岩中先快速降温,形成高温六方磁黄铁矿和低温单斜磁黄铁矿的交生体。同时,大量的含矿热液形成,并充填于有利的成矿空间(主要为层间破碎带)沉淀成矿,形成矽卡岩矿体,然后流体在矽卡岩矿段中经历缓慢降温,形成高温六方磁黄铁矿。结合矿床地质特征和相关元素地球化学特征,认为甲玛矿床类型为斑岩-矽卡岩型。  相似文献