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41.
We consider the identification and diagnostics of active and potentially active volcanic features (regional zones of cinder cones, fields sheet volcanism, fields of concentrated multivent extrusive volcanism, calderas, and underwater eruption centers in the sea) in the Kuril-Kamchatka island arc and in the Commander Islands link of the Aleutian island arc, as well as the condition of this region as of late 2007. We have identified and examined three periods in the research of active and potentially active volcanic features in the region: the early (1697–1934), the new (1935–1962), and the most recent, still in progress (1963 until today). We provide a new definition of the term “active volcano,” which is scientifically well-grounded, for the first time here. We present modified (compared with those available until now) catalogs of active and potentially active volcanic forms in Kamchatka and the Kuril Islands. For typical multieruption volcanoes now in phase I (the active) and II (the passive) of their evolution, we provide long-term forecasts of the character and parameters of future eruptions and the associated volcanic hazard.  相似文献   
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Bacteria that degrade natural organic matter in groundwater contain oxygenase enzymes that can co‐oxidize trichloroethene (TCE). This degradation pathway is promising for large dilute plumes, but its evaluation is limited because the density of the bacteria with oxygenase enzymes has not been correlated to field scale rates of degradation. A 14C–TCE assay was developed to determine pseudo first‐order rate constants for the aerobic co‐oxidation of TCE in groundwater. The assay involved incubating 14C–TCE in samples of groundwater contained in 160 mL serum bottles, and monitoring the accumulation of radiolabel in degradation products. A first‐order rate constant for co‐oxidation was extracted from the rate of accumulation of 14C in products, accounting for volumetric changes in the serum bottles due to sampling and subsequent changes to the distribution of TCE between the aqueous and gaseous phases. Of the groundwater samples evaluated from 19 wells at five sites, eight samples at three sites had 14C product accumulation rates that exceeded the accumulation rate in filter‐sterilized groundwater controls. First‐order rate constants ranged from 2.65 to 0.0066 year?1, which is equivalent to half‐lives of 0.26 to 105 years. Groundwater samples from a few of the wells in which co‐oxidation occurred had volatile organic contaminants in addition to TCE; their presence may have induced the oxygenase enzymes that are needed for TCE co‐oxidation. 14CO2 represented ~37% to 97% of the 14C products that accumulated; the balance of the products was soluble and non‐volatile.  相似文献   
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It is shown that the source for numerous magma superflows (MSFs) with complex structures, whose traces have been identified in the Bering Sea (Melekestsev and Slezin, 2017), was regional mantle plume-like formations (or plumes). The magmatic material propagated from these for some hundreds of kilometers or farther along interfaces at different depths between crustal layers during n × 105 to n × 106 years. The long-continued generation and multi-portion structure of the MSFs is explained by slow pulsations in the rising jet of primary melt in the form of a beaded (“peristalsis-like”) structure of successive bulges (which we shall refer to as “magmons”), which float up as “asthenoliths” as the through flow in the channel becomes lower. The most extensive and longest MSFs were formed at the end of the Eocene through Oligocene, while the youngest and shortest flow was generated in the Pleistocene.  相似文献   
44.
Cation binding by polysaccharides is observed in many environments and is important for predictive environmental modeling, and numerous industrial and food technology applications. The complexities of these cation-organic interactions are well suited for predictive molecular modeling and the analysis of conformation and configuration of polysaccharides and their influence on cation binding. In this study, alginic acid was chosen as a model polymer system and representative disaccharide and polysaccharide subunits were developed. Molecular dynamics simulation of the torsion angles of the ether linkage between various monomeric subunits identified local and global energy minima for selected disaccharides. The simulations indicate stable disaccharide configurations and a common global energy minimum for all disaccharide models at Φ = 274 ± 7°, Ψ = 227 ± 5°, where Φ and Ψ are the torsion angles about the ether linkage. The ability of disaccharide subunits to bind calcium ions and to associate with the surface of calcite was also investigated. Molecular models of disaccharide interactions with calcite provide binding energy differences for conformations that are related to the proximity and residence densities of the electron-donating moieties with calcium ions on the calcite surface, which are controlled, in part, by the torsion of the ether linkage between monosaccharide units. Dynamically optimized configurations for polymer alginate models with calcium ions were also derived.  相似文献   
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We present results from a SeaMARC II bathymetry, gravity, and magnetics survey of the northern end of the large-offset propagating East Rift of the Easter microplate. The East Rift is offset by more than 300 km from the East Pacific Rise and its northern end has rifted into approximately 3 Ma lithosphere of the Nazca Plate forming a broad (70–100 km) zone of high (up to 4 km) relief referred to as the Pito Rift. This region appears to have undergone distributed and asymmetric extension that has been primarily accommodated tectonically, by block faulting and tilting, and to a lesser degree by seafloor spreading on a more recently developed magmatic accretionary axis. The larger fault blocks have dimensions of 10–15 km and have up to several km of throw between adjacent blocks suggesting that isostatic adjustments occur on the scale of the individual blocks. Three-dimensional terrain corrected Bouguer anomalies, a three-dimensional magnetic inversion, and SeaMARC II backscatter data locate the recently developed magmatic axis in an asymmetric position in the western part of the rift. The zone of magmatic accretion is characterized by an axis of negative Bouguer gravity anomalies, a band of positive magnetizations, and a high amplitude magnetization zone locating its tip approximately 10 km south of the Pito Deep, the deepest point in the rift area. Positive Bouguer gravity anomalies and negative magnetizations characterize the faulted area to the east of the spreading axis supporting the interpretation that this area consists primarily of pre-existing Nazca plate that has been block faulted and stretched, and that no substantial new accretion has occurred there. The wide zone of deformation in the Pito Rift area and the changing trend of the fault blocks from nearly N-S in the east to NW-SE in the west may be a result of the rapidly changing kinematics of the Easter microplate and/or may result from ridge-transform like shear stresses developed at the termination of the East Rift against the Nazca plate. The broad zone of deformation developed at the Pito Rift and its apparent continuation some distance south along the East Rift has important implications for microplate mechanics and kinematic reconstructions since it suggests that initial microplate boundaries may consist in part of broad zones of deformation characterized by the formation of lithospheric scale fault blocks, and that what appear to be pseudofaults may actually be the outer boundaries of tectonized zones enclosing significant amounts of stretched pre-existing lithosphere.  相似文献   
48.
Volcanic plumes interact with the wind at all scales. On smaller scales, wind affects local eddy structure; on larger scales, wind shapes the entire plume trajectory. The polar jets or jetstreams are regions of high [generally eastbound] winds that span the globe from 30 to 60° in latitude, centered at an altitude of about 10 km. They can be hundreds of kilometers wide, but as little as 1 km in thickness. Core windspeeds are up to 130 m/s. Modern transcontinental and transoceanic air routes are configured to take advantage of the jetstream. Eastbound commercial jets can save both time and fuel by flying within it; westbound aircraft generally seek to avoid it.Using both an integral model of plume motion that is formulated within a plume-centered coordinate system (BENT) as well as the Active Tracer High-resolution Atmospheric Model (ATHAM), we have calculated plume trajectories and rise heights under different wind conditions. Model plume trajectories compare well with the observed plume trajectory of the Sept 30/Oct 1, 1994, eruption of Kliuchevskoi Volcano, Kamchatka, Russia, for which measured maximum windspeed was 30–40 m/s at about 12 km. Tephra fall patterns for some prehistoric eruptions of Avachinsky Volcano, Kamchatka, and Inyo Craters, CA, USA, are anomalously elongated and inconsistent with simple models of tephra dispersal in a constant windfield. The Avachinsky deposit is modeled well by BENT using a windspeed that varies with height.Two potentially useful conclusions can be made about air routes and volcanic eruption plumes under jetstream conditions. The first is that by taking advantage of the jetstream, aircraft are flying within an airspace that is also preferentially occupied by volcanic eruption clouds and particles. The second is that, because eruptions with highly variable mass eruption rate pump volcanic particles into the jetstream under these conditions, it is difficult to constrain the tephra grain size distribution and mass loading present within a downwind volcanic plume or cloud that has interacted with the jetstream. Furthermore, anomalously large particles and high mass loadings could be present within the cloud, if it was in fact formed by an eruption with a high mass eruption rate. In terms of interpretation of tephra dispersal patterns, the results suggest that extremely elongated isopach or isopleth patterns may often be the result of eruption into the jetstream, and that estimation of the mass eruption rate from these elongated patterns should be considered cautiously.  相似文献   
49.
The central part of the Kamchatka Peninsula is characterized by a well defined depression associated with active volcanism, aligned NE–SW. On the east, the depression is bounded by a prominent system of active faults known as the East Kamchatka Fault Zone (EKFZ). In order to improve understanding of the behaviour and kinematic role of this fault zone a fieldwork programme, including study of trenches, was conducted in the north-central part of this system. Aerial photograph analysis, ground-truthed, indicates a westward fault dip with predominantly normal slip, while lateral offsets of river terraces and stream channels demonstrate a combined dextral component. Over 20 excavated pits and natural exposures were examined to confirm a detailed tephra succession extending from the early Holocene to recent historic eruptions. This chronological framework then provided age control on five past faulting events recognised in three trenches. These events took place at about 10.5, 6.0, 4.5 and, in a two-event succession within a short time span, at 3.3–3.2 ka BP. Event clustering may be characteristic and fault length–displacement values suggest earthquakes of M6.5, thus representing a significant new element in regional seismic hazard evaluations; additional to events generated at the subduction interface. The relatively long gap in faulting since the two most recent events may also be significant for hazard scenarios and there is a possible link between the faulting and volcanic activity in the depression. Overall, the EKFZ, together with the Nachiki Transverse Zone farther south, is thought to define a regional-scale block that is extending eastwards independently from the rest of Kamchatka.  相似文献   
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