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The vibrational spectrum of Mg2SiO4 olivine was calculated at the Γ point by using the periodic ab initio CRYSTAL program. An all electron localized Gaussian-type basis set and the B3LYP Hamiltonian were employed. The full set of frequencies (35 IR active, 36 Raman active, 10 “silent” modes) was computed and compared to experimental data from different sources (four for IR and four for Raman). A generally good agreement is observed with experiment (the mean absolute difference ranging from 7 to 10 cm−1 for the various sets), when some of the experimental frequencies, whose attribution is uncertain or appears to be affected by large errors, are not taken into account. A small number of observed peaks are not consistent with calculated frequencies, and a few theoretical peaks do not correspond to measured values. The implications are discussed in detail. The full set of modes are characterized using different tools, namely isotopic substitution, direct inspection of the eigenvectors and graphical representation, so as to obtain a consistent mode assignment. 相似文献
55.
The tectonic evolution of the Por’ya Guba segment of the White Sea Rift System began in the late Paleoproterozoic, i.e., soon
after completion of the Svecofennian collision. The fracture system that controlled localization of the lamproite dike complex
was formed under conditions of horizontal compression combined with shear. Subsequently, this system predetermined the location
of a rift-graben segment that formed as a result of simple shear. The reactivation of the rift system in the Middle Paleozoic
proceeded in two stages. The first stage, when strike-slip movements along previously formed faults predominated, resulted
in formation of quartz-carbonate veins bearing base-metal mineralization. The veins that filled the shear fractures opened
owing to local reorientation of the stress field. The second stage fitted the transtension conditions, and the Late Devonian
alkaline ultramafic dikes of this stage introded into the already existing fracture system, which was oriented at a roughly
right angle to the predominant stress orientation. 相似文献
56.
We have mapped three star-forming regions (G265.14+1.45, G269.16?1.14, G291.27?0.71) in the CS(3–2) and C34S(2–1) lines using the 15 m SEST telescope (Chile), and analyzed the relative positions of methanol and H2O masers, IRAS sources, and emission maxima in the CS lines. In most cases, the maser positions are close to those of the IRAS sources. We compared the radial velocities of the maser sources and high-density CS cores, and estimated the CS column densities assuming LTE. The sizes, densities, and masses of the dense core are estimated; the masses obtained in the LTE approximation agree with the virial masses. 相似文献
57.
E. O. Groznova M. G. Dobrovol’skaya V. A. Kovalenker K. V. Davydov V. T. Bitarov M. V. Razin 《Geology of Ore Deposits》2006,48(2):108-133
The mineralogy and PT formation conditions of the Dzhimidon Pb-Zn deposit in the Sadon ore district are considered. The deposit is localized in metamorphic rocks of the Buron Formation, which pertain to the pre-Jurassic basement (lower structural stage) and are cut through by Upper Paleozoic granitoids, and in the Lower Jurassic terrigenous sequence (upper structural stage). Orebodies as quartz-sulfide veins are mainly hosted in the metamorphic rocks. Galena, sphalerite, chalcopyrite, pyrite, pyrrhotite, and arsenopyrite are the most abundant sulfides, while quartz, carbonates, chlorite, sericite, and feldspar are gangue minerals. The bismuth mineralization identified at this deposit for the first time is represented by diverse phases of the Ag-Pb-Bi-S system. Five stages of the ore deposit formation are recognized: a premineral stage (quartz-feldspar), three ore-bearing stages (pyrite-arsenopyrite, pyrrhotite-chalcopyrite-sphalerite, and arsenopyrite-sphalerite-galena), and a postmineral stage (quartz-calcite); each stage comprises one or several mineral assemblages. The study of fluid inclusions in quartz, calcite, and sphalerite of the premineral, ore-forming, and postmineral stages has shown that the ore was deposited mainly from Na chloride solution with a salinity varying from >22 to <1.0 wt % NaCl equiv at a temperature from 460 to ~120°C and 430–290 bars pressure. The third stage was characterized by an abrupt increase in temperature and by the appearance of Mg(Fe,Ca) chloride solutions equally with Na chloride fluids, presumably owing to the emplacement of granite porphyry. 相似文献
58.
Rudolf Brázdil Hubert Valáek Kateina Chromá 《Geografiska Annaler: Series A, Physical Geography》2006,88(2):79-86
This paper deals with documentary evidence of an economic character as a proxy for direct study of meteorological and hydrological extremes. Taxation records and reports of those who administrated domains and estates are described with respect to information about meteorological and hydrological extremes. Based on data from eight domains or estates from Moravia (in the Czech Republic), frequency series of floods and convective storms (including hailstorms) were developed for the period 1650–1849. One example of disastrous weather, which took place on 10 August 1694 in the Pern?tejn domain, is used to demonstrate the potential for such studies of the intensity of extremes and their impact on human activities. The importance of economic evidence in the instrumental period is shown through tax rebate data contingent upon hailstorm damage in Moravia (1896–1906). The benefits of employing documentary economic evidence for historical climatology and the study of the impact of meteorological and hydrological extremes on human activities are discussed. 相似文献
59.
V. L. Afanas’ev S. N. Dodonov A. V. Moiseev A. G. Gorshkov V. K. Konnikova M. G. Mingaliev 《Astronomy Reports》2006,50(4):255-272
We present classifications, optical identifications, and radio spectra for 19 radio sources from three complete samples, with declinations 4°–6° (B1950, S 3.9 GHz > 200 mJy), 10°–12°30′ (J2000, S 4.85 GHz > 200 mJy), and 74°–75° (J2000, S 4.85 GHz > 100 mJy). We also present corresponding information for the radio source J0527+0331. The right ascensions are 0–24h and the Galactic latitudes |b| > 15° for all the samples. Our observations were obtained with the 6 m telescope from the Special Astrophysical Observatory in the range 4000–9000 Å or 4000–7500 Å and the RATAN-600 radio telescope at frequencies in the range 0.97–21.7 GHz. We obtained flux densities for the radio sources and optical spectra for their optical counterparts. Nine objects were classified as quasars with redshifts from z = 1.029 to 3.212; nine objects are emission-line galaxies with redshifts from 0.172 to 0.546, and one is a galaxy with burstlike star formation at z = 0.156, and one is a BL Lac object with z = 0.509. The spectra of five radio sources were decomposed into extended and compact components. The radio source J0527+0331, identified with a BL Lac object, displays significant variations of time scales from several days to several years. Data on flux variations are presented for 11 radio sources, as well as their spectra at several epochs. 相似文献
60.
Based on ammonites, Upper Kimmeridgian sediments are first established in the Crimean Mountains. The Kimmeridgian-Tithonian boundary recognizable in a continuous section is placed inside the Dvuyakomaya Formation of uniform largely clayey sediments. Assemblages of Kimmeridgian ammonites Lingulaticeras cf. procurvum (Ziegler), Pseudowaagenia gemmellariana Oloriz, Euvirgalithacoceras cf. tantalus (Herbich), Subplanites sp.) and Tithonian forms (?Lingulaticeras efimovi (Rogov), Phylloceras consaguineum Gemmellaro, Oloriziceras cf. schneidi Tavera, and Paraulacosphinctes cf. transitorius (Oppel) are described. A new biostratigraphic scheme proposed for the upper Tithonian-Berriasian of the Crimean Mountains includes the following new biostratigraphic units: the Euvirgalithacoceras cf. tantalus Beds of the upper Kimmeridgian, ?Lingulaticeras efimovi Beds of the lower Tithonian, and Oloriziceras cf. schneidi and Paraulacosphinctes cf. transitorius beds of the upper Tithonian. The middle Tithonian is proposed to consist of the fallauxi and semiforme (presumably) zones. The ammonities found determine the early Kimmeridgian-Berriasian age of the Dvuyakornaya Formation that is most likely in tectonic contact with the underlying Khutoran Formation. 相似文献