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961.
Vincent Balter Philippe Telouk José Braga Francis Albarède 《Geochimica et cosmochimica acta》2008,72(16):3980-3990
We present in this study results obtained with a laser-ablation coupled with both a quadrupole and a multi-collector ICPMS. The simultaneous in situ Sr/Ca and 87Sr/86Sr measurements along growth profiles in enamel allows the concomitant diet and migration patterns in mammals to be reconstructed. Aliquots of the powdered international standard NIST “SRM1400 Bone Ash” with certified Sr and Ca contents, was sintered at high pressure and temperature and was adopted as the reference material for external reproducibility and calibration of the results. A total of 145 coupled elemental and isotopic measurements of herbivores enamel from the Kruger National Park, South Africa, gives intra-tooth Sr/Ca and 87Sr/86Sr variations that are well larger than external reproducibility. Sr/Ca profiles systematically decrease from the dentine-enamel junction to the outer enamel whereas 87Sr/86Sr profiles exhibit variable patterns. Using a simple geometric model of hypsodont teeth growth, we demonstrate that a continuous recording of the 87Sr/86Sr variations can be reconstructed in the tooth length axis. This suggests that the mobility of a mammal can be reconstructed over a period of more than a year with a resolution of a ten of days, by sampling enamel along growth profiles. Our geometric model of hypsodont teeth growth predicts that an optimal distance between two successive profiles is equal to the enamel thickness. However, this model does not apply to the Sr/Ca signal which is likely to be altered during the enamel maturation stage due to differential maturation processes along enamel thickness. Here, the observed constant decreases of the Sr/Ca ratios in the ungulates of Kruger National Park suggests that they did not changed of diet, while some of them were migrating. 相似文献
962.
F. Gaidies C. de Capitani R. Abart R. Schuster 《Contributions to Mineralogy and Petrology》2008,155(6):673-688
Garnet in metapelites from the Wölz Complex of the Austroalpine crystalline basement east of the Tauern Window characteristically consists of two growth phases, which preserve a comprehensive record of the geothermal history during polymetamorphism. From numerical modelling of garnet formation, detailed information on the pressure–temperature–time (P–T–t) evolution during prograde metamorphism is obtained. In that respect, the combined influences of chemical fractionation associated with garnet growth, modification of the original growth zoning through intragranular diffusion and the nucleation history on the chemical zoning of garnet as P and T change during growth are considered. The concentric chemical zoning observed in garnet and the homogenous rock matrix, which is devoid of chemical segregation, render the simulation of garnet growth through successive equilibrium states reliable. Whereas the first growth phase of garnet was formed at isobaric conditions of ~3.8 kbar at low heating/cooling rates, the second growth phase grew along a Barrovian P–T path marked with a thermal peak of ~625°C at ~10 kbar and a maximum in P of ~10.4 kbar at ~610°C. For the heating rate during the growth of the second phase of garnet, average rates faster than 50°C Ma?1 are obtained. From geochronological investigations the first growth phase of garnet from the Wölz Complex pertains to the Permian metamorphic event. The second growth phase grew in the course of Eo-Alpine metamorphism during the Cretaceous. 相似文献
963.
964.
965.
The San José silver–tin deposit, Oruro, is located in the Cordillera Oriental, which contains most of the metalliferous mineralizations of Bolivia and is related to a quartz-latite dome of Miocene age. The mineral paragenesis encountered in this study is composed of cassiterite, stannite, miargyrite, pyrargyrite, andorite and Bi-rich andorite, jamesonite, pavonite/benjaminite, boulangerite, owyheeite, ramdohrite and Bi-rich ramdohrite, bismuthinite, besides pyrite, chalcopyrite, Ag-rich tetrahedrite, galena and sphalerite, all of which are analyzed by electron microprobe analysis. With semi-quantitative SEM/EDS and XRD analyses, rhodostannite and kësterite/ferrokësterite were found in association with andorite, and chalcostibite was determined by XRD, in association with zinkenite, tetrahedrite and pyrite. 相似文献
966.
Anne Marie de Grosbois 《Environmental Geology》2008,54(6):1353-1354
967.
968.
Garnet growth at high- and ultra-high pressure conditions and the effect of element fractionation on mineral modes and composition 总被引:4,自引:0,他引:4
Matthias Konrad-Schmolke Patrick J. O'Brien Christian de Capitani Dennis A. Carswell 《Lithos》2008,103(3-4):309-332
In this paper we show that thermodynamic forward modelling, using Gibbs energy minimisation with consideration of element fractionation into refractory phases and/or liberated fluids, is able to extract information about the complex physical and chemical evolution of a deeply subducted rock volume. By comparing complex compositional growth zonations in garnets from high-and ultra-high pressure samples with those derived from thermodynamic forward modelling, we yield an insight into the effects of element fractionation on composition and modes of the co-genetic metamorphic phase assemblage. Our results demonstrate that fractionation effects cause discontinuous growth and re-crystallisation of metamorphic minerals in high pressure rocks. Reduced or hindered mineral growth at UHP conditions can control the inclusion and preservation of minerals indicative for UHP metamorphism, such as coesite, thus masking peak pressure conditions reached in subducted rocks.Further, our results demonstrate that fractional garnet crystallisation leads to strong compositional gradients and step-like zonation patterns in garnet, a feature often observed in high-and ultra-high pressure rocks. Thermodynamic forward modelling allows the interpretation of commonly observed garnet growth zonation patterns in terms of garnet forming reactions and the relative timing of garnet growth with respect to the rock's pressure–temperature path. Such a correlation is essential for the determination of tectonic and metamorphic rates in subduction zones as well as for the understanding of trace element signatures in subduction related rocks. It therefore should be commonplace in the investigation of metamorphic processes in subduction zones. 相似文献
969.
Jian-Wei Li Xin-Fu Zhao Mei-Fu Zhou Paulo Vasconcelos Chang-Qian Ma Xiao-Dong Deng Zorano Sérgio de Souza Yong-Xin Zhao Gang Wu 《Mineralium Deposita》2008,43(3):315-336
The Tongshankou Cu–Mo deposit, located in the westernmost Daye district of the Late Mesozoic Metallogenic Belt along the Middle-Lower
reaches of the Yangtze River, eastern China, consists mainly of porphyry and skarn ores hosted in the Tongshankou granodiorite
and along the contact with the Lower Triassic marine carbonates, respectively. Sensitive high-resolution ion microprobe zircon
U–Pb dating constrains the crystallization of the granodiorite at 140.6 ± 2.4 Ma (1σ). Six molybdenite samples from the porphyry ores yield Re–Os isochron age of 143.8 ± 2.6 Ma (2σ), while a phlogopite sample from the skarn ores yields an 40Ar/39Ar plateau age of 143.0 ± 0.3 Ma and an isochron age of 143.8 ± 0.8 Ma (2σ), indicating an earliest Cretaceous mineralization event. The Tongshankou granodiorite has geochemical features resembling
slab-derived adakites, such as high Sr (740–1,300 ppm) and enrichment in light rare earth elements (REE), low Sc (<10 ppm),
Y (<13.3 ppm), and depletion in heavy REE (<1.2 ppm Yb), and resultant high Sr/Y (60–92) and La/Yb (26–75) ratios. However,
they differ from typical subduction-related adakites by high K, low MgO and Mg#, and radiogenic Sr–Nd–Hf isotopic compositions,
with (87Sr/86Sr)
t
= 0.7062–0.7067, ɛ
Nd(t) = −4.37 to −4.63, (176Hf/177Hf)
t
= 0.282469–0.282590, and ɛ
Hf(t) = −3.3 to −7.6. The geochemical and isotopic data, coupled with geological analysis, indicate that the Tongshankou granodiorite
was most likely generated by partial melting of enriched lithospheric mantle that was previously metasomitized by slab melts
related to an ancient subduction system. Magmas derived from such a source could have acquired a high oxidation state, as
indicated by the assemblage of quartz–magnetite–titanite–amphibole–Mg-rich biotite in the Tongshankou granodiorite and the
compositions of magmatic biotite that fall in the field between the NiNiO and magnetite–hematite buffers in the Fe3+–Fe2+–Mg diagram. Sulfur would have been present as sulfates in such highly oxidized magmas, so that chalcophile elements Cu and
Mo were retained as incompatible elements in the melt, contributing to subsequent mineralization. A compilation of existing
data reveals that porphyry and porphyry-related Cu–Fe–Au–Mo mineralization from Daye and other districts of the Metallogenic
Belt along the Middle-Lower reaches of the Yangtze River took place coevally in the Early Cretaceous and was related to an
intracontinental extensional environment, distinctly different from the arc-compressive setting of the Cenozoic age that has
been responsible for the emplacement of most porphyry Cu deposits of the Pacific Rim. 相似文献
970.
Kevin Baker Kristien Ooms Steven Verstockt Pascal Brackman Philippe De Maeyer Rik Van de Walle 《制图学和地理信息科学》2017,44(5):422-435
ABSTRACTRouting and navigation services for leisure activities are conditioned by special needs and trade-offs. The advent of online communities and large crowdsourced datasets offers opportunities to improve the adoption of a user’s perspective in these suggested paths. This paper focuses on achieving two goals. First, the presented methodology analyses a dataset of 190,610 historical GPS traces to gain insights into the appreciation or attractiveness of each edge in a real-world network for a specific leisure activity (i.e. road cycling). Second, as literature on these leisure activities is still sparse, we want to create a thorough understanding of the activities at hand for future work. An appreciation model is proposed and the spread of this score is analyzed in shortest-path alternatives of popular routing engines for this activity. This analysis successfully discriminates these shortest paths based on the scoring value and three morphological parameters of the path. However, the robustness of the model should be improved to ensure the viability of the proposed approach in future work. More specifically, further research on the local optimality of the route choices will be imperative. 相似文献