Seasonal transport pattern of chromium(III and VI) in a stream receiving wastewater from tanneries     

Ewa Szalinska  Janusz Dominik  Davide A.L. Vignati  Andrzej Bobrowski  Boguslaw Bas 《Applied Geochemistry》2010

Water, suspended matter and sediment samples from a system heavily impacted by wastewater from numerous small tanneries (the upper Dunajec River, southern Poland) were collected to establish the annual cycle of Cr. To study possible oxidation processes the speciation of Cr and Mn concentrations were also investigated. This study showed that Cr(III and VI) temporal and spatial distributions are regulated by coupled anthropogenic (source location and emissions) and hydrologic factors (water flow and particle transport). Chromium(III) concentrations in all compartments varied seasonally as a function of the hydrological regime, production cycle in tanneries and distance from the discharge location. Cr(III) was largely associated with the particulate phase and rapidly deposited in river bed sediments. Contaminated river sediments were however flushed during flood periods to the reservoir located downstream from tanneries. During the tanning season (November to March), Chromium(III) concentrations in the water column and total Cr concentration in sediments exceeded relevant ecotoxicological guidelines only upstream from the reservoir, which trapped about 70% of the annual Cr(III) load transported by the Dunajec river. A correlation between Cr(VI)/Cr(III) ratios and Mn concentration in sediments downstream from the reservoir suggests the possibility of Cr(III) oxidation in natural conditions.  相似文献   

The Glarus Double Fold: a serious scientific advance in mid nineteenth century Alpine Geology     

Dominik Letsch 《Swiss Journal of Geoscience》2014,107(1):65-80

The Glarus overthrust is one of the best known examples of a thrust fault. Prior to its explanation as the base of an overthrust mass, this anomaly of the stratigraphic column had been explained by the Double Fold model, two recumbent folds facing each other. This model, advocated by Arnold Escher and Albert Heim, has been discredited by later geologists as a tectonically unsound concept which retarded the progress of science in this field of research. This article challenges parts of this view and tries instead to demonstrate that the Double Fold concept, though obviously wrong in retrospect, was a considerable scientific advance compared to the situation around 1850 when it was first proposed. To this end, the article summarizes the development of Swiss Alpine geology between 1800 and 1850 and places the Double Fold into its proper historical context. Earlier tectonic models (mostly proposed by Bernhard Studer) viewed crystalline rocks as the main driver of Alpine orogeny: due to somewhat mysterious metamorphic processes these rocks were supposed to have changed their lithology and physical properties and ascended vertically through small fissures. They uplifted, folded and eventually overflowed their sedimentary cover. The Glarus overthrust was also explained in this manner, probably even by Arnold Escher until the late 1840s. He later changed his mind and proposed the Double Fold concept which can be considered as one of the earliest attempts to apply the global contraction theory to the Alps. The global contraction theory later became the base of the geotectonic model of Eduard Suess and contributed to the final acceptance of large-scale horizontal displacements of rock masses around 1900. From this perspective, the Double Fold can be considered as a first step towards the nappe tectonic revolution and we suggest that its proposal was the expression of a fundamentally new way of thinking in Alpine tectonics.  相似文献   

Low‐cost monitoring of snow height and thermal properties with inexpensive temperature sensors     

Dominik E. Reusser  Erwin Zehe 《水文研究》2011,25(12):1841-1852

Small, self‐recording temperature sensors were installed at several heights along a metal rod at five locations in a case study catchment. For each sensor, the presence or absence of snow cover was determined on the basis of its insulating effect and the resulting reduction of the diurnal temperature oscillations. Sensor coverage was then converted into a time series of snow height for each location. Additionally, cold content was calculated. Snow height and cold content provide valuable information for spring flood prediction. Good agreement of estimated snow heights with reference measurements was achieved and increased discharge in the study catchment coincided with low cold content of the snow cover. The results of the proposed distributed assessment of snow cover and snow state show great potential for (i) flood warning, (ii) assimilation of snow state data and (iii) modelling snowmelt process. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

The Bison LL6 breccia     

B. Dominik  F. Bussy 《Meteoritics & planetary science》1994,29(2):235-237

Abstract— Bison LL6 chondrite is an impact breccia. The meteorite consists of unmolten clasts and accessory melt-breccia clasts incorporated into a host of the same parentage.  相似文献   

Stochastic models in the DORIS position time series: estimates for IDS contribution to ITRF2014     

Anna Klos  Janusz Bogusz  Guilhem Moreaux 《Journal of Geodesy》2018,92(7):743-763

This paper focuses on the investigation of the deterministic and stochastic parts of the Doppler Orbitography and Radiopositioning Integrated by Satellite (DORIS) weekly time series aligned to the newest release of ITRF2014. A set of 90 stations was divided into three groups depending on when the data were collected at an individual station. To reliably describe the DORIS time series, we employed a mathematical model that included the long-term nonlinear signal, linear trend, seasonal oscillations and a stochastic part, all being estimated with maximum likelihood estimation. We proved that the values of the parameters delivered for DORIS data are strictly correlated with the time span of the observations. The quality of the most recent data has significantly improved. Not only did the seasonal amplitudes decrease over the years, but also, and most importantly, the noise level and its type changed significantly. Among several tested models, the power-law process may be chosen as the preferred one for most of the DORIS data. Moreover, the preferred noise model has changed through the years from an autoregressive process to pure power-law noise with few stations characterised by a positive spectral index. For the latest observations, the medians of the velocity errors were equal to 0.3, 0.3 and 0.4 mm/year, respectively, for the North, East and Up components. In the best cases, a velocity uncertainty of DORIS sites of 0.1 mm/year is achievable when the appropriate coloured noise model is taken into consideration.  相似文献   

Modeling of changes in thermal bioclimate: examples based on urban spaces in Freiburg, Germany   总被引：2，自引：2，他引：0  

Dominik Fröhlich  Andreas Matzarakis 《Theoretical and Applied Climatology》2013,111(3-4):547-558

The Place of the Old Synagogue is a popular place in the city center of Freiburg, a medium-sized city in southwest Germany. It is going to be redesigned soon. In this paper the impact of urban street design and surface material on human thermal comfort is analyzed using the example of the Place of the Old Synagogue. The models SkyHelios, RayMan, and ENVI-met were applied to quantify and qualify the changes. All three models are freely available. Their combination allows analysis of development in long-term conditions, as well as changes in spatial distribution of thermal comfort, as well as of heat stress in summer. Results show that the models can provide valuable information. About the Place of the Old Synagogue, quantitative results show that the period with heat stress will become longer, while the intensity of heat stress increases. The spatial results show that the most significant changes are due to changes in shading. Nevertheless, an increase in thermal stress up to 10 °C is calculated for areas, where ground coverage changes from grass to pavement.  相似文献   

Effects of continuous flow centrifugation on measurements of trace elements in river water: intrinsic contamination and particle fragmentation     

Patrick Ross  Davide Vignati  Janusz Dominik 《水文研究》2006,20(13):2745-2754

Continuous flow centrifugation (CFC) is a well‐established technique used in natural surface water studies to collect large amounts of suspended solids, thus allowing a broad spectrum of measurements. However, a potential contamination or changes in the particle size distribution during the centrifugation may restrain the use of CFC effluents for element analysis in the colloidal and dissolved fractions. In this paper we evaluate the possibility of using the effluent of a Westfalia centrifuge (type KA2‐06‐075, 9700 rpm) for such analysis. This evaluation is based on two laboratory experiments with deionized and tap water and two field experiments in rivers. Elemental concentration changes across the CFC were assessed from the CFC influent and effluent after a filtration at 0·45 µm. Significant increases were found, mainly in the field experiments at a high suspended solids level and a slightly acid pH. A hypothesis was made on the origin of these increases as a superposition of a centrifuge intrinsic contamination and a particle fragmentation effect. A numerical model based on elemental concentration measurements (inductively coupled plasma mass spectrometry) gave a particle fragmentation level of 0·55% (mass percentage of particles broken up into smaller fragments during centrifugation). In another experiment, a direct particle counting (single particle counter) shows an excess of particles smaller than 500 nm in the CFC effluent, corresponding to a fragmentation level of 0·11%. In consequence, the use of CFC effluent for element analysis is possible in low‐turbidity river or lake waters, but should be carefully considered in waters with high suspended matter contents. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

The gaseous Halo of the Virgo Cluster Galaxy 45     

Gerhard Hensler  Daniel Tschöke  Dominik Bomans  Alessandro Boselli 《Astrophysics and Space Science》2003,284(2):467-470

Observations of the Virgo Cluster galaxy NGC 4569 in soft X-rays and in Hα reveal both an asymmetrically distributed hot gaseous halo and a giant filament of diffuse emission, respectively, extending from the same side of the disk, the latter one to at least 8.8 kpc. A deep longslit spectrum along the filament shows velocities systematically different from the systemic velocity of NGC 4569. With the inclination of the disk one can determine the Hα spur as a giant outflow in NGC 4569. This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献   

Measurements of biomarker levels in flounder (Platichthys flesus) and blue mussel (Mytilus trossulus) from the Gulf of Gdańsk (southern Baltic)     

Kopecka J  Lehtonen KK  Barsiene J  Broeg K  Vuorinen PJ  Gercken J  Pempkowiak J 《Marine pollution bulletin》2006,53(8-9):406-421

In the framework of the EU funded BEEP project a set of biomarkers, gross morphometric indices and tissue concentrations of selected organic pollutants were measured in flounder (Platichthys flesus) and mussels (Mytilus trossulus) collected twice a year (April and October) from three sites in the inner Gulf of Gdańsk between autumn 2001 and spring 2003. In flounder, seasonal differences in most biomarkers were observed, but no correlations with tissue pollutant levels could be found. In mussels, highly variable levels in biomarker responses were seen, but no clear seasonal or spatial trends, directly related to tissue concentrations, could be established. The observed biomarkers distribution the study sites are probably mostly caused by interannual, seasonal and individual variability and, in case of flounder, possibly by exchange of stocks between the sampling sites.  相似文献   

Use of biliary PAH metabolites as a biomarker of pollution in fish from the Baltic Sea   总被引：2，自引：0，他引：2  

Vuorinen PJ  Keinänen M  Vuontisjärvi H  Barsiene J  Broeg K  Förlin L  Gercken J  Kopecka J  Köhler A  Parkkonen J  Pempkowiak J  Schiedek D 《Marine pollution bulletin》2006,53(8-9):479-487

During field campaigns of the BEEP project (Biological Effects of Environmental Pollution in Marine Coastal Ecosystems) in 2001-2002, metabolites of polycyclic aromatic hydrocarbons (PAHs) were determined in bile samples from three fish species, flounder (Platichthys flesus), perch (Perca fluviatilis) and eelpout (Zoarces viviparus), from four separate areas in the Baltic Sea. Two determination methods were applied: fixed wavelength fluorescence (FF) for pyrene-type metabolites and high-performance liquid chromatography with fluorescence detection (HPLC). There was a good correlation between the FF method and 1-OH pyrene determined by HPLC. Normalisation of the FF data for absorbance at 380 nm or bile protein concentrations greatly increased variance in one third and decreased it in two thirds of the cases and resulted in a loss of significant differences (protein normalisation) between the sampling stations, but normalisation of the HPLC data had little effect on the results. The biliary PAH metabolite content was usually higher in males than in females. In perch and eelpout the biliary PAH contents were at similar levels, whereas in flounder the levels were lower. The sampling areas arranged in decreasing order of biliary PAH contents were: Wismar Bay > Gulf of Gdansk > Lithuanian coast > Kvadofj?rden (reference area). It is concluded that FF with un-normalised data is a reliable and simple method for monitoring purposes and only one sex of a selected species should be used.  相似文献