Inertial currents in the northern North sea     

P. J. Knight  M. J. Howarth  T. P. Rippeth 《Journal of Sea Research》2002,47(3-4)

Current profiles were measured in the northern North Sea during the autumnal breakdown of stratification (September and October) in 1998. The site was in 110 m of water and the depth-averaged M₂ tidal current amplitudes were about 0.15 m s⁻¹. The surface and bed mixed layers were initially well separated. The measurements were made principally with Acoustic Doppler Current Profilers (ADCP) which gave good coverage of the majority of the water column.During a two-month period several episodes of inertial currents were observed, exhibiting a range of responses some of which corresponded very closely to that predicted by theory. The structure of the inertial currents was primarily first mode baroclinic, with no inertial energy in the depth-averaged current. This implies that the currents in the lower layer are strongly linked to those in the surface layer and also that dissipation could be generated by bed friction, but the nature of the link is unclear. The level of least motion coincided with the thermocline. Since the currents in the upper and lower layers are 180° out of phase, large shears can occur across the thermocline; occasionally the bulk Richardson number determined with a four-metre vertical resolution was less than one.Turbulence measurements suggest that when large inertial current shears are present across the thermocline, which exceed the buoyancy frequencies, then mixing within and across the thermocline is significant. Future experiments should concentrate on enhanced dissipation measurements around the thermocline and higher spatial resolution time series measurements of current and density.  相似文献   

Sulfide oxidation as a process for the formation of copper-rich magmatic sulfides   总被引：1，自引：0，他引：1  

Cora C. Wohlgemuth-Ueberwasser  Raúl O. C. Fonseca  Chris Ballhaus  Jasper Berndt 《Mineralium Deposita》2013,48(1):115-127

Typical magmatic sulfides are dominated by pyrrhotite and pentlandite with minor chalcopyrite, and the bulk atomic Cu/Fe ratio of these sulfides is typically less than unity. However, there are rare magmatic sulfide occurrences that are dominated by Cu-rich sulfides (e.g., bornite, digenite, and chalcopyrite, sometimes coexisting with metallic Cu) with atomic Cu/Fe as high as 5. Typically, these types of sulfide assemblages occur in the upper parts of moderately to highly fractionated layered mafic–ultramafic intrusions, a well-known example being the Pd/Au reef in the Upper Middle Zone of the Skaergaard intrusion. Processes proposed to explain why these sulfides are so unusually rich in Cu include fractional crystallization of Fe/(Ni) monosulfide and infiltration of postmagmatic Cu-rich fluids. In this contribution, we explore and experimentally evaluate a third possibility: that Cu-rich magmatic sulfides may be the result of magmatic oxidation. FeS-dominated Ni/Cu-bearing sulfides were equilibrated at variable oxygen fugacities in both open and closed system. Our results show that the Cu/Fe ratio of the sulfide melt increases as a function of oxygen fugacity due to the preferential conversion of FeS into FeO and FeO_1.5, and the resistance of Cu₂S to being converted into an oxide component even at oxygen fugacities characteristic of the sulfide/sulfate transition (above FMQ?+?1). This phenomenon will lead to an increase in the metal/S ratio of a sulfide liquid and will also depress its liquidus temperature. As such, any modeling of the sulfide liquid line of descent in magmatic sulfide complexes needs to address this issue.  相似文献   

Mg and Si isotopic fractionation patterns in types B1 and B2 CAIs: Implications for formation under different nebular conditions     

Emma S. Bullock  Kim B. Knight  Frank M. Richter  Noriko T. Kita  Takayuki Ushikubo  Glenn J. MacPherson  Andrew M. Davis  Ruslan A. Mendybaev 《Meteoritics & planetary science》2013,48(8):1440-1458

Magnesium and silicon isotopic profiles across melilite grains in two type B1 and two type B2 calcium‐aluminum‐rich inclusions (CAIs) reveal differing but constant enrichments in heavy isotopes everywhere except ≤1000 μm from the CAI margins. There is no close correlation in the B1s or the B2s between isotopic composition and åkermanite content of the melilite, a measure of progressive igneous crystallization, yet such a correlation might be expected in a type B2: without a melilite mantle (as in B1s) to seal the interior off and prevent further evaporation, the melt would have maintained communication with the external gas. These observations indicate a model in which B1s and B2s solidified under differing conditions. The B2s solidified under lower hydrogen pressures ( ≤ 10^?4 – 10^?5 bars) than did B1s ( > 10^?4 bars), so surface volatilization was slower in the B2s and internal chemical and isotopic equilibrium was maintained over the interval of melilite crystallization. The outermost zones of the CAIs (≤1000 μm from the edge) are not consistently enriched in heavy isotopes relative to the interiors, as might be expected from diffusion‐limited surface evaporation of the melt. In all cases, the magnesium in the CAI margins is lighter than in the interiors. In one case, silicon in the margin also is lighter, but locally in some CAIs, it is isotopically heavier near the surface. If melt evaporation played a role in the formation of these outer zones, a later event in many cases caused isotopic re‐equilibration with an external and isotopically near‐normal reservoir.  相似文献   

The role of renewable energy in climate stabilization: results from the EMF27 scenarios     

Gunnar Luderer  Volker Krey  Katherine Calvin  James Merrick  Silvana Mima  Robert Pietzcker  Jasper Van Vliet  Kenichi Wada 《Climatic change》2014,123(3-4):427-441

This paper uses the EMF27 scenarios to explore the role of renewable energy (RE) in climate change mitigation. Currently RE supplies almost 20 % of global electricity demand. Almost all EMF27 mitigation scenarios show a strong increase in renewable power production, with a substantial ramp-up of wind and solar power deployment. In many scenarios, renewables are the most important long-term mitigation option for power supply. Wind energy is competitive even without climate policy, whereas the prospects of solar photovoltaics (PV) are highly contingent on the ambitiousness of climate policy. Bioenergy is an important and versatile energy carrier; however—with the exception of low temperature heat—there is less scope for renewables other than biomass for non-electric energy supply. Despite the important role of wind and solar power in climate change mitigation scenarios with full technology availability, limiting their deployment has a relatively small effect on mitigation costs, if nuclear and carbon capture and storage (CCS)—which can serve as substitutes in low-carbon power supply—are available. Limited bioenergy availability in combination with limited wind and solar power by contrast, results in a more substantial increase in mitigation costs. While a number of robust insights emerge, the results on renewable energy deployment levels vary considerably across the models. An in-depth analysis of a subset of EMF27 reveals substantial differences in modeling approaches and parameter assumptions. To a certain degree, differences in model results can be attributed to different assumptions about technology costs, resource potentials and systems integration.  相似文献   

Land-use transition for bioenergy and climate stabilization: model comparison of drivers,impacts and interactions with other land use based mitigation options   总被引：1，自引：0，他引：1  

Alexander Popp  Steven K. Rose  Katherine Calvin  Detlef P. Van Vuuren  Jan Phillip Dietrich  Marshall Wise  Elke Stehfest  Florian Humpenöder  Page Kyle  Jasper Van Vliet  Nico Bauer  Hermann Lotze-Campen  David Klein  Elmar Kriegler 《Climatic change》2014,123(3-4):495-509

In this article, we evaluate and compare results from three integrated assessment models (GCAM, IMAGE, and ReMIND/MAgPIE) regarding the drivers and impacts of bioenergy production on the global land system. The considered model frameworks employ linked energy, economy, climate and land use modules. By the help of these linkages the direct competition of bioenergy with other energy technology options for greenhouse gas (GHG) mitigation, based on economic costs and GHG emissions from bioenergy production, has been taken into account. Our results indicate that dedicated bioenergy crops and biomass residues form a potentially important and cost-effective input into the energy system. At the same time, however, the results differ strongly in terms of deployment rates, feedstock composition and land-use and greenhouse gas implications. The current paper adds to earlier work by specific looking into model differences with respect to the land-use component that could contribute to the noted differences in results, including land cover allocation, land use constraints, energy crop yields, and non-bioenergy land mitigation options modeled. In scenarios without climate change mitigation, bioenergy cropland represents 10–18 % of total cropland by 2100 across the different models, and boosts cropland expansion at the expense of carbon richer ecosystems. Therefore, associated emissions from land-use change and agricultural intensification as a result of bio-energy use range from 14 and 113 Gt CO2-eq cumulatively through 2100. Under climate policy, bioenergy cropland increases to 24–36 % of total cropland by 2100.  相似文献   

The impact of technology availability on the timing and costs of emission reductions for achieving long-term climate targets     

Jasper van Vliet  Andries F. Hof  Angelica Mendoza Beltran  Maarten van den Berg  Sebastiaan Deetman  Michel G. J. den Elzen  Paul L. Lucas  Detlef P. van Vuuren 《Climatic change》2014,123(3-4):559-569

While most long-term mitigation scenario studies build on a broad portfolio of mitigation technologies, there is quite some uncertainty about the availability and reduction potential of these technologies. This study explores the impacts of technology limitations on greenhouse gas emission reductions using the integrated model IMAGE. It shows that the required short-term emission reductions to achieve long-term radiative forcing targets strongly depend on assumptions on the availability and potential of mitigation technologies. Limited availability of mitigation technologies which are relatively important in the long run implies that lower short-term emission levels are required. For instance, limited bio-energy availability reduces the optimal 2020 emission level by more than 4 GtCO₂eq in order to compensate the reduced availability of negative emissions from bioenergy and carbon capture and storage (BECCS) in the long run. On the other hand, reduced mitigation potential of options that are used in 2020 can also lead to a higher optimal level for 2020 emissions. The results also show the critical role of BECCS for achieving low radiative forcing targets in IMAGE. Without these technologies achieving these targets become much more expensive or even infeasible.  相似文献   

Calibrating a Salt Water Intrusion Model with Time‐Domain Electromagnetic Data     

Daan Herckenrath  Nick Odlum  Vanessa Nenna  Rosemary Knight  Esben Auken  Peter Bauer‐Gottwein 《Ground water》2013,51(3):385-397

Salt water intrusion models are commonly used to support groundwater resource management in coastal aquifers. Concentration data used for model calibration are often sparse and limited in spatial extent. With airborne and ground‐based electromagnetic surveys, electrical resistivity models can be obtained to provide high‐resolution three‐dimensional models of subsurface resistivity variations that can be related to geology and salt concentrations on a regional scale. Several previous studies have calibrated salt water intrusion models with geophysical data, but are typically limited to the use of the inverted electrical resistivity models without considering the measured geophysical data directly. This induces a number of errors related to inconsistent scales between the geophysical and hydrologic models and the applied regularization constraints in the geophysical inversion. To overcome these errors, we perform a coupled hydrogeophysical inversion (CHI) in which we use a salt water intrusion model to interpret the geophysical data and guide the geophysical inversion. We refer to this methodology as a Coupled Hydrogeophysical Inversion‐State (CHI‐S), in which simulated salt concentrations are transformed to an electrical resistivity model, after which a geophysical forward response is calculated and compared with the measured geophysical data. This approach was applied for a field site in Santa Cruz County, California, where a time‐domain electromagnetic (TDEM) dataset was collected. For this location, a simple two‐dimensional cross‐sectional salt water intrusion model was developed, for which we estimated five uniform aquifer properties, incorporating the porosity that was also part of the employed petrophysical relationship. In addition, one geophysical parameter was estimated. The six parameters could be resolved well by fitting more than 300 apparent resistivities that were comprised by the TDEM dataset. Except for three sounding locations, all the TDEM data could be fitted close to a root‐mean‐square error of 1. Possible explanations for the poor fit of these soundings are the assumption of spatial uniformity, fixed boundary conditions and the neglecting of 3D effects in the groundwater model and the TDEM forward responses.  相似文献   

Electrical Resistivity Imaging of Seawater Intrusion into the Monterey Bay Aquifer System          下载免费PDF全文

A. Pidlisecky  T. Moran  B. Hansen  R. Knight 《Ground water》2016,54(2):255-261

We use electrical resistivity tomography to obtain a 6.8‐km electrical resistivity image to a depth of approximately 150 m.b.s.l. along the coast of Monterey Bay. The resulting image is used to determine the subsurface distribution of saltwater‐ and freshwater‐saturated sediments and the geologic controls on fluid distributions in the region. Data acquisition took place over two field seasons in 2011 and 2012. To maximize our ability to image both vertical and horizontal variations in the subsurface, a combination of dipole–dipole, Wenner, Wenner‐gamma, and gradient measurements were made, resulting in a large final dataset of approximately 139,000 data points. The resulting resistivity section extends to a depth of 150 m.b.s.l., and is used, in conjunction with the gamma logs from four coastal monitoring wells to identify four dominant lithologic units. From these data, we are able to infer the existence of a contiguous clay layer in the southern portion of our transect, which prevents downward migration of the saltwater observed in the upper 25 m of the subsurface to the underlying freshwater aquifer. The saltwater and brackish water in the northern portion of the transect introduce the potential for seawater intrusion into the hydraulically connected freshwater aquifer to the south, not just from the ocean, but also laterally from north to south.  相似文献   

The CLIVAR C20C project: which components of the Asian–Australian monsoon circulation variations are forced and reproducible?     

Tianjun Zhou  Bo Wu  A. A. Scaife  S. Brönnimann  A. Cherchi  D. Fereday  A. M. Fischer  C. K. Folland  K. E. Jin  J. Kinter  J. R. Knight  F. Kucharski  S. Kusunoki  N.-C. Lau  Lijuan Li  M. J. Nath  T. Nakaegawa  A. Navarra  P. Pegion  E. Rozanov  S. Schubert  P. Sporyshev  A. Voldoire  Xinyu Wen  J. H. Yoon  N. Zeng 《Climate Dynamics》2009,33(7-8):1051-1068

A multi-model set of atmospheric simulations forced by historical sea surface temperature (SST) or SSTs plus Greenhouse gases and aerosol forcing agents for the period of 1950–1999 is studied to identify and understand which components of the Asian–Australian monsoon (A–AM) variability are forced and reproducible. The analysis focuses on the summertime monsoon circulations, comparing model results against the observations. The priority of different components of the A–AM circulations in terms of reproducibility is evaluated. Among the subsystems of the wide A–AM, the South Asian monsoon and the Australian monsoon circulations are better reproduced than the others, indicating they are forced and well modeled. The primary driving mechanism comes from the tropical Pacific. The western North Pacific monsoon circulation is also forced and well modeled except with a slightly lower reproducibility due to its delayed response to the eastern tropical Pacific forcing. The simultaneous driving comes from the western Pacific surrounding the maritime continent region. The Indian monsoon circulation has a moderate reproducibility, partly due to its weakened connection to June–July–August SSTs in the equatorial eastern Pacific in recent decades. Among the A–AM subsystems, the East Asian summer monsoon has the lowest reproducibility and is poorly modeled. This is mainly due to the failure of specifying historical SST in capturing the zonal land-sea thermal contrast change across the East Asia. The prescribed tropical Indian Ocean SST changes partly reproduce the meridional wind change over East Asia in several models. For all the A–AM subsystem circulation indices, generally the MME is always the best except for the Indian monsoon and East Asian monsoon circulation indices.  相似文献   

The thermal expansion and crystal structure of mirabilite (Na<Subscript>2</Subscript>SO<Subscript>4</Subscript>·10D<Subscript>2</Subscript>O) from 4.2 to 300 K,determined by time-of-flight neutron powder diffraction     

H. E. A. Brand  A. D. Fortes  I. G. Wood  K. S. Knight  L. Vočadlo 《Physics and Chemistry of Minerals》2009,36(1):29-46

We have collected high resolution neutron powder diffraction patterns from Na₂SO₄·10D₂O over the temperature range 4.2–300 K following rapid quenching in liquid nitrogen, and over a series of slow warming and cooling cycles. The crystal is monoclinic, space-group P2₁/c (Z = 4) with a = 11.44214(4) Å, b = 10.34276(4) Å, c = 12.75486(6) Å, β = 107.847(1)°, and V = 1436.794(8) Å³ at 4.2 K (slowly cooled), and a = 11.51472(6) Å, b = 10.36495(6) Å, c = 12.84651(7) Å, β = 107.7543(1)°, V = 1460.20(1) Å³ at 300 K. Structures were refined to R _P (Rietveld powder residual, \( R_{P} = {{\sum {\left| {I_{\text{obs}} - I_{\text{calc}} } \right|} } \mathord{\left/ {\vphantom {{\sum {\left| {I_{\text{obs}} - I_{\text{calc}} } \right|} } {\sum {I_{\text{obs}} } }}} \right. \kern-\nulldelimiterspace} {\sum {I_{\text{obs}} } }} \)) better than 2.5% at 4.2 K (quenched and slow cooled), 150 and 300 K. The sulfate disorder observed previously by Levy and Lisensky (Acta Cryst B34:3502–3510, 1978) was not present in our specimen, but we did observe changes with temperature in deuteron occupancies of the orientationally disordered water molecules coordinated to Na. The temperature dependence of the unit-cell volume from 4.2 to 300 K is well represented by a simple polynomial of the form V = ? 4.143(1) × 10^?7 T ³ + 0.00047(2) T² ? 0.027(2) T + 1437.0(1) Å³ (R ² = 99.98%). The coefficient of volume thermal expansion, α _V , is positive above 40 K, and displays a similar magnitude and temperature dependence to α _V in deuterated epsomite and meridianiite. The relationship between the magnitude and orientation of the principal axes of the thermal expansion tensor and the main structural elements are discussed; freezing in of deuteron disorder in the quenched specimen affects the thermal expansion, manifested most obviously as a change in the behaviour of the unit-cell parameter β.  相似文献