Hot Spots of Nitrification in the Elbe Estuary and Their Impact on Nitrate Regeneration     

Tina Sanders  Andreas Schöl  Kirstin Dähnke 《Estuaries and Coasts》2018,41(1):128-138

Estuaries act as an organic matter and nutrient filter in the transition between the land, rivers and the ocean. In the past, high nutrient and organic carbon load and low oxygen concentration made the Elbe River estuary (NW Europe) a sink for dissolved inorganic nitrogen. A recent reduction in loads and subsequent recovery of the estuary changed its biogeochemical function, so that nitrate is no longer removed on its transition towards the coastal North Sea. Nowadays in the estuary, nitrification appears to be a significant nitrate source. To quantify nitrification and determine actively nitrifying regions in the estuary, we measured the concentrations of ammonium, nitrite and nitrate, the dual stable isotopes of nitrate and net nitrification rates in the estuary on five cruises from August 2012 to August 2013. The nitrate concentration increased markedly downstream of the port of Hamburg in summer and spring, accompanied by a decrease of nitrate isotope values that was clearest in summer exactly at the location where nitrate concentration started to increase. Ammonium and nitrite peaked in the Hamburg port region (up to 18 and 8 μmol L^?1, respectively), and nitrification rates in this region were up to 7 μmol L^?1 day^?1. Our data show that coupled re-mineralization and nitrification are significant internal nitrate sources that almost double the estuary’s summer nitrate concentration. Furthermore, we find that the port of Hamburg is a hot spot of nitrification, whereas the maximum turbidity zone (MTZ) only plays a subordinate role in turnover of nitrate.  相似文献   

Accessing effects and signals of leakage from a CO<Subscript>2</Subscript> reservoir to a shallow freshwater aquifer by reactive transport modelling     

Zsuzsanna Szabó  Nóra Edit Gál  Éva Kun  Teodóra Szőcs  György Falus 《Environmental Earth Sciences》2018,77(12):460

CO₂ geological storage is a transitional technology for the mitigation of climate change. In the vicinity of potential CO₂ reservoirs in Hungary, protected freshwater aquifers used for drinking water supplies exist. Effects of disaster events of CO₂ escape and brine displacement to one of these aquifers have been studied by kinetic 1D reactive transport modelling in PHREEQC. Besides verifying that ion concentrations in the freshwater may increase up to drinking water limit values in both scenarios (CO₂ or brine leakage), total porosity of the rock is estimated. Pore volume is expected to increase at the entry point of CO₂ and to decrease at further distances, whereas it shows minor increase along the flow path for the effect of brine inflow. Additionally, electrical conductivity of water is estimated and suggested to be the best parameter to measure for cost-effective monitoring of both worst-case leakage scenarios.  相似文献   

Bioerosion and encrustation rates in recent mollusk death assemblages on a supratidal siliciclastic setting,Playa Norte,Veracruz State,Mexico     

Catalina Gómez-Espinosa  F. Raúl Gío-Argáez  Ester A. Farinati  Salvador Aliotta  Sergio Adrian Salgado-Souto 《Arabian Journal of Geosciences》2018,11(8):188

This study presents both qualitative and quantitative data regarding marine mollusk (gastropods and bivalves) shell bioerosion and encrustation based on death assemblages obtained from a recent supratidal environment in Playa Norte, Veracruz State. The objectives of this study were to assess the nature of bioerosion and encrustation processes and to investigate the role of these taphonomic features contributing to the deterioration of natural shell accumulations within a tropical siliciclastic tidal environment. The assemblage comprises 31 species: 13 gastropods and 18 bivalves. The bioerosion and encrustation degrees were low to moderate for both types. The most abundant traces were predatory gastropod structures (Oichnus paraboloides and O. simplex), whereas sponge borings (Entobia isp.), polychaete dwellings (Caulostrepsis taeniola), and echinoid raspings (Gnatichnus isp.) were less frequent. The encrusting organisms include polychaete serpulids, bryozoans, and rare foraminifers (Homotrema rubrum). Because of the low bioerosion and encrustation degrees occurring in this area, accumulation is expected to predominate over biotic destruction. As deposition conditions (richly fossiliferous carbonate sandstone beds) were similar to those prevailing in the Tuxpan Formation during the Miocene (Langhian), it is suggested that this study provides an equivalent reference to interpret mollusk fossil assemblages located in this site.  相似文献   

Synthesis of monticellite–forsterite and merwinite–forsterite symplectites in the CaO–MgO–SiO<Subscript>2</Subscript> model system: influence of temperature and water content on microstructure evolution     

P.?Remmert  W.?Heinrich  B.?Wunder  L.?Morales  R.?Wirth  D.?Rhede  R.?AbartEmail authorView author&#;s OrcID profile 《Contributions to Mineralogy and Petrology》2018,173(1):5

Homogeneous single crystals of synthetic monticellite with the composition \({\text{Ca}}_{0.88}{\text{Mg}}_{1.12}{\text{SiO}}_4\) (Mtc I) were annealed in a piston-cylinder apparatus at temperatures between 1000 and \(1200\,^{\circ }\hbox {C}\), pressures of 1.0–1.4 GPa, for run durations from 10 min to 24 h and applying bulk water contents ranging from 0.0 to 0.5 wt% of the total charge. At these conditions, Mtc I breaks down to a fine-grained, symplectic intergrowth. Thereby, two types of symplectites are produced: a first symplectite type (Sy I) is represented by an aggregate of rod-shaped forsterite immersed in a matrix of monticellite with end-member composition (Mtc II), and a second symplectite type (Sy II) takes the form of a lamellar merwinite–forsterite intergrowth. Both symplectites may form simultaneously, where the formation of Sy I is favoured by the presence of water. Sy I is metastable with respect to Sy II and is successively replaced by the latter. For both symplectite types, the characteristic spacing of the symplectite phases is independent of run duration and is only weeakly influenced by the water content, but it is strongly temperature dependent. It varies from about 400 nm at \(1000\,^{\circ }\hbox {C}\) to 1200 nm at \(1100\,^{\circ }\hbox {C}\) in Sy I, and from 300 nm at \(1000\,^{\circ }\hbox {C}\) to 700 nm at \(1200\,^{\circ }\hbox {C}\) in Sy II. A thermodynamic analysis reveals that the temperature dependence of the characteristic spacing of the symplectite phases is due to a relatively high activation energy for chemical segregation by diffusion within the reaction front as compared to the activation energy for interface reactions at the reaction front. The temperature dependence of the characteristic lamellar spacing and the temperature-time dependence of overall reaction progress have potential for applications in geo-thermometry and geo-speedometry.  相似文献   

An analytic model for phase transitions in the early Universe     

L. Disi  B. Lukcs  B. Keszthelyi  G. Pal 《Astronomische Nachrichten》1985,306(4):213-230

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Seasonality and duration in extreme value distributions of significant wave height     

Fernando J. Mndez  Melisa Menndez  Alberto Luceo  Raúl Medina  Nicholas E. Graham 《Ocean Engineering》2008,35(1):131-138

This paper presents a statistical model to characterize the long-term extreme value distribution of significant wave height, conditioning to the duration of the storm and accounting for seasonality. A time-dependent version of the peak over threshold (POT) approach is used to build the model, which is then applied to specific reanalysis time series and NOAA buoy records. The model considers the annual and semiannual cycles which are parameterized in terms of harmonic functions. The inclusion of seasonal variabilities substantially reduces the residuals of the fitted model. The information obtained in this study can be useful to design maritime works, because (a) the model improves the understanding of the variability of extreme wave climate along a year and (b) the model accounts for the duration of the storm, which is a key parameter in several formulations for rubble mound breakwater design.  相似文献   

Diagnosis of trace metal contamination in sediments: the example of Ensenada and El Sauzal, two harbors in Baja California, Mexico   总被引：1，自引：0，他引：1  

Huerta-Diaz MA  Delgadillo-Hinojosa F  Hernández-Ayón M  Segovia-Zavala JA  García-Esquivel Z  López-Zárate H  Siqueiros-Valencia A  Galindo-Bect S 《Marine environmental research》2008,66(3):345-358

Total metal concentrations in sediments from within Ensenada and El Sauzal Harbors are generally higher than at the mouths. Grain-size analyses suggested that this enrichment could be due to the presence of fine-grained sediments in the inner part of the harbors rather than to anthropogenic perturbations. The (Me/Al)(sample) ratios for Pb, Co, Ni and Fe were significantly higher for Ensenada Harbor relative to El Sauzal Harbor, whereas the ratios for Cd, Mn, Zn and Cu were statistically equivalent for both harbors. Calculated enrichment factors [EF(Me)=(Me/Al)(sample)/(Me/Al)(shale)] indicated that the metals showing slight enrichment were those associated with anthropogenic contamination (Pb, Zn), or probably related to primary productivity in the water column (Cd, Co). The levels of most of the metals were not greatly enriched, a consideration that is of the utmost importance when contamination issues are at stake.  相似文献   

Marine spatial planning from the perspective of a small seaside community in Ireland   总被引：3，自引：2，他引：1  

Wesley Flannery  Michel Cinnide 《Marine Policy》2008,32(6):980-987

Marine spatial planning (MSP) is advocated as a means of managing human uses of the sea in a manner that is consistent with the maintenance of the ecological goods and services of the marine environment. Support for the process is evident at international and national levels but the degree to which it is acceptable to local level stakeholders is not clear. An Daingean (formely Dingle) is a small sea-oriented town situated on the southwest coast of Ireland in which marine-based tourism and other relatively new uses of the sea are pursued along side traditional fishing activities. Stakeholders in An Daingean are found to be positively disposed to a local process of MSP that incorporates meaningful local involvement.  相似文献   

Dynamics of coastline changes in Mexico     

Valderrama-Landeros  Luis H.  Martell-Dubois  Raúl  Ressl  Rainer  Silva-Casarín  Rodolfo  Cruz-Ramírez  Cesia J.  Muñoz-Pérez  Juan J. 《地理学报(英文版)》2019,29(10):1637-1654

Journal of Geographical Sciences - The goal of our work was to locate and quantify changes that occurred in 66% of the Mexican coastline, based on four land cover maps generated by the Mexican...  相似文献   

Access routes to high mountain huts facing climate-induced environmental changes and adaptive strategies in the Western Alps since the 1990s     

Jacques Mourey  Ludovic Ravanel  Christophe Lambiel  Joël Strecker  Mattia Piccardi 《Norsk geografisk tidsskrift. Norwegian journal of geography》2019,73(4):215-228

ABSTRACT

In the European Alps, high mountain environments are subject to major impacts resulting from climate change, which strongly affect human activities such as mountaineering. The purpose of the study was to examine changes in access routes to 30 high mountain huts in the Western Alps since the 1990s. Data were derived from the use of two different methods, geo-historical studies and a questionnaire, and were used to identify both the climate-related processes affecting the climbing routes and the strategies implemented by public entities, Alpine clubs, guide companies, and hut keepers to maintain acceptable safety and technical conditions. The case studies revealed issues affecting three access routes and the results from the questionnaire showed that the main processes affecting access routes were loss of ice thickness and retreat from the front of the glaciated areas. Commonly, in situ equipment was installed to facilitate access for mountaineers and/or a part of a route was relocated to a safer area. The authors conclude that in most cases, the measures were effective but they were limited by financial, ethical and legal issues, especially in protected or classified areas that could jeopardise their durability and effectiveness.  相似文献