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This paper presents a finite-volume method for hexahedral multiblock grids to calculate multiphase flow in geologically complex reservoirs. Accommodating complex geologic and geometric features in a reservoir model (e.g., faults) entails non-orthogonal and/or unstructured grids in place of conventional (globally structured) Cartesian grids. To obtain flexibility in gridding as well as efficient flow computation, we use hexahedral multiblock grids. These grids are locally structured, but globally unstructured. One major advantage of these grids over fully unstructured tetrahedral grids is that most numerical methods developed for structured grids can be directly used for dealing with the local problems. We present several challenging examples, generated via a commercially available tool, that demonstrate the capabilities of hexahedral multiblock gridding. Grid quality is discussed in terms of uniformity and orthogonality. The presence of non-orthogonal grid and full permeability tensors requires the use of multi-point discretization methods. A flux-continuous finite-difference (FCFD) scheme, previously developed for stratigraphic hexahedral grid with full-tensor permeability, is employed for numerical flow computation. We extend the FCFD scheme to handle exceptional configurations (i.e. three- or five-cell connections as opposed to the regular four), which result from employing multiblock gridding of certain complex objects. In order to perform flow simulation efficiently, we employ a two-level preconditioner for solving the linear equations that results from the wide stencil of the FCFD scheme. The individual block, composed of cells that form a structured grid, serves as the local level; the higher level operates on the global block configuration (i.e. unstructured component). The implementation uses an efficient data structure where each block is wrapped with a layer of neighboring cells. We also examine splitting techniques [14] for the linear systems associated with the wide stencils of our FCFD operator. We present three numerical examples that demonstrate the method: (1) a pinchout, (2) a faulted reservoir model with internal surfaces and (3) a real reservoir model with multiple faults and internal surfaces.  相似文献   
43.
The hydrothermal reaction kinetics of aspartic acid   总被引:1,自引:0,他引:1  
Experimental data on the hydrothermal reaction kinetics of aspartic acid were acquired using a custom-built spectrophotometric reaction cell which permits in situ observation under hydrothermal conditions. The results of this study indicate that the reaction kinetics of dilute aspartic acid solutions are significantly different depending on the presence or absence of catalytic surfaces such as standard metal alloys. The spectroscopic data presented here represent the first direct observations, in situ and in real time, of an amino acid reacting in a hydrothermal solution. Quantitative kinetic information, including rate constants, concentration versus time profiles, and calculations of the individual component spectra, was obtained from the data using a chemometric approach based on factor analysis/principle component analysis which treats the rate expressions simultaneously as a system of differential algebraic equations (DAE) of index 1. Identification of the products was confirmed where possible by high pressure anion exchange chromatography with pulsed amperometric detection (HPAEC-PAD). The reaction kinetics of aspartic acid under hydrothermal conditions was observed to be highly complex, in contrast to previous studies which indicated almost exclusively deamination. At lower temperatures (120-170 °C), several different reaction pathways were observed, including decarboxylation and polymerization, and the catalytic effects of reactor surfaces on the aspartic acid system were clearly demonstrated. At higher temperatures (above 170 °C), aspartic acid exhibited highly complex behaviour, with evidence indicating that it can simultaneously dimerize and cyclize, deaminate (by up to two pathways), and decarboxylate (by up to two pathways). These higher temperature kinetics were not fully resolvable in a quantitative manner due to the complexity of the system and the constraints of UV spectroscopy. The results of this study provide strong evidence that the reaction kinetics of aspartic acid are very sensitive to parameters such as temperature, reactor materials (i.e., reactive surfaces), and additives, and that previous observations on aspartic acid were specific to the choice of experimental conditions.  相似文献   
44.
The discovery of a new Cretaceous/Palaeogene (K/Pg) bathyal marine sequence on Gorgonilla Island, SW Colombia, extends the presence of Chicxulub impact spherule deposits to the Pacific region of northern South America and to the Eastern Pacific Ocean. The Gorgonilla spherule layer is approximately 20 mm thick and consists of extraordinarily well‐preserved glass spherules up to 1.1 mm in diameter. About 70–90% of the spherules are vitrified, and their chemical composition is consistent with Haiti (Beloc) impact glass spherules. Normal size‐grading, delicate spherule textures, welded melt components and an absence of bioturbation or traction transport suggest that the Gorgonilla spherule layer represents an almost undisturbed settling deposit.  相似文献   
45.
In order to facilitate the understanding of the geological evolution of the Kalahari Craton and its relation to South America, the provenance of the first large-scale cratonic cover sequence of the craton, namely the Ordovician to Carboniferous Cape Supergroup was studied through geochemical analyses of the siliciclastics, and age determinations of detrital zircon. The Cape Supergroup comprises mainly quartz-arenites and a Hirnantian tillite in the basal Table Mountain Group, subgreywackes and mudrocks in the overlying Bokkeveld Group, while siltstones, interbedded shales and quartz-arenites are typical for the Witteberg Group at the top of the Cape Supergroup. Palaeocurrent analyses indicate transport of sediment mainly from northerly directions, off the interior of the Kalahari Craton with subordinate transport from a westerly source in the southwestern part of the basin near Cape Town. Geochemical provenance data suggest mainly sources from passive to active continental margin settings. The reconnaissance study of detrital zircons reveals a major contribution of Mesoproterozoic sources throughout the basin, reflecting the dominance of the Namaqua-Natal Metamorphic Belt, situated immediately north of the preserved strata of Cape Supergroup, as a source with Archaean-aged zircons being extremely rare. We interpret the Namaqua-Natal Metamorphic Belt to have been a large morphological divide at the time of deposition of the Cape Supergroup that prevented input of detrital zircons from the interior early Archaean Kaapvaal cratonic block of the Kalahari Craton. Neoproterozoic and Cambrian zircons are abundant and reflect the basement geology of the outcrops of Cape strata. Exposures close to Cape Town must have received sediment from a cratonic fragment that was situated off the Kalahari Craton to the west and that has subsequently drifted away. This cratonic fragment predominantly supplied Meso- to Neoproterozoic, and Cambrian-aged zircon grains in addition to minor Silurian to Lower Devonian zircons and very rare Archaean (2.5?Ga) and late Palaeoproterozoic (1.8-2.0?Ga) ones. No Siluro-Devonian source has yet been identified on the Kalahari Craton, but there are indications for such a source in southern Patagonia. Palaeozoic successions in eastern Argentina carry a similar detrital zircon population to that found here, including evidence of a Silurian to Lower Devonian magmatic event. The Kalahari and Río de la Plata Cratons were thus in all likelihood in close proximity until at least the Carboniferous.  相似文献   
46.
Four phases of cross‐cutting tunnel valleys imaged on 3‐D seismic datasets are mapped within the Middle–Late Pleistocene succession of the central North Sea basin (Witch Ground area). In plan the tunnel valleys form complex anastomosing networks, with tributary valleys joining main valleys at high angles. The valleys have widths ranging from 250 to 2300 m, and base to shoulder relief varying between 30 and 155 m, with irregular long‐axis profiles characteristic of erosion by water driven by glaciostatic pressures. The youngest phase of tunnel valleys are smaller and have a thinner infill than the older generations. The fill of the larger valleys comprises three seismic facies, the lowermost of which has high amplitudes and is discontinuous. The middle facies consists of wedge‐shaped packages of low‐angle dipping reflectors and is overlain by a facies characterised by sub‐horizontal reflectors, which onlap the valley margins. The seismic character, and comparison with lithologies identified in other northwest European Pleistocene tunnel valleys both onshore and offshore, suggests that the lower two seismic facies are most likely sand and gravel‐dominated, while the uppermost facies consists of glaciolacustrine and marine muds. The 3‐D morphology of the valley margins combined with the geometry of the infill packages suggest that episodic discharge of subglacial meltwater was responsible for incising the valleys and depositing at least some of the infill. Proglacial glaciofluvial deposits are inferred to account for some of the fill overlying the subglacial deposits. Glaciolacustrine and marine muds filled remaining valley topography as the ice sheet retreated. The preserved valley margins are shown to be time‐transgressive erosion surfaces that record changes in geometry of the tunnel valley system as it evolved through time, implying that valleys associated with each ice‐sheet advance/retreat cycle were dynamic and probably long‐lived. Within the constraints of the existing stratigraphy the oldest tunnel valleys in the Witch Ground area of the central North Sea are most likely to be Marine Isotope Stage (MIS) 12 (Elsterian, ca. 470 ka) in age and the youngest pre‐MIS 5e (last interglacial, ca. 120 ka). If each tunnel valley phase was formed during the retreat of a major ice sheet then four glaciations with ice coverage of the central North Sea are recorded in the pre‐Weichselian, Middle–Late Pleistocene stratigraphy. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   
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48.
The adaptive composite map projection technique changes the projection to minimize distortion for the geographic area shown on a map. This article improves the transition between the Lambert azimuthal projection and the transverse equal-area cylindrical projection that are used by adaptive composite projections for portrait-format maps. Originally, a transverse Albers conic projection was suggested for transforming between these two projections, resulting in graticules that are not symmetric relative to the central meridian. We propose the alternative transverse Wagner transformation between the two projections and provide equations and parameters for the transition. The suggested technique results in a graticule that is symmetric relative to the central meridian, and a map transformation that is visually continuous with changing map scale.  相似文献   
49.
Loading and unloading effects of the Scandinavian Ice Sheet triggered halotectonic movements in Northern Germany. We present newly detected geomorphological features—termed surface cracks—which indicate a relation between ice sheet-induced salt movement and surface processes. As a part of the Central European Basin System, numerous Zechstein salt structures are abundant in the North German Basin. On the basis of high-resolution digital terrain data, more than 160 surface cracks were mapped in Northern Germany, which were grouped into 30 clusters. Almost all of the surface cracks occur above the top regions of Zechstein salt structures. The surface cracks can be several kilometres long, up to more than 20 m deep and more than 100 m wide. The comparison of the shape of the salt structures and the orientation of the cracks reveals a geometric dependency, indicating that the cracks preferably occur near the crest margins of the salt structures. Furthermore, 3D seismic data from two sites show that subsurface faults originating from salt movement exist beneath the surface cracks. We interpret the cracks as surface ruptures due to ice sheet-induced halotectonic movements. The cracks occur in a variety of Quaternary sediments and landforms. This indicates that widespread halokinetic movements occurred in the region after the last (Weichselian) deglaciation and likely before the thawing of the permafrost, possibly in a time frame from c. 30–20 ka until c. 15 ka.  相似文献   
50.
SPICES (Spectro-Polarimetric Imaging and Characterization of Exoplanetary Systems) is a five-year M-class mission proposed to ESA Cosmic Vision. Its purpose is to image and characterize long-period extrasolar planets and circumstellar disks in the visible (450?C900 nm) at a spectral resolution of about 40 using both spectroscopy and polarimetry. By 2020/2022, present and near-term instruments will have found several tens of planets that SPICES will be able to observe and study in detail. Equipped with a 1.5 m telescope, SPICES can preferentially access exoplanets located at several AUs (0.5?C10?AU) from nearby stars (<25 pc) with masses ranging from a few Jupiter masses to Super Earths (??2 Earth radii, ??10 M??) as well as circumstellar disks as faint as a few times the zodiacal light in the Solar System.  相似文献   
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