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521.
522.
We report isotope analyses of helium, neon, argon, and xenon using different extraction techniques such as stepwise dynamic and static crushing, and high-resolution stepwise heating of three mantle xenoliths from Réunion Island. He and Ne isotopic compositions were similar to previously reported Réunion data, yielding a more radiogenic composition when compared to the Hawaiian or Icelandic mantle plume sources. We furthermore observed correlated 129Xe/130Xe and 136Xe/130Xe ratios following the mantle trend with maximum values of 6.93 ± 0.14 and 2.36 ± 0.06, respectively. High-resolution argon analyses resulted in maximum 40Ar/36Ar ratios of 9000–11,000, in agreement with maximum values obtained in previous studies. We observed a well-defined hyperbolic mixing curve between an atmospheric and a mantle component in a diagram of 40Ar/36Ar vs. 20Ne/22Ne. Using a mantle 20Ne/22Ne of 12.5 (Ne–B) a consistent 40Ar/36Ar value of 11,053 ± 220 in sample ILR 84-4 was obtained, whereas extrapolations to a higher mantle 20Ne/22Ne ratio of 13.8 (solar wind) would lead to a much higher 40Ar/36Ar ratio of 75,000, far above observed maximum values. This favours a mantle 20Ne/22Ne of about 12.5 considered to be equivalent to Ne–B. Extrapolated and estimated 40Ar/36Ar ratios of the Réunion, Iceland, Loihi, and MORB mantle sources, respectively, tend to be linearly correlated with air corrected 21Ne/22Ne and show the same systematic sequence of increasing relative contributions in radiogenic isotopes (Iceland–Loihi–Réunion–MORB) as observed for 4He/3He. In general, He–Ne–Ar isotope systematics of the oceanic mantle can be explained by following processes: (i) different degree of mixing between pure radiogenic and pure primordial isotopes generating the MORB and primitive plume (Loihi-type) endmembers; (ii) relatively recent fractionation of He relative to Ne and Ar, in one or both endmembers; (iii) after the primary fractionation event, different degrees of mixing between melts or fluids of MORB and primitive plume affinity generate the variety of observed OIB data, also on a local scale; (iv) very late-stage secondary fractionation during magma ascent and magma degassing leads to further strong variation in He/Ne and He/Ar ratios. 相似文献
523.
We used the local seismicity for the period of 1993 to 2001, in the northeast of Colombia to show the existence of two slabs in the north and south of the Bucaramanga nest. The northern slab has a dip angle of about 25° and the southern slab has a 50° dip angle, while the dip in the Bucaramanga nest is about 29°. In order to explain the nature of the Bucaramanga nest, we proposed the scenario of collision between these two slabs. Using a 3D Finite Element Model (FEM) we show that collision can concentrate, modify and perturb the stress field. The active process of dehydration embrittlement at intermediate depths and the concentrated stress field in the collision zone may explain the high rate of seismic activity inside the Bucaramanga nest. The perturbed and modified stress field resulting from the simultaneous effect of collision between two subducted slabs and subduction of the lithosphere under its own weight can explain the variation in the focal mechanism of micro-earthquakes and the complexity in the source of the moderate size earthquakes in the Bucaramanga nest. 相似文献
524.
It is shown that temporal variation in hydrochemistry may be attributed, in part, to continuous seismotectonic activity occurring before the onset of the 1995 “Kobe” earthquake, Japan, challenging the “one earthquake–one signal” hypothesis with respect to potential precursory signals to this devastating event. A possible continuous seismotectonic influence on chloride and sulphate ion-concentration is evaluated with aggregate earthquake-information by transforming a multivariate earthquake time series (including coordinates and magnitude) into a one-dimensional time series (considering geometric relationships between earthquakes and the well-site). A piecewise analysis of ion-concentration and seismotectonic-activity time series compares trends and change points between the two time series: a positive correlation (before the proposed onset of the preparation stage) is followed by a negative correlation (during the proposed preparation stage) which, in turn, is succeeded by a positive correlation (after the heaviest aftershock sequences). This suggests that seismotectonic processes occurring before the Kobe earthquake dynamically influenced aquifer characteristics, leading to temporal variations in the hydrochemical time series. Accordingly, a dynamic change in the mixing ratios of waters with different hydrochemical characteristics is proposed as a mechanism for explaining observed variation. The research can be extended by considering vectors in the stress field that lead to changes in the aquifer-well system.The influence of seismotectonics on precursory changes in groundwater composition for the 1995 Kobe earthquake, Japan. 相似文献
525.
A summary of the PRUDENCE model projections of changes in European climate by the end of this century 总被引:3,自引:0,他引:3
An overview of the PRUDENCE fine resolution climate model experiments for Europe is presented in terms of their climate change signals, in particular 2-meter temperature and precipitation. A comparison is made with regard to the seasonal variation in climate change response of the different models participating in the project. In particular, it will be possible to check how representative a particular PRUDENCE regional experiment is of the overall set in terms of seasonal values of temperature and precipitation. This is of relevance for such further studies and impact models that for practical reasons cannot use all the PRUDENCE regional experiments. This paper also provides some guidelines for how to select subsets of the PRUDENCE regional experiments according to such main sources of uncertainty in regional climate simulations as the choice of the emission scenario and of the driving global climate model. 相似文献
526.
Bo. R. Larsen Dario Di Bella Marianne Glasius Richard Winterhalter Niels R. Jensen Jens Hjorth 《Journal of Atmospheric Chemistry》2001,38(3):231-276
Smog chamber experiments have beenconducted in which cyclic monoterpenes were oxidisedin the gas phase by OH. The evolved secondary organicaerosol (SOA) was analysed by LC-MSn and thegas-phase products were analysed by FT-IR. Theconcentrations of the identified compoundscorresponded to carbon mass balances in the range of40%–90%. The identified compounds in the particularphase corresponded to 0.5%–4.2% of the reactedcarbon. The most abundant compounds in SOA fromterpenes with an endocyclic C=C double bond wereC10-keto-aldehydes, C10-keto-carboxylicacids, C10-hydroxy-keto-carboxylic acids, andC10-hydroxy-keto-aldehydes (pinonaldehyde,pinonic acid, hydroxy-pinonic acid isomers, andhydroxy-pinonaldehyde isomers from -pinene;3-caronaldehyde, 3-caronic acid, hydroxy-3-caronicacid isomers, and hydroxy-3-caronaldehyde isomers from3-carene). The most abundant compounds in SOA fromterpenes with an exocyclic C=C double bond wereC9-ketones, C9-dicarboxylic acids, andC10-hydroxy-keto-carboxylic acids (nopinone,pinic acid, and hydroxy-pinonic acid isomers from-pinene; sabinaketone, sabinic acid andhydroxy-sabinonic acid isomers from sabinene).Decarboxylated analogues of most of the compounds werepresent in SOA in minor concentrations, such asC9-keto-carboxylic acids (norpinonic acid,nor-3-caronic acid) and C8-dicarboxylic acids(norpinic acid, nor-3-caric acid, norsabinic acid). InSOA from limonene, which contains an endocyclic aswell as an exocyclic C=C double bond, the mostabundant compounds were a C10-keto-aldehyde andits oxo-derivative (limononaldehyde and keto-limononaldehyde) together with hydroxy-derivatives of aC10-keto-carboxylic acid (isomers ofhydroxy-limononic acid). Also aC10-keto-carboxylic acid (limononic acid) waspresent together with minor concentrations of aC9-dicarboxylic acids (limonic acid), itsoxo-derivative (keto-limonic acid), and itsdecarboxylated analogue (norlimonic acid). Mechanisticpathways for the formation of these products, some ofwhich are identified here for the first time, areproposed. 相似文献
527.
528.
Although the computational burden of global navigation satellite systems (GNSS) data processing is nowadays already a big challenge, especially for huge networks, integrated processing of denser networks with data of multi-GNSS and multi-frequency is desired in the expectation of more accurate and reliable products. Based on the concept of carrier range, in this study, the precise point positioning with integer ambiguity resolution is engaged to obtain the integer ambiguities for converting carrier phases to carrier ranges. With such carrier ranges and pseudo-ranges, rigorous integrated processing is realized computational efficiently for the orbit and clock estimation using massive networks. The strategy is validated in terms of computational efficiency and product quality using data of the IGS network with about 460 stations. The experimental validation shows that the computation time of the new strategy increases gradually with the number of stations. It takes about 14 min for precise orbit and clock determination with 460 stations, while the current strategy needs about 82 min. The overlapping orbit RMS is reduced from 27.6 mm with 100 stations to 24.8 mm using the proposed strategy, and the RMS could be further reduced to 23.2 mm by including all 460 stations. Therefore, the new strategy could be applied to massive networks of multi-GNSS and multi-frequency receivers and possibly to achieve GNSS data products of higher quality. 相似文献
529.
530.
B. Garitte T. S. Nguyen J. D. Barnichon B. J. Graupner C. Lee K. Maekawa C. Manepally G. Ofoegbu B. Dasgupta R. Fedors P. Z. Pan X. T. Feng J. Rutqvist F. Chen Jens Birkholzer Q. Wang O. Kolditz H. Shao 《Environmental Earth Sciences》2017,76(9):345
Coupled thermal–hydrological–mechanical (THM) processes in the near field of deep geological repositories can influence several safety features of the engineered and geological barriers. Among those features are: the possibility of damage in the host rock, the time for re-saturation of the bentonite, and the perturbations in the hydraulic regime in both the rock and engineered seals. Within the international cooperative code-validation project DECOVALEX-2015, eight research teams developed models to simulate an in situ heater experiment, called HE-D, in Opalinus Clay at the Mont Terri Underground Research Laboratory in Switzerland. The models were developed from the theory of poroelasticity in order to simulate the coupled THM processes that prevailed during the experiment and thereby to characterize the in situ THM properties of Opalinus Clay. The modelling results for the evolution of temperature, pore water pressure, and deformation at different points are consistent among the research teams and compare favourably with the experimental data in terms of trends and absolute values. The models were able to reproduce the main physical processes of the experiment. In particular, most teams simulated temperature and thermally induced pore water pressure well, including spatial variations caused by inherent anisotropy due to bedding. 相似文献