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91.
We present an organic geochemical study of surface sediments of Lake Sarbsko, a shallow coastal lake on the middle Polish Baltic coast. The aim was to provide evidence concerning the origin of the organic matter (OM) and its compositional diversity in surface deposits of this very productive, highly dynamic water body. The content and composition of the OM in the bottom sediments were investigated at 11 sampling stations throughout the lake basin. OM sources were assigned on the basis of bulk indicators [total organic carbon (TOC), total nitrogen (TN), δ13CTOC and δ15N and extractable OM yield], biomarker composition of extractable OM and compound-specific C isotope signatures. The source characterization of autochthonous compounds was verified via phytoplankton analysis. The distribution of gaseous hydrocarbons in the sediments, as well as temporal changes in lake water pH, the concentration of DIC (dissolved inorganic carbon) and δ13CDIC were used to trace OM decomposition.The sedimentary OM is composed mainly of well preserved phytoplankton compounds and shows minor spatial variability in composition. However, the presence of CH4 and CO2 in the bottom deposits provides evidence for microbial degradation of sedimentary OM. The transformation of organic compounds in surface, bottom and pore waters via oxidative processes influences carbonate equilibrium in the lake and seasonally favours precipitation or dissolution of CaCO3.The data enhance our understanding of the relationships between the composition of sedimentary OM and environmental conditions within coastal ecosystems and shed light on the reliability of OM proxies for environmental reconstruction of coastal lakes.  相似文献   
92.
Wind-induced drift of objects at sea: The leeway field method   总被引:3,自引:0,他引:3  
A method for conducting leeway field experiments to establish the drift properties of small objects (0.1-25 m) is described. The objective is to define a standardized and unambiguous procedure for condensing the drift properties down to a set of coefficients that may be incorporated into existing stochastic trajectory forecast models for drifting objects of concern to search and rescue operations and other activities involving vessels lost at sea such as containers with hazardous material.An operational definition of the slip or wind and wave-induced motion of a drifting object relative to the ambient current is proposed. This definition taken together with a strict adherence to a 10 m wind speed allows us to refer unambiguously to the leeway of a drifting object. We recommend that all objects if possible be studied using what we term the direct method, where the object’s leeway is studied directly using an attached current meter.We establish a minimum set of parameters that should be estimated for a drifting object for it to be included in the operational forecast models used for prediction of search areas for drifting objects.We divide drifting objects into four categories, depending on their size. For the smaller objects (less than 0.5 m), an indirect method of measuring the object’s motion relative to the ambient current must be used. For larger objects, direct measurement of the motion through the near-surface water masses is strongly recommended. Larger objects are categorized according to the ability to attach current meters and wind monitoring systems to them.The leeway field method proposed here is illustrated with results from field work where three objects were studied in their distress configuration; a 1:3.3 sized model of a 40-foot Shipping container, a World War II mine and a 220 l (55-gallon) oil drum.  相似文献   
93.
In this paper, possibilities and limits of the application of REE3+ luminescence (especially the Nd3+ 4F3/24I9/2 emission) as structural probe are evaluated. Important factors controlling the Nd3+ luminescence signal are discussed, including effects of the crystal-field, crystal orientation, structural state, and temperature. Particular attention was paid to the study of the accessory minerals zircon (ZrSiO4), xenotime–(Y) (YPO4), monazite–(Ce) (CePO4) and their synthetic analogues. Based on these examples we review in short that (1) REE3+ luminescence can be used as non-destructive phase identification method, (2) the intensities of certain luminescence bands are strongly influenced by crystal orientation effects, and (3) increased widths of REE3+-related emission bands are a strong indicator for structural disorder. We discuss the potential of luminescence spectroscopy, complementary to Raman spectroscopy, for the quantitative estimation of chemical (and potentially also radiation-induced) disorder. For the latter, emissions of Nd3+-related centres are found to be promising candidates.  相似文献   
94.
Influence of instruments on the H/V spectral ratios of ambient vibrations   总被引:3,自引:3,他引:0  
For an optimal analysis of the H/V curve, it appears necessary to check the instrument signal to noise ratio in the studied frequency band, to ensure that the signal from the ground noise is well above the internal noise. We assess the reliability and accuracy of various digitizers, sensors and/or digitizer-sensor couples. Although this study is of general interest for any kind of seismological study, we emphasize the influence of equipment on H/V analysis results. To display the impact of the instrumental part on the H/V behavior, some series of tests have been carried out following a step-by-step procedure: first, the digitizers have been tested in the lab (sensitivity, internal noise...), then the three components sensors, still in the lab, and finally the usual user digitizers-sensors couple in lab and outdoors. In general, the digitizer characteristics, verified during this test, correspond well to the manufacturer specifications, however, depending on the digitizer, the quality of the digitized waveform can be very good to very poor, with variation from a channel to another channel (gain, time difference etc.). It appears very clearly that digitizers need a warming up time before the recording to avoid problems in the low-frequency range. Regarding the sensors, we recommend strongly to avoid the use of “classical” accelerometers (i.e., usual force balance technology). The majority of tested seismometers (broadband and short period, even 4.5 Hz) can be used without problems from 0.4 to 25 Hz. In all cases, the instrumentation should be checked first to verify that it works well for the defined study aim, but also to define its limit of use (frequency, sensitivity...).  相似文献   
95.
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97.
In the German State Brandenburg, water clarity and the concentrations of the water quality components chlorophyll a, seston and gelbstoff were measured in 27 lakes. Correlation analysis showed, that spectral beam attenuation at 662 and 514 nm was mainly dependent on changes in chlorophyll a concentrations. In the UV-channel at 360 nm, beam attenuation depended mostly on gelbstoff.

Multiple linear regression provided a direct model of beam attenuation at 514 nm with the inputs of inorganic seston, chlorophyll a and gelbstoff. The specific beam attenuation coefficients were comparable to other natural waters around the world. An inverse model is presented, from which gelbstoff and chlorophyll a could be predicted with some accuracy from the inputs of beam attenuation coefficients at 514 and 360 nm. However, it became obvious that biological variability put major constraints on the predictive capacity of both the direct and the inverse model.

Furthermore, we observed a good correspondence of Secchi depth and the inverse of beam attenuation at 514 nm. The predictions of Secchi depth and chlorophyll a concentration from the inverse model were assessed in perspective of using this instrument instead of laborious chemical analysis for future trophic status classification according to LAWA (Länderarbeitsgemeinschaft Wasser). Predictions of trophic status were principally good when using calibrated models, however, quality of classification critically depended on predictions of chlorophyll a.  相似文献   

98.
A general shift towards higher mineralogical and textural maturity changes the reservoir character across the Triassic–Jurassic transition in the southwestern Barents Sea basin (SWBSB), largely affecting the hydrocarbon prospectivity in the region. Petrographic and geochronological provenance data presented in this paper suggest that the shift from mineralogically immature to mature sandstones initiated during the deposition of the Norian–Rhaetian Fruholmen Formation, and varies with basin location. Strong contrasts between the Fruholmen Formation and underlying formations are associated with proximity to the rejuvenated Caledonian and Fennoscandian hinterlands and are mainly restricted to the southern basin margins. In the basin interior, subtle petrographic variations between the Fruholmen Formation and older Triassic sandstones reflect a distal position relative to the southern hinterland. The long-lived misconception of a regional compositional contrast in the Arctic at the turn of the Norian can be attributed to higher sampling frequency associated with hydrocarbon exploration activity along the southern basin margins, and masking by increased annual precipitation and subsequent reworking during the Jurassic. Geothermal signatures and rearrangement of ferric clay material across the Carnian–Norian transition support a recycled origin for the Fruholmen Formation in the basin interior. As the closest tectonically active region at the time, the Novaya Zemlya fold-and-thrust belt represents the best provenance candidate for polycyclic components in Norian–Rhaetian strata. In addition to recycling in the hinterland during the Late Triassic, local erosion of exposed intrabasinal highs and platforms at the Triassic–Jurassic transition represents a second process where thermodynamically unstable mineral components originally sourced from the Uralides may be removed. Textural and mineralogical modification may also have occurred in marginal-marine depositional environments during periods with elevated sea level. Mature sediment supply from the rejuvenated hinterland in the south, multiple cycles of reworking and gradual accumulation of polycyclic grains have likely led to the extreme compositional maturity registered in the Tubåen, Nordmela and Stø formations in the SWBSB. It is likely that increased annual precipitation since the latest Carnian had an amplifying effect on sandstone maturation across the Triassic–Jurassic boundary, but we consider the effect to be inferior compared to provenance shifts and reworking. Findings from this study are important for understanding compositional and textural maturity enhancement processes in siliciclastic sedimentary basins.  相似文献   
99.
An important indicator of the rangeland health, associated with land degradation, is the ability of semi-natural rangelands to provide forage of sufficient quality for livestock production. In Qilian Mountains(Gansu Province, NW China) biomass production and forage quality are dependent on the seasonality of precipitation and temperature; most of the precipitation falls during summer season, when sheep, goats and yaks graze mountain rangelands. To sustain the rangelands and to improve the management strategies, the assessment of the forage quality should be implemented. The purpose of this research was to study the response of biomass, forage quality and macronutrient content different levels of grazing intensity in Qilian rangelands. We sampled aboveground biomass in the growing seasons in 2012 and 2013 within spring/autumn or summer grazing regimes in two altitudinal zones below and above 3000 m a.s.l.(montane-subalpine and subalpine-alpine respectively). In order to estimate forage quality, biomass was sampled in 1 m × 1 m plots, assigned to the center of 10 ×10 m sites, fromwhich we collected different indicator parameters of rangeland health. Mineral and fiber content of forage biomass was estimated under different levels of grazing intensity with regard to the growing period. It was found that an increase in grazing intensity led to a decrease in dry matter weight. No linearity was observed in the relationship between nutritive value and grazing intensity. The highest fiber content(59.20 %) was found in plots mostly disturbed by grazing. The highest protein(16.30 %) and the lowest fiber(51.30 %) contents were associated with slightly grazing intensity. Concentrations of the mineral elements, such as Zn, P, K and S varied significantly and showed maximum values under low grazing intensity.  相似文献   
100.
There has, in recent years, been an increasing interest in developing nutrient load mitigation measures focussing on tile drains. To plan the location of such tile drain measures, it is important to know where in the landscape drain flow is generated and to understand the key factors governing drain flow dynamics. In the present study, we test two approaches to assess spatial patterns in drain flow generation and thereby assess the importance of including geological information. The approaches are the widely used topographical wetness index (TWI), based solely on elevation data, and hydrological models that include the subsurface geology. We set‐up an ensemble of 20 hydrological models based on 20 stochastically generated geological models to predict drain flow dynamics in the clay till Norsminde catchment in Denmark and test the results against TWI. We find that the hydrological models predict observed daily drain flow reasonably well. High drain flow volumes were found in stream valleys and in wetlands and lower drain flow volumes in the more hilly parts of the catchment. In spite of the apparent connection to the landscape, there was no statistically significant correlation between TWI and drain flow at grid scale (100 × 100 m). TWI was therefore not found to be a sufficient index on its own to assess where drain flow is generated, especially in the highlands of the catchment. The geology below 3 m was found to have a large impact on the drain flow, and correlations between sand percentage in the subsurface geology and drain flow volume were found to be statistically significant. Geological uncertainty therefore give rise to uncertainty on simulated drain flow, and this uncertainty was found to be high at the model grid scale but decreasing with increasing scale.  相似文献   
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