Oil-oil and oil-source rock correlations in the Alpine Foreland Basin of Austria: Insights from biomarker and stable carbon isotope studies     

Reinhard Gratzer  Achim BechtelReinhard F. Sachsenhofer  Hans-Gert LinzerDoris Reischenbacher  Hans-Martin Schulz 《Marine and Petroleum Geology》2011,28(6):1171-1186

The Alpine Foreland Basin is a minor oil and moderate gas province in central Europe. In the Austrian part of the Alpine Foreland Basin, oil and minor thermal gas are thought to be predominantly sourced from Lower Oligocene horizons (Schöneck and Eggerding formations). The source rocks are immature where the oil fields are located and enter the oil window at ca. 4 km depth beneath the Alpine nappes indicating long-distance lateral migration. Most important reservoirs are Upper Cretaceous and Eocene basal sandstones.Stable carbon isotope and biomarker ratios of oils from different reservoirs indicate compositional trends in W-E direction which reflect differences in source, depositional environment (facies), and maturity of potential source rocks. Thermal maturity parameters from oils of different fields are only in the western part consistent with northward displacement of immature oils by subsequently generated oils. In the eastern part of the basin different migration pathways must be assumed. The trend in S/(S + R) isomerisation of ααα-C₂₉ steranes versus the αββ (20R)/ααα (20R) C₂₉ steranes ratio from oil samples can be explained by differences in thermal maturation without involving long-distance migration. The results argue for hydrocarbon migration through highly permeable carrier beds or open faults rather than relatively short migration distances from the source. The lateral distance of oil fields to the position of mature source rocks beneath the Alpine nappes in the south suggests minimum migration distances between less than 20 km and more than 50 km.Biomarker compositions of the oils suggest Oligocene shaly to marly successions (i.e. Schoeneck, Dynow, and Eggerding formations) as potential source rocks, taking into account their immature character. Best matches are obtained between the oils and units a/b (marly shale) and c (black shale) of the “normal” Schöneck Formation, as well as with the so-called “Oberhofen Facies”. Results from open system pyrolysis-gas chromatography of potential source rocks indicate slightly higher sulphur content of the resulting pyrolysate from unit b. The enhanced dibenzothiophene/phenanthrene ratios of oils from the western part of the basin would be consistent with a higher contribution of unit b to hydrocarbon expulsion in this area. Differences in the relative contribution of sedimentary units to oil generation are inherited from thickness variations of respective units in the overthrusted sediments. The observed trend towards lighter δ¹³C values of hydrocarbon fractions from oil fields in a W-E direction are consistent with lower δ¹³C values of organic matter in unit c.  相似文献   

Composition and origin of organic matter in surface sediments of Lake Sarbsko: A highly eutrophic and shallow coastal lake (northern Poland)   总被引：1，自引：0，他引：1  

Micha? Woszczyk  Achim Bechtel  Reinhard Gratzer  Maciej J. Kotarba  Miko?aj Kokociński  Jens Fiebig  Roman Cie?liński 《Organic Geochemistry》2011,42(9):1025-1038

We present an organic geochemical study of surface sediments of Lake Sarbsko, a shallow coastal lake on the middle Polish Baltic coast. The aim was to provide evidence concerning the origin of the organic matter (OM) and its compositional diversity in surface deposits of this very productive, highly dynamic water body. The content and composition of the OM in the bottom sediments were investigated at 11 sampling stations throughout the lake basin. OM sources were assigned on the basis of bulk indicators [total organic carbon (TOC), total nitrogen (TN), δ¹³C_TOC and δ¹⁵N and extractable OM yield], biomarker composition of extractable OM and compound-specific C isotope signatures. The source characterization of autochthonous compounds was verified via phytoplankton analysis. The distribution of gaseous hydrocarbons in the sediments, as well as temporal changes in lake water pH, the concentration of DIC (dissolved inorganic carbon) and δ¹³C_DIC were used to trace OM decomposition.The sedimentary OM is composed mainly of well preserved phytoplankton compounds and shows minor spatial variability in composition. However, the presence of CH₄ and CO₂ in the bottom deposits provides evidence for microbial degradation of sedimentary OM. The transformation of organic compounds in surface, bottom and pore waters via oxidative processes influences carbonate equilibrium in the lake and seasonally favours precipitation or dissolution of CaCO₃.The data enhance our understanding of the relationships between the composition of sedimentary OM and environmental conditions within coastal ecosystems and shed light on the reliability of OM proxies for environmental reconstruction of coastal lakes.  相似文献   

A consistent combination of GNSS and SLR with minimum constraints   总被引：1，自引：1，他引：0  

Susanne Glaser  Mathias Fritsche  Krzysztof Sośnica  Carlos Javier Rodríguez-Solano  Kan Wang  Rolf Dach  Urs Hugentobler  Markus Rothacher  Reinhard Dietrich 《Journal of Geodesy》2015,89(12):1165-1180

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Continental slope sedimentation adjacent to an ice margin I. Seismic facies of Labrador Slope   总被引：1，自引：0，他引：1  

Reinhard Hesse 《Geo-Marine Letters》1992,12(4):189-199

Sleeve-gun, 3.5-kHz, and 12-kHz profiles from the Labrador Slope provide the basis for an analysis of sedimentary facies, processes, and evolution of a continental slope adjacent to an ice margin. The upper slope is deeply incised by numerous canyons reflecting headward canyon branching. The less rugged middle-slope topography has fewer canyons and large slide and slump scars followed downslope by debris-flow deposits. Echo character of seismic profiles reflects the difference in sediment types supplied from mud-dominated sources and sand-, gravel- and till-dominated sources. On the rise, debris-flow deposits are largely confined to canyons. Intercanyon areas are dominated by spill-over turbidites alternating with hemipelagic sediments, which on some of the southern to southwestern levees occur in sediment-wave fields formerly attributed to bottom-current activity.  相似文献   

Fabric evolution at basement–cover interfaces in a fold-and-thrust belt and implications for décollement tectonics (Autochthon, Lower Allochthon, central Scandinavian Caledonides)     

Thomas Angerer  Reinhard O. Greiling 《International Journal of Earth Sciences》2012,101(7):1763-1788

Microstructural and magnetic investigations (anisotropy of magnetic susceptibility, AMS) on sections across basement–cover interfaces (BCI) revealed a complex evolution in the crystalline basement rocks beneath and in the basal units of the Caledonian fold-and-thrust belt: (1) Pre-Caledonian mylonitic fabrics in basement granite relate to steep shear zones. (2) Palaeoweathering formed smectite and illite at the expense of feldspar and mica. Secondary Fe-bearing clay minerals and the intensity of the chemical weathering control the bulk susceptibility. Changing susceptibility and AMS relate to a (time) sequence from primary magnetite to secondary paramagnetic clay to pyrite and ferrimagnetic pyrrhotite. (3) Burial compaction with BCI-parallel fabrics. (4) Caledonian cleavage, overprinted by décollement zones with S–C–C′ fabrics. Décollement cataclasis overprinted pre-existing magnetic fabrics and produced horizontal magnetic lineations and subhorizontal foliations defined by the S–C–C′ fabrics. Clay mineral enrichment, together with subsequent, BCI-parallel compaction fabrics, decreased the shear strength in the basement rocks beneath the BCI. Detachments initiated at such low-strength zones and produced allochthonous units with their footwall within crystalline basement rocks, an observation of general importance for orogenic fold-and-thrust belts.  相似文献   

Species richness,diversity and density of understory vegetation along disturbance gradients in the Himalayan conifer forest     

Kesang WANGCHUK  András DARABANT  Prem Bahadur RAI  Maria WURZINGER  Werner ZOLLITSCH  Georg GRATZER 《山地科学学报》2014,11(5):1182-1191

We investigated whether species richness, diversity and density of understory herbaceous plants differed along logging(gap) and grazing(primarily by cattle) disturbance gradients, and sought to identify drivers of richness, diversity and density of understory vegetation of logged sites. A factorial experiment was conducted in the mixed conifer forest of Gidakom in Western Bhutan. Levels of the logging treatment included small(0.15 – 0.24 ha), medium(0.25 – 0.35 ha) and large(0.36 – 1.31 ha) gaps. The grazing treatment included grazed(primarily by cattle) and ungrazed(where herbivores were excluded by a fence) plots nested within each gap. Data were collected from 12 gaps(4 replicates at each level of logging) using the point intercept method. Shannon Weaver Diversity and Margalef's indices were used to estimate species diversity and describe species richness, respectively. Soil samples were analyzed for pH and nutrients. The interaction effect of logging and grazing was significant(p≤0.001) only on species diversity. Relative to ungrazed areas, species diversity was significantly higher(0.01≤p≤0.05) in medium grazed gaps. Under grazed conditions, soil P was negatively correlated with gap size and species diversity. While species diversity was positivelycorrelated(0.01≤p≤0.05) with soil N in grazed plots species richness was positively correlated(0.001≤p≤0.01) with soil N in ungrazed plots. Relative density of Yushania microphylla and Carex nubigena were higher under ungrazed conditions. Our study suggests that the combined effect of cattle grazing and logging results in higher species diversity of understory vegetation in medium and grazed gaps in mixed conifer forests of Bhutan,whereas increase or decrease in relative density of major species is determined primarily by the independent effects of grazing and logging. From management perspective, forest managers must refrain from creating large gaps to avoid loss of nutrients(mainly P and N), which may eventually affect tree regeneration. Managers intending to maintain understory vegetation diversity must consider the combined effects of grazing and logging, ensuring low to moderate grazing pressure.  相似文献   

Sedimentary pigments as indicators of cyanobacterial dynamics in a hypereutrophic lake     

Bethany N. Deshpande  Roxane Tremblay  Reinhard Pienitz  Warwick F. Vincent 《Journal of Paleolimnology》2014,52(3):171-184

Lac Saint-Augustin is an urban lake located on the outskirts of Quebec City, one of North America’s oldest cities. Anthropogenic inputs from land clearing, agriculture, highway development and urbanization in the surrounding catchment have resulted in strong impacts on the limnology of the lake throughout the past three centuries. In recent years, this lake has experienced severe eutrophication, including persistent cyanobacterial blooms. In winter 2011, a sediment core was extracted from the deepest area of the lake. A detailed paleopigment analysis was used to assess eutrophication processes in the lake and to determine the timing and appearance of cyanobacterial blooms and their subsequent variability. Extracted chlorophyll a, its degradation products and 11 carotenoid pigments were identified and quantified via reverse-phase high performance liquid chromatography to examine relative changes in the phytoplankton. The results revealed large variations in the phytoplankton community structure of Lac Saint-Augustin over the past 356 years. Chlorophyll a concentrations per unit organic matter (OM) increased significantly from the base of the core to present day, rising more than 15-fold from 18.4 µg (g OM)^?1 at the base of the core to 287 µg (g OM)^?1 in the most recent strata. Biostratigraphical analysis revealed three major periods of enrichment, with episodes of cyanobacterial abundance from the 1890s onwards. The greatest changes occurred in the most recent period (from the 1960s to the present) relative to earlier periods, with pigment increases for all phytoplankton groups. The cyanobacterial pigments canthaxanthin, echinenone and zeaxanthin (also a marker for green algae) showed concentrations in the surface sediments that were significantly above values at the bottom of the core, and these differences were large, even giving consideration to the lesser pigment degradation near the surface. Overall, the results indicate that cyanobacterial blooms are not a recent feature of Lac Saint-Augustin but began to occur soon after catchment modification 150 years ago. The pigment records also imply that cyanobacterial and associated algal populations have risen to unprecedented levels over the last few decades of ongoing development of the Lac Saint-Augustin catchment. This study highlights the utility of multiple pigment analysis of lake sediments for identifying the timing and magnitude of anthropogenic impacts.  相似文献   

Hydrochemistry and hydrogen sulfide generating processes in the Malm aquifer,Bavarian Molasse Basin,Germany     

Christina Mayrhofer  Reinhard Niessner  Thomas Baumann 《Hydrogeology Journal》2014,22(1):151-162

Knowledge about the hydrochemical conditions of deep groundwater is crucial for the design and operation of geothermal facilities. In this study, the hydrochemical heterogeneity of the groundwaters in the Malm aquifer, Germany, is assessed, and reasons for the extraordinarily high H₂S concentrations in the central part of the Bavarian Molasse Basin are proposed. Samples were taken at 16 sites, for a total of 37 individual wells, to analyze cations, anions, gas loading and composition. The hydrochemical characteristics of the Malm groundwater in the center of the Molasse Basin are rather heterogeneous. Although the groundwater in the central basin is dominated by meteoric waters, there is a significant infiltration of saline water from higher strata. Care has to be taken in the interpretation of data from geothermal sites, as effects of chemical stimulation of the boreholes may not be fully removed before the final analyses. The distribution of H₂S in the gas phase is correlated to the gas loading of the water which increases in the central basin. Temperatures, isotopic data and the sulfur mass balance indicate that H₂S in the central basin is related to thermochemical sulfate reduction (south of Munich) and bacterial sulfate reduction (north of Munich).  相似文献   

Calcareous nannoplankton, planktonic foraminiferal, and carbonate carbon isotope stratigraphy of the Cenomanian–Turonian boundary section in the Ultrahelvetic Zone (Eastern Alps, Upper Austria)     

Michael Wagreich  Ana-Voica Bojar  Reinhard F. Sachsenhofer  Stephanie Neuhuber  Hans Egger 《Cretaceous Research》2008,29(5-6):965

Ultrahelvetic units of the Eastern Alps were deposited on the distal European continental margin of the (Alpine) Tethys. The Rehkogelgraben section (“Buntmergelserie”, Ultrahelvetic unit, Upper Austria) comprises a 5 m thick succession of upper Cenomanian marl-limestone cycles overlain by a black shale interval composed of three black shale layers and carbonate-free claystones, followed by lower Turonian white to light grey marly limestones with thin marl layers. The main biostratigraphic events in the section are the last occurrence of Rotalipora and the first occurrences of Helvetoglobotruncana helvetica and Quadrum gartneri. The thickest black shale horizon has a TOC content of about 5%, with predominantly marine organic matter of kerogen type II. Vitrinite reflectance and Rock-Eval parameter T_max (<424 °C) indicate low maturity. HI values range from 261 to 362 mg HC/g TOC. δ¹³C values of bulk rock carbonates display the well documented positive shift around the black shale interval, allowing correlation of the Rehkogelgraben section with other sections such as the Global Boundary Stratotype Section and Point (GSSP) succession at Pueblo, USA, and reference sections at Eastbourne, UK, and Gubbio, Italy. Sediment accumulation rates at Rehkogelgraben (average 2.5 mm/ka) are significantly lower than those at Pueblo and Eastbourne.  相似文献   

Comparison of a Manual and an Automated Tracking Method for Tibetan Plateau Vortices     

Julia CURIO  Yongren CHEN  Reinhard SCHIEMANN  ANDrew G.TURNER  Kai Chi WONG  Kevin HODGES  Yueqing LI 《大气科学进展》2018,35(8):965-980

Tibetan Plateau vortices(TPVs) are mesoscale cyclones originating over the Tibetan Plateau(TP) during the extended summer season(April–September).Most TPVs stay on the TP,but a small number can move off the TP to the east.TPVs are known to be one of the main precipitation-bearing systems on the TP and moving-off TPVs have been associated with heavy precipitation and flooding downstream of the TP(e.g.,in Sichuan province or over the Yangtze River Valley).Identifying and tracking TPVs is difficult because of their comparatively small horizontal extent(400–800 km) and the limited availability of soundings over the TP,which in turn constitutes a challenge for short-term predictions of TPV-related impacts and for the climatological study of TPVs.In this study,(i) manual tracking(MT) results using radiosonde data from a network over and downstream of the TP are compared with(ii) results obtained by an automated tracking(AT) algorithm applied to ERA-Interim data.Ten MT-TPV cases are selected based on method(i) and matched to and compared with the corresponding AT-TPVs identified with method(ii).Conversely,ten AT-TPVs are selected and compared with the corresponding MT-TPVs.In general,the comparison shows good results in cases where the underlying data are in good agreement,but considerable differences are also seen in some cases and explained in terms of differences in the tracking methods,data availability/coverage and disagreement between sounding and ERA-Interim data.Recommendations are given for future efforts in TPV detection and tracking,including in an operational weather forecasting context.  相似文献