Secondary mineralization pathways induced by dissimilatory iron reduction of ferrihydrite under advective flow   总被引：6，自引：0，他引：6  

Colleen M Hansel  Shawn G Benner  Jim Neiss  Ravi K Kukkadapu 《Geochimica et cosmochimica acta》2003,67(16):2977-2992

Iron (hydr)oxides not only serve as potent sorbents and repositories for nutrients and contaminants but also provide a terminal electron acceptor for microbial respiration. The microbial reduction of Fe (hydr)oxides and the subsequent secondary solid-phase transformations will, therefore, have a profound influence on the biogeochemical cycling of Fe as well as associated metals. Here we elucidate the pathways and mechanisms of secondary mineralization during dissimilatory iron reduction by a common iron-reducing bacterium, Shewanella putrefaciens (strain CN32), of 2-line ferrihydrite under advective flow conditions. Secondary mineralization of ferrihydrite occurs via a coupled, biotic-abiotic pathway primarily resulting in the production of magnetite and goethite with minor amounts of green rust. Operating mineralization pathways are driven by competing abiotic reactions of bacterially generated ferrous iron with the ferrihydrite surface. Subsequent to the initial sorption of ferrous iron on ferrihydrite, goethite (via dissolution/reprecipitation) and/or magnetite (via solid-state conversion) precipitation ensues resulting in the spatial coupling of both goethite and magnetite with the ferrihydrite surface. The distribution of goethite and magnetite within the column is dictated, in large part, by flow-induced ferrous Fe profiles. While goethite precipitation occurs over a large Fe(II) concentration range, magnetite accumulation is only observed at concentrations exceeding 0.3 mmol/L (equivalent to 0.5 mmol Fe[II]/g ferrihydrite) following 16 d of reaction. Consequently, transport-regulated ferrous Fe profiles result in a progression of magnetite levels downgradient within the column. Declining microbial reduction over time results in lower Fe(II) concentrations and a subsequent shift in magnetite precipitation mechanisms from nucleation to crystal growth. While the initial precipitation rate of goethite exceeds that of magnetite, continued growth is inhibited by magnetite formation, potentially a result of lower Fe(III) activity. Conversely, the presence of lower initial Fe(II) concentrations followed by higher concentrations promotes goethite accumulation and inhibits magnetite precipitation even when Fe(II) concentrations later increase, thus revealing the importance of both the rate of Fe(II) generation and flow-induced Fe(II) profiles. As such, the operating secondary mineralization pathways following reductive dissolution of ferrihydrite at a given pH are governed principally by flow-regulated Fe(II) concentration, which drives mineral precipitation kinetics and selection of competing mineral pathways.  相似文献   

Analyses of Slug Tests and Hydraulic Conductivity Variations in the Near Field of a Two-Well Tracer Experiment Site     

Josep Mas-Pla  T.-C. Jim Yeh  Thomas M. Williams  John F. McCarthy 《Ground water》1997,35(3):492-501

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Assessing natural and cultural influence on soil in remnant tropical woodlands     

C Y Jim  Michael W H Chan 《Area》2004,36(1):6-18

Rural Hong Kong contains culturally protected enclaves of remnant woodlands that provide sanctuary for vegetation, wildlife and soil. This study focuses on the influence of natural and cultural factors on soil properties in woodlands with different human activities. At each of the nine selected sites, two pits were dug to collect soil samples for analysis of 24 physical and chemical properties. Analyses of variance between soil attributes and site factors suggest the prominence of woodland size, and important contribution of topography, aspect and parent material. Soil indicators of human impacts and the tenacity of woodland soil towards anthropogenic disturbance were demonstrated.  相似文献   

A sea surface height control dam at the Strait of Gibraltar     

Jim Gower 《Natural Hazards》2015,78(3):2109-2120

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HPToday: retrospective and prospective          下载免费PDF全文

Jim Buttle 《水文研究》2015,29(15):3441-3442

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Sensitivity of a hydraulic model to channel erosion uncertainty during extreme flooding          下载免费PDF全文

Jefferson S. Wong  Jim E. Freer  Paul D. Bates  David A. Sear  Elisabeth M. Stephens 《水文研究》2015,29(2):261-279

Recent research into flood modelling has primarily concentrated on the simulation of inundation flow without considering the influences of channel morphology. River channels are often represented by a simplified geometry that is implicitly assumed to remain unchanged during flood simulations. However, field evidence demonstrates that significant morphological changes can occur during floods to mobilize the boundary sediments. Despite this, the effect of channel morphology on model results has been largely unexplored. To address this issue, the impact of channel cross‐section geometry and channel long‐profile variability on flood dynamics is examined using an ensemble of a 1D–2D hydraulic model (LISFLOOD‐FP) of the ~1 : 2000 year recurrence interval floods in Cockermouth, UK, within an uncertainty framework. A series of simulated scenarios of channel erosional changes were constructed on the basis of a simple velocity‐based model of critical entrainment. A Monte‐Carlo simulation framework was used to quantify the effects of this channel morphology together with variations in the channel and floodplain roughness coefficients, grain size characteristics and critical shear stress on measures of flood inundation. The results showed that the bed elevation modifications generated by the simplistic equations reflected an approximation of the observed patterns of spatial erosion that enveloped observed erosion depths. The effect of uncertainty on channel long‐profile variability only affected the local flood dynamics and did not significantly affect the friction sensitivity and flood inundation mapping. The results imply that hydraulic models generally do not need to account for within event morphodynamic changes of the type and magnitude of event modelled, as these have a negligible impact that is smaller than other uncertainties, e.g. boundary conditions. Instead, morphodynamic change needs to happen over a series of events to become large enough to change the hydrodynamics of floods in supply limited gravel‐bed rivers such as the one used in this research. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

The need for national deep decarbonization pathways for effective climate policy     

Chris Bataille  Henri Waisman  Michel Colombier  Laura Segafredo  Jim Williams  Frank Jotzo 《Climate Policy》2016,16(4):S7-S26

Constraining global average temperatures to 2 °C above pre-industrial levels will probably require global energy system emissions to be halved by 2050 and complete decarbonization by 2100. In the nationally orientated climate policy framework codified under the Paris Agreement, each nation must decide the scale and method of their emissions reduction contribution while remaining consistent with the global carbon budget. This policy process will require engagement amongst a wide range of stakeholders who have very different visions for the physical implementation of deep decarbonization. The Deep Decarbonization Pathways Project (DDPP) has developed a methodology, building on the energy, climate and economics literature, to structure these debates based on the following principles: country-scale analysis to capture specific physical, economic and political circumstances to maximize policy relevance, a long-term perspective to harmonize short-term decisions with the long-term objective and detailed sectoral analysis with transparent representation of emissions drivers through a common accounting framework or ‘dashboard’. These principles are operationalized in the creation of deep decarbonization pathways (DDPs), which involve technically detailed, sector-by-sector maps of each country’s decarbonization transition, backcasting feasible pathways from 2050 end points. This article shows how the sixteen DDPP country teams, covering 74% of global energy system emissions, used this method to collectively restrain emissions to a level consistent with the 2 °C target while maintaining development aspirations and reflecting national circumstances, mainly through efficiency, decarbonization of energy carriers (e.g. electricity, hydrogen, biofuels and synthetic gas) and switching to these carriers. The cross-cutting analysis of country scenarios reveals important enabling conditions for the transformation, pertaining to technology research and development, investment, trade and global and national policies.

Policy relevance

In the nation-focused global climate policy framework codified in the Paris Agreement, the purpose of the DDPP and DDPs is to provide a common method by which global and national governments, business, civil society and researchers in each country can communicate, compare and debate differing concrete visions for deep decarbonization in order to underpin the necessary societal and political consensus to design and implement short-term policy packages that are consistent with long-term global decarbonization.  相似文献   

Emerging Asias: Transnational Forces,Developmental States,and “Asian Values”     

Jim Glassman 《The Professional geographer》2016,68(2):322-329

Discussions of East Asian developmental states and Asian values discourse have been deformed by national-territorial frameworks that limit scholars' ability to highlight transnational phenomena. Such limits can be overcome by adopting a “Pacificist” perspective, one that highlights the transnational collaborative efforts of Pacific ruling class members, from both Asia and the United States. Such a Pacificist approach has the virtue of highlighting phenomena of transnational class formation that help account for the emergence of both developmental states in East Asia and Asian values discourse, and it also suggested the importance of attending to other kinds of emerging actors in Asian development politics, such as labor and democracy movements.  相似文献   

Hydrogeology of a montane headwater groundwater system downgradient of a coal-mine waste rock dump: Elk Valley,British Columbia,Canada     

Jakub T. Szmigielski  S. Lee Barbour  Sean K. Carey  John Kurylo  A. F. McClymont  M. Jim Hendry 《Hydrogeology Journal》2018,26(7):2341-2356

Steelmaking-coal waste rock placed in mountain catchments in the Elk Valley, British Columbia, Canada, drain constituents of interest (CIs) to surface water downgradient of the waste rock dumps. The role of groundwater in transporting CIs in the headwaters of mountain catchments is not well understood. This study characterizes the physical hydrogeology of a portion of a 10-km² headwater catchment (West Line Creek) downgradient of a 2.7-km² waste rock dump placed over a natural headwater valley-bottom groundwater system. The study site was instrumented with 13 monitoring wells. Drill core samples were collected to determine subsurface lithology and geotechnical properties. The groundwater system was characterized using field testing and water-level monitoring. The valley-bottom sediments were composed of unconsolidated glacial and meltwater successions (<64 m thick) deposited as a series of cut and fill structures overlying shale bedrock. An unconfined basal alluvial aquifer located above fractured bedrock was identified as the primary conduit for groundwater flow toward Line Creek (650 m from the toe of the dump). Discharge through the basal alluvial aquifer was estimated using the geometric mean hydraulic conductivity (±1 standard deviation). These calculations suggest groundwater discharge could account for approximately 15% (ranging from 2 to 60%) of the total water discharged from the watershed. The residence time from the base of the waste rock dump to Line Creek was estimated at <3 years. The groundwater system was defined as a snowmelt (i.e., nival) regime dominated by direct recharge (percolation of precipitation) across the catchment.  相似文献   

Rainfall thresholds for the triggering of landslides considering previous soil moisture conditions (Asturias,NW Spain)   总被引：1，自引：0，他引：1  

Pablo Valenzuela  María José Domínguez-Cuesta  Manuel Antonio Mora García  Montserrat Jiménez-Sánchez 《Landslides》2018,15(2):273-282

Given its geological and climatic conditions and its rugged orography, Asturias is one of the most landslide prone areas in the North of Spain. Most of the landslides occur during intense rainfall episodes. Thus, precipitation is considered the main triggering factor in the study area, reaching average annual values of 960 mm. Two main precipitation patterns are frequent: (i) long-lasting periods of moderate rainfall during autumn and winter and (ii) heavy short rainfall episodes during spring and early summer. In the present work, soil moisture conditions in the locations of 84 landslides are analysed during two rainfall episodes, which represent the most common precipitation patterns: October–November 2008 and June 2010. Empirical data allowed the definition of available water capacity percentages of 99–100% as critical soil moisture conditions for the landslide triggering. Intensity-duration rainfall thresholds were calculated for each episode, considering the periods with sustained high soil moisture levels before the occurrence of each analysed landslide event. For this purpose, data from daily water balance models and weather stations were used. An inverse relationship between the duration of the precipitation and its intensity, consistent with published intensity-duration thresholds, was observed, showing relevant seasonal differences.  相似文献