Sequential extraction and leaching characteristics of heavy metals in abandoned tungsten mine tailings sediments   总被引：1，自引：0，他引：1  

Pyeong-Koo Lee  Min-Ju Kang  Ho Young Jo  Sang-Hoon Choi 《Environmental Earth Sciences》2012,66(7):1909-1923

The chemical speciation of potentially toxic elements (As, Cd, Cu, Pb, and Zn) in the contaminated soils and sulfides-rich tailings sediments of an abandoned tungsten mine in Korea was evaluated by conducting modified BCR sequential extraction tests. Kinetic and static batch leaching tests were also conducted to evaluate the potential release of As and other heavy metals by acidic rain water and the leaching behaviors of these heavy metals. The major sources of the elements were As-, Zn- and Pb-bearing sulfides, Pb carbonates (i.e., cerussite), and Pb sulfates (i.e., anglesite). The biggest pollutant fraction in these soil and tailing samples consists of metals bound to the oxidizable host phase, which can be released into the environment if conditions become oxidative, and/or to residual fractions. No significant difference in total element concentrations was observed between the tailings sediments and contaminated soils. For both sample types, almost no changes occurred in the mobility of As and the other heavy metals at 7 days, but the mobility increased afterwards until the end of the tests at 30 days, regardless of the initial pH. However, the mobility was approximately 5–10 times higher at initial pH 1.0 than at initial pHs of 3.0 and 5.0. The leached amounts of all the heavy metal contents were higher from tailings sediments than from contaminated soils at pH > 3.0, but were lower at pH < 3.0 except for As. Results of this study suggest that further dissolution of heavy metals from soil and tailing samples may occur during extended rainfall, resulting in a serious threat to surface and groundwater in the mine area.  相似文献   

GPS/VRS positioning using atmospheric modeling     

Daniele Barroca Marra Alves  João Francisco Galera Monico 《GPS Solutions》2011,15(3):253-261

  相似文献   

Response of single benthic metrics and multi-metric methods to anthropogenic pressure gradients, in five distinct European coastal and transitional ecosystems   总被引：4，自引：0，他引：4  

Borja A  Barbone E  Basset A  Borgersen G  Brkljacic M  Elliott M  Garmendia JM  Marques JC  Mazik K  Muxika I  Magalhães Neto J  Norling K  Rodríguez JG  Rosati I  Rygg B  Teixeira H  Trayanova A 《Marine pollution bulletin》2011,62(3):499-513

In recent times many benthic indices have been proposed to assess the ecological quality of marine waters worldwide. In this study we compared single metrics and multi-metric methods to assess coastal and transitional benthic status along human pressure gradients in five distinct environments across Europe: Varna bay and lake (Bulgaria), Lesina lagoon (Italy), Mondego estuary (Portugal), Basque coast (Spain) and Oslofjord (Norway). Hence, 13 single metrics (abundance, number of taxa, and several diversity and sensitivity indices) and eight of the most common indices used within the European Water Framework Directive (WFD) for benthic assessment were selected: index of size spectra (ISS), Benthic assessment tool (BAT), Norwegian quality index (NQI), Multivariate AMBI (M-AMBI), Benthic quality index (BQI), (Benthic ecosystem quality index (BEQI), Benthic index based on taxonomic sufficiency (BITS), and infaunal quality index (IQI). Within each system, sampling sites were ordered in an increasing pressure gradient according to a preliminary classification based on professional judgement. The different indices are largely consistent in their response to pressure gradient, except in some particular cases (i.e. BITS, in all cases, or ISS when a low number of individuals is present). Inconsistencies between indicator responses were most pronounced in transitional waters (i.e. IQI, BEQI), highlighting the difficulties of the generic application of indicators to all marine, estuarine and lagoonal environments. However, some of the single (i.e. ecological groups approach, diversity, richness) and multi-metric methods (i.e. BAT, M-AMBI, NQI) were able to detect such gradients both in transitional and coastal environments, being these multi-metric methods more consistent in the detection than single indices. This study highlights the importance of survey design and good reference conditions for some indicators. The agreement observed between different methodologies and their ability to detect quality trends across distinct environments constitutes a promising result for the implementation of the WFD’s monitoring plans. Moreover, these results have management implications, regarding the dangers of misclassification, uncertainty in the assessment, use of conflicting indices, and testing and validation of indices.  相似文献   

Pathogenic fungi: an unacknowledged risk at coastal resorts? New insights on microbiological sand quality in Portugal     

Sabino R  Veríssimo C  Cunha MA  Wergikoski B  Ferreira FC  Rodrigues R  Parada H  Falcão L  Rosado L  Pinheiro C  Paixão E  Brandão J 《Marine pollution bulletin》2011,62(7):1506-1511

Whilst the potential impact on beach users from microorganisms in water has received considerable attention, there has been relatively little investigation into microbial contaminants in sand. Thirty three beaches across Portugal were analyzed during a five year period (2006-2010) to determine the presence of yeasts, pathogenic fungi, dermatophytes, total coliforms, Escherichia coli and intestinal enterococci in sand.Our results showed that 60.4% of the samples were positive for fungi and that 25.2% were positive for the bacterial parameters. The most frequent fungal species found were Candida sp. and Aspergillus sp., whereas intestinal enterococci were the most frequently isolated bacteria. Positive associations were detected among analyzed parameters and country-regions but none among those parameters and sampling period.Regarding threshold values, we propose 15 cfu/g for yeasts, 17 cfu/g for potential pathogenic fungi, 8 cfu/g for dermatophytes. Eighty four cfu/g for coliforms, 250 cfu/g for E. coli, and 100 cfu/g for intestinal enterococci.  相似文献   

Food Web Structure and Habitat Connectivity in Fish Estuarine Nurseries—Impact of River Flow     

Catarina Vinagre  João Salgado  Henrique N. Cabral  Maria J. Costa 《Estuaries and Coasts》2011,34(4):663-674

River flow variability is known to influence estuarine production, yet knowledge on its effect upon estuarine food webs dynamics is still scarce. Stable carbon and nitrogen isotopes were used to assess the effect of river flow in the connectivity and food web interactions between the two main fish nursery areas of the Tagus estuary. The aims of the present work were to investigate the seasonal variation in food web structure and the exchange rate of individuals of marine juvenile fish among estuarine nurseries, to compare the spring of a rainy year (2001) with that of an average year (2000), and to investigate the impact of the winter floods of 2001. A low level of connectivity was observed for the fish species that use these areas as nurseries. In low river flow conditions, two isotopically distinct food webs were established in each nursery area. These food webs were very sensitive to small variations in the freshwater input. Winter floods seem to disrupt the localized food webs that are established in low river flow periods, leading to the re-establishment of a wider food web. While in rainy years this wide food web is maintained until spring, in average years the food web undergoes fragmentation into two localized and isotopically distinctive food webs. The increase in frequency of droughts due to climate change should lower the connectivity of the estuarine fish nurseries food webs, causing habitat fragmentation and consequent loss in complexity and resilience.  相似文献   

Groundwater nitrate vulnerability assessment in alluvial aquifer using process-based models and weights-of-evidence method: Lower Savinja Valley case study (Slovenia)     

Jože Uhan  Goran Vižintin  Jože Pezdič 《Environmental Earth Sciences》2011,64(1):97-105

This paper describes the implementation of process-based models reflecting relative groundwater nitrate vulnerability of the shallow alluvial Lower Savinja Valley (LSV) aquifer in Slovenia. A spatially explicit identification of the potentially vulnerable priority areas within groundwater bodies at risk from a chemical point of view is being required for cost-effective measures and monitoring planning. The shallow LSV unconfined aquifer system consists of high-permeable Holocene and middle- to low-permeable Pleistocene gravel and sand, with a maximum thickness of about 30 m, mainly covered by shallow eutric fluvisoils or variously deep eutric cambisoil. The hydrogeological parameters, e.g. the depth to the groundwater, hydrological role of the topographic slope, etc. usually used in different point count schemes are, in the case of the lowland aquifer and shallow groundwater, spatially very uniform with low variability. Furthermore, the parametric point count methods are generally not able to illustrate and analyze important physical processes, and validation of the results is difficult and expensive. Instead of a parametric point count scheme, we experimentally used the Arc-WofE extension for weights-of-evidence (WofE) modelling. All measurement locations with a concentration higher than the value of 20 mg NO₃ ⁻ per litre of groundwater have been considered as training points (173), and the three process-based models generalized output layers of groundwater recharge (GROWA), nitrate leached from the soil profile (SWAT) and groundwater flow velocity (FEFLOW), served as evidential themes. The technique is based on the Bayesian idea of phenomena occurrences probability before (prior probability) and after consideration of any evidential themes (posterior probability), which were measured by positive and negative weights as an indication of the association between a phenomena and a prediction pattern. The response theme values describe the relative probability that a 100 × 100 m spatial unit will have a groundwater nitrate concentration higher than the training points’ limit values with regard to prior probability value. The lowest probability of groundwater nitrate occurrence is in the parts of the LSV aquifer, which are known as anoxic condition areas with very likely denitrification processes. The cross-validation of the dissolved oxygen and dissolved nitrate response theme confirmed the accuracy of the groundwater nitrate prediction. The WofE model results very clearly indicate regional groundwater nitrate distribution and enable spatial prediction of the probability for increased groundwater nitrate concentration in order to plan the groundwater nitrate reduction measures and optimize the programme for monitoring the effects of these measures.  相似文献   

Chemistry of the Ferraria thermal water, S. Miguel Island, Azores: mixing and precipitation processes   总被引：1，自引：1，他引：0  

Maria do Rosário Carvalho  António Mateus  Jo?o C. Nunes  José M. Carvalho 《Environmental Earth Sciences》2011,64(2):539-547

The Ferraria thermal water emerges at the sea level in the Ferraria lava delta (western edge of S. Miguel Island, Azores) with temperature of ca. 60°C and pH varying between 5.4 and 6.2. It is of sodium chloride type, resulting from ca. 50% seawater mixing with an acid brackish, at ≈100°C, denoting the presence of significant CO₂(g) and the progress of water–rock interactions in open system conditions. The thermal Na–Cl water is strongly enriched with Sr and Mn and, comparatively, has low concentrations in Al, Fe and As. These elements are removed from the solution as critical conditions for the formation of several neo-formed mineral phases are gradually attained. Thermodynamic equilibrium calculations are consistent with this interpretation, showing that the thermal fluid can precipitate Fe³⁺-(hydr-)oxides, kaolinite and non-crystalline silica. Wells logging show fracture planes and pores fully/partly filled up with polyphase botryoidal aggregates mostly composed of goethite + ferrihydrite and displaying variable adsorbed contents of Si, P and As. These neo-formed phases result from the pristine fluid oxidation due to seawater mixing; its precipitation is easily affected by pH and redox variations of the brackish, due to volcanic gases pressure alterations, and fluid pressure or flow-velocity oscillation in the fractured aquifer.  相似文献   

Delivery and deposition of organic matter in surface sediments of Lagoa do Caçó (Brazil)     

Abdelfettah Sifeddine  Renato Campello Cordeiro

  Ana Luiza S. Albuquerque
  Marcelo Bernardes
  Bruno Turcq
  Jorge João Abrão
《Journal of Paleolimnology》2011,45(3):385-396

Elemental and isotopic compositions of organic matter in surficial sediments from five transects across Lagoa do Caçó (Brazil) were analyzed to identify the depth-related processes that affect the production and deposition of sedimentary organic matter in this shallow tropical lake. Each of four transverse transects began at a margin dominated by aquatic macrophytes (Eleocharis), crossed the central deep part of the lake, and terminated in the opposite, macrophyte-dominated margin. In each transect, TOC concentrations, C/N ratios, and δ¹³C values decreased between 0 and 4 m, whereas δ¹⁵N values increased. The variables remained stable in sediment from 4 m water depth to the center of the lake at 10 m. The depth-related patterns reflect differences in both the delivery and the deposition of organic matter in the lake. Organic matter is produced in abundance in the marginal area by emersed and submerged macrophyte vegetation that diminishes with depth and disappears at 4 meters. After the disappearance of macrophytes, organic matter is produced at low rates principally by open-lake phytoplankton. Drawdown of dissolved oxygen is high in the lake margins, but it is low in the oligotrophic open waters of the lake. Preservation of organic matter is consequently better in sediments of the lake margins than in deep waters. The depth-related pattern of organic matter delivery and deposition in the sediments of Lagoa do Caçó, in which water levels are sensitive to groundwater fluctuations, shows that the elemental and isotopic compositions of sediment organic matter can provide a record of changes in the paleohydrology of this and other similar shallow lake systems.  相似文献   

Isotope geochemistry of Paleoproterozoic metacarbonates from Itatuba,Borborema Province,Northeastern Brazil: Evidence of marble melting within a collisional suture     

Roberto Ventura Santos  Edilton J. dos Santos  João Adauto de Souza Neto  Luis Christian Montreuil Carmona  Alcides Nóbrega Sial  Luis Henrique Mancini  Lauro Cézar Montefalco de Lira Santos  Gilzênia Henrique do Nascimento  Lucas UpaDafubigin Santos Mendes  Emerson Marcello Ferreira Anastácio 《Gondwana Research》2013,23(1):380-389

Strongly-deformed marbles may be easily confused with linear and elongated carbonatite intrusions. Both rocks may present similar texture and foliation to the host rock, or even cross cutting field relationships, which could be interpreted either as igneous or high-grade metamorphosed marble. Diagnostic criteria are even more complex when there is evidence of melting of the metasedimentary carbonate rock, such as has been described in the Himalayas and in the Eastern Ghats, India.In the Alto Moxotó Terrane, a high-grade gneissic domain of the Borborema Province, Northeastern Brazil, there are metacarbonates associated with banded gneisses and different metaplutonic rocks. Field evidence indicates the absence of other metasedimentary rocks associated with these marbles, thus suggesting that these carbonates were separated from other siliciclastic metasedimentary rocks. The presence of marble also suggests that it may represent the initial stage of a crustal carbon recycling into the mantle. These marbles present many field similarities to carbonatites (e.g., fluid-flow structure) and, together with metagranites and metamafic intrusions, may represent a major collisional tectonic suture.A detailed study of the carbon, oxygen and strontium isotopic composition of these marbles is presented. This study aims to identify the origin of the different isotopic components. It is argued that these rocks were subjected to temperature and pressure conditions that were sufficiently high to have melted them. The isotopic data presented here support this interpretation and indicate the mixing of two components: (i) one characterized by radiogenic Sr isotopes and mantle-like carbon isotopes, which is associated with the gneissic and mafic rocks, and (ii) another characterized by low ⁸⁷Sr/⁸⁶Sr ratios and highly positive δ¹³C values. Available geochemical data for the upper Paleoproterozoic indicate that the ⁸⁷Sr/⁸⁶Sr ratio of ocean water, varying between 0.7050 (2.25 ± 0.25 Ga) and 0.7047 (1.91 Ga), falls within the lower range of the samples from Itatuba and thus reinforces the interpretation that these marbles are sedimentary-derived and were partially contaminated by interaction with the host gneissic and mafic rocks.  相似文献   

The Value of Information in Mineral Exploration Within a Multi-Gaussian Framework     

Jo Eidsvik  Steinar L. Ellefmo 《Mathematical Geosciences》2013,45(7):777-798

In mineral resource evaluation a careful analysis and assessment of the geology, assay data and structural data is required. One important question is where to position the exploration boreholes, another is what method to use when analyzing the grade in the collected material. Here, a challenge of this type is whether one should analyze the collected core samples with accurate and expensive lab equipment or a simpler hand-held meter. A dataset of about 2000 oxide observations is available, along with relevant explanatory variables, from a deposit in Norway. A Gaussian geostatistical model is used to predict the grade parameter on block support. To improve the predictions, several new boreholes are planned, giving 265 additional samples. The associated uncertainty reduction is evaluated, and a resource evaluation is performed with and without the planned data. Then the value of information of the planned data is computed, using assumed costs, recovery rates and revenues. The data acquired with the hand-held meter has almost the same value as the more expensive acquisition strategy, given that the already established correlation between the two datasets is valid.  相似文献