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Composite granite–quartz veins occur in retrogressed ultrahigh pressure (UHP) eclogite enclosed in gneiss at General's Hill in the central Sulu belt, eastern China. The granite in the veins has a high‐pressure (HP) mineral assemblage of dominantly quartz+phengite+allanite/epidote+garnet that yields pressures of 2.5–2.1 GPa (Si‐in‐phengite barometry) and temperatures of 850–780°C (Ti‐in‐zircon thermometry) at 2.5 GPa (~20°C lower at 2.1 GPa). Zircon overgrowths on inherited cores and new grains of zircon from both components of the composite veins crystallized at c. 221 Ma. This age overlaps the timing of HP retrograde recrystallization dated at 225–215 Ma from multiple localities in the Sulu belt, consistent with the HP conditions retrieved from the granite. The εHf(t) values of new zircon from both components of the composite veins and the Sr–Nd isotope compositions of the granite consistently lie between values for gneiss and eclogite, whereas δ18O values of new zircon are similar in the veins and the crustal rocks. These data are consistent with zircon growth from a blended fluid generated internally within the gneiss and the eclogite, without any ingress of fluid from an external source. However, at the peak metamorphic pressure, which could have reached 7 GPa, the rocks were likely fluid absent. During initial exhumation under UHP conditions, exsolution of H2O from nominally anhydrous minerals generated a grain boundary supercritical fluid in both gneiss and eclogite. As exhumation progressed, the volume of fluid increased allowing it to migrate by diffusing porous flow from grain boundaries into channels and drain from the dominant gneiss through the subordinate eclogite. This produced a blended fluid intermediate in its isotope composition between the two end‐members, as recorded by the composite veins. During exhumation from UHP (coesite) eclogite to HP (quartz) eclogite facies conditions, the supercritical fluid evolved by dissolution of the silicate mineral matrix, becoming increasingly solute‐rich, more ‘granitic’ and more viscous until it became trapped. As crystallization began by diffusive loss of H2O to the host eclogite concomitant with ongoing exhumation of the crust, the trapped supercritical fluid intersected the solvus for the granite–H2O system, allowing phase separation and formation of the composite granite–quartz veins. Subsequently, during the transition from HP eclogite to amphibolite facies conditions, minor phengite breakdown melting is recorded in both the granite and the gneiss by K‐feldspar+plagioclase+biotite aggregates located around phengite and by K‐feldspar veinlets along grain boundaries. Phase equilibria modelling of the granite indicates that this late‐stage melting records P–T conditions towards the end of the exhumation, with the subsolidus assemblage yielding 0.7–1.1 GPa at <670°C. Thus, the composite granite–quartz veins represent a rare example of a natural system recording how the fluid phase evolved during exhumation of continental crust. The successive availability of different fluid phases attending retrograde metamorphism from UHP eclogite to amphibolite facies conditions will affect the transport of trace elements through the continental crust and the role of these fluids as metasomatic agents interacting with the mantle wedge in the subduction channel.  相似文献   
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New activity–composition (ax) relations for minerals commonly occurring in metapelites are presented for use with the internally consistent thermodynamic dataset of Holland & Powell ( 2011 , Journal of Metamorphic Geology, 29 , 333–383). The ax relations include a broader consideration of Fe2O3 in minerals, changes to the formalism of several phases and order–disorder in all ferromagnesian minerals where Fe–Mg mixing occurs on multiple sites. The ax relations for chlorite, biotite, garnet, chloritoid, staurolite, cordierite, orthopyroxene, muscovite, paragonite and margarite have been substantially reparameterized using the approach outlined in the companion paper in this issue. For the first time, the entire set of ax relations for the common ferromagnesian minerals in metapelitic rocks is parameterized simultaneously, with attention paid to ensuring that they can be used together to calculate phase diagrams of geologically appropriate topology. The ax relations developed are for use in the Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O–TiO2–O2 (NCKFMASHTO) system for both subsolidus and suprasolidus conditions. Petrogenetic grids in KFMASH and KFMASHTO are similar in topology to those produced with earlier end‐member datasets and ax relations, but with some notable differences. In particular, in subsolidus equilibria, the FeO/(FeO + MgO) of garnet is now greater than in coexisting staurolite, bringing a number of key staurolite‐bearing equilibria into better agreement with inferences from field and petrographic observations. Furthermore, the addition of Fe3+ and Ti to a number of silicate phases allows more plausible equilibria to be calculated in relevant systems. Pseudosections calculated with the new ax relations are also topologically similar to equivalent diagrams using earlier ax relations, although with many low variance fields shifting in PT space to somewhat lower pressure conditions.  相似文献   
55.
Incipient charnockites have been widely used as evidence for the infiltration of CO2‐rich fluids driving dehydration of the lower crust. Rocks exposed at Kakkod quarry in the Trivandrum Block of southern India allow for a thorough investigation of the metamorphic evolution by preserving not only orthopyroxene‐bearing charnockite patches in a host garnet–biotite felsic gneiss, but also layers of garnet–sillimanite metapelite gneiss. Thermodynamic phase equilibria modelling of all three bulk compositions indicates consistent peak‐metamorphic conditions of 830–925 °C and 6–9 kbar with retrograde evolution involving suprasolidus decompression at high temperature. These models suggest that orthopyroxene was most likely stabilized close to the metamorphic peak as a result of small compositional heterogeneities in the host garnet–biotite gneiss. There is insufficient evidence to determine whether the heterogeneities were inherited from the protolith or introduced during syn‐metamorphic fluid flow. U–Pb geochronology of monazite and zircon from all three rock types constrains the peak of metamorphism and orthopyroxene growth to have occurred between the onset of high‐grade metamorphism at c. 590 Ma and the onset of melt crystallization at c. 540 Ma. The majority of metamorphic zircon growth occurred during protracted melt crystallization between c. 540 and 510 Ma. Melt crystallization was followed by the influx of aqueous, alkali‐rich fluids likely derived from melts crystallizing at depth. This late fluid flow led to retrogression of orthopyroxene, the observed outcrop pattern and to the textural and isotopic modification of monazite grains at c. 525–490 Ma.  相似文献   
56.
The Ediacaran Jibalah Group comprises volcano‐sedimentary successions that filled small fault‐bound basins along the NW–SE‐trending Najd fault system in the eastern Arabian‐Nubian Shield. Like several other Jibalah basins, the Antaq basin contains exquisitely preserved sedimentary structures and felsic tuffs, and hence is an excellent candidate for calibrating late Ediacaran Earth history. Shallow‐marine strata from the upper Jibalah Group (Muraykhah Formation) contain a diversity of load structures and intimately related textured organic (microbial) surfaces, along with a fragment of a structure closely resembling an Ediacaran frond fossil and a possible specimen of Aspidella. Interspersed carbonate beds through the Muraykhah Formation record a positive δ13C shift from ?6 to 0‰. U‐Pb zircon geochronology indicates a maximum depositional age of ~570 Ma for the upper Jibalah Group, consistent with previous age estimates. Although this age overlaps with that of the upper Huqf Supergroup in nearby Oman, these sequences were deposited in contrasting tectonic settings on opposite sides of the final suture of the East African Orogen.  相似文献   
57.
We studied a data set of 28 well‐preserved lunar craters in the transitional (simple‐to‐complex) regime with the aim of investigating the underlying cause(s) for morphological differences of these craters in mare versus highland terrains. These transitional craters range from 15 to 42 km in diameter, demonstrating that the transition from simple to complex craters is not abrupt and occurs over a broad diameter range. We examined and measured the following crater attributes: depth (d), diameter (D), floor diameter (Df), rim height (h), and wall width (w), as well as the number and onset of terraces and rock slides. The number of terraces increases with increasing crater size and, in general, mare craters possess more terraces than highland craters of the same diameter. There are also clear differences in the d/D ratio of mare versus highland craters, with transitional craters in mare targets being noticeably shallower than similarly sized highland craters. We propose that layering in mare targets is a major driver for these differences. Layering provides pre‐existing planes of weakness that facilitate crater collapse, thus explaining the overall shallower depths of mare craters and the onset of crater collapse (i.e., the transition from simple to complex crater morphology) at smaller diameters as compared to highland craters. This suggests that layering and its interplay with target strength and porosity may play a more significant role than previously considered.  相似文献   
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Water temperature (Tw) is a key determinant of freshwater ecosystem status and cause for concern under a changing climate. Hence, there is growing interest in the feasibility of moderating rising Tw through management of riparian shade. The Loughborough University Temperature Network (LUTEN) is an array of 36 water and air temperature (Ta) monitoring sites in the English Peak District set‐up to explore the predictability of local Tw, given Ta, river reach, and catchment properties. Year 1 of monitoring shows that 84%–94% of variance in daily Tw is explained by Ta. However, site‐specific logistic regression parameters exhibit marked variation and dependency on upstream riparian shade. Perennial spring flows in the lower River Dove also affect regression model parameters and strongly buffer daily and seasonal mean Tw. The asymptote of the models (i.e. maximum expected Tw) is particularly sensitive to groundwater inputs. We conclude that reaches with spring flows potentially offer important thermal refuges for aquatic organisms against expected long‐term warming of rivers and should be afforded special protection. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   
60.
Topographic maps and aerial photographs are particularly useful when geoscientists are faced with fieldwork tasks such as selecting paths for observation, establishing sampling schemes, or defining field regions. These types of images are crucial in bedrock geologic mapping, a cognitively complex field-based problem-solving task. Geologic mapping requires the geologist to correctly identify rock types and three-dimensional bedrock structures from often partial or poor-quality outcrop data while navigating through unfamiliar terrain. This paper compares the walked routes of novice to expert geologists working in the field (n = 66) with the results of a route planning and navigation survey of a similar population of geologists (n = 77). Results show clearly that those geologists with previous mapping experience make quick and decisive determinations about field areas from available imagery and maps, regardless of whether they are or not physically present in the field area. Recognition of geologic features enabled experts to form and verbalize a specific plan for travel through a landscape based on those features. Novices were less likely to develop specific travel route plans and were less likely to identify critical landscape cues from aerial photographs.  相似文献   
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