An aromatase inhibitor and tamoxifen decrease plasma levels of o,p'-DDT and its metabolites in Nile tilapia (Oreochromis niloticus)     

Leaños-Castañeda O  Gold-Bouchot G  Van Der Kraak G  Lister A  Ceja-Moreno V  Simá-Alvarez R 《Marine environmental research》2004,58(2-5):337-342

The objective of this study was to determine if tamoxifen or an aromatase inhibitor (4-hydroxyandrostenedione; 4-OHA) affected plasma concentrations of o,p' -DDT and its metabolites, o,p'-DDD and o,p'-DDE, in mature tilapia. Male and female tilapia were injected 6 times intraperitoneally with o,p'-DDT (40 mg/kg) alone or in combination with 4-OHA (2 mg/kg) over a 12 day period. An additional group of male fish was injected with tamoxifen (5 mg/kg) plus o,p'-DDT. At the end of the treatment period, plasma samples were extracted and analyzed by GC/ECD. Females injected only with o,p'-DDT had significantly higher levels of o,p'-DDT compared with males. Interestingly, females and males treated concomitantly with o,p'-DDT and 4-OHA or tamoxifen had significantly lower concentrations of plasma o,p'-DDT (about 50%) compared with fish treated with only o,p'-DDT. These initial results suggest that an interaction between endocrine-active compounds occurs in vivo in tilapia and may involve alterations in metabolism of o,p'-DDT.  相似文献   

A comparative mineralogical study of gas-related sediments of the Gulf of Cádiz     

C. Martín-Puertas  M. P. Mata  M. C. Fernández-Puga  V. Díaz del Río  J. T. Vázquez  L. Somoza 《Geo-Marine Letters》2007,27(2-4):223-235

The Gulf of Cádiz area has been extensively surveyed in recent years and several gas-related fluid escape seafloor structures have been identified. In this study, gravity cores, collected during the ANASTASYA/00 and ANASTASYA/01 cruises, on mud volcanoes, hemipelagic sediments and dredged material from diapiric structures, have been studied. A comparative mineralogical analysis by XRD and SEM of samples from different areas has been performed in order to determine whether there is a characteristic mineralogy related to these fluid escape structures, and also to determine the origin of the mud matrix and constrain the depth of the parent units. The mineralogical analysis reflects the different origins of the different units described in the cores: hemipelagic material of the slope, clays that underlie the mud volcanoes and are discharged at the sea bottom surface, and authigenic and diagenetic minerals possibly involved in the anaerobic oxidation of methane in the mud volcano sediments.  相似文献   

Mercury speciation in surface and deep waters of the Mediterranean Sea     

Jože Kotnik  Milena Horvat  Emmanuel Tessier  Nives Ogrinc  Mathilde Monperrus  David Amouroux  Vesna Fajon  Darija Gibičar  Suzana Žižek  Francesca Sprovieri  Nicola Pirrone 《Marine Chemistry》2007

Mercury speciation and its distribution in surface and deep waters of the Mediterranean Sea were studied during two oceanographic cruises on board the Italian research vessel URANIA in summer 2003 and spring 2004 as part of the Med Oceaneor and MERCYMS projects. The study included deep water profiles of dissolved gaseous Hg (DGM), reactive Hg (RHg), total Hg (THg), monomethyl Hg (MeHg) and dimethyl Hg (DMeHg) in open ocean waters. Average concentrations of measured Hg species were characterized by seasonal and spatial variations. Overall average THg concentrations ranged between 0.41 and 2.65 pM (1.32 ± 0.48 pM) and were comparable to those obtained in previous studies of the Mediterranean Sea. A significant fraction of Hg was present as “reactive” Hg (average 0.33 ± 0.32 pM). Dissolved gaseous Hg (DGM), which consists mainly of Hg⁰, represents a considerable proportion of THg (average 20%, 0.23 ± 0.11 pM). The portion of DGM typically increased towards the bottom, especially in areas with strong tectonic activity (Alboran Sea, Strait of Sicily, Tyrrhenian Sea), indicating its geotectonic origin. No dimethyl Hg was found in surface waters down to the depth of 40 m. Below this depth, its average concentration was 2.67 ± 2.9 fM. Dissolved fractions of total Hg and MeHg were measured in filtered water samples and were 0.68 ± 0.43 pM and 0.29 ± 0.17 pM for THg and MeHg respectively. The fraction of Hg as MeHg was in average 43%, which is relatively high compared to other ocean environments. The concentrations reported in this study are among the lowest found in marine environments and the quality of analytical methods are of key importance. Speciation of Hg in sea water is of crucial importance as THg concentrations alone do not give adequate data for understanding Hg sources and cycling in marine environments. For example, photoinduced transformations are important for the presence of reactive and elemental mercury in the surface layers, biologically mediated reactions are important for the production/degradation of MeHg and DGM in the photic zones of the water column, and the data for DGM in deep sea indicate the natural sources of Hg in geotectonicaly active areas of the Mediterranean Sea.  相似文献   

Onshore Neogene stratigraphy in the North of the Alboran Sea (Betic Internal Zones): Paleogeographic implications     

J. Rodríguez Fernández  C. Sanz de Galdeano 《Geo-Marine Letters》1992,12(2-3):123-128

The Neogene is the period in which the Betic Cordillera, the Rif, and the Alboran Sea acquired their present configuration. The Neogene sediments of the Betic Internal Zones (located directly to the North of the Alboran Sea) show the effects of important periods of deformation. Deposition was clearly controlled by tectonics. Therefore the generation, evolution, and total or partial destruction of basins and the formation of new, often superimposed, basins are common phenomena, according to the locations of the basins in the Betic Cordillera and to the different geodynamic situations.  相似文献   

Phosphate adsorption and desorption in a tropical estuary (Maracaibo system)     

D. López-Hernández  T. Herrera  F. Rotondo 《Marine environmental research》1980,4(2):153-163

The Maracaibo Estuary is of particular interest because of its location in the tropics, its large size (over 12,000 km²), the economic importance of its underlying hydrocarbon deposits and its increasing rate of pollution. Sediments from this estuary were studied in order to characterise their capacity to adsorb and desorb phosphorus. Considerable variability in capacity for phosphate sorption was found among the seventeen samples studied. This variability can be attributed first to the differences among the samples in total P content and, secondly, to their differences in free iron content. Also, it appears that P retention contributes to the control of P concentration in the water and therefore the sediments serve as a buffer in controlling P eutrophication in the estuary.  相似文献   

Three-Dimensional Velocity Field and Cross-Frontal Water Exchange in the Kuroshio Extension     

Susana Sainz-Trápaga  Takashige Sugimoto 《Journal of Oceanography》2000,56(1):79-92

A spread of warm water from the first crest of the Kuroshio Extension is periodically enhanced by northward warm water intrusions from the main current. The water type in the spread area was previously found to be the same as that in the Kuroshio front at depth. In looking for the possible mechanism responsible for the northward warm water intrusions, a dynamic analysis in the Kuroshio front was carried out by using CTD, ADCP, AVHRR and ARGOS buoy data, obtained in 1996 by the R.V. Hakuho Maru. Downstream, cross-stream and vertical velocities in the Kuroshio Extension were found by using a "stream coordinate system". The velocity field in the Kuroshio front at the first crest showed a double structure with two surface velocity maxima. In the inner part of the front, relatively high cross-stream (northward) and vertical (upward) velocities were found. Thus, this study suggests that while water particles flow downstream along the first stationary meander of the Kuroshio Extension, they also experience lateral and vertical movements which allow the deeper water from an upstream location to rise to the surface layer, and in certain locations to deflect northward. By assuming isopycnal movement and conservation of potential vorticity, it was found that in those locations where anticyclonic curvature of the meander increases, warm water is more likely to deflect northward. High ageostrophic components observed in the first 300 m of the water column are probably related to the relatively high cross-stream and vertical velocities in the inner part of the front.  相似文献   

The Equatorial Atlantic Mid-Ocean Channel: An Ultra High-Resolution Image of Its Burial History Based on TOPAS Profiles     

Baraza  J.  Ercilla  G.  Farrán  M.  Casamor  J. L.  Sorribas  J.  Flores  J. A.  Sierro  F.  Wersteeg  W. 《Marine Geophysical Researches》1997,19(2):115-135

Multibeam bathymetric and ultra high-resolution seismic data reveal that the distal course of the Equatorial Atlantic Mid-Ocean Channel (EAMOC) extends further east and south than was previously known, and is controlled by the presence of morphologic highs related to the Fernando de Noronha Fracture Zone. Distal course of the EAMOC is buried by sediments, and does not have bathymetric expression on the seafloor. The channel fill consists of three seismic sequences, suggesting that the recent geological evolution of the channel is composed of successive phases of decreasing sedimentary activity that finally resulted in its complete burial. Tectonic and volcanic activity related to the Fernando de Noronha Fracture Zone and Ridge, together with the effect of strong pulses of the Antarctic bottom water current during the upper Pliocene are suggested to have contributed to the progressive burial and the final abandonment of the EAMOC.  相似文献   

Geodynamic Evolution of the Eastern Segment of the Azores-Gibraltar Zone: The Gorringe Bank and the Gulf of Cadiz Region     

Tortella  D.  Torne  M.  Pérez-Estáun  A. 《Marine Geophysical Researches》1997,19(3):211-230

Detailed structural interpretation of the recently acquired deep seismic multichannel profiles along the Iberian Atlantic Margins (IAM Project) provides new results on the geodynamic evolution of the eastern part of the Azores-Gibraltar plate boundary. Thrusting and folding of the oceanic basement and of Mesozoic and Cenozoic sedimentary cover of the Gorringe Bank region are consistent with the N–S convergence of Iberia and Africa. Compressive structures in the Gorringe Bank region are spread over a wide area. Deformation under compression took place mainly in Tertiary times, as is evidenced by a basal unconformity and several discontinuities in Tertiary sediments, although some deformation has also been recorded in Quaternary sediments. The compressive structures in the Gulf of Cadiz are E–W oriented thrusts, folds and related diapiric structures. N–S oriented transpressive deformation is likely to occur in the western Portuguese platform. There is no continuity of structures from the oceanic to the continental domain, suggesting that deformation transfers from one side to the other through a transcurrent fault zone. The fault contact between the two domains is located in the ocean-continent transition zone.  相似文献   

Miocene extensional detachments in the outcropping basement of the northern Alboran Basin (Betics) and their tectonic implications     

V. García-Dueñas  J. C. Balanyá  J. M. Martínez-Martínez 《Geo-Marine Letters》1992,12(2-3):88-95

Whether or not there are extensional detachment faults in the Alboran basement can be tested directly because a part of the Alboran Basin is now emerged. These detachments, related to crustal thinning beneath the Alboran Basin, occurred from the Aquitanian to Tortonian. The resulting extensional geometries can be described in general terms. During the Serravalian a considerable southwest extension of the basin took place, accompanied by south-southeast extension in the northern Gibraltar Arc. Other detachments affected by Serravalian extension can be found. The spreading of the Alboran was nearly coeval with roughly westward migration of the Gibraltar mountain front.  相似文献   

Stratigraphic framework of gas accumulations in the Ría de Pontevedra (NW Spain)     

Ruth Durán  Soledad García-Gil  Raquel Diez  Federico Vilas 《Geo-Marine Letters》2007,27(2-4):77-88

Knowledge of marine geological environments in which shallow gas is accumulating is becoming increasingly important in global studies of climate change because a measurable proportion of the total methane source comes from continental margins. Previous studies have revealed that coastal environments represent important geological environments where microbial methane is being generated, is accumulating, and is being released. In the Ría de Pontevedra, at least 4.5 km² of seafloor in the innermost part of the ría is underlain by sediments containing natural gas. Seismic interpretation contributes new findings for the definition of periods and geological environments in which the gas could have been generated, and is accumulating and released in the Ría de Pontevedra. Groundtruthing the seismic data (facies, environments) makes it possible to identify favourable geological environments for gas generation in the sedimentary infill of the Ría de Pontevedra. Sequence stratigraphy based on high-resolution seismic profiles and post-Last Glacial Maximum sea-level records makes it possible to establish the stratigraphic architecture of the ría and to define the periods in which gas could have been generated. The results of this study show that the sedimentary infill is composed of a fifth-order sequence developed since the Last Glacial Maximum. Within this sequence, gas appears to have accumulated in the Holocene deposits associated with the latest transgressive and highstand system tracts. Seismic analysis shows that gas could have been generated in different geological environments in the Ría de Pontevedra. If coastal environments at times of lower sea level were similar to those of the present, organic-rich mud deposits (deposited mainly in lakes, estuaries and floodplains) could have survived transgression and remained buried as potential gas sources in the inner part of the ría.  相似文献