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31.
The team behind a successful project to broaden the understanding of astrochemistry – Serena Viti, Wendy Brown, Martin McCoustra, Helen Fraser, Nigel Mason and Robert Massey – recount how they went about it and what benefits resulted.  相似文献   
32.
This study explores the fractionation of iron isotopes (57Fe/54Fe) in an organic-rich mudstone succession, focusing on core and outcrop material sampled from the Upper Jurassic Kimmeridge Clay Formation type locality in south Dorset, UK. The organic-rich environments recorded by the succession provide an excellent setting for an investigation of the mechanisms by which iron isotopes are partitioned among mineral phases during biogeochemical sedimentary processes.Two main types of iron-bearing assemblage are defined in the core material: mudstones with calcite ± pyrite ± siderite mineralogy, and ferroan dolomite (dolostone) bands. A cyclic data distribution is apparent, which reflects variations in isotopic composition from a lower range of δ57Fe values associated with the pyrite/siderite mudstone samples to the generally higher values of the adjacent dolostone samples. Most pyrite/siderite mudstones vary between −0.4 and 0.1‰ while dolostones range between −0.1 and 0.5‰, although in very organic-rich shale samples below 360 m core depth higher δ57Fe values are noted. Pyrite nodules and pyritized ammonites from the type exposure yield δ57Fe values of −0.3 to −0.45‰. A fractionation model consistent with the δ57Fe variations relates the lower δ57Fe pyrite and siderite ± pyrite mudstones values to the production of isotopically depleted Fe(II) during biogenic reduction of the isotopically heavier lithogenic Fe(III) oxides. A consequence of this reductive dissolution is that a 57Fe-enriched iron species must be produced that potentially becomes available for the formation of the higher δ57Fe dolostones. An isotopic profile across a dolostone band reveals distinct zonal variations in δ57Fe, characterized by two peaks, respectively located above and below the central part of the band, and decoupling of the isotopic composition from the iron content. This form of isotopic zoning is shown to be consistent with a one-dimensional model of diffusional-chromatographic Fe-isotope exchange between dolomite and isotopically enriched pore water. An alternative mechanism envisages the infiltration of dissolved ferrous iron from variable (high and low) δ57Fe sources during coprecipitation of Fe(II) ion with dolomite. The study provides clear evidence that iron isotopes are cycled during the formation and diagenesis of organic carbon-rich sediments.  相似文献   
33.
Women in many rural areas of the US often engage in small-scale businesses as one of several avenues for contributing to household incomes. In those geographical areas that contain a significant minority population, many of the women's businesses display the cultural diversity of the regions in which they live. Likewise, women's roles as economic providers as well as wives and mothers are reflected in the manner in which they operate their businesses. Candida Brush suggests that women's strategies for operating their businesses are highly integrative because women's business decisions are intertwined with familial responsibilities, household economic demands and desires to contribute to their communities. Hispanic and Native American women in the Four Corners region of southwestern US and African American women in central Virginia participated in interviews in which they responded to numerous short answer and open-ended questions about their businesses and decision-making strategies. From these interviews an image emerges of rural minority business women who are operating their businesses at the nexus of family obligations, economic necessities, cultural ties and with a commitment for serving their communities. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   
34.
35.
New satellite technology to measure changes in the Earth’s gravity field gives new possibilities to detect layers of low viscosity inside the Earth. We used density models for the Earth mantle based on slab history as well as on tomography and fitted the viscosity by comparison of predicted gravity to the new CHAMP gravity model. We first confirm that the fit to the observed geoid is insensitive to the presence of a low viscosity anomaly in the upper mantle as long as the layer is thin ( 200 km) and the viscosity reduction is less than two orders of magnitude. Then we investigated the temporal change in geoid by comparing two stages of slablet sinking based on subduction history or by advection of tomography derived densities and compared the spectra of the geoid change for cases with and without a low viscosity layer, but about equal fit to the observed geoid. The presence of a low viscosity layer causes relaxation at smaller wavelength and thus leads to a spectrum with relatively stronger power in higher modes and a peak around degrees 5 and 6. Comparing the spectra to the expected degree resolution for GRACE data for a 5 years mission duration shows a weak possibility to detect changes in the Earth’s gravity field due to large scale mantle circulation, provided that other causes of geoid changes can be taken into account with sufficient accuracy. A discrimination between the two viscosity cases, however, demands a new generation of gravity field observing satellites.  相似文献   
36.
The 1998 eruption of Volcán Cerro Azul in the Galápagos Islands produced two intra-caldera vents and a flank vent that erupted more than 1.0×108 m3 of lava. Lava compositions changed notably during the 5-week eruption, and contemporaneous eruptions in the caldera and on the flank produced different compositions. Lavas erupted from the flank vent range from 6.3 to 14.1% MgO, nearly the entire range of MgO contents previously reported from the volcano. On-site monitoring of eruptive activity is linked with petrogenetic processes such that geochemical variations are evaluated in a temporal context. Lavas from the 1998 eruption record two petrogenetic stages characterized by progressively more mafic lavas as the eruption proceeded. Crystal compositions, whole rock major and trace element compositions, and isotope ratios indicate that early lavas are the product of mixing between 1998 magma and remnant magma of the 1979 eruption. Intra-caldera lavas and later lavas have no 1979 signature, but were produced by the 1998 magma incorporating olivine and clinopyroxene xenocrysts. Thus, early magma petrogenesis is characterized by mixing with the 1979 magma, followed by the magma progressively entraining wehrlite cumulate mush.Editorial Responsibility: M.R. Carroll  相似文献   
37.
Models capable of estimating losses in future earthquakes are of fundamental importance for emergency planners, for the insurance and reinsurance industries, and for code drafters. Constructing a loss model for a city, region or country involves compiling databases of earthquake activity, ground conditions, attenuation equations, building stock and infrastructure exposure, and vulnerability characteristics of the exposed inventory, all of which have large associated uncertainties. Many of these uncertainties can be classified as epistemic, implying—at least in theory—that they can be reduced by acquiring additional data or improved understanding of the physical processes. The effort and cost involved in refining the definition of each component of a loss model can be very large, for which reason it is useful to identify the relative impact on the calculated losses due to variations in these components. A mechanically sound displacement‐based approach to loss estimation is applied to a test case of buildings along the northern side of the Sea of Marmara in Turkey. Systematic variations of the parameters defining the demand (ground motion) and the capacity (vulnerability) are used to identify the relative impacts on the resulting losses, from which it is found that the influence of the epistemic uncertainty in the capacity is larger than that of the demand for a single earthquake scenario. Thus, the importance of earthquake loss models which allow the capacity parameters to be customized to the study area under consideration is highlighted. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   
38.
This paper examines labour market behaviour of the highly skilled in high-tech local economies, taking the UK examples of Oxfordshire and Cambridgeshire as case studies. It reports on data from a survey of members of three scientific institutes to compare rates of employee mobility in the two locations and considers the likely explanations and implications of those patterns.  相似文献   
39.
Rare earth element (REE) adsorption onto sand from a well characterized aquifer, the Carrizo Sand aquifer of Texas, has been investigated in the laboratory using a batch method. The aim was to improve our understanding of REE adsorption behavior across the REE series and to develop a surface complexation model for the REEs, which can be applied to real aquifer-groundwater systems. Our batch experiments show that REE adsorption onto Carrizo sand increases with increasing atomic number across the REE series. For each REE, adsorption increases with increasing pH, such that when pH >6.0, >98% of each REE is adsorbed onto Carrizo sand for all experimental solutions, including when actual groundwaters from the Carrizo Sand aquifer are used in the experiments. Rare earth element adsorption was not sensitive to ionic strength and total initial REE concentrations in our batch experiments. It is possible that the differences in experimental ionic strength conditions (i.e., 0.002-0.01 M NaCl) chosen were insufficient to affect REE adsorption behavior. However, cation competition (e.g., Ca, Mg, and Zn) did affect REE adsorption onto Carrizo sand, especially for light rare earth elements (LREEs) at low pH. Rare earth element adsorption onto Carrizo sand can be successfully modeled using a generalized two-layer surface complexation model. Our model calculations suggest that REE complexation with strong surface sites of Carrizo sand exceeds the stability of the aqueous complexes LnOH2+, LnSO4+, and LnCO3+, but not that of Ln(CO3)2- or LnPO4o in Carrizo groundwaters. Thus, at low pH (<7.3), where major inorganic ligands did not effectively compete with surface sites for dissolved REEs, free metal ion (Ln3+) adsorption was sufficient to describe REE adsorption behavior. However, at higher pH (>7.3) where solution complexation of the dissolved REEs was strong, REEs were adsorbed not only as free metal ion (Ln3+) but also as aqueous complexes (e.g., as Ln(CO3)2- in Carrizo groundwaters). Because heavy rare earth elements (HREEs) were preferentially adsorbed onto Carrizo sand compared to LREEs, original HREE-enriched fractionation patterns in Carrizo groundwaters from the recharge area flattened along the groundwater flow path in the Carrizo Sand aquifer due to adsorption of free- and solution-complexed REEs.  相似文献   
40.
EU-US (European Union-United States) interactions in relation to the regulation of genetically modified organisms (GMOs) have been examined in detail in recent years. To do this scholars have tended to focus on a small number of high profile processes, such as the formal complaint of the US to the World Trade Organisation regarding the regulation of GMOs in the Europe. It is important to analyse developments of this kind but overemphasis on them has also lead to a distorted view of the case and a failure to appreciate the significance of other, less visible, types of interaction. In this paper we focus instead on trying to understand the roles played by various EU-US transnational networks—The Transatlantic Business Dialogue, The Transatlantic Economic Partnership, The Transatlantic Consumer Dialogue, The Transatlantic Environmental Dialogue and the EU-US Consultative Forum on Biotechnology. These networks have been trying to shape the regulation of GMOs in both jurisdictions since the mid 1990s. By analysing them through a ‘governance lens’ we find that we can better understand EU-US interactions and the dynamics and influences around the regulation of GMOs. This gives us valuable insights into processes of contemporary governance.  相似文献   
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