Implications of trace element composition of syntaxial quartz cements for the geochemical conditions during quartz precipitation in sandstones     

Thomas Götte  Karl Ramseyer  Thomas Pettke  Monika Koch‐Müller 《Sedimentology》2013,60(5):1111-1127

A petrographic investigation revealed polyphase quartz cementation in the Finefrau Sandstone (Upper Carboniferous, Western Germany) and the Solling Sandstone (Lower Triassic, Central Germany). Three different cements could be distinguished in each sandstone based on their cathodoluminescence and trace element composition. The first quartz generation is suggested to have been formed during eogenesis due to dissolution and replacement of feldspar. The mesogenetic paragenesis comprises two generations of quartz and illite, which are accompanied by albite in the Solling Sandstone. Sharp luminescence zoning in quartz overgrowths points to distinct episodes of cementation in both sandstones. Significant amounts of Al, Li and H and traces of Ge and B have been detected in the quartz overgrowths. The Al‐content of the quartz cements in the Finefrau Sandstones exceeds that in the quartz cements in the Solling Sandstone by a factor of five. It is suggested that this compositional variation reflects the conditions in the pore‐water, such as temperature and pH. The Al‐concentration is generally correlated to the Li‐content with the exception of the latest quartz generation in the Finefrau Sandstones which is also most enriched in trace elements. The ratio of Li/Al varies between 0·11 and 0·25 in the two sandstones. The Li/H‐ratio, which ranges from 0·12 to 0·3, is controlled by the activity ratio of Li and H in the pore fluid. Clay minerals are the most important source for Li and high salinities favour the mobilization of Li during diagenesis. Thus, a relatively low salinity and low pH are responsible for the low Li/H‐ratio in the Finefrau Sandstone, while high salinity and neutral to alkaline pH results in a high Li/H‐ratio for the Solling Sandstone. The Ge‐contents are generally near the average of detrital quartz and indicate that pressure dissolution is a major source for quartz cementation. Different chemical compositions of distinct quartz generations indicate changes in the physico‐chemical conditions and point to mobilization of silica from different sources (for example, pressure solution and clay mineral transformations).  相似文献   

Time–space continuity of daily maps of fractional snow cover and albedo from MODIS     

Jeff Dozier  Thomas H. Painter  Karl Rittger  James E. Frew 《Advances in water resources》2008

Using reflectance values from the seven MODIS “land” bands with 250 or 500 m resolution, along with a corresponding cloud product, we estimate the fraction of each 500 m pixel that snow covers, along with the albedo of that snow. The daily products have data gaps and errors because of cloud cover and sensor viewing geometry. Rather than make users interpolate and filter these patchy daily maps without completely understanding the retrieval algorithm and instrument properties, we use the daily time series to improve the estimate of the measured snow properties for a particular day. We use a combination of noise filtering, snow/cloud discrimination, and interpolation and smoothing to produce our best estimate of the daily snow cover and albedo. We consider two modes: one is the “predictive” mode, whereby we estimate the snow-covered area and albedo on that day using only the data up to that day; the other is the “retrospective” mode, whereby we reconstruct the history of the snow properties for a previous period.  相似文献   

A Bayesian approach to inverse modelling of stratigraphy, part 1: method   总被引：2，自引：0，他引：2  

Karl Charvin  Kerry Gallagher†  Gary L. Hampson  Richard Labourdette‡ 《Basin Research》2009,21(1):5-25

The inference of ancient environmental conditions from their preserved response in the sedimentary record still remains an outstanding issue in stratigraphy. Since the 1970s, conceptual stratigraphic models (e.g. sequence stratigraphy) based on the underlying assumption that accommodation space is the critical control on stratigraphic architecture have been widely used. Although these methods considered more recently other possible parameters such as sediment supply and transport efficiency, they still lack in taking into account the full range of possible parameters, processes, and their complex interactions that control stratigraphic architecture. In this contribution, we present a new quantitative method for the inference of key environmental parameters (specifically sediment supply and relative sea level) that control stratigraphy. The approach combines a fully non‐linear inversion scheme with a ‘process–response’ forward model of stratigraphy. We formulate the inverse problem using a Bayesian framework in order to sample the full range of possible solutions and explicitly build in prior geological knowledge. Our methodology combines Reversible Jump Markov chain Monte Carlo and Simulated Tempering algorithms which are able to deal with variable‐dimensional inverse problems and multi‐modal posterior probability distributions, respectively. The inverse scheme has been linked to a forward stratigraphic model, BARSIM (developed by Joep Storms, University of Delft), which simulates shallow‐marine wave/storm‐dominated systems over geological timescales. This link requires the construction of a likelihood function to quantify the agreement between simulated and observed data of different types (e.g. sediment age and thickness, grain size distributions). The technique has been tested and validated with synthetic data, in which all the parameters are specified to produce a ‘perfect’ simulation, although we add noise to these synthetic data for subsequent testing of the inverse modelling approach. These tests addressed convergence and computational‐overhead issues, and highlight the robustness of the inverse scheme, which is able to assess the full range of uncertainties on the inferred environmental parameters and facies distributions.  相似文献   

A Bayesian approach to inverse modelling of stratigraphy, part 2: Validation tests     

Karl Charvin  Gary J. Hampson  Kerry Gallagher†  Richard Labourdette‡ 《Basin Research》2009,21(1):27-45

A novel inverse modelling method is applied to the problem of constraining the environmental parameters (e.g. relative sea level, sediment supply) that control stratigraphic architecture. This technique links forward modelling of shallow-marine wave/storm-dominated stratigraphy to a combination of inverse methods formulated in a Bayesian framework. We present a number of examples in which relative sea-level and sediment-supply curves were inferred from synthetic vertical successions of grain size (e.g. wells) and synthetic thickness curves (e.g. seismically derived isopachs) extracted from a forward model simulation. These examples represent different scenarios that are designed to test the impact of data distribution, quantity and quality on the uncertainty of the inferred parameters. The inverse modelling approach successfully reproduces the gross stratigraphic architectures and relative sea level and sediment-supply histories of the synthetic forward model simulation, within the constraints of the modelled data quality. The relative importance of the forcing parameters can be evaluated by their sensitivity and impact on the inverted data. Of equal importance, the inverse results allow complete characterisation of the uncertainties inherent to the stratigraphic modelling tool and to the data quality, quantity and distribution. The numerical scheme also successfully deals with the problem of non-uniqueness of the solution of the inverse problem. These preliminary results suggest that the inverse method is a powerful tool in constraining stratigraphic architecture for hydrocarbon reservoir characterisation and modelling, and it may ultimately provide a process-based geological complement to standard geostatistical tools.  相似文献   

A parallel mesh-free contaminant transport model based on the Analytic Element and Streamline Methods     

Karl W. Bandilla  Alan J. RabideauIgor Janković 《Advances in water resources》2009

This paper introduces a new method for simulating large-scale subsurface contaminant transport that combines an Analytic Element Method (AEM) groundwater flow solution with a split-operator Streamline Method for modeling reactive transport. The key feature of the method is the manner in which the vertically integrated AEM flow solution is used to construct three-dimensional particle tracks that define the geometry of the Streamline Method. The inherently parallel nature of the algorithm supports the development of reactive transport models for spatial domains much larger than current grid-based methods. The applicability of the new approach is verified for cases with negligible transverse dispersion through comparisons to analytic solutions and existing numerical solutions, and parallel performance is demonstrated through a realistic test problem based on the regional-scale transport of agricultural contaminants from spatially distributed sources.  相似文献   

Delimiting the eastern extent of the Altyn Tagh Fault: Insights from structural analyses of seismic reflection profiles     

Yuqing Zhang  Fengqi Zhang  Xiaogan Cheng  Xiubin Lin  Hanlin Chen  Karl‐Heinz Wyrwoll  Lei Wu  Jie Chen  Bryan Krape  Yanchou Lu  Weiwei Ding  Kaixuan An  Yaguang Chen  Chunyang Li 《地学学报》2021,33(1):1-11

The Altyn Tagh Fault (ATF) serves as a key continental‐scale controlling structural element of the Tibetan Plateau. However, its eastward extent remains controversial. Here we use high‐resolution seismic reflection profiles to investigate the subsurface structures of the easternmost ATF and use these to delimit the easternmost extent of the fault. The structural analyses show an eastward geometric change from transpressional positive flower structures to compressional thrusts, with transpression‐induced shortening magnitudes decreasing eastwards from a maximum of ~5.3 km to being absent. Stratigraphic controls indicate that the deformation took place over the last ~<1.2 Ma. Our wider findings lead us to: (a) reject the suggestion that the ATF previously extended beyond the Kuantan Shan‐Hei Shan to link with the Alxa‐East Mongolia Fault; and (b) propose that the rigid block model used to describe the Tibetan Plateau crust is not consistent with the extent and structural details of the easternmost ATF.  相似文献   

Differences in vegetation characteristics with shoreline position on a tropical pocket beach     

Rosana Grafals-Soto  Karl F. Nordstrom  Nancy L. Jackson 《自然地理学》2020,41(4):315-331

ABSTRACT

Composition and richness of coastal vegetation differs with distance from the water and sheltering by topography. Transition from pioneer beach plants to mature forests is expected to be narrow on low wave energy coasts with a tropical climate favorable to vegetation growth. The goal of this paper is to determine whether vegetation on the beach and foredune will be denser and have a greater number of species and more woody shrubs near the water as wave and wind stresses diminish because of favorable shoreline orientation within a pocket beach. Field data on beach width, beach mobility, dune height, vegetation species, vegetation height and percent vegetation cover were collected in Puerto Rico along six cross-shore transects. Beaches are more stable at transects in the lee of an eolianite barrier and a tombolo. The vegetation gradient there is compressed, with denser, taller, more diverse vegetation and more tree species close to the waterline than at more exposed sites. The lack of mobility of the beaches and dunes and lack of geomorphically significant disturbance events is in contrast to the conspicuous feedbacks between overwash, topography, and vegetation on exposed mid-latitude coasts, revealing the need for more study of low-energy beach environments.  相似文献   

Liminosity distribution function for visual binary stars     

Karl D. Rakos 《Astrophysics and Space Science》1985,110(1):143-148

The cosmic scatter of 147 of the best known visual binary stars on the Main Sequence is discussed and a new estimation of the luminosity distribution function for multiple star systems is presented. As long as the mass ratioq of a close binary is not smaller than 0.5, the distribution of close binary components is identical to the van Rhijn liminosity-function. For smaller mass ratios (q<0.5) the number of close companions decreases rapidly. It appears that less than 13% of visual binaries in our sample are simple binary systems.Communication presented at the International Conference on Astrometric Binaries, held on 13–15 June, 1984, at the Remeis-Sternwarte Bamberg, Germany, to commemorate the 200th anniversary of the birth of Friedrich Wilhelm Bessel (1784–1846).  相似文献   

Demise of the northern Tethyan Urgonian carbonate platform and subsequent transition towards pelagic conditions: The sedimentary record of the Col de la Plaine Morte area, central Switzerland     

Karl B. Fllmi  Franois Gainon 《Sedimentary Geology》2008,205(3-4):142-159

The sedimentary succession of the Col de la Plaine Morte area (Helvetic Alps, central Switzerland) documents the disappearance of the northern Tethyan Urgonian platform in unprecedented detail and suggests stepwise platform demise, with each drowning phase documented by erosion and phosphogenesis. The first identified drowning phase terminated Urgonian carbonate production in a predominantly photozoan mode. Using a correlation of the whole-rock δ¹³C record with the well-dated record from SE France, its age is inferred to as Middle Early Aptian (near the boundary between the weissi and deshayesi zones). A subsequent drowning phase is dated by ammonites and by a correlation of the whole-rock δ¹³C record as Late Early Aptian (late deshayesi to early furcata zone). A third drowning phase provides an ammonite-based age of Early Late Aptian (subnodosocostatum and melchioris zones) and is part of a widely recognized phase of sediment condensation and phosphogenesis, which is dated as latest Early to Middle Late Aptian (late furcata zone to near the boundary of the melchioris and nolani zones). The fourth and final drowning phase started in the latest Aptian (jacobi zone) as is also indicated by ammonite findings at the Col de la Plaine Morte. The phases of renewed platform-carbonate production intervening between the drowning phases were all in a heterozoan mode.

During the ultimate drowning phase, phosphogenesis continued until the Early Middle Albian, whereas condensation processes lasted until the Middle Turonian. Coverage of the external margin of the drowned Urgonian platform by a drape of pelagic carbonates started only in the Late Turonian. During the Santonian, the external part of the drowned platform underwent normal faulting and saw the re-exposure of already lithified Urgonian carbonates at the seafloor.

Based on the here-inferred ages, the first drowning phase just precedes oceanic anoxic episode 1a (OAE 1a or “selli event”) in time, and the second drowning phase partly overlaps with OAE 1a. The onset of the third drowning event slightly predates two further periods of increased organic-matter accumulation in the Vocontian Basin (Noir and Fallot levels), and the onset of the fourth and final drowning phase may coincide with two further periods of increased organic-matter accumulation in the Vocontian Basin (Jacob and Kilian levels, part of OAE 1b). These correlations indicate a relationship between the so-called anoxic episodes and the stepwise demise of the Urgonian platform, even if the onset of environmental change is registered earlier on the platform than in basinal sediments.  相似文献   

The structure of the lower crust at the Argentine continental margin, South Atlantic at 44°S     

Michael Schnabel  Dieter Franke  Martin Engels  Karl Hinz  Snke Neben  Volkmar Damm  Stefan Grassmann  Hugo Pelliza  Paulo Ricardo Dos Santos 《Tectonophysics》2008,454(1-4):14-22

It is well established that the Argentine passive margin is of the rifted volcanic margin type. This classification is based primarily on the presence of a buried volcanic wedge beneath the continental slope, manifested by seismic data as a seaward dipping reflector sequence (SDRS). Here, we investigate the deep structure of the Argentine volcanic margin at 44°S over 200 km from the shelf to the deep oceanic Argentine Basin. We use wide-angle reflection/refraction seismic data to perform a joint travel time inversion for refracted and reflected travel times. The resulting P-wave velocity-depth model confirms the typical volcanic margin structure. An underplated body is resolved as distinctive high seismic velocity (v_p up to 7.5 km/s) feature in the lower crust in the prolongation of a seaward dipping reflector sequence. A remarkable result is that a second, isolated body of high seismic velocity (v_p up to 7.3 km/s) exists landward of the first high-velocity feature. The centres of both bodies are 60 km apart. The high-velocity lower-crustal bodies likely were emplaced during transient magmatic–volcanic events accompanying the late rifting and initial drifting stages. The lateral variability of the lower crust may be an expression of a multiple rifting process in the sense that the South Atlantic rift evolved by instantaneous breakup of longer continental margin segments. These segments are confined by transfer zones that acted as rift propagation barriers. A lower-crustal reflector was detected at 3 to 5 km above the modern Moho and probably represents the lower boundary of stretched continental crust. With this finding we suggest that the continent–ocean boundary is situated 70 km more seaward than in previous interpretations.  相似文献