Product study of the reaction of OH radicals with isoprene in the atmosphere simulation chamber SAPHIR     

M. Karl  H.-P. Dorn  F. Holland  R. Koppmann  D. Poppe  L. Rupp  A. Schaub  A. Wahner 《Journal of Atmospheric Chemistry》2006,55(2):167-187

Atmospheric oxidation of isoprene and its oxidation products methacrolein (MACR) and methyl vinyl ketone (MVK) have an important impact on the photochemical activity in the boundary layer, in particular in forested areas. The oxidation of isoprene by OH radicals was investigated in chamber experiments conducted under tropospheric conditions in the atmosphere simulation chamber SAPHIR at the Research Center Jülich. The aim was to determine the product yield of MVK and MACR in the OH-induced isoprene oxidation and the rate constant of their reaction with OH under real atmospheric conditions. The recently published updated degradation scheme for isoprene from Geiger et al. (2003) was used to determine rate constants and product yields. The fractional yields in the isoprene peroxy radical reaction with NO were found to be 0.41±0.03 for MVK and 0.27±0.03 for MACR. The rate coefficient for MACR with OH was found to be in very good agreement with the recommended value of IUPAC Atkinson (Atkinson et al., 2005). while the rate coefficient for MVK with OH was 27% lower.  相似文献   

The future of industrial cities and regions in central and eastern Europe     

Gerd Lintz  Bernhard Müller  Karl Schmude 《Geoforum》2007,38(3):512-519

Economic transition in central and eastern Europe (CEE) has had a particularly strong impact on industrial cities and regions. Following their economic collapse, most of them are now confronted with serious problems such as high unemployment and vast ecological damage. The paper presents findings from a pan European research project that investigated the problems of these cities and regions as well as the strategies being adopted to cope with structural change. It examines the differences in approaches and addresses the question whether existing EU policy is suitable for supporting the redevelopment of old industrial cities and regions in CEE countries. The paper concludes with recommendations for future directions in policy making.  相似文献   

The behavior of natural and anthropogenic osmium in the Hudson River-Long Island Sound estuarine system     

Karl K. Turekian  Mukul Sharma 《Geochimica et cosmochimica acta》2007,71(17):4135-4140

The extent to which riverine Os is trapped in a temperate estuary was the aim of this study. The behavior of Os through the Hudson River, East River and the Long Island Sound (LIS) system is addressed using both natural Os and anthropogenically mobilized Os. The Os concentration ([Os]) and isotopic composition (¹⁸⁷Os/¹⁸⁸Os) of the Mid-Atlantic Bight as inferred from the analysis of a water sample of 31‰ salinity (S) at Vineyard Sound, MA are 46 fM and 1.070, respectively. In comparison, the Hudson River at Newburgh, NY has [Os] = 68 fM and ¹⁸⁷Os/¹⁸⁸Os = 1.265. The Os concentration of the East River at the Whitestone Bridge is 51 fM and remains essentially constant proceeding eastward in the LIS despite the increase of salinity from 20‰ towards the higher value of the Mid-Atlantic Bight. The ¹⁸⁷Os/¹⁸⁸Os ratio of water at Whitestone Bridge is 0.945 and increases eastward through the Sound to 0.979 at 7 km and then to 1.019 at 39.6 km. The behavior of Os through LIS appears to be conservative at S > 20‰. On the basis of Os concentration and isotopic composition we infer that anthropogenic Os is being added to the East River through sewers with the likely isotopic ratio of ∼0.13 and that about 24% of riverine Os must be removed at S ? 20‰. There is a net transport of about 0.4-1 mole of anthropogenic Os per year from the East River into the LIS. The residence time of Os in the ocean at present must be about 39,000 years, unless an independent source of supply of Os can be identified.  相似文献   

Formation of Thin Current Sheets and Other Recent Developments in Magnetospheric Activity     

Karl Schindler 《Astrophysics and Space Science》1998,264(1-4):289-302

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Diskordante Tektonik     

Prof. Dr. Karl Krejci-Graf 《International Journal of Earth Sciences》1981,70(3):1263-1275

Zusammenfassung Die Verfolgung tektonischer Strukturen in die Tiefe ist nur bei kontinuierlicher Verformung einfach. Physikalische oder strukturelle Änderungen innerhalb der sich verformenden Körper, sowie Änderungen in der Richtung der verformenden KrÄfte, bedingungen diskontinuierliche Änderungen in den erzeugten Strukturen, z. B. Scheitelverschiebung, Rückverformung, DurchprÄgung überwÄltigter Strukturen.

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To pursue tectonical structures beyond observations is simple only if deformations are continuous. Changes of physical or structural properties of rocks, as well as changes in the direction of transforming forces, create discontinuous alterations within thus generated structures, e. g. displacement of apex, retrograde transformation, penetration of subdued lower structures.

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Résumé Le prolongement des structures tectoniques en profondeur n'est simple que dans le cas de déformations continues. Des changements de propriétés physiques ou structurales durant les déformations à l'intérieur des corps tectoniques, ainsi que des modifications dans la direction des forces actives, produisent des transformations discontinues dans les structures engendrées, p. ex. déplacements des sommets des anticlinaux, déformations en retour, rejeu de structures anciennes et leur pénétration dans les structures superposées; etc.

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Seismische Anisotropie des oberen Erdmantels und Intraplatten-Tektonik     

Prof. Dr. Karl Fuchs 《International Journal of Earth Sciences》1975,64(1):700-716

Specially planned explosion seismic measurements in the oceans provided conclusive evidence that the velocity of P_n-waves depends on the azimuths of the direction of propagation through the upper mantle. The orientation of this azimuthal anisotropy suggests a close connection with the generation of the oceanic lithosphere: in the Pacific the maximum and minimum velocities are measured in a perpendicular and parallel direction to the axis of the oceanic ridges respectively. The observed anisotropy is so strong that a number of models for the generation of anisotropy can be discarded. The most likely cause is a preferred orientation of minerals. The generation of the anisotropy can be simulated in the laboratory under P-T-conditions of the upper mantle. The influence of the rate of deformation can be studied as well. A recent analysis of explosion seismic data in Southern Germany suggests that the continental upper mantle possesses also a velocity anisotropy dependent on azimuth.  相似文献   

Mitteilungen     

Dr. Dieter Stadler  Karl Schomaker 《Ocean Dynamics》1975,28(3):117-120

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A method to determine crystallization temperatures of hydrated crystals by intracrystalline oxygen isotope effects     

Karl Heinzinger  Dieter Götz 《Earth and Planetary Science Letters》1975,27(2):219-220

The fractionation of the oxygen isotopes between water molecules from different sites in CuSO₄ · 5H₂O has been measured for crystallization temperatures of 25, 40 and 50°C. The temperature dependence found provides a basis for the determination of crystallization temperatures from such intracrystalline oxygen isotope effects; also for hydrated crystals of mineralogical and geological interest. Necessary suppositions for the application of this method are discussed.  相似文献   

Mikrofazielle Untersuchungsmethoden von Kalken | Flügel,E., 1978. (Methods of Investigation of Limestone Microfacies.) Springer-Verlag,Heidelberg, Berlin,New York, 454 pp., D.M. 78.00, U.S. $39.00     

Karl H. Wolf 《Earth》1979,14(4):368-370

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Prospecting and exploration of mineral deposits | M. Kuz`vart and M. Böhmer, 1978. Elsevier,Amsterdam, 431 pp., Dfl. 130.00, U.S. $ 55.00     

Karl H. Wolf 《Earth》1980,15(4):406-407

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