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121.
Ricardo Oyarzún Sandro Zambra Hugo Maturana Jorge Oyarzún Evelyn Aguirre Nicole Kretschmer 《水文科学杂志》2013,58(12):2193-2204
ABSTRACTThis paper analyses the composition of surface water and shallow groundwater in the Grande River basin, North-Central Chile, using this information to characterize water interactions. Chemical and isotopic data for surface water and groundwater (7 and 6 sampling locations, respectively) were obtained from three sampling campaigns performed in March–April (autumn), August–September (late winter) and December (early summer) 2012. Precipitation samples were also collected. Data was processed using spatial distribution charts, Piper and Stiff diagrams, and multivariate analysis. In general, the results for each method converge on a high degree of connectivity between surface water and shallow groundwater in the study area. Furthermore, approximately a 10% of groundwater contribution to the surface flow discharge was estimated for a particular reach. This multi-method approach was useful for the characterization of surface water–groundwater interactions in the Grande River basin, and may become a suitable and replicable scheme for studies in arid and semi-arid basins facing similar water management challenges.
Editor D. Koutsoyiannis; Associate editor B. Dewals 相似文献
122.
Víctor Alcaraz‐González Fabián Azael Fregoso‐Sanchez Hugo Oscar Mendez‐Acosta Victor Gonzalez‐Alvarez 《洁净——土壤、空气、水》2013,41(12):1157-1164
In this paper, a multiple‐input multiple‐output (MIMO) model‐based robust control scheme is proposed for the indirect control of both total alkalinity and the ratio (intermediate alkalinity)/(total alkalinity) by regulating volatile fatty acid concentrations and strong ions concentration, while guaranteeing the so‐called operational stability in anaerobic digestion (AD) processes. The proposed MIMO regulator is an adaptive controller derived from an AD model which incorporates the physicochemical equilibrium of the system as well as the use of a robust interval observer to estimate key process bounds that are used in the computation of the control efforts. Numerical simulations were carried out for a number of operating conditions under the most uncertain scenarios. Results showed that the proposed multivariable control law is able to recover the system stability around a pre‐determined set point in the face of parameter uncertainty and load disturbances. 相似文献
123.
124.
Kim Hanjun Kang Sarah M. Takahashi Ken Donohoe Aaron Pendergrass Angeline G. 《Climate Dynamics》2021,56(1-2):17-27
Climate Dynamics - We investigate the possible causes for inter-model spread in tropical zonal-mean precipitation pattern, which is divided into hemispherically symmetric and anti-symmetric modes... 相似文献
125.
Claire Granier Bertrand Bessagnet Tami Bond Ariela D��Angiola Hugo Denier van der Gon Gregory J. Frost Angelika Heil Johannes W. Kaiser Stefan Kinne Zbigniew Klimont Silvia Kloster Jean-Fran?ois Lamarque Catherine Liousse Toshihiko Masui Frederik Meleux Aude Mieville Toshimasa Ohara Jean-Christophe Raut Keywan Riahi Martin G. Schultz Steven J. Smith Allison Thompson John van Aardenne Guido R. van der Werf Detlef P. van Vuuren 《Climatic change》2011,109(1-2):163-190
Several different inventories of global and regional anthropogenic and biomass burning emissions are assessed for the 1980?C2010 period. The species considered in this study are carbon monoxide, nitrogen oxides, sulfur dioxide and black carbon. The inventories considered include the ACCMIP historical emissions developed in support of the simulations for the IPCC AR5 assessment. Emissions for 2005 and 2010 from the Representative Concentration Pathways (RCPs) are also included. Large discrepancies between the global and regional emissions are identified, which shows that there is still no consensus on the best estimates for surface emissions of atmospheric compounds. At the global scale, anthropogenic emissions of CO, NOx and SO2 show the best agreement for most years, although agreement does not necessarily mean that uncertainty is low. The agreement is low for BC emissions, particularly in the period prior to 2000. The best consensus is for NOx emissions for all periods and all regions, except for China, where emissions in 1980 and 1990 need to be better defined. Emissions of CO need better quantification in the USA and India for all periods; in Central Europe, the evolution of emissions during the past two decades needs to be better determined. The agreement between the different SO2 emissions datasets is rather good for the USA, but better quantification is needed elsewhere, particularly for Central Europe, India and China. The comparisons performed in this study show that the use of RCP8.5 for the extension of the ACCMIP inventory beyond 2000 is reasonable, until more global or regional estimates become available. Concerning biomass burning emissions, most inventories agree within 50?C80%, depending on the year and season. The large differences between biomass burning inventories are due to differences in the estimates of burned areas from the different available products, as well as in the amount of biomass burned. 相似文献
126.
Ken?M.?FritzEmail author Jack?W.?Feminella 《Aquatic Sciences - Research Across Boundaries》2011,73(4):459-469
Ecological flows between habitats are vital for predicting and understanding structure and function of recipient systems.
Ecological flows across riparian areas and headwater intermittent streams are likely to be especially important in many river
networks because of the shear extent of these interfaces, their high edge-to-width ratio, and the alternation of wet and dry
conditions in intermittent channels. While there has been substantial research supporting the importance of riparian-stream
linkages above-ground, comparatively less research has investigated below-ground linkages. We tested the hypothesis that riparian
roots are colonized by invertebrates as a food source within stream beds of intermittent headwater streams. We compared benthic
invertebrate assemblages colonizing three types of buried substrates (leaves, roots, and plastic roots) among three intermittent
Coastal Plain streams, each with a different riparian management treatment (clearcut, thinned, and reference), over a 1-year
period. Invertebrate density was significantly lower in root litterbags than in plastic roots litterbags, but neither differed
from densities in leaf litterbags. Total invertebrate abundances, however, were significantly higher in leaf and root litterbags
compared to abundances in plastic root litterbags. Invertebrate biomass and richness did not vary among substrates, but invertebrate
density, abundance, and richness all declined from the wet phase (September–December) through the dry phase (June–August).
Meiofauna and aquatic dipterans were the primary colonizing invertebrates during the wet phase. Relative abundance of terrestrial
taxa increased during the dry phase, but their absolute abundance remained lower than aquatic taxa during the wet phase. Invertebrate
composition did not differ among substrate types, but was significantly different among streams and time periods. Cumulative
number of dry days, degree days, and redox depth all strongly correlated with assemblage structure as indicated by ordination
scores. Our results suggest that subsurface invertebrates respond to leaves and roots as food sources, but assemblage composition
is not substrate specific. Colonization of leaves and roots within stream beds by aquatic and terrestrial taxa supports the
idea that headwater intermittent streams are important interfaces for the reciprocal exchange of energy and materials between
terrestrial and aquatic ecosystems. 相似文献
127.
Small (1–3 mm), hollow spherules of hexahydrite have been collected falling out of the magmatic gas plume downwind of Kīlauea’s
summit vent. The spherules were observed on eight separate occasions during 2009–2010 when a lake of actively spattering lava
was present ~150–200 m below the rim of the vent. The shells of the spherules have a fine bubbly foam structure less than
0.1 mm thick, composed almost entirely of hexahydrite [MgSO4·6H2O] Small microspherules of lava (<5 μm across) along with mineral and rock fragments from the magmatic plume adhered to the
outside of the hexahydrite spherules. Phase relationships and the particulate matter in the magmatic plume indicate that the
spherules originated as a bubbly solution injected into and mixed with the magmatic plume. The most likely mechanism for production
of hexahydrite spherules is boiling of MgSO4-saturated meteoric water in the walls of the conduit above the surface of the lava lake. Solfataric sulfates may thus be
recycled and reinjected into the plume, creating particulates of sulfate minerals that can be distributed far from their original
source. 相似文献
128.
The hyporheic zone is an ecologically important ecotone that describes the extent to which nutrient-rich surface waters penetrate the shallow subsurface adjacent to a flowing surface water body. Although steady-state models satisfactorily explain the incursion of surface water into the subsurface as a function of head gradients developed across streambed riffles, they fail to account for the depth that surface water is observed to penetrate the subsurface or for the extent to which the hyporheic zone develops adjacent to the stream channel. To investigate these issues, transient flow modeling has been conducted at the riffle scale and supported by data for an instrumented site in northern Ontario where stream-stage fluctuations are strictly regulated. Model results show that daily stream-stage fluctuations between 0.6 and 4 m produce oscillating solute flow paths that typically reduce residence times of water and solutes in the hyporheic zone from 60 days or more under steady-state conditions to less than 1 day. Furthermore, similar stream-stage fluctuations increase the depth that solutes pervade the subsurface and banks lateral to the stream from around 1 m under steady-state conditions to as much as 2 and 10 m, respectively. The results demonstrate that the transient flow conditions triggered in the subsurface by variable stream stage can exert a strong influence on hyporheic zone development and have important implications for the hyporheos. The results are especially important for hyporheic communities that may survive gradual changes to their living conditions by migrating to more hospitable aquatic habitats, but are unable to respond to rapid changes provoked by more extreme hydrological events. 相似文献
129.
Cornel E. J. de Ronde Gary J. Massoth David A. Butterfield Bruce W. Christenson Junichiro Ishibashi Robert G. Ditchburn Mark D. Hannington Robert L. Brathwaite John E. Lupton Vadim S. Kamenetsky Ian J. Graham Georg F. Zellmer Robert P. Dziak Robert W. Embley Vesselin M. Dekov Frank Munnik Janine Lahr Leigh J. Evans Ken Takai 《Mineralium Deposita》2011,46(5-6):541-584
Brothers volcano, of the Kermadec intraoceanic arc, is host to a hydrothermal system unique among seafloor hydrothermal systems known anywhere in the world. It has two distinct vent fields, known as the NW Caldera and Cone sites, whose geology, permeability, vent fluid compositions, mineralogy, and ore-forming conditions are in stark contrast to each other. The NW Caldera site strikes for ??600?m in a SW?CNE direction with chimneys occurring over a ??145-m depth interval, between ??1,690 and 1,545?m. At least 100 dead and active sulfide chimney spires occur in this field and are typically 2?C3?m in height, with some reaching 6?C7?m. Their ages (at time of sampling) fall broadly into three groups: <4, 23, and 35?years old. The chimneys typically occur near the base of individual fault-controlled benches on the caldera wall, striking in lines orthogonal to the slopes. Rarer are massive sulfide crusts 2?C3?m thick. Two main types of chimney predominate: Cu-rich (up to 28.5?wt.% Cu) and, more commonly, Zn-rich (up to 43.8?wt.% Zn). Geochemical results show that Mo, Bi, Co, Se, Sn, and Au (up to 91?ppm) are correlated with the Cu mineralization, whereas Cd, Hg, Sb, Ag, and As are associated with the dominant Zn-rich mineralization. The Cone site comprises the Upper Cone site atop the summit of the recent (main) dacite cone and the Lower Cone site that straddles the summit of an older, smaller, more degraded dacite cone on the NE flank of the main cone. Huge volumes of diffuse venting are seen at the Lower Cone site, in contrast to venting at both the Upper Cone and NW Caldera sites. Individual vents are marked by low-relief (??0.5?m) mounds comprising predominately native sulfur with bacterial mats. Vent fluids of the NW Caldera field are focused, hot (??300°C), acidic (pH????2.8), metal-rich, and gas-poor. Calculated end-member fluids from NW Caldera vents indicate that phase separation has occurred, with Cl values ranging from 93% to 137% of seawater values. By contrast, vent fluids at the Cone site are diffuse, noticeably cooler (??122°C), more acidic (pH?1.9), metal-poor, and gas-rich. Higher-than-seawater values of SO4 and Mg in the Cone vent fluids show that these ions are being added to the hydrothermal fluid and are not being depleted via normal water/rock interactions. Iron oxide crusts 3?years in age cover the main cone summit and appear to have formed from Fe-rich brines. Evidence for magmatic contributions to the hydrothermal system at Brothers includes: high concentrations of dissolved CO2 (e.g., 206?mM/kg at the Cone site); high CO2/3He; negative ??D and ??18OH2O for vent fluids; negative ??34S for sulfides (to ?4.6??), sulfur (to ?10.2??), and ??15N2 (to ?3.5??); vent fluid pH values to 1.9; and mineral assemblages common to high-sulfidation systems. Changing physicochemical conditions at the Brothers hydrothermal system, and especially the Cone site, occur over periods of months to hundreds of years, as shown by interlayered Cu?+?Au- and Zn-rich zones in chimneys, variable fluid and isotopic compositions, similar shifts in 3He/4He values for both Cone and NW Caldera sites, and overprinting of ??magmatic?? mineral assemblages by water/rock-dominated assemblages. Metals, especially Cu and possibly Au, may be entering the hydrothermal system via the dissolution of metal-rich glasses. They are then transported rapidly up into the system via magmatic volatiles utilizing vertical (??2.5?km long), narrow (??300-m diameter) ??pipes,?? consistent with evidence of vent fluids forming at relatively shallow depths. The NW Caldera and Cone sites are considered to represent stages along a continuum between water/rock- and magmatic/hydrothermal-dominated end-members. 相似文献
130.
Ken?NiwaEmail author Takehiko?Yagi Kenya?Ohgushi 《Physics and Chemistry of Minerals》2011,38(1):21-31
Compression behaviors of CaIrO3 with perovskite (Pv) and post-perovskite (pPv) structures have been investigated up to 31.0(1.0) and 35.3(1) GPa at room
temperature, respectively, in a diamond-anvil cell with hydrostatic pressure media. CaIrO3 Pv and pPv phases were compressed with the axial compressibility of β
a > β
c > β
b and β
b > β
a > β
c, respectively and no phase transition was observed in both phases up to the highest pressure in the present study. The order
of axial compressibility for pPv phase is consistent with the crystallographic consideration for layer structured materials
and previous experimental results. On the other hand, Pv phase shows anomalous compression behavior in b axis, which exhibit constant or slightly expanded above 13 GPa, although the applied pressure remained hydrostatic. Volume
difference between Pv and pPv phases was gradually decreased with increasing pressure and this is consistent with the results
of theoretical study based on the ab initio calculation. Present results, combined with theoretical study, suggest that these
complicate compression behaviors in CaIrO3 under high pressure might be caused by the partially filled electron of Ir4+. Special attention must be paid in case of using CaIrO3 as analog materials to MgSiO3, although CaIrO3 exhibits interesting physical properties under high pressure. 相似文献