Feldspar dissolution rates in the Topopah Spring Tuff, Yucca Mountain, Nevada     

Charles R. Bryan  Katheryn B. Helean  Brian D. Marshall  Patrick V. Brady 《Applied Geochemistry》2009,24(11):2133-2143

Two different field-based methods are used here to calculate feldspar dissolution rates in the Topopah Spring Tuff, the host rock for the proposed nuclear waste repository at Yucca Mountain, Nevada. The center of the tuff is a high silica rhyolite, consisting largely of alkali feldspar (60 wt%) and quartz polymorphs (35 wt%) that formed by devitrification of rhyolitic glass as the tuff cooled. First, the abundance of secondary aluminosilicates is used to estimate the cumulative amount of feldspar dissolution over the history of the tuff, and an ambient dissolution rate is calculated by using the estimated thermal history. Second, the feldspar dissolution rate is calculated by using measured Sr isotope compositions for the pore water and rock. Pore waters display systematic changes in Sr isotopic composition with depth that are caused by feldspar dissolution. The range in dissolution rates determined from secondary mineral abundances varies from 10⁻¹⁶ to 10⁻¹⁷ mol s⁻¹ kg tuff⁻¹ with the largest uncertainty being the effect of the early thermal history of the tuff. Dissolution rates based on pore water Sr isotopic data were calculated by treating percolation flux parametrically, and vary from 10⁻¹⁵ to 10⁻¹⁶ mol s⁻¹ kg tuff⁻¹ for percolation fluxes of 15 mm a⁻¹ and 1 mm a⁻¹, respectively. Reconciling the rates from the two methods requires that percolation fluxes at the sampled locations be a few mm a⁻¹ or less. The calculated feldspar dissolution rates are low relative to other measured field-based feldspar dissolution rates, possibly due to the age (12.8 Ma) of the unsaturated system at Yucca Mountain; because oxidizing and organic-poor conditions limit biological activity; and/or because elevated silica concentrations in the pore waters (50 mg L⁻¹) may inhibit feldspar dissolution.  相似文献   

Controlled electrochemical dissolution of hydrothermal and sedimentary pyrite     

Ran Liu  Amy L. Wolfe  David A. Dzombak  Colin P. Horwitz  Brian W. Stewart  Rosemary C. Capo 《Applied Geochemistry》2009

Electrochemically controlled pyrite dissolution was performed with three pyrite materials from different geological origins under mixed potential and high overpotential conditions. Both solid electrodes and C paste electrodes of powdered pyrite were used. The rate of pyrite dissolution increased with applied positive potential and was strongly affected by temperature. Current density measurements over the applied potential range successfully described the rate of pyrite dissolution of each pyrite electrode. Controlled dissolution performed under mixed potential conditions on the solid electrodes successfully reflected the same pyrite reactivity and dissolution rate order as in batch reactor dissolution studies with the same pyrite materials. Therefore, the relative reactivity of different pyrite materials can be determined through current density measurements on their solid electrodes under mixed potential conditions. This technique could be a useful tool to compare rapidly the relative reactivity for different pyrite materials. In contrast, electrochemically controlled dissolution studies with C paste electrodes constructed with fine-grained pyrite and paraffin/graphite mixture did not result in accurate ranking of pyrite samples by dissolution rate.  相似文献   

In situ study of the $$ R\overline{3} c \to R\overline{3} m $$ orientational disorder in calcite     

Sytle M. Antao  Ishmael Hassan  Willem H. Mulder  Peter L. Lee  Brian H. Toby 《Physics and Chemistry of Minerals》2009,36(3):159-169

The temperature dependences of the crystal structure and intensities of the (113) and (211) reflections in calcite, CaCO₃, were studied using Rietveld structure refinements based on synchrotron powder X-ray diffraction data. Calcite transforms from to at about T _c = 1,240 K. A CO₃ group occupies, statistically, two positions with equal frequency in the disordered phase, but with unequal frequency in the partially ordered phase. One position for the CO₃ group is rotated by 180° with respect to the other. The unequal occupancy of the two orientations in the partially ordered phase is obtained directly from the occupancy factor, x, for the O1 site and gives rise to the order parameter, S = 2x − 1. The a cell parameter shows a negative thermal expansion at low T, followed by a plateau region at higher T, then a steeper contraction towards T _c, where the CO₃ groups disorder in a rapid process. Using a modified Bragg–Williams model, fits were obtained for the order parameter S, and for the intensities of the (113) and (211) reflections. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

3D visualization and analysis of fractured rock using digital photogrammetry     

Klaus Gessner  Hagen Deckert  Michael Drews 《Journal of Geochemical Exploration》2009

  相似文献   

The effect of dissolved magnesium on creep of calcite II: transition from diffusion creep to dislocation creep     

Lili Xu  Jörg Renner  Marco Herwegh  Brian Evans 《Contributions to Mineralogy and Petrology》2009,157(3):339-358

We extended a previous study on the influence of Mg solute impurity on diffusion creep in calcite to include deformation under a broader range of stress conditions and over a wider range of Mg contents. Synthetic marbles were produced by hot isostatic pressing (HIP) mixtures of calcite and dolomite powders for different intervals (2–30 h) at 850°C and 300 MPa confining pressure. The HIP treatment resulted in high-magnesian calcite aggregates with Mg content ranging from 0.5 to 17 mol%. Both back-scattered electron images and chemical analysis suggested that the dolomite phase was completely dissolved, and that Mg distribution was homogeneous throughout the samples at the scale of about two micrometers. The grain size after HIP varied from 8 to 31 μm, increased with time at temperature, and decreased with increasing Mg content (>3.0 mol%). Grain size and time were consistent with a normal grain growth equation, with exponents from 2.4 to 4.7, for samples containing 0.5–17.0 mol% Mg, respectively. We deformed samples after HIP at the same confining pressure with differential stresses between 20 and 200 MPa using either constant strain rate or stepping intervals of loading at constant stresses in a Paterson gas-medium deformation apparatus. The deformation tests took place at between 700 and 800°C and at strain rates between 10⁻⁶ and 10⁻³ s⁻¹. After deformation to strains of about 25%, a bimodal distribution of large protoblasts and small recrystallized neoblasts coexisted in some samples loaded at higher stresses. The deformation data indicated a transition in mechanism from diffusion creep to dislocation creep. At stresses below 40 MPa, the strength was directly proportional to grain size and decreased with increasing Mg content due to the reductions in grain size. At about 40 MPa, the sensitivity of log strain rate to log stress, (n), became greater than 1 and eventually exceeded 3 for stresses above 80 MPa. At a given strain rate and temperature, the stress at which that transition occurred was larger for samples with higher Mg content and smaller grain size. At given strain rates, constant temperature, and fixed grain size, the strength of calcite in the dislocation creep regime increased with solute content, while the strength in the diffusion creep regime was independent of Mg content. The results suggest that chemical composition will be an important element to consider when solid substitution can occur during natural deformation.  相似文献   

Development of an Uncertainty Propagation Equation for Scalar Fields     

Brian Calder  Paul Elmore 《Marine Geodesy》2017,40(5):341-360

  相似文献   

Using remotely sensed data to modify wind forcing in operational storm surge forecasting     

David Byrne  Kevin Horsburgh  Brian Zachry  Paolo Cipollini 《Natural Hazards》2017,89(1):275-293

Storm surges are abnormal coastal sea level events caused by meteorological conditions such as tropical cyclones. They have the potential to cause widespread loss of life and financial damage and have done so on many occasions in the past. Accurate and timely forecasts are necessary to help mitigate the risks posed by these events. Operational forecasting models use discretisations of the governing equations for fluid flow to model the sea surface, which is then forced by surface stresses derived from a model wind and pressure fields. The wind fields are typically idealised and generated parametrically. In this study, wind field datasets derived from remotely sensed data are used to modify the model parametric wind forcing and investigate potential improvement to operational forecasting. We examine two methods for using analysis wind fields derived from remotely sensed observations of three hurricanes. Our first method simply replaces the parametric wind fields with its corresponding analysis wind field for a period of time. Our second method does this also but takes it further by attempting to use some of the information present in the analysis wind field to estimate future wind fields. We find that our methods do yield some forecast improvement, most notably for our second method where we get improvements of up to 0.29 m on average. Importantly, the spatial structure of the surge is changed in some places such that locations that were previously forecast small surges had their water levels increased. These results were validated by tide gauge data.  相似文献   

Quantification of Storm-Induced Bathymetric Change in a Back-Barrier Estuary     

Neil K. Ganju  Steven E. Suttles  Alexis Beudin  Daniel J. Nowacki  Jennifer L. Miselis  Brian D. Andrews 《Estuaries and Coasts》2017,40(1):22-36

Geomorphology is a fundamental control on ecological and economic function of estuaries. However, relative to open coasts, there has been little quantification of storm-induced bathymetric change in back-barrier estuaries. Vessel-based and airborne bathymetric mapping can cover large areas quickly, but change detection is difficult because measurement errors can be larger than the actual changes over the storm timescale. We quantified storm-induced bathymetric changes at several locations in Chincoteague Bay, Maryland/Virginia, over the August 2014 to July 2015 period using fixed, downward-looking altimeters and numerical modeling. At sand-dominated shoal sites, measurements showed storm-induced changes on the order of 5 cm, with variability related to stress magnitude and wind direction. Numerical modeling indicates that the predominantly northeasterly wind direction in the fall and winter promotes southwest-directed sediment transport, causing erosion of the northern face of sandy shoals; southwesterly winds in the spring and summer lead to the opposite trend. Our results suggest that storm-induced estuarine bathymetric change magnitudes are often smaller than those detectable with methods such as LiDAR. More precise fixed-sensor methods have the ability to elucidate the geomorphic processes responsible for modulating estuarine bathymetry on the event and seasonal timescale, but are limited spatially. Numerical modeling enables interpretation of broad-scale geomorphic processes and can be used to infer the long-term trajectory of estuarine bathymetric change due to episodic events, when informed by fixed-sensor methods.  相似文献   

Geostandards and Geoanalytical Research Bibliographic Review 2016          下载免费PDF全文

Ulrike Weis  Beate Schwager  Brigitte Stoll  Uwe Nohl  Patricia Karlowski  Isabelle Leisgang  Florentine Zwillich  Klaus Peter Jochum 《Geostandards and Geoanalytical Research》2017,41(4):487-491

  相似文献   

Contemporaneous assembly of Western Gondwana and final Rodinia break-up: Implications for the supercontinent cycle   总被引：2，自引：0，他引：2  

Sebastián Oriolo  Pedro Oyhantçabal  Klaus Wemmer  Siegfried Siegesmund 《地学前缘(英文版)》2017,8(6):1431-1445

Geological, geochronological and isotopic data are integrated in order to present a revised model for the Neoproterozoic evolution of Western Gondwana. Although the classical geodynamic scenario assumed for the period 800–700 Ma is related to Rodinia break-up and the consequent opening of major oceanic basins, a significantly different tectonic evolution can be inferred for most Western Gondwana cratons. These cratons occupied a marginal position in the southern hemisphere with respect to Rodinia and recorded subduction with back-arc extension, island arc development and limited formation of oceanic crust in internal oceans. This period was thus characterized by increased crustal growth in Western Gondwana, resulting from addition of juvenile continental crust along convergent margins. In contrast, crustal reworking and metacratonization were dominant during the subsequent assembly of Gondwana. The Río de la Plata, Congo-São Francisco, West African and Amazonian cratons collided at ca. 630–600 Ma along the West Gondwana Orogen. These events overlap in time with the onset of the opening of the Iapetus Ocean at ca. 610–600 Ma, which gave rise to the separation of Baltica, Laurentia and Amazonia and resulted from the final Rodinia break-up. The East African/Antarctic Orogen recorded the subsequent amalgamation of Western and Eastern Gondwana after ca. 580 Ma, contemporaneously with the beginning of subduction in the Terra Australis Orogen along the southern Gondwana margin. However, the Kalahari Craton was lately incorporated during the Late Ediacaran–Early Cambrian. The proposed Gondwana evolution rules out the existence of Pannotia, as the final Gondwana amalgamation postdates latest connections between Laurentia and Amazonia. Additionally, a combination of introversion and extroversion is proposed for the assembly of Gondwana. The contemporaneous record of final Rodinia break-up and Gondwana assembly has major implications for the supercontinent cycle, as supercontinent amalgamation and break-up do not necessarily represent alternating episodic processes but overlap in time.  相似文献