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101.
Chemical, physical, and biological features of streams and ground water of the North-Eastern area of Rome are jointly analyzed in order to assess the status of water resources. Ground water was investigated with classical survey methods (pH, temperature, and electric conductivity). Microbiological pollution, faunal composition, and stream surrounding area conditions of surface waters were studied, in order to quantify the residual value of these ecosystems from both a human and an environmental point of view. Results show a general impairment of the system and the comparison between superficial waters and shallow ground waters makes it possible to detect the presence of a connection between the two levels. This relationship occurs as an exchange from superficial waters (streams and rivers) to the shallow aquifers. Where superficial waters are contaminated, as in the Tor Sapienza stream, pollutants move to the shallow aquifers too, due to the decreased pressure of the over-exploited aquifer. Moreover, uncontrolled drilling activity, diffused in urban areas, makes it possible the connection between shallow and deep ground water. Notwithstanding this, the mixing between superficial and deep ground water system in Rome is not very widespread and, apparently, limited to restricted areas.  相似文献   
102.
Dust grains that formed around ancient stars and in stellar explosions seeded the early solar protoplanetary disk. While most of such presolar grains were destroyed during solar system formation, a fraction of such grains were preserved in primitive materials such as meteorites. These grains can provide constraints on stellar origins and secondary processing such as aqueous alteration and thermal metamorphism on their parent asteroids. Here, we report on the nature of aqueous alteration in the Miller Range (MIL) 07687 chondrite through the analysis of four presolar silicates and their surrounding material. The grains occur in the Fe-rich and Fe-poor lithologies, reflecting relatively altered and unaltered material, respectively. The O-isotopic compositions of two grains, one each from the Fe-rich and Fe-poor matrix, are consistent with formation in the circumstellar envelopes of low-mass Asymptotic Giant Branch (AGB)/Red Giant Branch (RGB) stars. The other two grains, also one each from the Fe-rich and Fe-poor matrix, have O-isotopic compositions consistent with formation in the ejecta of type-II supernovae (SNe). The grains derived from AGB/RGB stars include two polycrystalline pyroxene grains that contain Fe-rich rims. The SNe grains include a polycrystalline Ca-bearing pyroxene and a polycrystalline assemblage consistent with a mixture of olivine and pyroxene. Ferrihydrite is observed in all focused ion beam sections, consistent with parent-body aqueous alteration of the fine-grained matrix under oxidizing conditions. The Fe-rich rims around presolar silicates in this study are consistent with Fe-diffusion into the grains resulting from early-stage hydrothermal alteration, but such alteration was not extensive enough to lead to isotopic equilibration with the surrounding matrix.  相似文献   
103.
We analyze changes of four extreme hydroclimatic indices in the RCP8.5 projections of the Phase I CREMA experiment, which includes 21st century projections over 5 CORDEX domains (Africa, Central America, South America, South Asia, Mediterranean) with the ICTP regional model RegCM4 driven by three CMIP5 global models. The indices are: Heat Wave Day Index (HWD), Maximum Consecutive Dry Day index (CDD), fraction of precipitation above the 95th intensity percentile (R95) and Hydroclimatic Intensity index (HY-INT). Comparison with coarse (GPCP) and high (TRMM) resolution daily precipitation data for the present day conditions shows that the precipitation intensity distributions from the GCMs are close to the GPCP data, while the RegCM4 ones are closer to TRMM, illustrating the added value of the increased resolution of the regional model. All global and regional model simulations project predominant increases in HWD, CDD, R95 and HY-INT, implying a regime shift towards more intense, less frequent rain events and increasing risk of heat wave, drought and flood with global warming. However, the magnitudes of the changes are generally larger in the global than the regional models, likely because of the relatively low “climate sensitivity” of the RegCM4, especially when using the CLM land surface scheme. In addition, pronounced regional differences in the change signals are found. The data from these simulations are available for use in impact assessment studies.  相似文献   
104.
Lack of high-spatial-resolution soil and sediment arsenic data for Hawai‘i has generated substantial disagreement between researchers and regulators regarding the magnitude of natural levels of arsenic in Hawai‘i and rendered difficult the defining of areas of anthropogenically elevated arsenic. Our earlier research into the occurrence of arsenic in terrestrial and marine environments revealed widely disparate concentrations of arsenic with no apparent spatial pattern. To better understand the distribution and abundance of arsenic in soils and sediments of O‘ahu, we collected an additional 64 samples at locations chosen to represent different environments with varying degrees of human impact. We found surface arsenic values that ranged from 0.28 to 740 ppm with a median concentration of 8.1 ppm, which is above the global median of 5 ppm and US soil median of 5.2 ppm. Higher concentrations of arsenic (up to 913 ppm) were encountered at depth in soil cores. The median arsenic in streambed sediments from one of our earlier studies of 6.1 ppm was comparable to the conterminous US median of 6.3 ppm; however, we encountered arsenic concentrations as high as 43.9 ppm (median = 8.60 ppm, n = 75) in marine sediments in recent work off the leeward coast of O‘ahu. Overall, arsenic in the soils and sediments of O‘ahu is elevated relative to world and national values, but there still is no readily discernible pattern in the distribution of arsenic to explain these elevated values.  相似文献   
105.
106.
Extensive deposition of marine evaporites occurred during the Early–Middle Eocene in the South‐eastern Pyrenean basin (north‐east Spain). This study integrates stratigraphic and geochemical analyses of subsurface data (oil wells, seismic profiles and gravity data) together with field surveys to characterize this sedimentation in the foredeep and adjacent platform. Four major evaporite units were identified. The oldest was the Serrat Evaporites unit, with a platform‐slope‐basin configuration. Thick salina and sabkha sulphates accumulated on the platform, whereas resedimented and gravity‐derived sulphates were deposited on the slope, and salt and sulphates were deposited in the deep basin. In the subsequent unit (Vallfogona evaporites), thin sulphates formed on the platform, whereas very thick siliciclastic turbidites accumulated in the foredeep. However, some clastic gypsum coming from the platform (gypsarenites and gypsum olistoliths) was intercalated in these turbidites. The following unit, the Beuda Gypsum Formation developed in a sulphate platform‐basin configuration, where the topography of the depositional surface had become smooth. The youngest unit, the Besalú Gypsum, formed in a shallow setting. This small unit provides the last evidence of marine influence in a residual basin. Sulphur and oxygen isotope compositions are consistent with a marine origin for all evaporites. However, δ34S and δ18O values also suggest that, except for the oldest unit (Serrat Evaporites), there was some sulphate recycling from the older into the younger units. The South‐eastern Pyrenean basin constitutes a fine example of a foreland basin that underwent multiepisodic evaporitic sedimentation. In the basin, depositional factors evolved with time under a structural control. Decreasing complexity is observed in the lithofacies, as well as in the depositional models, together with a diminishing thickness of the evaporite units.  相似文献   
107.
Seismic wave transmission and digital image correlation (DIC) are employed to study slip processes along frictional discontinuities. A series of biaxial compression experiments are performed on gypsum specimens with non-homogeneous contact surfaces. The specimens are composed of two blocks with perfectly mated contact surfaces with a smooth surface with low frictional strength on the upper half and a rough surface with high frictional strength on the lower half. Compressional, P, and shear, S, wave pulses were transmitted through the discontinuity while digital images of the specimen surface were acquired during the test. A distinct peak in the amplitude of transmitted wave occurs prior to the peak shear strength and is considered a “precursor” to the failure. Precursors indicate that slip initiates from the smooth surface and extends to the rough surface as the shear load is increased. From the DIC data, slip is identified as a jump in the displacement field along the fracture that initiates from the smooth surface and propagates to the rough surface. Precursors are associated with an increase in the rate of slip across the discontinuity and are a measure of the reduction in the fracture shear stiffness.  相似文献   
108.
In the aftermath of a hurricane, local emergency managers need to communicate reentry plans to households that might be scattered over multiple counties or states. To better understand evacuees’ households’ reliance on different information sources at the time they decided to return home, this study collected data on reentry after Hurricane Ike. The results from a survey of 340 evacuating households indicated that there was low compliance with official reentry plans and that none of the information sources produced greater compliance with official reentry plans. Nonetheless, there were significant changes in the utilization of different sources of emergency information over the course of an evacuation but local news media remained the most common sources throughout the event. There also were significant differences in the relative importance of different sources of reentry information, with people relying most on information from peers. In summary, local authorities need to identify more effective ways to communicate with evacuees that have relocated to distant communities and to motivate them to comply with official reentry plans.  相似文献   
109.
The Komsomolskaya kimberlite is one of numerous (>1,000) kimberlite pipes that host eclogite xenoliths on the Siberian craton. Eclogite xenoliths from the adjacent Udachnaya kimberlite pipe have previously been geochemically well characterized; however, data from surrounding diamond-bearing kimberlite pipes from the center of the craton are relatively sparse. Here, we report major- and trace-element data, as well as oxygen isotope systematics, for mineral separates of diamondiferous eclogite xenoliths from the Komsomolskaya kimberlite, suggesting two distinct subgroups of a metamorphosed, subducted oceanic crustal protolith. Using almandine contents, this suite can be divided into two subgroups: group B1, with a high almandine component (>20 mol%) and group B2, with a low almandine component (<20 mol%). Reconstructed REE profiles for B1 eclogites overlap with typical oceanic basalts and lack distinct Eu anomalies. In addition, elevated oxygen isotope values, which are interpreted to reflect isotopic exchange with seawater at low temperatures (<350 °C), are consistent with an upper-oceanic crustal protolith. Reconstructed REE profiles for B2 eclogites are consistent with oceanic gabbros and display distinct Eu anomalies, suggesting a plagioclase-rich cumulate protolith. In contrast to B1, B2 eclogites do not display elevated oxygen isotope values, suggesting an origin deep within the crustal pile, where little-to-no interaction with hydrothermal fluids has occurred. Major-element systematics were reconstructed based on mineral modes; group B1 eclogites have higher MgO wt% and lower SiO2 wt%, with respect to typical oceanic basalts, reflecting a partial melting event during slab subduction. Calculated residues from batch partial melt modeling of a range of Precambrian basalts overlap with group B1 trace-element chemistry. When taken together with the respective partial melt trajectories, these melting events are clearly linked to the formation of Tonalite–Trondhjemite–Granodiorite (TTG) complexes. As a result, we propose that many, if not all, diamondiferous eclogite xenoliths from Komsomolskaya represent mantle ‘restites’ that preserve chemical signatures of Precambrian oceanic crust.  相似文献   
110.
Abstract The well-preserved 2.5 km diameter Roter Kamm impact crater is located in the Namib desert in Namibia. The impact has occurred in Precambrian granitic and granodioritic orthogneisses of the 1200–900 Ma old Namaqualand Metamorphic Complex which were partly covered by Gariep metasediments; the granites are invaded by quartz veins and quartz-feldspar-pegmatites. Previous geological field evidence suggested a crater age of about 5–10 Ma. In order to constrain this age, we selected a set of basement rocks (granites, granodiorites) exposed at the crater rim and studied the Rb-Sr, K-Ar, 40Ar-39Ar, and 10Be-26Al isotopic systems as well as apatite fission track ages of these samples. The Rb-Sr isotopic systematics confirm the derivation of these samples from the Namaqualand basement (age about 1.29 Ga), which underwent Damaran orogenesis at about 650 Ma. No basement rocks with Rb-Sr ages younger than about 410 Ma were identified. The K-Ar ages of pseudotachylite and melt breccia samples show that these samples are dominated by incompletely degassed fragments of basement rocks, with some retaining their original metamorphic ages of about 470 Ma. The apatite fission track ages range from 20–28 Ma, which may be interpreted as an extension of the 25 Ma Burdigalian peneplanation event, or as incomplete resetting of the apatite fission tracks during the impact event. The 10Be and 26Al exposure age of a quartz sample isolated from a quartz-pegmatite was found to be 150 ka; it is likely that the exposure of the sample began after material covering it had been removed by erosion 150 ka ago. Two glassy fractions extracted from a rim granite were dated by 40Ar-39Ar analysis. One sample gives practically a plateau age of 3.7 ± 0.3 Ma, while the other gives a minimum age of 3.6 Ma. The best available age estimate for the Roter Kamm crater is therefore 3.7 ± 0.3 Ma.  相似文献   
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