Anthropogenic influence on the degradation of an urban lake - The Pampulha reservoir in Belo Horizonte, Minas Gerais, Brazil     

Kurt Friese  Gerald Schmidt  Jorge Carvalho de Lena  Dieter W. Zachmann 《Limnologica》2010,40(2):114-125

The artificial reservoir Lagoa da Pampulha in central Brazil has been increasingly affected by sediment deposition and pollution from urban and industrial sources. This study investigates water chemistry and heavy metal concentrations and their fractionation in the lake sediment using ICP-OES, ICP-MS, and XRD analyses. Fractionation analysis was done by sequential extraction under inert gas as well as after oxidation. The lake exhibits a permanent stratification with an oxygen-free hypolimnion below 2 m depth. Nutrient concentrations are enriched for phosphorous components (SRP, PO₄). In the sediment it was not possible to detect oxygen. Carbon, sulfur, and most of the analyzed heavy metals are enriched in the top sediment layer with a pronounced downward decrease, indicating the presence of an anthropogenic influence. Statistical analysis, including correlations and a Principal Component Analysis (PCA) of depth-related total concentration data, helps to distinguish presumably anthropogenic heavy metals from geogenic components. Some samples with high element concentrations in the sediment also show elevated concentrations in their pore water. Analyses of element distribution between sediment and pore water suggest a strong bonding of heavy metals to the anoxic sediment. The trend towards elevated solubility in the pore water of oxidized samples is clear for most of the analyzed elements. Fractionation analysis reveals characteristic associations of selected elements to specific mineral bonding forms. In addition, it indicates that the behavior of heavy metals in the sediment is strongly influenced by organic substances. These substances provide buffering against oxidation, acidification, and metal release. The high nutrient loading causes reducing conditions in the lake sediment. These conditions trigger the accumulation of sediments rich in S²⁻, which stabilizes the fixation of heavy elements. In the future, care must be taken to reduce the supply of contaminants and to prevent the release of heavy metals from sediments dredged for remediation purposes.  相似文献   

Fourier transform infrared spectroscopy,a new method for rapid determination of total organic and inorganic carbon and biogenic silica concentration in lake sediments   总被引：1，自引：0，他引：1  

Peter Rosén  Hendrik Vogel  Laura Cunningham  Nina Reuss  Daniel J. Conley  Per Persson 《Journal of Paleolimnology》2010,43(2):247-259

We demonstrate the use of Fourier transform infrared spectroscopy (FTIRS) to make quantitative measures of total organic carbon (TOC), total inorganic carbon (TIC) and biogenic silica (BSi) concentrations in sediment. FTIRS is a fast and cost-effective technique and only small sediment samples are needed (0.01 g). Statistically significant models were developed using sediment samples from northern Sweden and were applied to sediment records from Sweden, northeast Siberia and Macedonia. The correlation between FTIRS-inferred values and amounts of biogeochemical constituents assessed conventionally varied between r = 0.84–0.99 for TOC, r = 0.85–0.99 for TIC, and r = 0.68–0.94 for BSi. Because FTIR spectra contain information on a large number of both inorganic and organic components, there is great potential for FTIRS to become an important tool in paleolimnology.  相似文献   

Fourier transform infrared spectroscopy,a new cost-effective tool for quantitative analysis of biogeochemical properties in long sediment records   总被引：1，自引：0，他引：1  

Hendrik Vogel  Peter Rosén  Bernd Wagner  Martin Melles  Per Persson 《Journal of Paleolimnology》2008,40(2):689-702

Measurements of Fourier transform infrared spectroscopy (FTIRS) in the mid-infrared (MIR) region were conducted on sedimentary records from Lake El’gygytgyn, NE Siberia, and Lake Ohrid, Albania/Macedonia. Calibration models relating FTIR spectral information to biogeochemical property concentrations were established using partial least squares regression (PLSR). They showed good statistical performance for total organic carbon (TOC), total nitrogen (TN), and biogenic silica (opal) in the sediment record from Lake El’gygytgyn, and for TOC, total inorganic carbon (TIC), TN, and opal in sediments from Lake Ohrid. In both cases, the calibration models were successfully applied for down-core analysis. The results, in combination with the small amount of sample material needed, negligible sample pre-treatments, and low costs of analysis, demonstrate that FTIRS is a promising, cost-effective tool that allows high-resolution paleolimnological studies.  相似文献   

Climate change, patch choice, and intensification at Pont d'Ambon (Dordogne, France) during the Younger Dryas     

Emily Lena Jones   《Quaternary Research》2009,72(3):371-376

This paper considers the impact of the Younger Dryas on the prehistoric inhabitants of Pont d'Ambon, a site in the Dordogne region of southwestern France, through an examination of the zooarchaeological remains from this site. An investigation of patch choice indicates that patch choice evenness declines during the Younger Dryas due to increasing local dominance of the grassland patch. Analyses of demographic composition, cutmark frequency, and marrow processing in the wild European rabbit (Oryctolagus cuniculus) assemblage suggest intensified rabbit use during this period. This study thus supports the hypothesis that changing climate had significant impacts on the prehistoric inhabitants of Pont d'Ambon. However, the traditional climate hypothesis—that changing climate negatively impacted the availability of larger fauna, forcing a switch to smaller, lower-ranked prey items—is not supported here. The inhabitants of Pont d'Ambon seem to have adapted to changing climate by efficiently exploiting the new species available to them, and possibly, during the Younger Dryas, by intensifying their use of one of these new species, the European rabbit.  相似文献   

The PONAM project     

Christian Hjort  Krstin Malmberg Persson 《Boreas: An International Journal of Quaternary Research》1994,23(4):281-281

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Detailed geomorphological survey of a small mountain drainage area, Abisko, northern Swedish Lapland     

Lena Rubensdotter 《Geografiska Annaler: Series A, Physical Geography》2002,84(3-4):267-273

A thorough geomorphological survey of a small (2km²) drainage area has been conducted using digital magnification of aerial photographs in conjunction with field visits. The result presented is a geomorphological map where individual geomorphological features down to metre size can be identified. The study was done in connection with a project focusing on the relationship between geomorphological processes and lacustrine sedimentation. Good knowledge of the geomorphological setting and the related process activity in the catchment is important in studies using lacustrine sediments as environmental archives.
The survey reveals a small–scale geomorphology dominated by a number of different periglacial upfreezing forms together with bedrock–controlled slope processes. Three different geographically separated geomorphological assemblages were recognised with few sediment transportation pathways connecting them. Composition of substrate, soil water content and vegetation cover combined with different slope angles are probably the most important factors controlling the distribution of the geomorphological features.  相似文献   

Discrete diopside in alnöite from Alnö Island     

Peter Kresten  Lars Persson 《Lithos》1975,8(3):187-192

The first occurrence of a discrete diopside nodule in alnöite from Alnö Island is reported. The diopside differs from all other Alnö clinopyroxenes by its subcalcic composition, low titanium content (0.5% TiO₂) and elevated chromium content (0.2% Cr₂O₂). An upper mantle origin for the diopside is suggested. The conditions of equilibration are estimated to 975°C at 15–20 kb. Pressure estimates have been deduced from the geotherm obtained for the Fen (Norway) lherzolites. This geotherm (oceanic type) is regarded as a maximum geotherm for the Alnö intrusion.  相似文献   

Isotopic datings of reddish granitoids in southern Värmland,southwestern Sweden     

Per -Olof Persson  Lars Malmström  Bent T. Hansen 《International Journal of Earth Sciences》1987,76(2):389-406

Three reddish granites from the Gneiss Complex of south-western Sweden have been dated with the U-Pb and one of them also with the Rb-Sr method. The Gneiss Complex consists of two mega-units separated by a tectonic discontinuity. The two granites from the western mega-unit (»the Western Gneiss Segment«) yield zircon upper-intercept ages of 1552 _–36 ⁺³⁸ and 1499 _–36 ⁺³⁶ Ma (2). These ages are minimum estimates of the intrusion ages, but the difference between the obtained and the true age is probably small. This assumption is based on studies of the morphology and internal structures of the zircons and also on air abrasion experiments.The third granite is located in the eastern mega-unit (the »Eastern Gneiss Segment«) and forms a number of small massifs, 50 m in diameter. The U-Pb and Rb-Sr ages agree within the limits of the errors — 1140 _–52 ⁺⁵⁴ Ma (upper intercept) and 1104 ± 100 Ma, respectively — but the obtained age is nevertheless dubious. Thin-section studies reveal that the zircons are heterogeneous with different types of material making up the inner and outer parts. Electron-microscopic studies as well as air abrasion and leaching experiments were performed to establish possible differences in age and chemistry between the inner and outer parts. The central parts are made up of almost pure ZrSiO₄ whereas the outer parts are layered with alternating pure ZrSiO₄ layers and layers rich in trace elements. The leaching and air abrasion data do not indicate any age difference between the inner and outer parts. This supports the validity of the upper-intercept age as an intrusion age.The Rb-Sr age is questionable since the obtained initial⁸⁷Sr/⁸⁶Sr ratio is as low as 0.7027. This cannot possibly be true for a felsic, late Proterozoic granite. A plausible explanation could be a rotation of the isochron due to migration of Rb and Sr during a low-grade event. This event is also responsible for the alteration of the biotites and plagioclases.These data provide additional evidence for extensive ensialic magmatism in the period succeeding the lithosphere-forming event.

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Zusammenfassung Drei rötliche Granite aus dem Südwestschwedischen Gneiskomplex sind mit der U-Pb Methode und einer davon zusätzlich mit der Rb-Sr Methode datiert worden. Der Gneiskomplex besteht aus zwei Haupteinheiten, die tektonisch voneinander getrennt sind. Zwei Granite aus der westlichen Haupteinheit (dem sogenannten »Western Gneiss Segment«) ergeben obere Schnittpunktsalter der Zirkone von 1552 _–36 ⁺³⁸ bzw. 1499 _–36 ⁺³⁶ Ma (2). Diese Alter stellen Minimumalter für die Instrusionen dar, die nur geringfügig jünger sind als die wahren Instrusionsaltern. Diese Vermutung stützt sich auf Untersuchungen der Morphologie und der internen Struktur der Zirkone sowie auf Experimente mit Hilfe der Luftabriebstechnik (air abrasion technique).Der dritte Granit stammt aus der östlichen Haupteinheit (dem sogenannten »Eastern Gneiss Segment«), in der er kleine Körper von etwa 50 m Durchmesser bildet. Die U-Pb und Rb-Sr Alter von 1140 _–52 ⁺⁵⁴ Ma (oberer Schnittpunkt), bzw. 1104 ± 100 Ma stimmen innerhalb des Fehlers überein. Trotzdem ist dieses Alter fragwürdig. Dünnschliffuntersuchungen zeigen, da\ die Zirkone heterogen sind, und da\ Rand und Kern unterschiedlich zusammengesetzt sind. Um Unterschiede in Alter und Chemismus zwischen Rand und Kern festzustellen, wurden Untersuchungen mit dem Elektronenmikroskop, Luftabriebsexperimente und Anätzexperimente durchgeführt. Die Kerne bestehen fast aus reinem ZrSiO₄, wogegen die äu\eren Ränder aus Wechsellagerungen von reinem ZrSiO₄ und Lagen mit hohem Spurenelementgehalt bestehen.Die Anätzversuche und die Luftabriebsexperimente brachten keinen Altersunterschied zwischen Rand und Kern. Diese Tatsachen sprechen dafür, da\ das obere Schnittpunktsalter dem Instrusionsalter entspricht.Das Rb-Sr Alter ist fragwürdig, zumal das⁸⁷Sr/⁸⁶Sr-Initialverhältnis einen sehr niedrigen Wert von 0,7027 aufweist, der für einen spätproterozoischen Granit viel zu niedrig ist. Eine mögliche Erklärung ist die Rotation der Isochrone wegen einer Migration von Rb und Sr während eines Ereignisses bei niedriger Temperatur, ein Ereignis, das auch für die Umwandlung von Biotit und Plagioklas verantwortlich zu sein scheint. Die oben aufgeführten Daten geben zusätzliche Hinweise für einen sialischen Magmatismus im Zeitraum des fortschreitenden Ereignisses der Bildung der Lithosphäre.

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Résumé Trois granites rougeâtres provenant du complexe gneissique du sud-ouest de la Suède ont été datés par la méthode U-Pb et, pour l'un d'entre eux, également par la méthode Rb-Sr. Le complexe gneissique consiste en deux grandes unités séparées par une discontinuité tectonique. Les zircons de deux granites provenant de l'unité occidentale (»Western Gneiss Segment«) fournissent des âges (intersection supérieure) de 1552 _–36 ⁺³⁸ et 1499 _–36 ⁺³⁶ Ma (2). Ces âges constituent des estimations minimales des âges d'intrusion, la différence entre l'âge mesuré et l'âge véritable étant probablement minime. Cette supposition se base sur l'étude de la morphologie et des structures internes des zircons, ainsi que sur des expériences d'abrasion à l'air.Le troisième granite est situé dans l'unité orientale (»Eastern Gneiss Segment«) et se présente en plusieurs massifs d'une cinquantaine de mètres de diamètre. Les âges U-Pb et Rb-Sr coÏncident dans les limites des erreurs (1140 _–52 ⁺⁵⁴ (point d'intersection supérieur) et 1104±100 Ma) l'âge obtenu étant néanmoins incertain. L'étude en coupes minces montre que les zircons sont hétérogènes, leurs parties centrales et périphériques présentant des constitutions différentes. Des examens au microscope électronique, ainsi que des essais d'abrasion à l'air et de corrosion à l'acide ont eté effectués afin de mettre en évidence des différences éventuelles d'âge et de composition chimique entre les parties contrales et périphériques. Tandis que les parties centrales consistent en ZrSiO₄ pratiquement pur, les parties extérieures se composent de couches de ZrSiO₄ pur alternant avec des couches contenant de multiples éléments en traces. Les données obtenues sur les grains corrodés à l'acide ou soumis à une abrasion à l'air n'indiquent cependant pas de différence d'âge entre les parties centrales et périphériques. Ceci confirme la validité de l'âge obtenu (point d'intersection supérieur) comme âge d'intrusion.L'âge Rb-Sr est douteux, étant donné que le rapport initial⁸⁷Sr/⁸⁶Sr n'est que de 0,7027, valeur improbable pour un granite felsique du ProtérozoÏque supérieur. Il paraÎt raisonnable de supposer une rotation de l'isochrone, due à une migration de Rb et Sr durant un événement à basse température. Cet événement serait également responsable de l'altération des biotites et des plagioclases. Ces données fournissent un argument supplémentaire en faveur d'un magmatisme ensialique pendant la période qui suit la formation de la lithosphère.

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- U/Pb, Rb/Sr. , . — . . Western Gneiss Segments — 1552 _–36 ⁺³⁸ 1499 _–36 ⁺³⁶ (2). . , air abrasion technique. — Eastern Gneiss Segments —, 50 . U/Pb 1140 _–52 ⁺⁵⁴ Ma ( ), Rb/Sr - 1104 ± 100 ; , . . , . , : , air abrasion technique . ZrSiO₄, ZrSiO₄, . air abrasion technique . , ., Rb/Sr, , ⁸⁷Sr/⁸⁶Sr (0,7027), . . - . — , , , . , .

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Arsenic in the groundwater of Ouro Preto (Brazil): its temporal behavior as influenced by the hydric regime and hydrogeology     

José Augusto Costa Gonçalves  Jorge Carvalho de Lena  José Fernando Paiva  Hermínio Arias Nalini Jr  Janice Cardoso Pereira 《Environmental Geology》2007,53(4):785-793

In the city of Ouro Preto (MG), water catchment for public supply originates from superficial drainage, springs, old abandoned mines and some driven wells. In the rocks of the region, As is originally found in gold-enriched sulphide-bearing mineral deposits. The weathering process introduces As into the hydrological system by dissolution of this element into the leachate. Measurement of the As content in the groundwater of some catchments was carried out during 1 year and these measurements demonstrated high As content—up to 224 μg L⁻¹ of As(V)—during the rainy season (the maximum concentration limit according to World Health Organization is 10 μg L⁻¹). Lower values were observed during the dry season and in some sampling stations, As was not even detected. The As concentration variability during 1 year shows a strict and direct relationship to seasonal and hydrological conditions. For city authorities, responsible for public water supply, it is necessary to perform a complete inventory of the water sources used and constantly monitor the As content in the water.  相似文献   

An attempt to use LA-ICP-SMS to quantify enrichment of trace elements on pyrite surfaces in oxidizing mine tailings     

Björn Öhlander  Barbara Müller  Mikael Axelsson  Lena Alakangas 《Journal of Geochemical Exploration》2007

Metals released from oxidation and weathering of sulphide minerals in mine tailings are to a high degree retained at deeper levels within the tailings themselves. To be able to predict what could happen in the future with these secondarily retained metals, it is important to understand the retention mechanisms. In this study an attempt to use laser ablation high-resolution ICP-MS (LA-ICP-SMS) to quantify enrichment of trace elements on pyrite surfaces in mine tailings was performed. Pyrite grains were collected from a profile through the pyrite-rich tailings at the Kristineberg mine in northern Sweden. At each spot hit by the laser, the surface layer was analyzed in the first shot, and a second shot on the same spot gave the chemical composition of the pyrite immediately below. The crater diameter for a laser shot was known, and by estimating the crater depth and total pyrite surface, the total enrichment on pyrite grains was calculated. Results are presented for As, Cd, Co, Cu, Ni and Zn. The results clearly show that there was an enrichment of As, Cd, Cu and Zn on the pyrite surfaces below the oxidation front in the tailings, but not of Co and Ni. Arsenic was also enriched on the pyrite grains that survived in the oxidized zone. Copper has been enriched on pyrite surfaces in unoxidized tailings in the largest amount, followed by Zn and As. However, only 1.4 to 3.1% of the Cd and Zn released by sulphide oxidation in the oxidized zone have been enriched on the pyrite surfaces in the unoxidized tailings, but for As and Cu corresponding figures are about 64 and 43%, respectively. There were many uncertainties in these calculations, and the results shall not be taken too literally but allowed the conclusion that enrichment on pyrite surfaces is an important process for retention of As and Cu below the oxidation front in pyrite rich tailings. Laser ablation is not a surface analysis technique, but more of a thin layer method, and gives no information on the type of processes resulting in enrichment on the pyrite surfaces. Although only pyrite grains that appeared to be fresh and without surface coatings were used in this study, the possibility that a thin layer of Fe-hydroxides occurred must be considered. Both adsorption to the pyrite directly or to Fe-oxyhydroxides may explain the enrichment of As, Cd, Cu and Zn on the pyrite surfaces, and, in the case of Cu, also the replacement of Fe(II) by Cu(II) in pyrite.  相似文献