The influence of hydrocarbon expulsion on carbon isotopic compositions of individual n-alkanes in pyrolysates of selected terrestrial kerogens     

Yuhong Liao  Ansong Geng  Yongqiang Xiong  Dehan Liu  Jialan Lu  Jinzhong Liu  Haizu Zhang  Xinhua Geng 《Organic Geochemistry》2004,35(11-12):1479

Expulsion of petroleum from source rock is a complex part of the entire migration process. There exist fractional effects on chemical compositions in hydrocarbon expulsion. Does the carbon isotopic fractionation occur during expulsion and to what extent? Here the influence of hydrocarbon expulsion on carbon isotopic compositions of individual n-alkanes from pyrolysates of selected terrestrial kerogens from Tuha basin and Fushun, Liaoning Province of China has been experimentally studied. The pyrogeneration-expulsion experiments were carried out under semi-closed system. The carbon isotopic compositions of individual n-alkanes were measured by GC-IRMS. The main conclusions are as follows. First, there is carbon isotopic fractionation associated with hydrocarbon expulsion from Type III kerogens in Tuha Basin. There exist differences of carbon isotopic compositions between the unexpelled n-alkanes and expelled n-alkanes from Tuha desmocollinite and Tuha mudstone. Second, there is almost no carbon isotopic fractionation associated with hydrocarbon expulsion from Type II kerogens in Fushun and Liaohe Basin. Third, carbon isotopic fractionation in hydrocarbon expulsion should be considered in making oil-source correlation of Type III kerogens at least in the Tuha Basin. Further studies need to be carried out to determine whether this is true in other basins. Fourth, oil and source at different maturity levels cannot be correlated directly for Type III kerogens since the carbon isotopic compositions of expelled hydrocarbons at different temperatures are different. The expelled hydrocarbons are usually lighter (depleted in ¹³C) than the hydrocarbons remaining in the source rock at the same maturity.  相似文献   

Suspended sediment and total dissolved solid yield patterns at the headwaters of Urumqi River,northwestern China: a comparison between glacial and non‐glacial catchments          下载免费PDF全文

Wenhua Gao  Shu Gao  Zhongqin Li  X. X. Lu  Mingjun Zhang  Shengjie Wang 《水文研究》2014,28(19):5034-5047

In order to understand the differences in the suspended sediment and total dissolved solid (TDS) yield patterns between the glacial and non‐glacial catchments at the headwaters of Urumqi River, northwestern China, water samples were collected from a glacier catchment and an empty cirque catchment within the region, during three melting seasons from 2006 to 2008. These samples were analyzed to estimate suspended sediment and TDS concentrations, fluxes and erosion rates in the two adjoining catchments. There were remarked differences in suspended sediment and TDS yield patterns between the two catchments. Suspended sediment concentrations were controlled mainly by the sediment source, whereas TDS concentrations were primarily related to the hydrologic interaction with soil minerals. Generally, the glacial catchment had much higher suspended sediment and TDS yields, together with higher denudation rates, than the non‐glacial catchment. Overall, glacial catchment was mainly dominated by physical denudation process, whereas the non‐glacial catchment was jointly influenced by physical and chemical denudation processes. The observed differences in material delivery patterns were mainly controlled by the runoff source and the glacial processes. The melting periods of glacier and snow were typically the most important time for the suspended sediment and TDS yields. Meanwhile, episodic precipitation events could generate disproportionately large yields. Subglacial hydrology dynamics, glaciers pluck and grind processes could affect erodibility, and the large quantities of dust stored on the glacier surface provided additional sources for suspended sediment transport in the glacial catchment. These mechanisms imply that, in response to climate change, the catchment behaviour will be modified significantly in this region, in terms of material flux. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Characteristics of the Asian–Pacific Oscillation in Boreal Summer Simulated by BCC_CSM with Different Horizontal Resolutions     

Yazhou Zhang  Zhijie Liao  Yaocun Zhang  Feng Nie 《大气科学进展》2016,33(12):1401-1412

The summer Asian–Pacific Oscillation(APO) is a major teleconnection pattern that reflects the zonal thermal contrast between East Asia and the North Pacific in the upper troposphere. The performance of Beijing Climate Center Climate System Models(BCC CSMs) with different horizontal resolutions, i.e., BCC CSM1.1 and BCC CSM1.1(m), in reproducing APO interannual variability, APO-related precipitation anomalies, and associated atmospheric circulation anomalies, is evaluated.The results show that BCC CSM1.1(m) can successfully capture the interannual variability of the summer APO index. It is also more capable in reproducing the APO's spatial pattern, compared to BCC CSM1.1, due to its higher horizontal resolution. Associated with a positive APO index, the northward-shifted and intensified South Asian high, strengthened extratropical westerly jet, and tropical easterly jet in the upper troposphere, as well as the southwesterly monsoonal flow over North Africa and the Indian Ocean in the lower troposphere, are realistically represented by BCC CSM1.1(m), leading to an improvement in reproducing the increased precipitation over tropical North Africa, South Asia, and East Asia, as well as the decreased precipitation over subtropical North Africa, Japan, and North America. In contrast, these features are less consistent with observations when simulated by BCC CSM1.1. Regression analysis further indicates that surface temperature anomalies over the North Pacific and the southern and western flanks of the Tibetan Plateau are reasonably reproduced by BCC CSM1.1(m), which contributes to the substantial improvement in the simulation of the characteristics of summer APO compared to that of BCC CSM1.1.  相似文献   

“东方之星”客轮翻沉事件周边区域风灾现场调查与多尺度特征分析   总被引：12，自引：3，他引：9  

郑永光  田付友  孟智勇  薛明  姚聃  白兰强  周晓霞  毛旭  王明筠 《气象》2016,42(1):1-13

2015年6月1日21:30左右长江湖北监利段发生"东方之星"客轮翻沉特大事故。本文根据事发周边陆地区域现场天气调查结果,结合卫星和雷达观测资料分析认为,6月1日21:00-21:40左右事发江段和周边区域发生了下击暴流导致的强烈大风灾害,最强风力超过12级,并具有空间分布不连续、多尺度和强灾害时空尺度小等特征。事发周边区域北部受中气旋影响陆地区域(顺星村、老台深水码头、四台村养猪场附近、新沟子养鸡场附近等)灾情较南部阵风锋及其后侧下击暴流影响的陆地区域更为显著。综合雷达观测资料和现场调查资料分析判断多数调查点灾害为显著微下击暴流所致,其中老台深水码头有龙卷发生的可能。导致此次风灾的强对流风暴气流具有显著的多尺度性;事发周边区域北部的四台村养猪场附近树林中同时发生了多条相邻的微下击暴流条迹,呈现出辐散和辐合交替分布的特征,展示了此次强对流风暴中大气运动的复杂分布特点。虽然下击暴流会伴随中小尺度的涡旋特征,但此次现场调查发现的与下击暴流相联系的辐合特征水平尺度仅几十米,远小于弓形回波两端的书挡涡旋或者中涡旋等几千米级的水平尺度。  相似文献   

基于外弹道计算的人影高炮作业安全评估方法     

黎祖贤  刘红武  廖俊  张中波  周盛 《气象科技》2016,44(1):152-156

随着经济的高速发展,各个高炮作业点所在地的周边环境已经发生了很大变化,为了进一步提高人工影响天气作业的安全性,针对高炮作业特点提出了一套安全论证方法。推导了弹道计算的方法,在此基础上结合安全射界法和地理信息系统对作业安全性进行了更精确的评估,并给出实例说明。提出用危险系数的方法进行安全性评估,给出了具体的危险系数定义方法,通过评估系统的一次实际作业评估证明了危险系数进行安全性评估的可行性。以该方法进行安全性评估可有效保障人影作业的安全性,为人影作业提供重要的参考。  相似文献   

FDR自动土壤水分数据标定问题及解决方法   总被引：4，自引：0，他引：4  

周旭辉  王黎明  王建波  陈晨  王爱珍  刘焕乾  廖华 《气象科技》2016,44(4):535-541

针对目前FDR自动土壤水分数据可用性低的实际情况,本文从FDR自动土壤水分站传感器原理出发,结合数据处理流程与方法对湖南60个站点不同层次的标定参数及部分站点的相关观测数据进行了分析,指出目前田间标定法在自然条件下几乎无法得到覆盖土壤各个湿度区间的均匀样本数据,导致二次标定参数不合理是造成FDR自动土壤水分站数据可用性差的根本原因。二次标定方程参数不合理主要表现为方程斜率过大、过小、负值3种情况,导致观测数据增幅过大、常年不变、与实际土壤湿度变化趋势完全相反等问题。最后针对该问题提出了大样本原状取土,实验室标定的解决方法,并对方法进行了初步验证,结果表明该方法能从源头上有效改善土壤水分站观测数据质量。  相似文献   

The impacts of migrant workers consumption on energy use and CO2 emissions in China     

Jing-Li Fan  Hua Liao  Bao-Jun Tang  Su-Yan Pan  Hao Yu  Yi-Ming Wei 《Natural Hazards》2016,81(2):725-743

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刚果(金)地质特征与主要矿产资源概况   总被引：1，自引：0，他引：1  

张学良  姚锦其  邓贵安  徐文彦  黄学强  李明君 《矿产与地质》2016,(4):555-560

刚果(金)主要由刚果盆地和环盆地高原组成,盆地主要由中生代到新生代地层及近现代沉积物组成,沿着盆地内边缘分布有泛非时期的火山沉积物,环盆地高原主要为抬升的前寒武纪基底。刚果(金)优势金属矿产资源主要分布环盆地高原的加丹加新元古代铜-钴多金属成矿带、KIB-KAB中元古代锡-铌-钽-钨多金属成矿带、刚果东北太古代绿岩带型金-铁多金属成矿带上,而金刚石则主要分布开赛及东北部地区中新生代金刚石成矿区内。  相似文献   

Distribution and geochemical significance of trace elements in shale rocks and their residual kerogens     

Jian-bing Xu  Bin Cheng  Qian Deng  Yun-gan Liang  Oluwabamise Lekan Faboya  Ze-wen Liao 《中国地球化学学报》2018,37(6):886-900

There is a dearth of information about the distribution of trace elements in kerogen from shale rocks despite several reports on trace element composition in many shale samples. In this study, trace elements in shale rocks and their residual kerogens were determined by inductively coupled plasma–mass spectrometry. The results from this study show redox-sensitive elements relatively concentrated in the kerogens as compared to the shales. This may be primarily due to the adsorption and complexation ability of kerogen, which enables enrichment in Ni, Co, Cu, and Zn. For the rare earth elements (REEs), distinct distribution characteristics were observed for shales dominated by terrigenous minerals and their kerogen counterparts. However, shales with less input of terrigenous minerals showed similar REE distribution patterns to their residual kerogen. It is speculated that the distribution patterns of the REEs in shales and kerogens may be source-related.  相似文献   

Dual Control of Depositional Facies on Uranium Mineralization in Coal‐bearing Series: Examples from the Tuanyushan Area of the Northern Qaidam Basin,NW China     

GUO Biao  SHAO Longyi  WEN Huaijun  HUANG Guangnan  ZOU Mingjun  LI Yonghong 《《地质学报》英文版》2018,92(2):733-754

The uranium deposits in the Tuanyushan area of northern Qaidam Basin commonly occur in coal-bearing series. To decipher the U-enrichment mechanism and controlling factors in this area, a database of 72 drill cores, including 56 well-logs and 3 sampling wells, was examined for sedimentology and geochemistry in relation to uranium concentrations. The results show that coal-bearing series can influence uranium mineralization from two aspects, i.e., spatial distribution and dynamic control. Five types of uranium-bearing rocks are recognized, mainly occurring in the braided river and braided delta sedimentary facies, among which sandstones near the coals are the most important. The lithological associations of sandstone-type uranium deposits can be classified into three subtypes, termed as U-coal type, coal-U-coal type, and coal-U type, respectively. The coal and fine siliciclastic rocks in the coalbearing series confined the U-rich fluid flow and uranium accumulation in the sandstone near them. Thus, the coal-bearing series can provide good accommodations for uranium mineralization. Coals and organic matters in the coal-bearing series may have served as reducing agents and absorbing barriers. Methane is deemed to be the main acidolysis hydrocarbon in the U-bearing beds, which shows a positive correlation with U-content in the sandstones in the coal-bearing series. Additionally, the δ13 C in the carbonate cements of the U-bearing sandstones indicates that the organic matters, associated with the coal around the sandstones, were involved in the carbonation, one important component of alteration in the Tuanyushan area. Recognition of the dual control of coal-bearing series on the uranium mineralization is significant for the development of coal circular economy, environmental protection during coal utilization and the security of national rare metal resources.  相似文献