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51.
This article aims to generate insights into both private governance and partnerships within the shipping industry, but also tries to improve understanding of the complex process of institutionalisation.This is achieved through a case study of the Clean Shipping Project, a public/private partnership that aims to promote sustainability in the shipping industry. A set of enabling and constraining factors are examined that shape the institutionalisation process and determine to what extent the Clean Shipping Project can establish and expand authority as an industry norm.Overall, the Clean Shipping Project cannot yet be considered a full-fledged private governance institution, because of an insufficient level of collaborative advantage mainly due to weak system robustness and unfavourable market characteristics and conditions. However, institutionalisation is an ongoing process and the future outlook for the Clean Shipping Project remains promising. The Clean Shipping Project is certainly a relevant supplement to existing regulations and there is a basic level of commitment and cohesion within the partnership, so it is not unlikely that in the future this initiative may help to uncouple growth in shipping activities from environmental harm.  相似文献   
52.
A recent dynamo model for Mercury assumes that the upper part of the planet's fluid core is thermally stably stratified because the temperature gradient at the core–mantle boundary is subadiabatic. Vigorous convection driven by a superadiabatic temperature gradient at the boundary of a growing solid inner core and by the associated release of light constituents takes place in a deep sub-layer and powers a dynamo. These models have been successful at explaining the observed weak global magnetic field at Mercury's surface. They have been based on the concept of codensity, which combines thermal and compositional sources of buoyancy into a single variable by assuming the same diffusivity for both components. Actual diffusivities in planetary cores differ by a large factor. To overcome the limitation of the codensity model, we solve two separate transport equations with different diffusivities in a double diffusive dynamo model for Mercury. When temperature and composition contribute comparable amounts to the buoyancy force, we find significant differences to the codensity model. In the double diffusive case convection penetrates the upper layer with a net stable density stratification in the form of finger convection. Compared to the codensity model, this enhances the poloidal magnetic field in the nominally stable layer and outside the core, where it becomes too strong compared to observation. Intense azimuthal flow in the stable layer generates a strong axisymmetric toroidal field. We find in double diffusive models a surface magnetic field of the observed strength when compositional buoyancy plays an inferior role for driving the dynamo, which is the case when the sulphur concentration in Mercury's core is only a fraction of a percent.  相似文献   
53.
As debris‐covered glaciers become a more prominent feature of a shrinking mountain cryosphere, there is increasing need to successfully model the surface energy and mass balance of debris‐covered glaciers, yet measurements of the processes operating in natural supraglacial debris covers are sparse. We report measurements of vertical temperature profiles in debris on the Ngozumpa glacier in Nepal, that show: (i) conductive processes dominate during the ablation season in matrix‐supported diamict; (ii) ventilation may be possible in coarse surface layers; (iii) phase changes associated with seasonal change have a marked effect on the effective thermal diffusivity of the debris. Effective thermal conductivity determined from vertical temperature profiles in the debris is generally ~30% higher in summer than in winter, but values depend on the volume and phase of water in the debris. Surface albedo can vary widely over small spatial scales, as does the debris thickness. Measurements indicate that debris thickness is best represented as a probability density function with the peak debris thickness increasing down‐glacier. The findings from Ngozumpa glacier indicate that the probability distribution of debris thickness changes from positively skewed in the upper glacier towards a more normal distribution nearer the terminus. Although many of these effects remain to be quantified, our observations highlight aspects of spatial and temporal variability in supraglacial debris that may require consideration in annual or multi‐annual distributed modelling of debris‐covered glacier surface energy and mass balance. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
54.
In this article we study the wave-induced drift of large, flexible shallow floating objects, referred to as sheets. When surface waves propagate through a sheet, they provide a mean stress on the sheet, resulting in a mean drift. In response, the sheet generates an Ekman current. The drift velocity of the sheet is determined by (i) the wave-induced stress, (ii) the viscous stress due to the Ekman current, and (iii) the Coriolis force. The sheet velocity and the current beneath the sheet are determined for constant and depth-varying eddy viscosities.  相似文献   
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56.
We analyze the optimal design of a pumping test for estimating hydrogeologic parameters that are subsequently used to predict stream depletion caused by groundwater pumping in a leaky aquifer. A global optimization method is used to identify the test’s optimal duration and the number and locations of observation wells. The objective is to minimize predictive uncertainty (variance) of the estimated stream depletion, which depends on the sensitivities of depletion and drawdown to relevant hydrogeologic parameters. The sensitivities are computed analytically from the solutions of Zlotnik and Tartakovsky [Zlotnik, V.A., Tartakovsky, D.M., 2008. Stream depletion by groundwater pumping in leaky aquifers. ASCE Journal of Hydrologic Engineering 13, 43–50] and the results are presented in a dimensionless form, facilitating their use for planning of pumping test at a variety of sites with similar hydrogeological settings. We show that stream depletion is generally very sensitive to aquitard’s leakage coefficient and stream-bed’s conductance. The optimal number of observation wells is two, their optimal locations are one close to the stream and the other close to the pumping well. We also provide guidelines on the test’s optimal duration and demonstrate that under certain conditions estimation of aquitard’s leakage coefficient and stream-bed’s conductance requires unrealistic test duration and/or signal-to-noise ratio.  相似文献   
57.
A significant practical problem with the pilot point method is to choose the location of the pilot points. We present a method that is intended to relieve the modeler from much of this responsibility. The basic idea is that a very large number of pilot points are distributed more or less uniformly over the model area. Singular value decomposition (SVD) of the (possibly weighted) sensitivity matrix of the pilot point based model produces eigenvectors of which we pick a small number corresponding to significant eigenvalues. Super parameters are defined as factors through which parameter combinations corresponding to the chosen eigenvectors are multiplied to obtain the pilot point values. The model can thus be transformed from having many-pilot-point parameters to having a few super parameters that can be estimated by nonlinear regression on the basis of the available observations. (This technique can be used for any highly parameterized groundwater model, not only for models parameterized by the pilot point method.)  相似文献   
58.
Abandoned mining operations continue to severely degrade many ecosystems worldwide by releasing acidic water and/or heavy metals into surface and groundwater. Contaminant concentrations in affected streams vary with discharge in patterns that reflect both geochemical reactions and variable mixing of contaminated and non-contaminated waters. However, controls on concentration-discharge (C-Q) patterns remain unclear, particularly for constituents that experience changing solubility across redox and pH gradients. Understanding the C-Q behaviour of contaminants aids in predicting both downstream transport and effects on aquatic life under variable flow. Here, we examined the C-Q behaviours of non-reactive (Na, K, Ca, Mg, Cl) and reactive (Fe, Mn, Al, H+, SO42−) solutes in a stream contaminated with acid mine drainage in northeastern Ohio, USA. Concentration-discharge patterns at the watershed outlet primarily reflected mixing of contaminated baseflow with intermittent inputs of high pH water draining from a passive limestone treatment system into the stream. The treatment system acted as an ephemeral tributary that mitigated contamination in the stream by diluting solutes, raising pH, and driving metal precipitation, but only when flow was present during wet seasons. Consequently, AMD-derived reactive solutes (H+, Fe, Mn, Al) decreased with increasing stream discharge while relatively conservative solutes (e.g., Ca, Mg, K, Na) decreased only slightly or were chemostatic. This study highlights both the unique C-Q patterns of reactive solutes when compared to those of non-reactive solutes and the potential for intermittent streams to control C-Q behaviour in headwater catchments.  相似文献   
59.
It is shown that compact designs of multifocus, conical approximations to highly nested Wolter I telescopes, as well as single reflection concentrators, employing realistic graded period W/Si or Ni/C multilayer coatings, allow one to obtain more than 1000 cm2 of on-axis effective area at 40 keV and up to 200 cm2 at 100 keV. The degree of concentration is defined by a focusing factor i.e., the effective area divided by the half power focal area. For the cases studied, this is 400 at 40 keV and 200 at 100 keV for a 2 arcmin imaging resolution. This result is quite insensitive to the specifics of the telescope configuration provided that mirrors can be coated to an inner radius of 3 cm. Specifically we find that a change of focal length from 5 to 12 m affects the effective area by less than 10%. In addition the result is insensitive to the thickness of the individual mirror shell provided that it is smaller than roughly 1 mm. The design can be realized with foils as thin (0.4 mm) as used for ASCA and SODART or with closed, slightly thicker (1.0 mm) mirror shells as used for JET-X and XMM. The effect of an increase of the inner radius is quantified on the effective area for multilayered mirrors up to 9 cm. The calculated Field of View (full width at half maximum), ranges from 9 arcmin at 1 keV to 5 arcmin at 60 keV. Finally, the continuum sensitivity of the design assuming a signal to noise ratio of 5 and a 10% energy bandwidth has been calculated. For a balloon flight observation of 104 sec. with a telescope having 2 arcmin imaging resolution the point source sensitivity is 3 · 10–6 photons/cm2/s/keV up to 70 keV for a W/Si coated telescope and up to 100 keV for a Ni/C coated telescope. For a satellite observation time of 105 sec and an imaging resolution of 1 arcmin the sensitivity is 10–7 photons/cm2/s/keV which demonstrates the great potential of this hard X-ray imaging telescope in the energy range up to 100 keV.  相似文献   
60.
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