Nuclear field shift effects on stable isotope fractionation: a review     

Sha Yang  Yun Liu 《中国地球化学学报》2016,35(3):227-239

An anomalous isotope effect exists in many heavy element isotope systems (e.g., Sr, Gd, Zn, U). This effect used to be called the “odd–even isotope effect” because the odd mass number isotopes behave differently from the even mass number isotopes. This mass-independent isotope fractionation driving force, which originates from the difference in the ground-state electronic energies caused by differences in nuclear size and shape, is currently denoted as the nuclear field shift effect (NFSE). It is found that the NFSE can drive isotope fractionation of some heavy elements (e.g., Hg, Tl, U) to an astonishing degree, far more than the magnitude caused by the conventional mass-dependent effect (MDE). For light elements, the MDE is the dominant factor in isotope fractionation, while the NFSE is neglectable. Furthermore, the MDE and the NFSE both decrease as temperatures increase, though at different rates. The MDE decreases rapidly with a factor of 1/T², while the NFSE decreases slowly with a factor of 1/T. As a result, even at high temperatures, the NFSE is still significant for many heavy element isotope systems. In this review paper, we begin with an introduction of the basic concept of the NSFE, including its history and recent progress, and follow with the potential implications of the inclusion of the NFSE into the kinetic isotope fractionation effect (KIE) and heavy isotope geochronology.  相似文献   

Fractionation characteristics of rare earth elements (REEs) linked with secondary Fe,Mn, and Al minerals in soils     

Chunying Chang  Fangbai Li  Chengshuai Liu  Jianfeng Gao  Hui Tong  Manjia Chen 《中国地球化学学报》2016,35(4):329-339

Soil secondary minerals are important scavengers of rare earth elements (REEs) in soils and thus affect geochemical behavior and occurrence of REEs. The fractionation of REEs is a common geochemical phenomenon in soils but has received little attention, especially fractionation induced by secondary minerals. In this study, REEs (La to Lu and Y) associated with soil-abundant secondary minerals Fe-, Al-, and Mn-oxides in 196 soil samples were investigated to explore the fractionation and anomalies of REEs related to the minerals. The results show right-inclined chondrite-normalized REE patterns for La–Lu in soils subjected to total soil digestion and partial soil extraction. Light REEs (LREEs) enrichment features were negatively correlated with a Eu anomaly and positively correlated with a Ce anomaly. The fractionation between LREEs and heavy REEs (HREEs) was attributed to the high adsorption affinity of LREEs to secondary minerals and the preferred activation/leaching of HREEs. The substantial fractions of REEs in soils extracted by oxalate and Dithionite-Citrate-Bicarbonate buffer solutions were labile (10 %–30 %), which were similar to the mass fraction of Fe (10 %–20 %). Furthermore, Eu was found to be more mobile than the other REEs in the soils, whereas Ce was less mobile. These results add to our understanding of the distribution and geochemical behavior of REEs in soils, and also help to deduce the conditions of soil formation from REE fractionation.  相似文献   

陕北风沙区含砾石工程堆积体坡面产流产沙试验   总被引：1，自引：0，他引：1       下载免费PDF全文

康宏亮  王文龙  薛智德  郭明明  李建明  白芸  邓利强  李艳富 《水科学进展》2016,27(2):256-265

采用室内人工模拟降雨方法,研究了陕北风沙区含砾石工程堆积体边坡的产流产沙过程。结果表明:①砾石存在改变了坡面入渗速率,径流系数受入渗速率的影响,随砾石含量的增加先线性递减后线性递增,并在10%砾石含量处存在阈值;径流系数随降雨强度的增加线性递增。②含砾石堆积体坡面流速较纯土堆积体降低,且随雨强增大,砾石延缓径流流动的作用越显著;雨强对径流流速的影响随砾石含量增加持续减弱。③土壤剥蚀率在产流24~33 min后显著增加,砾石主要对显著增加后的平均剥蚀率产生影响。④雨强1.0 mm/min时,砾石存在促进降雨侵蚀,产沙量增大;雨强大于1.0 mm/min时,砾石具有显著的减沙效应。  相似文献   

Study on the Global Carbon Assimilation System Based on Multisource Remote Sensing Data     

Ju Weimin  Fang Hongliang  Tian Xiangjun  Jiang Fei  Zhan Wenfeng  Liu Yang  Wang Zhengxing  He Jianfeng  Wang Shaoqiang  Peng Shushi  Zhang Yongguang  Zhou Yanlian  Jia Binghao  Yang Dongxu  Fu Yu  Li Rong  Liu Jingxian  Wang Haikun  Li Guicai  Chen Zhuoqi 《地球科学进展》2016,31(11):1105-1110

The Paris agreement signed in April, 2016 aims to balance global anthropogenic carbon emissions and terrestrial carbon sinks by the middle of the 21^st century. To fulfill this goal, it is necessary to calculate carbon fluxes of different regions reliably. The global carbon assimilation system is an effective technique for achieving this goal. The Ministry of Science and Technology of China supports the project entitled as study on the global carbon assimilation system based on multisource remote sensing data through the national key research and development programs for global change and adaptation during the thirteen-five period. This project will develop synergic inversion techniques for retrieving key parameters of biological and atmospheric cycles and for assimilating multisource remote sensing and ground based data. Then, the high resolution global carbon assimilation system coupled with an ecological model will be constructed. This system is able to assimilate jointly multisource observation data and to optimize key model parameters, photosynthesis and respiration carbon fluxes of global terrestrial ecosystems, and anthropogenic carbon emission fluxes of key regions. This system will be used to study quantitatively the spatial and temporal patterns of carbon fluxes of global terrestrial ecosystems and anthropogenic carbon emission fluxes of key regions and to identify the mechanisms driving the global terrestrial carbon sinks and sources. The outputs of this study will be helpful for the fulfillment of the key research and development programs for global change and adaptation and provide valuable data and technical support for the decision-making in China.  相似文献   

Fifteen Years of Ocean Observations with China Argo     

Liu Zenghong  Wu Xiaofen  Xu Jianping  Li Hong  Lu Shaolei  Sun Chaohui  Cao Minjie 《地球科学进展》2016,31(5):445-460

For 15 years since the beginning of China Argo project, China has deployed over 350 profiling floats in Pacific and Indian ocean, and constructed China Argo ocean observing network. Moreover, we have setup the Argo data receiving, processing and distributing system, and developed various Argo data products using Argo observations, which has promoted the progress of ocean data sharing in China. The abundant Argo data have become a main data source in oceanic and atmospheric basic researches and operational applications. A batch of important achievements in basic research and operational application have been brought, e.g. in aspects of tropical cyclone (typhoon), ocean circulation, meso-scale eddy, turbulence, heat/salt storage and transport and water mass, as well as in ocean, atmosphere/climate operational forecasting and predicting. With the extension of the international Argo program from “Core Argo” to “Global Argo”, we are faced with great challenges in the long-term maintaining and sustained developing of our Argo ocean observing network. It is suggested that we should take the opportunity to construct China regional Argo ocean observing network as soon as possible in adjacent northwestern Pacific and Indian ocean using Chinese BeiDou profiling floats, which will make us to take responsibility and obligation of a big country for addressing global climate changes and preventing natural disasters.  相似文献   

Change Analysis of Three Major Antarctic Ice Shelves Based on Multi-source Remote Sensing Data     

Wu Chenxi  Liu Shijie  Tian Yixiang  Tong Xiaohua 《地球科学进展》2016,31(2):206-212

In recent years, melting and calving happen in the Antarctic ice shelves. In this paper, seven periods of coastlines were applied to provide an analysis of the ice front changes of Ross, Filchner-Ronne and Amery ice shelves with the inclusion of 1997 and 2000 Radarsat products, 2003/2004 and 2008/2009 MODIS products and 2006, 2012, 2015 coastline which were extracted from MODIS images. Change area, SCE (Shoreline Change Envelope) and NSM (Net Shoreline Movement) were applied to analyze the variation of the ice shelf front. The results shows that, the ice front of Amery ice shelf has advanced since 1997 and the total outward extension distance of the ice front was about 20 to 25 km while the advance area reached 3.03×10³ km². Ross ice shelf and Filchner-Ronne ice shelf continued to advance after ice calving events under the driver action of glacier. However, the advance area was less than the retreat area and the net change area is respectively -9.39×10³ km² and -5.86×10³ km². The retreat distance of the collapse area were up to 53 km and 39 km in the two biggest ice shelves.  相似文献   

Active Characteristics and Paleoearthquakes in the West Kalpin Nappe Since the Holocene,SW Tianshan Mountain     

Li An  Ran Yongkang  Liu Huaguo  Xu Liangxin 《地球科学进展》2016,31(4):377-390

the Kalpin nappe is an important multiple thrust system. It is important to study the Cenozoic tectonic of the Tianshan Mountain. Holocene active characteristics and paleoearthquake of the Kalpin nappe can be used to evaluate the neotectonic of this area. In this paper, we accurately measured the fault scarp in the front of three thrust-fold faults and analyzed paleoearthquake events in the trenches of the Kalpin nappe. Using the ¹⁰Be exposure age, we obtained those geomorphic surface ages and paleoearthquake times. The result showed that the slip rates of the west Kalpintag fault, aozitag fault and the tuoketag fault were 1.45(+1.68/-0.44) mm/a, 0.81(+0.35/-0.19) mm/a and (0.3±0.05) mm/a, respectively since the Holocene. The slip rate indicated that the increased activity transferred from back-row fault to front-row fault and accorded with the piggy-back propagation model in the Tianshan Mountain. Displacements and recurrence intervals of paleoearthquakes was similar to the slip rate characteristics. It also showed paleoearthquakes in the front row fault were stronger than paleoearthquakes of the back row fault. The strong paleoearthquake which caused the highest surface rupture happened in the Kalpintag fault. The interval of paleoearthquakes was about 4 ka and the displacement of every paleoearthquake was about 3 m in the west Kalpintag fault; the interval of paleoearthquakes was about 2 ka and the displacement of every paleoearthquake was about 1m in the aozitag fault; the tuoketag fault ruptured only one paleoearthquake since 7 ka. The Piqiang tear fault was the tectonic result of different shortening rate between the west Kalpin system and the east Kalpin system. The shortening rate of west Kalpin system was obviously stronger than the east Kalpin system. The huge separation distance was near 20 km between the east and the west back-row fault. Because the slip rate of system transferred to the front-row fault in the piggy-back propagation model, the separation distance (~4 km) between the east and the west front-row fault was increasing.  相似文献   

多元时间序列分析的滑坡演化阶段划分          下载免费PDF全文

罗文强  李飞翱  刘小珊  黄丽 《地球科学》2016,41(4):711-717

滑坡的时间-位移曲线一般具有3个阶段特征,即初始变形阶段、等速变形阶段和加速变形阶段,不同演化阶段加速度具有不同的变化特点.目前往往是依据对加速度曲线特征的分析来人为划分演化阶段,缺少相应的理论支持和定量计算.针对上述问题,选取月降雨量、月库水位高程变化量对滑坡的累计位移建立多因素的时间序列预测模型.然后利用Chow分割点检验理论,以所建模型中F和LR统计量最大值点作为分割点对滑坡演化阶段进行划分.以新滩滑坡和三峡库区白水河滑坡为例,利用累计位移、降雨及库水位变化数据进行计算验证.结果表明,对多元时间序列模型进行Chow分割点检验可对滑坡的演化阶段进行准确划分,为滑坡的临滑预警预报提供重要判据.   相似文献   

Recognition of the early permian volcanic rocks and Its geological significance in chifeng region of inner Mongolia北大核心CSCD     

Peng B.  Wang G.-Q.  Liu L.  Yang Y.  Liu F. 《矿物岩石地球化学通报》2016,(6):1329-1340

In order to investigate the geological significance of the large area of volcanics in the Uplift bell of Mingshan in western Chifeng,When carrying out the I :5 million regional mineral geological survey in the area,Through the research work of field geology investigation, petrology, LA-1CP-MS zircon U-Pb isotopic dating and regional stratigraphic correlation and so on.Found that the volcano rocks in the area is different from the Late Jurassic-Early Cretaceous volcanic rocks. And the obvious green alteration phenomenon was developed : The dating results of the Hornblende andesite in the lower parts is 273. 6±2. 2 Ma,it should belong to the Permian Elitu formation^ The Volcanics in the area belong to Calc-Alkaline-high-k calc-Alkaline series volcanic rocks. And volcanic magma experienced the separation and crystallization of minerals, it was the product of the continuous evolution of cognate magma, having the Characteristics that from bottom to top Intermediate-Mafic to Acidic magmatic evolution and the REE content increased gradually 0 Studies suggest that the Formation of volcanic rocks in the area is related to the ancient Asian Ocean to the North China block subduction in the Late Paleozoic period . It should be formed in the Archean to Proterozoic crystalline basement and late devonian magma Kemelting eruption, the tectonic environment formation of the volcanics in this area was andreessen arcc.  相似文献   

Late mesozoic A-Type granitoids in se China and paleo-pacific plate subduction and slab rollback北大核心CSCD     

Xia Y.  Liu L.  Xu X.-S. 《矿物岩石地球化学通报》2016,(6):1109-1119

This study has reviewed the distribution and pedogenesis of late Mesozoic A-Type granitoids in SE China. These A-Type granitoids belong to four belts ( S Jiangxi-SW Fujian belt, Xiang-Gui-Yue belt, Can-Hang belt and coastal belt) due to their temporal-spatial distribution. Based on the comparative analysis of chronology, geochemistry and magmatic association, this study has discussed the formation of A-Type granitoids and the subduction and slab rollback process of paleo-Pacific plate beneath SE China.  相似文献