Development and Re‐Evaluation of Tourmaline Reference Materials for In Situ Measurement of Boron δ Values by Secondary Ion Mass Spectrometry     

Katharina Marger  Matthieu Harlaux  Andrea Rielli  Lukas P. Baumgartner  Andrea Dini  Barbara L. Dutrow  Anne‐Sophie Bouvier 《Geostandards and Geoanalytical Research》2020,44(3):593-615

Six tourmaline samples were investigated as potential reference materials (RMs) for boron isotope measurement by secondary ion mass spectrometry (SIMS). The tourmaline samples are chemically homogeneous and cover a compositional range of tourmaline supergroup minerals (primarily Fe, Mg and Li end‐members). Additionally, they have homogeneous boron delta values with intermediate precision values during SIMS analyses of less than 0.6‰ (2s). These samples were compared with four established tourmaline RMs, that is, schorl IAEA‐B‐4 and three Harvard tourmalines (schorl HS#112566, dravite HS#108796 and elbaite HS#98144). They were re‐evaluated for their major element and boron delta values using the same measurement procedure as the new tourmaline samples investigated. A discrepancy of about 1.5‰ in δ¹¹B was found between the previously published reference values for established RMs and the values determined in this study. Significant instrumental mass fractionation (IMF) of up to 8‰ in δ¹¹B was observed for schorl–dravite–elbaite solid solutions during SIMS analysis. Using the new reference values determined in this study, the IMF of the ten tourmaline samples can be modelled by a linear combination of the chemical parameters FeO + MnO, SiO₂ and F. The new tourmaline RMs, together with the four established RMs, extend the boron isotope analysis of tourmaline towards the Mg‐ and Al‐rich compositional range. Consequently, the in situ boron isotope ratio of many natural tourmalines can now be determined with an uncertainty of less than 0.8‰ (2s).  相似文献   

Pure elastic stiffness of sand represented by response envelopes derived from cyclic triaxial tests with local strain measurements     

Knittel  Lukas  Wichtmann  Torsten  Niemunis  Andrzej  Huber  Gerhard  Espino  Edgar  Triantafyllidis  Theodoros 《Acta Geotechnica》2020,15(8):2075-2088

Acta Geotechnica - The elastic stiffness of a fine sand at small to moderate strains ( $$\varepsilon \le 2 \times 10^{-4}$$ ) has been studied based on cyclic triaxial tests on cube-shaped samples...  相似文献   

Biotite Reference Materials for Secondary Ion Mass Spectrometry 18O/16O Measurements          下载免费PDF全文

Guillaume Siron  Lukas Baumgartner  Anne‐Sophie Bouvier  Benita Putlitz  Torsten Vennemann 《Geostandards and Geoanalytical Research》2017,41(2):243-253

Five new biotite reference materials were calibrated at the SwissSIMS laboratory (University of Lausanne) for oxygen isotope determination by secondary ion mass spectrometry (SIMS) and are available to the scientific community. The oxygen isotope composition of the biotites, UNIL_B1 to B5, was determined by laser‐heating fluorination to be 11.4 ± 0.11‰, 8.6 ± 0.15‰, 6.1 ± 0.04‰, 7.1 ± 0.05‰ and 7.6 ± 0.04‰, respectively. SIMS analyses on spots smaller than 20 μm gave a measurement repeatability of 0.3‰ (2 standard deviation, 2s). The matrix effect due to solid solution in natural biotite could be expressed as a linear function of X_Mg and X_F for biotite. No effect was found for different crystallographic orientations. SIMS analysis allows the oxygen isotope composition of biotite to be measured with a measurement uncertainty of 0.3–0.4‰ (2s) for biotites with similar major element compositions. A measurement uncertainty of 0.5‰ (2s) is realistic when F poor biotites (lower than 0.2% m/m oxides) within the compositional range of X_Mg of 0.3–0.9 were compared from different sessions. The linear correlation with F content offers a reasonable working curve for F‐rich biotites, but additional reference materials are needed to confirm the model.  相似文献   

Measuring the benefits and costs of community education and outreach in marine protected areas     

Craig Leisher  Sangeeta Mangubhai  Sebastiaan Hess  Hesti Widodo  Tri Soekirman  Salomina Tjoe  Stevanus Wawiyai  S. Neil Larsen  Lukas Rumetna  A. Halim  M. Sanjayan 《Marine Policy》2012

Conservation organizations often invest considerable resources in education and outreach activities in and around marine protected areas (MPAs). The expectation is that such efforts will change local knowledge, attitudes and ultimately behavior. This is one of the first studies to assess the efficacy of using education and outreach activities to improve community knowledge and attitudes about an MPA. Random sample surveys in 2005 and 2010 (n=1213) before and after education and outreach activities are compared. Program budgets for the same period give the investment levels. With an investment level averaging US$24 per capita/year, the result was an average increase of 33% in “yes” responses across 15 indicators of knowledge and attitudes towards marine conservation. The increase in knowledge and positive attitudes was associated with a large decrease in “not sure” responses, suggesting that community members with fewer initial preconceptions are the most effective target for education and outreach activities. This study demonstrates that investments in MPA education and outreach can generate increases in local knowledge and positive attitudes, and changing knowledge and attitudes is expected to contribute to the long-term compliance with MPA regulations.  相似文献   

Dykes, faults and palaeostresses in the Teno and Anaga massifs of Tenerife (Canary Islands)     

L. B. Marinoni  A. Gudmundsson   《Journal of Volcanology and Geothermal Research》2000,103(1-4)

A structural field study was made of 578 sheet intrusions (mostly dykes) and 153 (mostly normal) faults dissecting the Anaga and Teno massifs, where a complex volcanic succession of Tertiary age (the ‘Old Basaltic Series’) representing the shield-building stage of Tenerife (Canary Islands) crops out. Many of the intrusions, mostly sub-vertical mafic dykes, are emplaced by multiple magma injections, with cumulative thicknesses mostly less than 2 m. Dyke tips are exposed and preserved for 12% of the dykes. Three differently oriented sets of dykes exist in the Anaga massif (NNW–SSE, NNE–SSW, E–W), whereas there is only one main set in Teno, trending NNW–SSE. Dyke swarms and other structural features having similar orientations also exist in other Canary Islands. A minimum value of the horizontal component of extension induced by dykes is computed using a step of 5° of azimuth, accounting also for the dip of dykes. The cumulative crustal dilation is at least 300 m (4%) in Anaga and 270 m (6%) in Teno; the maximum extension peaks at N75° in Anaga and N60° in Teno, indicating a general prevailing extension in direction ENE–WSW. Most of the measured faults are normal and strike NNW–SSE. Computation of palaeostresses from inversion of fault-slip data sets suggests the existence of a polyphase brittle deformation due to an extensional stress field with the minimum compressive principal axes trending NE–SW and WNW–ESE.  相似文献   

On entropy and clustering in earthquake hypocentre distributions   总被引：3，自引：0，他引：3  

T. Nicholson  M. Sambridge  & Ó. Gudmundsson 《Geophysical Journal International》2000,142(1):37-51

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Protracted storage of CR chondrules in a region of the disk transparent to galactic cosmic rays          下载免费PDF全文

Antoine S. G. Roth  Knut Metzler  Lukas P. Baumgartner  Beda A. Hofmann  Ingo Leya 《Meteoritics & planetary science》2017,52(10):2166-2177

Renazzo‐type carbonaceous (CR) chondrites are accretionary breccias that formed last. As such they are ideal samples to study precompaction exposures to cosmic rays. Here, we present noble gas data for 24 chondrules and 3 dark inclusion samples (DIs) from Shi?r 033 (CR2). The meteorite was selected based on the absence of implanted solar wind noble gases and an anomalous oxygen isotopic composition of the DIs; the oxygen isotopes match those in CV3 and CO3 chondrites. Our samples contain variable mixtures of galactic cosmic ray (GCR)‐produced cosmogenic noble gases and trapped noble gases of presolar origin. Remarkably, all chondrules have cosmogenic ³He and ²¹Ne concentrations up to 4.3 and 7.1 times higher than the DIs, respectively. We derived an average ³He‐²¹Ne cosmic ray exposure (CRE) age for Shi?r 033 of 2.03 ± 0.20 Ma (2 SD) and excesses in cosmogenic ³He and ²¹Ne in chondrules (relative to the DIs) in the range (in 10^?8 cm³STP/g) 3.99–7.76 and 0.94–1.71, respectively. Assuming present‐day GCR flux density, the excesses translate into average precompaction ³He‐²¹Ne CRE ages of 3.1–27.3 Ma depending on the exposure geometry. The data can be interpreted assuming a protracted storage of a single chondrule generation prior to the final assembly of the Shi?r 033 parent body in a region of the disk transparent to GCRs.  相似文献   

Coastal upwelling along the north coast of Papua New Guinea and SST cooling over the pacific warm pool: A case study for the 2002/03 El Niño event     

Takuya Hasegawa  Kentaro Ando  Keisuke Mizuno  Roger Lukas 《Journal of Oceanography》2009,65(6):817-833

We investigate an overlooked mechanism—coastal upwelling—for sea surface temperature (SST) cooling in the western side of the mean location of the Pacific warm pool (WSWP: 5°S–5°N, 140°E–150°E) prior to El Niño onset. We analyze various observed data such as the TRIangle Trans-Ocean buoy Network (TRITON) moored buoy data, Conductivity-Temperature-Depth (CTD) data, satellite data and a hindcast experiment output by a high-resolution ocean general circulation model (OGCM). We focus on the precondition of the 2002/03 El Niño event, for which many datasets are available. Relatively cool water upwelled along the north coast of Papua New Guinea (PNG) during December 2001, prior to the onset of the 2002/03 El Niño event, and then spread out over a wider area to the northeast. Simultaneously, strong west-northerly surface winds occur along the north coast. Heat budget analysis of TRITON buoy data in the WSWP reveals that negative zonal heat advection due to eastward current is the main factor for cooling the mixed layer in the WSWP in contrast to the warming effect of the surface heat flux during the period. This cooling requires a source of colder water to the west. Similar analysis of OGCM outputs also suggests that the upwelled relatively cool water along the PNG north coast, and its northeastward extension to the equatorial region, contributes to cooling of the surface water over the WSWP mainly via negative zonal heat advection. Similar mechanisms are confirmed also for the 1982/83 and 1997/98 El Niño events by analyses of OGCM outputs and historical SST data. The low SST in the WSWP generated a positive zonal SST gradient together with high SST east of the WSWP. It may contribute to enhancement of the westerly surface wind in this region, leading to the onset of the 2002/03 El Niño event.  相似文献   

Relation between mean stress,thermodynamic, and lithostatic pressure     

Evangelos Moulas  Stefan M. Schmalholz  Yury Podladchikov  Lucie Taj manov  Dimitrios Kostopoulos  Lukas Baumgartner 《Journal of Metamorphic Geology》2019,37(1):1-14

Pressure is one of the most important parameters to be quantified in geological problems. However, in metamorphic systems the pressure is usually calculated with two different approaches. One pressure calculation is based on petrological phase equilibria and this pressure is often termed thermodynamic pressure. The other calculation is based on continuum mechanics, which provides a mean stress that is commonly used to estimate the thermodynamic pressure. Both thermodynamic pressure calculations can be justified by the accuracy and applicability of the results. Here, we consider systems with low‐differential stress (<1 kbar) and no irreversible volumetric deformation, and refer to them as conventional systems. We investigate the relationship between mean stress and thermodynamic pressure. We discuss the meaning of thermodynamic pressure and its calculation for irreversible processes such as viscous deformation and heat conduction, which exhibit entropy production. Moreover, it is demonstrated that the mean stress for incompressible viscous deformation is essentially equal to the mean stress for the corresponding viscous deformation with elastic compressibility, if the characteristic time of deformation is five times longer than the Maxwell viscoelastic relaxation time that is equal to the ratio of shear viscosity to bulk modulus. For typical lithospheric rocks, this Maxwell time is smaller than c. 10,000 years. Therefore, numerical simulations of long‐term (>10 kyr) geodynamic processes, employing incompressible deformation, provide mean stress values that are close to the mean‐stress value associated with elastic compressibility. Finally, we show that for conventional systems the mean stress is essentially equal to the thermodynamic pressure. However, mean stress and, hence, thermodynamic pressure can be significantly different from the lithostatic pressure.  相似文献   

Tjörnes fracture zone. New and old seismic evidences for the link between the North Iceland rift zone and the Mid-Atlantic ridge   总被引：1，自引：1，他引：0  

Ragnar Stefansson  Gunnar B. Gudmundsson  Pall Halldorsson 《Tectonophysics》2008,447(1-4):117

The Tjörnes facture zone (TFZ) connects the EW extension of the Mid-Atlantic ridge north of Iceland to the extension of the North volcanic zone (NVZ) of Iceland. Earthquakes up to magnitude 7 (Ms) can occur in TFZ, volcanic eruptions have been observed and large crustal deformations are expected in similar way as have been observed in the NVZ. Most of the zone is below ocean, which limits the historical information and geological observations. For studying the dynamics of the zone we must rely on interpretation and modelling based on seismic observations, especially on microearthquake observations for the last 10 years. In this paper we demonstrate how microearthquakes can be applied to map the details of the plate boundary, and how this information can be applied to find epicenters and fault planes of large historical earthquakes, also how seismic information can be applied in dynamic modelling and to infer spatial and temporal interplay in activity, and to enhance hazard assessment.  相似文献