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951.
Conventional understanding of the nitrogen cycle in marine sediments has changed in recent years with the discovery of an alternative pathway for ammonia oxidation via the reduction of manganese oxides (during anoxic nitrification). In anoxic sediments, the potential for manganese oxides to serve as oxidant for nitrification may be considerable yet previous work on manganese-rich sediments has suggested anoxic nitrification may not be significant. In this study, the potential for anoxic nitrification in a range of sediment types was investigated. Laboratory incubation of sediment from three sites on the Humber Estuary, a microbially diverse environment, showed anoxic accumulation of nitrate, nitrite and dinitrogen gas, with and without the addition of synthetic manganese oxides. Incubation experiments confirmed anoxic nitrification as microbially mediated, with heat-killed controls yielding negative results. The anoxic nitrification reaction significantly depleted ammonia concentrations, and occurred simultaneously with manganese-, iron- and sulphate reduction, and methanogenesis. Taken in conjunction with other studies, results suggest anoxic nitrification may not only be dependent on total manganese concentrations but on manganese dynamics. Anoxic nitrification may be explained as a non-steady state reaction, dependent on the recent stability of a sediment system. Physical perturbation of sediments may cause the redistribution and/or introduction of manganese oxides and promote anoxic nitrification. The significance and persistence of anoxic nitrification is likely to depend on the frequency and magnitude of sediment perturbation, which explains why the reaction varies so widely across studied sites, and why it may not occur in some manganese-rich sediment. 相似文献
952.
Paul R. Craddock Olivier J. Rouxel Lary A. Ball Wolfgang Bach 《Chemical Geology》2008,253(3-4):102-113
We have developed a technique for the accurate and precise determination of 34S/32S isotope ratios (δ34S) in sulfur-bearing minerals using solution and laser ablation multiple-collector inductively coupled plasma mass spectrometry (MC-ICP-MS). We have examined and determined rigorous corrections for analytical difficulties such as instrumental mass bias, unresolved isobaric interferences, blanks, and laser ablation- and matrix-induced isotopic fractionation. Use of high resolution sector-field mass spectrometry removes major isobaric interferences from O2+. Standard-sample bracketing is used to correct for the instrumental mass bias of unknown samples. Background on sulfur masses arising from memory effects and residual oxygen-tailing are typically minor (< 0.2‰, within analytical error), and are mathematically removed by on-peak zero subtraction and by bracketing of samples with standards determined at the same signal intensity (within 20%). Matrix effects are significant (up to 0.7‰) for matrix compositions relevant to many natural sulfur-bearing minerals. For solution analysis, sulfur isotope compositions are best determined using purified (matrix-clean) sulfur standards and sample solutions using the chemical purification protocol we present. For in situ analysis, where the complex matrix cannot be removed prior to analysis, appropriately matrix-matching standards and samples removes matrix artifacts and yields sulfur isotope ratios consistent with conventional techniques using matrix-clean analytes. Our method enables solid samples to be calibrated against aqueous standards; a consideration that is important when certified, isotopically-homogeneous and appropriately matrix-matched solid standards do not exist. Further, bulk and in situ analyses can be performed interchangeably in a single analytical session because the instrumental setup is identical for both. We validated the robustness of our analytical method through multiple isotope analyses of a range of reference materials and have compared these with isotope ratios determined using independent techniques. Long-term reproducibility of S isotope compositions is typically 0.20‰ and 0.45‰ (2σ) for solution and laser analysis, respectively. Our method affords the opportunity to make accurate and relatively precise S isotope measurement for a wide range of sulfur-bearing materials, and is particularly appropriate for geologic samples with complex matrix and for which high-resolution in situ analysis is critical. 相似文献
953.
Using ALSM to map sinkholes in the urbanized covered karst of Pinellas County,Florida—1, methodological considerations 总被引:1,自引:0,他引:1
Larry D. Seale Lee J. Florea H. L. Vacher Robert Brinkmann 《Environmental Geology》2008,54(5):995-1005
Comparison of a database of interpreted sinkholes made using airborne laser swath mapping (ALSM) with databases of sinkholes
made from interpretation of aerial photographs reveals substantial disagreement. The discrepancies involve the location, number,
areas, and circularity of interpreted sinkholes. Methodological factors that contribute to the discrepancies include blockage
of ALSM laser returns in thick vegetation, multi-path reflections, and misrepresentation of the true extent of sinkholes.
Comparison of two ALSM-derived databases made (1) independently from versus (2) in combination with earlier air photo analysis
in undeveloped regions had the following result: one-fourth of the sinkholes interpreted by using the composite method were
missed by the independent analysis, and one-third of the sinkholes that were interpreted from the independent analysis were
not interpreted as sinkholes using the composite method. Subjective interpretation leads to a high level of uncertainty such
that the results of the remote sensing studies are suspect, if not invalid. 相似文献
954.
Improper design, faulty planning, mismanagement and incorrect operation of irrigation schemes are the principle reasons for
the deterioration of groundwater quality in a large number of countries, in particular in semi-arid and arid regions. The
aim of this study is to determine the dimensions of groundwater quality after surface irrigation was begun in the semi-arid
Harran Plain. Physical and chemical parameters of the groundwater including pH, temperature, electrical conductivity (EC),
sodium, potassium, calcium, magnesium, chloride, bicarbonate, sulphate, nitrate, nitrite, ammonium, total phosphorus, total
organic carbon and turbidity were determined monthly during the 2006 water year. The quality of the groundwater in the study
area was assessed hydrochemically in order to determine its suitability for human consumption and agricultural purposes. In
the general plain, the EC values measured were considerably above the guide level of 650 μS/cm, while nitrate in particular
was found in almost all groundwater samples to be significantly above the maximum admissible concentration of 50 mg/l for
the quality of water intended for human consumption as per the international and national standards. Total hardness reveals
that a majority of the groundwater samples fall in the very hard water category. Interpretation of analytical data shows that
Ca–HCO3 and Ca–SO4 are the dominant hydrochemical facies in the study area. 相似文献
955.
Delineation of groundwater protection zones by the backward particle tracking method: theoretical background and GIS-based stochastic analysis 总被引:1,自引:0,他引:1
Konstadinos N. Moutsopoulos Alexandra Gemitzi Vassilios A. Tsihrintzis 《Environmental Geology》2008,54(5):1081-1090
The backward particle tracking method, an effective and powerful tool that can be used to delineate groundwater protection
zones, is presented. The theoretical background and insights on the applicability of this method are provided. Moreover, the
present work enriches the backward particle tracking method with an uncertainty analysis concerning the porosity values, applying
a Monte Carlo (MC) approach, coupled with the use of geographical information systems (GIS). As an application example, a
wellfield in the Komotini area, Greece, is investigated. The present study may serve as a potential guideline for wellfield
delineation, particularly in areas like Greece where lack of data related to the hydrogeological system is often a problem. 相似文献
956.
The uptake and release of trace metals (Cu, Ni, Zn, Cd, and Co) in estuaries are studied using river and sea end-member waters
and suspended particulate matter (SPM) collected from the Changjiang Estuary, China. The kinetics of adsorption and desorption
were studied in terms of environmental factors (pH, SPM loading, and salinity) and metal concentrations. The uptake of the
metals studied onto SPM occurred mostly within 10 h and reached an asymptotic value within 40 h in the Changjiang Estuary.
As low pH river water flows into the high pH seawater and the water become more alkaline as it approaches to the seaside of
estuary, metals adsorb more on SPM in higher pH water, thus, particulate phase transport of metal become increasingly important
in the seaward side of the estuary. The percentage of adsorption recovery and the distribution coefficients for trace metals
remained to be relatively invariable and a significant reduction only occurred in very high concentrations of metals (>0.1 mg L−1). The general effect of salinity on metal behavior was to decrease the degree of adsorption of Cu, Zn, Cd, Co, and Ni onto
SPM but to increase their adsorption equilibrium pH. The adsorption–desorption kinetics of trace metals were further investigated
using Kurbatov adsorption model. The model appears to be most useful for the metals showing the conservative behavior during
mixing of river and seawater in the estuary. Our work demonstrates that dissolved concentration of trace metals in estuary
can be modeled based on the metal concentration in SPM, pH and salinity using a Kurbatov adsorption model assuming the natural
SPM as a simple surfaced molecule. 相似文献
957.
Multivariate analysis of heavy metal contents of sediments from Gumusler creek, Nigde, Turkey 总被引:2,自引:0,他引:2
In this study, heavy metal contents of samples from Gumusler creek in Turkey were studied and the metal contamination characteristics
were investigated. In this respect, considering the pollutant sites in the area, systematic sediment samples were collected
in a zone starting from the manifestation part of the water to the entrance of the Karasu creek in Gumusler town. Samples
were taken from lower section of the river bed at 30 stations along Gumusler creek, 13 km in length and their heavy metal
contents were analyzed with XRF Spectrometer. Correlation coefficients, element coefitic coefficient correlation, dendogram
hierarchical cluster, model summary and Annova analysis statistical methods were applied to data. Strong positive correlations
were determined for some elements which are believed to have possibly the same origin. In addition, mineralizations in the
area are thought to cause variation in metal contents. Results of chemical analysis show that soil limit values and clark
values were exceeded. The heavy metal accumulation in the creek is believed to be derived from non-operated Sb-Hg-W and Fe
quarries. 相似文献
958.
Anne Marie de Grosbois 《Environmental Geology》2008,54(5):1121-1126
959.
The carbonate-rock aquifer in the Great Valley, West Virginia, USA, was evaluated using a database of 687 sinkholes and 350
specific capacity tests to assess structural, lithologic, and topographic influences on the groundwater flow system. The enhanced
permeability of the aquifer is characterized in part by the many sinkholes, springs, and solutionally enlarged fractures throughout
the valley. Yet, vertical components of subsurface flow in this highly heterogeneous aquifer are currently not well understood.
To address this problem, this study examines the apparent relation between geologic features of the aquifer and two spatial
indices of enhanced permeability attributed to aquifer karstification: (1) the distribution of sinkholes and (2) the occurrence
of wells with relatively high specific capacity. Statistical results indicate that sinkholes (funnel and collapse) occur primarily
along cleavage and bedding planes parallel to subparallel to strike where lateral or downward vertical gradients are highest.
Conversely, high specific capacity values are common along prominent joints perpendicular or oblique to strike. The similarity
of the latter distribution to that of springs suggests these fractures are areas of upward-convergent flow. These differences
between sinkhole and high specific capacity distributions suggest vertical flow components are primarily controlled by the
orientation of geologic structure and associated subsurface fracturing. 相似文献
960.
Controlling of landsides safely and economically is a great challenge to mine operators because landslides are major geological
problems especially in open-pit mines. In this paper, a case history at Panluo open-pit mine is presented in detail to share
the experiences and lessons with mine operators. Panluo open-pit mine is located in the southwestern Fujian province of China.
It is the largest open-pit iron mine in the Fujian province and was planned in 1965 and is in full operation from 1978. In
July 1990, an earthquake of magnitude 5.3 in Taiwan Strait and big rainstorms impacted the mine slope, causing tension cracks
and rather large-scale failures, and forming a U-shaped landslide. Total potential volume was estimated to be up to 1.0 × 106 m3. This directly threatened the mine production. In order to protect the mine production and the dwellers’ safety around, a
dynamic comprehensive method was implemented including geotechnical investigations, in-situ testing and monitoring, stability
analysis, and many mitigation and preventive measures. These measures slowed down the development and further occurrence of
the landslide. The results showed that the landslides were still active, it was slowed with the control measures and moved
rapidly with rainfall and mining down. However, no catastrophic accidents occurred and the pit mining was continued till it
was closed at the elevation of 887 m in 2000. As a successful case of landslide control at an open-pit mine for 10 years,
this paper reports the controlling measures in details. These experiences of landslide control may be beneficial to other
similar mines for landslide control. 相似文献