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31.
Xavier Mangenot Jean‐Francois Deoninck Magali Bonifacie Virgile Rouchon Pierre‐Yves Collin Didier Quesne Marta Gasparrini Jean‐Pierre Sizun 《Basin Research》2019,31(2):361-379
Assessing the thermal evolution of sedimentary basins over time is a major aspect of modern integrated basin analysis. While the behavior of clay minerals and organic matter with increasing burial is well documented in different geological and thermal settings, these methods are often limited by the temperature ranges over which they can be precisely applied and by the available material. Here, we explore the emergent Δ47 clumped isotope geospeedometry (based on the diffusional redistribution of carbon and oxygen isotopes in the carbonate lattice at elevated temperatures) to refine time‐temperature paths of carbonate rocks during their burial evolution. This study provides a reconstruction of the thermal and exhumation history of the Upper Cretaceous thrust belt series in the western subalpine massifs (Bauges and Bornes, French Alps) by a new approach combining for the first time available data from three independent geothermometers. The investigated area presents two zones affected by contrasting thermal histories. The most external zone has undergone a relatively mild thermal history (T < 70°C) and does not record any significant clay mineral diagenetic transformation. By contrast, the internal zone has experienced tectonic burial (prealpine nappes) in response to thrusting, resulting in overheating (T > 160–180°C) that induced widespread clay mineral diagenetic transformations (progressive illitization from R0 to R1 and R3 illite‐smectite mixed‐layers), organic matter maturation (oil window) and Δ47 thermal resetting with apparent equilibrium temperatures above 160°C. The three employed geothermal indicators conjointly reveal that the investigated Upper Cretaceous rocks have suffered a wide range of burial temperatures since their deposition, with a thermal maximum locally up to 160–180°C. High temperatures are associated with the tectonic emplacement of up to 4 km of prealpine nappes in the northern part of the studied area. Finally, a forward thermal modeling using Δ47, vitrinite reflectance and clay mineral data, is attempted to precisely refine the burial and exhumation histories of this area. 相似文献
32.
Sergio Caetano-Filho Pierre Sansjofre Magali Ader Gustavo M.Paula-Santos Cristian Guacaneme Marly Babinski Carolina Bedoya-Rueda Matheus Kuchenbecker Humberto L.S.Reis Ricardo I.F.Trindade 《地学前缘(英文版)》2021,12(1):203-218
Carbon isotope compositions of both sedimentary carbonate and organic matter can be used as key proxies of the global carbon cycle and of its evolution through ... 相似文献
33.
Christopher J. Daughney Matthias Raiber Magali Moreau-Fournier Uwe Morgenstern Rob van der Raaij 《Hydrogeology Journal》2012,20(1):185-200
Baseline monitoring of groundwater quality aims to characterize the ambient condition of the resource and identify spatial or temporal trends. Sites comprising any baseline monitoring network must be selected to provide a representative perspective of groundwater quality across the aquifer(s) of interest. Hierarchical cluster analysis (HCA) has been used as a means of assessing the representativeness of a groundwater quality monitoring network, using example datasets from New Zealand. HCA allows New Zealand??s national and regional monitoring networks to be compared in terms of the number of water-quality categories identified in each network, the hydrochemistry at the centroids of these water-quality categories, the proportions of monitoring sites assigned to each water-quality category, and the range of concentrations for each analyte within each water-quality category. Through the HCA approach, the National Groundwater Monitoring Programme (117 sites) is shown to provide a highly representative perspective of groundwater quality across New Zealand, relative to the amalgamated regional monitoring networks operated by 15 different regional authorities (680 sites have sufficient data for inclusion in HCA). This methodology can be applied to evaluate the representativeness of any subset of monitoring sites taken from a larger network. 相似文献
34.
The activities of particulate and soluble phosphatase were analyzed monthly for 1 year in the coastal ecosystems of the NW Mediterranean Sea. The mean contribution of the particulate activity increased from 56% at an MUF-P concentration of 30 μM to 77% at 0.04 μM. This particulate activity was negatively correlated with the DIP, DOP and TDP concentrations when the activities were related to the seawater volume, chlorophyll a or the protein concentration. The TDP correlations were highly significant (p: 0.001). The DOP correlations were significant (p: 0.04) and became highly significant (p: 0.009) at low DIP concentrations (<0.13 μM). The DIP correlations were significant (p: 0.04) only at low DOP concentrations (<0.18 μM). Thus, the effects of seawater DIP and DOP were found to be linked. The soluble activity exhibited distinct phosphatase fractions with high (0.5–29.5 μM) and low (0.02–2 μM) Km values, but none exhibited significant correlations with phosphorus compounds. 相似文献
35.
Denis Wirrmann Anne-Marie Sémah Jean-Pierre Debenay Magali Chacornac-Rault 《Quaternary Research》2011,76(2):229-242
Multiproxy analysis of three littoral cores from western New Caledonia supports the hypothesis that the main controlling factors of environmental changes are sea-level change, ENSO variability and extra-tropical phenomena, such as the Medieval Warm Period (MWP) marked by a tendency for La Niña-like conditions in the tropical Pacific. The record starts during the late Holocene sea-level rise when the terrestrial vegetation indicated wet and cool conditions. The site was a coastal bay definitely transformed into a freshwater swamp at around 3400 cal yr BP, after the rapid drawdown of sea level to its current level. Sediments and foraminiferal assemblages indicated subsequent episodes of freshwater infillings, emersion or very high-energy conditions, likely related to climatic changes and mostly controlled by ENSO variability. Between 2750 and 2000 cal yr BP, relatively dry and cool climate prevailed, while wetter conditions predominated between ca. 1800 and 900 cal yr BP. The Rhizophoraceae peak between ca. 1080 and 750 cal yr BP, coeval with the MWP, may indicate a global phenomenon. Microcharcoal particles present throughout the record increased after 1500 cal yr BP, suggesting an anthropogenic source. From ca. 750 cal yr BP the appearance of current type of vegetation marks the human impact. 相似文献
36.
Jaume Bech Magali Suarez Ferran Reverter Pedro Tume Pedro Sánchez Joan Bech Alejandro Lansac 《Journal of Geochemical Exploration》2010
Selenium is an essential trace element in regard to human and other animals' health, but it presents a narrow range of dietary deficiency and toxic excess. Some phosphate rocks are rich in selenium. Furthermore it is necessary to control selenium's and other trace elements’ compositions in the phosphate rocks, because phosphorite ores of different geographical sites are varied, and even ores from the same outcrop can vary substantially in trace element levels. 相似文献
37.
Rainer Dähn André M ScheideggerAlain Manceau Michel L Schlegel Bart BaeyensMichael H Bradbury Magali Morales 《Geochimica et cosmochimica acta》2002,66(13):2335-2347
Wet chemistry kinetics and powder and polarized extended X-ray absorption fine structure (EXAFS and P-EXAFS) spectroscopy were combined to investigate the mechanism of Ni uptake on montmorillonite, at pH 8, high ionic strength (0.2 M Ca(NO3)2), initial Ni concentration of 660 μM, and solid concentration of 5.3 g/L. Approximately 20% of Ni sorbed within the first 24 h; thereafter, the Ni uptake rate slowed, and 12% of the initial Ni concentration remained in solution after 206 d of reaction time. Powder EXAFS spectra collected on wet pastes at 1, 14, 90, and 206 d showed the presence of Ni-Ni pairs at ∼3.08 Å in an amount that gradually increased with time. Results were interpreted by the nucleation of a Ni phase having either an α-Ni-hydroxide- or a Ni-phyllosilicate-like local structure. The latter possibility was confirmed by recording P-EXAFS spectra of a highly textured, self-supporting montmorillonite film prepared in the same conditions as the wet samples and equilibrated for 14 d. The orientation distribution of the c*-axes of individual clay particles off the film plane, as measured by quantitative texture analysis, was 32.8° full width at half maximum, and this value was used to correct from texture effect the effective numbers of Ni and Si nearest neighbors determined by P-EXAFS. Ni atoms were found to be surrounded by 2.6 ± 0.5 Ni atoms at 3.08 Å in the in-plane direction and by 4.2 ± 0.5 Si atoms at 3.26 Å in the out-of-plane direction. These structural parameters, but also the orientation and angular dependence of the Ni and Si shells, strongly support the formation of a Ni phyllosilicate having its layers parallel to the montmorillonite layers. The neoformation of a phyllosilicate on metal uptake on montmorillonite, documented herein for the first time, has important geochemical implications because this dioctahedral smectite is overwhelmingly present in the environment. The resulting sequestration of sorbed trace metals in sparingly soluble phyllosilicate structure may durably decrease their migration and bioavailability at the Earth’s surface and near surface. 相似文献
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39.
Thomas Franck Rizza Magali Bellier Olivier Billant Jérémy Dussouillez Philippe Fleury Jules Delanghe Doriane Ollivier Vincent Godard Vincent Talon Brigitte 《Natural Hazards》2021,105(2):1453-1490
Natural Hazards - The Provence region, located in the south-east of France, has experienced a few destructive earthquakes during the last centuries, such as the 1909 Lambesc earthquake or the 1509... 相似文献
40.
Alix Toulier Jean-Lambert Join Pierre Staménoff Yoan Benoit Geneviève Lebeau Maxime Gautier Caroline Gorge Eric Gayer Emmanuel Cordier Victor Kbidi Guillaume Payen Magali David Sophie Ferreira François Bonnardot Julien Bonnier Stéphane Martel Jimmy Gonthier Emilie Roulleau Jean-Pierre Cammas Dominique Strasberg Olivier Flores Fabrice R. Fontaine Thomas Giambelluca Claudine Ah-Peng 《水文研究》2024,38(2):e15061
Tropical volcanic islands are biodiversity hotspots where the Critical Zone (CZ) still remains poorly studied. In such steep topographic environments associated with extreme climatic events (cyclones), deployment and maintenance of monitoring equipment is highly challenging. While a few Critical Zone Observatories (CZOS) are located in tropical volcanic regions, none of them includes a Tropical Montane Cloud Forest (TMCF) at the watershed scale. We present here the dataset of the first observatory from the French network of critical zone observatories (OZCAR) located in an insular tropical and volcanic context, integrating a ‘Tropical Montane Cloud Forest’: The ERORUN-STAFOR observatory. This collaborative observatory is located in the northern part of La Réunion island (Indian Ocean) within the 45.0 km2 watershed of Rivière des Pluies (i.e., Rainfall river) which hosts the TMCF of Plaines des Fougères, one of the best preserved natural habitats in La Réunion Island. Since 2014, the ERORUN-STAFOR monitoring in collaboration with local partners collected a multidisciplinary dataset with a constant improvement of the instrumentation over time. At the watershed scale and in its vicinity, the ERORUN-STAFOR observatory includes 10 measurement stations covering the upstream, midstream and downstream part of the watershed. The stations record a total of 48 different variables through continuous (sensors) or periodic (sampling) monitoring. The dataset consists of continuous time series variables related to (i) meteorology, including precipitation, air temperature, relative humidity, wind speed and direction, net radiation, atmospheric pressure, cloud water flux, irradiance, leaf wetness and soil temperature, (ii) hydrology, including water level and temperature, discharge and electrical conductivity (EC) of stream, (iii) hydrogeology, including (ground)water level, water temperature and EC in two piezometers and one horizontally drilled groundwater gallery completed by soil moisture measurements under the canopy. The dataset is completed by periodic time series variables related to (iv) hydrogeochemistry, including field parameters and water analysis results. The periodic sampling survey provides chemical and isotopic compositions of rainfall, groundwater, and stream water at different locations of this watershed. The ERORUN-STAFOR monitoring dataset extends from 2014 to 2022 with an acquisition frequency from 10 min to hourly for the sensor variables and from weekly to monthly frequency for the sampling. Despite the frequent maintenance of the monitoring sites, several data gaps exist due to the remote location of some sites and instrument destruction by cyclones. Preliminary results show that the Rivière des Pluies watershed is characterized by high annual precipitation (>3000 mm y−1) and a fast hydrologic response to precipitation (≈2 h basin lag time). The long-term evolution of the deep groundwater recharge is mainly driven by the occurrence of cyclone events with a seasonal groundwater response. The water chemical results support existing hydrogeological conceptual models suggesting a deep infiltration of the upstream infiltrated rainfall. The TMCF of Plaine des Fougères shows a high water storage capacity (>2000% for the Bryophytes) that makes this one a significant input of water to groundwater recharge which still needs to be quantified. This observatory is a unique research site in an insular volcanic tropical environment offering three windows of observation for the study of critical zone processes through upstream-midstream-downstream measurements sites. This high-resolution dataset is valuable to assess the response of volcanic tropical watersheds and aquifers at both event and long-term scales (i.e., global change). It will also provide insights in the hydrogeological conceptual model of volcanic islands, including the significant role of the TMCFs in the recharge processes as well as the watershed hydrosedimentary responses to extreme climatic events and their respective evolution under changing climatic conditions. All data sets are available at https://doi.org/10.5281/zenodo.7983138 . 相似文献