Coal mining‐derived ochres in the UK: a potential selenium trap     

Liam A. Bullock  John Parnell  Magali Perez  Joseph G.T. Armstrong 《Geology Today》2019,35(4):140-145

Thanks to the pioneering research of Paul Younger over the past 20 years, acid mine drainage in the UK has been recognized as a major environmental issue. Acid mine drainage and hydrous ferric oxide deposition are environmental hazards resulting from centuries of extensive coal mining activities across the UK. Oxidative weathering of pyrite in coal from spoil heaps and exposed bedrock can liberate trace elements, releasing them into local water systems. In addition to posing an environmental threat through water and ground contamination, ochres can also act as a remediation material, trapping elements such as selenium. Trace elements with a close association to iron oxides, such as selenium, may fix to the fine‐grained ochre materials, resulting in hyper‐enriched ochres. Selenium in coals has been known to cause an environmental issue in areas of North America but is also an important commodity for solar cells and nanotechnologies. Coal‐bearing areas of the UK, such as Northumberland, are known to contain a high selenium content, and coal‐derived ochres in these regions also contain significant selenium. The widespread occurrence of ochres in UK coal‐mining regions may therefore present a unique ‘E tech’ trace element source and prevent a toxicity problem for which they were once thought to be responsible.  相似文献   

Climatic and structural controls on Late-glacial and Holocene rockfall occurrence in high-elevated rock walls of the Mont Blanc massif (Western Alps)     

Xavi Gallach  Julien Carcaillet  Ludovic Ravanel  Philip Deline  Christophe Ogier  Magali Rossi  Emmanuel Malet  David Garcia-Sellés 《地球表面变化过程与地形》2020,45(13):3071-3091

In the Mont Blanc massif (European Western Alps), rockfalls are one of the main natural hazards for alpinists and infrastructure. Rockfall activity after the Little Ice Age is well documented. An increase in frequency during the last three decades is related to permafrost degradation caused by rising air temperatures. In order to understand whether climate exerts a long-term control on rockfall occurrence, a selection of paleo-rockfall scars was dated in the Glacier du Géant basin [>3200 m above sea level (a.s.l.)] using terrestrial cosmogenic nuclides. Rockfall occurrence was compared to different climatic and glacial proxies. This study presents 55 new samples (including replicates) and 25 previously-published ages from nine sampling sites. In total, 62 dated rockfall events display ages ranging from 0.03 ± 0.02 ka to 88.40 ± 7.60 ka. Holocene ages and their uncertainties were used to perform a Kernel density function into a continuous dataset displaying rockfall probability per 100 years. Results highlight four Holocene periods of enhanced rockfall occurrence: (i) c. 7–5.7 ka, related to the Holocene Warm Periods; (ii) c. 4.5–4 ka, related to the Sub-boreal Warm Period; (iii) c. 2.3–1.6 ka, related to the Roman Warm Period; and (iv) c. 0.9–0.3 ka, related to the Medieval Warm Period and beginning of the Little Ice Age. Laser and photogrammetric three-dimensional (3D) models of the rock walls were produced to reconstruct the detached volumes from the best-preserved rockfall scars (≤0.91 ± 0.12 ka). A structural study was carried out at the scale of the Glacier du Géant basin using aerial photographs, and at the scale of four selected rock walls using the 3D models. Two main vertical and one horizontal fracture sets were identified. They correspond respectively to alpine shear zones and veins opened-up during long-term exhumation of the Mont Blanc massif. Our study confirms that climate primarily controls rockfall occurrence, and that structural settings, coincident at both the massif and the rock wall scales, control the rock-wall shapes as well as the geometry and volume of the rockfall events. © 2020 John Wiley & Sons, Ltd.  相似文献   

Inter‐laboratory Characterisation of Apatite Reference Materials for Chlorine Isotope Analysis     

Alicja Wudarska  Ewa S&#x;aby  Michael Wiedenbeck  Jaime D. Barnes  Magali Bonifacie  Neil C. Sturchio  Grard Bardoux  Frdric Couffignal  Johannes Glodny  Linnea Heraty  Timm John  Christof Kusebauch  Sathish Mayanna  Franziska D. H. Wilke  Ewa Deput 《Geostandards and Geoanalytical Research》2021,45(1):121-142

Here we report on a set of six apatite reference materials (chlorapatites MGMH#133648, TUBAF#38 and fluorapatites MGMH#128441A, TUBAF#37, 40, 50) which we have characterised for their chlorine isotope ratios; these RMs span a range of Cl mass fractions within the apatite Ca₁₀(PO₄)₆(F,Cl,OH)₂ solid solution series. Numerous apatite specimens, obtained from mineralogical collections, were initially screened for ³⁷Cl/³⁵Cl homogeneity using SIMS followed by δ³⁷Cl characterisation by gas source mass spectrometry using both dual‐inlet and continuous‐flow modes. We also report major and key trace element compositions as determined by EPMA. The repeatability of our SIMS results was better than ± 0.10‰ (1s) for the five samples with > 0.5 % m/m Cl and ± 0.19‰ (1s) for the low Cl abundance material (0.27% m/m). We also observed a small, but significant crystal orientation effect of 0.38‰ between the mean ³⁷Cl/³⁵Cl ratios measured on three oriented apatite fragments. Furthermore, the results of GS‐IRMS analyses show small but systematic offset of δ³⁷Cl_SMOC values between the three laboratories. Nonetheless, all studied samples have comparable chlorine isotope compositions, with mean 10³δ³⁷Cl_SMOC values between +0.09 and +0.42 and in all cases with 1s ≤ ± 0.25.  相似文献   

Calderas,landslides and paleo-canyons on Piton de la Fournaise volcano (La Réunion Island,Indian Ocean)     

Olivier Merle  Philippe Mairine  Laurent Michon  Patrick Bachèlery  Magali Smietana 《Journal of Volcanology and Geothermal Research》2010,189(1-2):131-142

Based upon a re-interpretation of previous data and a new field campaign, a structural evolution is proposed for the early history of Piton de la Fournaise volcano from 500,000 to 50,000 years. Conceptually, it is shown that the formation of a caldera in which lava flows are contained inside the caldera depression, gives time for erosion to excavate deep canyons on the external slopes of the volcano, for example, the Rivière des Remparts, the Rivière Langevin and the Rivière de l'Est canyons on Piton de la Fournaise volcano. These canyons are infilled when lavas, filling the caldera and overflowing its rim, are able again to flow on the external slopes of the volcano. In the past, this excavating/infilling process has occurred twice following the formation of the Rivière des Remparts and Morne Langevin calderas. The formation of the third caldera, the Plaine des Sables caldera, was followed by the excavation of the current canyons. In addition to this process, two large landslides have been documented in the field. The first, which happened about 300,000 years ago, is apparently the first episode of the break up of Piton de la Fournaise volcano, predating the formation of the four large calderas. The second landslide, which occurred 150,000 years ago and is considered to be less extensive, has carried away the entire southern flank of the Rivière des Remparts caldera.  相似文献   

Tellurium,selenium and cobalt enrichment in Neoproterozoic black shales,Gwna Group,UK: Deep marine trace element enrichment during the Second Great Oxygenation Event          下载免费PDF全文

Joseph G. T. Armstrong  John Parnell  Liam A. Bullock  Magali Perez  Adrian J. Boyce  Jorg Feldmann 《地学学报》2018,30(3):244-253

Black shales of the late Neoproterozoic Gwna Group (570–580 Ma), UK, contain enrichments of tellurium (Te), selenium (Se) and cobalt (Co) relative to average shale compositions. The Te and Co enrichments bear comparison with those of ferromanganese crusts in the modern deep ocean. Gwna Group deposition coincides with the Second Great Oxidation Event, which had a significant effect on trace element fixation globally. Selenium and Te concentrations within these black shales indicate increased continental weathering rates, high biological productivity and corresponding increases in atmospheric O₂ concentrations. Cobalt, nickel (Ni) and arsenic (As) enrichments in this succession are secondary mineralisation phases. Demand for many of the trace elements found enriched in the Gwna Group black shales make their mechanisms of accumulation, and variations through the geological record, important to understand, and suggests that new resources may be sought based on black shale protoliths from this period.  相似文献   

Impact of Hydropower Regulation on River Water Composition in Northern Sweden     

Dmytro Siergieiev  Anders Widerlund  Angela Lundberg  Lisbeth Almqvist  Magali Collomp  Johan Ingri  Björn Öhlander 《Aquatic Geochemistry》2014,20(1):59-80

Using hydrogeochemical analysis of two large boreal rivers (pristine Kalix and hydropower regulated Lule) discharging into the Gulf of Bothnia, the major impacts of regulation on water discharge, element transport and their seasonal redistribution have been assessed. The pre-regulation hydrogeochemical features were assumed to be similar for the two rivers. For the Lule River, the average maximum runoff was almost halved, while the average minimum was tripled as a result of the regulation. The fraction of winter transport of total organic carbon (TOC), Fe, Si, suspended Mn and P in the Lule River was, according to a conservative estimate, two to three times higher than in the pristine river. Longer residence time in the Lule River delayed arrival of the suspended Mn peak and dissolved Si decline to the river mouth. During summer, the suspended C/N ratio in the regulated river was 10–20 compared to <10 for the pristine, suggesting presence of predominantly old organic material. This was supported by a virtually constant suspended P/Fe ratio throughout the year in the Lule River, indicating low abundance of phytoplankton. TOC varied irregularly in the Lule River suggesting temporal disconnection between the river and the upper riparian zone. The disappearance of the spring flow maximum, a shift of element transport from spring to winter and supply of mainly old organic material during the vegetation growth season may have a pronounced impact on the ecosystem of the Gulf of Bothnia and the river itself.  相似文献   

A comment on “The nitrogen record of crust-mantle interaction and mantle convection from Archean to Present” by B. Marty and N. Dauphas [Earth Planet. Sci. Lett. 206(2003) 397-410]     

Pierre Cartigny  Magali Ader 《Earth and Planetary Science Letters》2003,216(3):425-432

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Shear wave velocity, seismic attenuation, and thermal structure of the continental upper mantle   总被引：3，自引：0，他引：3  

Irina M. Artemieva  Magali Billien  Jean-Jacques Lévêque  Walter D. Mooney 《Geophysical Journal International》2004,157(2):607-628

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Extension tardi-orogénique et formation des bassins intracontinentaux: le bassin stéphanien des Cévennes     

Pascal Allemand  Jean-Marc Lardeaux  Gilles Dromart  Magali Ader 《Geodinamica Acta》2013,26(2):70-80

Résumé

Le bassin carbonifère des Cévennes, voisin du décrochement sénestre de Villefort, a été étudié en intégrant les données sédimentologiques, les données structurales du socle et du remplissage, ainsi que les données de la pétrologie métamorphique du socle. Le remplissage du bassin est contrôlé par des failles subméridiennes induisant une subsidence localisée en début d’ouverture. Cette subsidence devient plus régionale en fin d’histoire. Un grenat mangane- sifère est associé aux minéraux du faciès schistes verts, des blastes d’andalousite recoupent l’ensemble. Cette association minéralogique indique un gradient de température de 50°C/km. Ce gradient est semblable au gradient estimé dans le bassin sur la matière organique. La schistosité porte trois familles de linéation : 1- une famille à biotite-chlorite-quartz, orientée N45 ± 20° et associée à la mise en place des nappes cévenoles; 2- une famille à minéraux phylliteux dont l’orientation est située autour de N90 et associée à l’ouverture du bassin; 3- une famille à minéraux phylliteux orientée NO horizontale sur des plans de schistosité redressés près de la faille de Villefort. La schistosité régionale est affectée par des plis asymétriques, des bandes de cisaillement et des zones cata- clasées, le tout ayant une cinématique en faille normale vers l’Est. Les relations entre ces différentes structures suggèrent un continuum de déformation depuis des niveaux ductiles jusqu’à des niveaux fragiles. Le remplissage du bassin est affecté par des décrochements parallèles à la faille de Ville- fort. Le bassin des Cévennes s’est donc ouvert dans un contexte extensif est-ouest sur une croûte épaissie. La région a ensuite été reprise par des décrochements nord-sud dont celui de Villefort.  相似文献   

Interactive Visualization to Advance Earthquake Simulation     

Louise H. Kellogg  Gerald W. Bawden  Tony Bernardin  Magali Billen  Eric Cowgill  Bernd Hamann  Margarete Jadamec  Oliver Kreylos  Oliver Staadt  Dawn Sumner 《Pure and Applied Geophysics》2008,165(3-4):621-633

The geological sciences are challenged to manage and interpret increasing volumes of data as observations and simulations increase in size and complexity. For example, simulations of earthquake-related processes typically generate complex, time-varying data sets in two or more dimensions. To facilitate interpretation and analysis of these data sets, evaluate the underlying models, and to drive future calculations, we have developed methods of interactive visualization with a special focus on using immersive virtual reality (VR) environments to interact with models of Earth’s surface and interior. Virtual mapping tools allow virtual “field studies” in inaccessible regions. Interactive tools allow us to manipulate shapes in order to construct models of geological features for geodynamic models, while feature extraction tools support quantitative measurement of structures that emerge from numerical simulation or field observations, thereby enabling us to improve our interpretation of the dynamical processes that drive earthquakes. VR has traditionally been used primarily as a presentation tool, albeit with active navigation through data. Reaping the full intellectual benefits of immersive VR as a tool for scientific analysis requires building on the method’s strengths, that is, using both 3D perception and interaction with observed or simulated data. This approach also takes advantage of the specialized skills of geological scientists who are trained to interpret, the often limited, geological and geophysical data available from field observations.  相似文献