Effect of artificial maturation on carbazole distributions, as revealed by the hydrous pyrolysis of an organic-sulphur-rich source rock (Ghareb Formation, Jordan)     

Heather Clegg  Brian Horsfield  Heinz Wilkes  Jaap Sinninghe Damst  Martin P. Koopmans 《Organic Geochemistry》1998,29(8):1953-1960

Hydrous pyrolysis experiments were performed on the Ghareb Formation (Upper Cretaceous, Jordan), a carbonate- and organic-rich (TOC 19.6%) source rock, using a temperature range of 200 to 360°C (72 h). The original sediment contains only low amounts of carbazoles, (maximum 2.2 μg/g bitumen for 1-methylcarbazole). With increasing thermal maturation, intense generation begins at temperatures only in excess of 300°C, reaching a maximum at 360°C. Likewise, during natural maturation, generation occurs at later stages of maturity (e.g. for Tithonian source rocks at >0.81% R_r and for Posidonia Shale at >0.88% R_r). Some isomeric changes during hydrous pyrolysis do not resemble those in nature whereas others do. The relative abundances of selected C₁- and C₂-alkylcarbazoles on ternary diagrams reveal differences, whereas the benzo[a]carbazole/benzo[a]carbazole+benzo[c]carbazole ratio is closely similar. The latter result supports the contention that maturation plays a key role in controlling carbazole distributions in source rocks. However, the results for alkylcarbazoles, especially the C₂-carbazoles, are not easy to interpret.  相似文献   

Release of sulfur- and oxygen-bound components from a sulfur-rich kerogen during simulated maturation by hydrous pyrolysis     

Anke Putschew  Christine Schaeffer-Reiss  Philippe Schaeffer  Martin P Koopmans  Jan W de Leeuw  Michael D Lewan  Jaap S Sinninghe Damsté  James R Maxwell 《Organic Geochemistry》1998,29(8):1875-1890

An immature sulfur-rich marl from the Gessosso-solfifera Formation of the Vena del Gesso Basin (Messinian, Italy) has been subjected to hydrous pyrolysis (160 to 330°C) to simulate maturation under natural conditions. The kerogen of the unheated and heated samples was isolated and the hydrocarbons released by selective chemical degradation (Li/EtNH₂ and HI/LiAlH₄) were analysed to allow a study of the fate of sulfur- and oxygen-bound species with increasing temperature. The residues from the chemical treatments were also subjected to pyrolysis–GC to follow structural changes in the kerogens. In general, with increasing hydrous pyrolysis temperature, the amounts of sulfide- and ether-bound components in the kerogen decreased significantly. At the temperature at which the generation of expelled oil began (260°C), almost all of the bound components initially present in the unheated sample were released from the kerogen. Comparison with an earlier study of the extractable organic matter using a similar approach and the same samples provides molecular evidence that, with increasing maturation, solvent-soluble macromolecular material was initially released from the kerogen, notably as a result of thermal cleavage of weak carbon–heteroatom bonds (sulfide, ester, ether) even at temperatures as low as 220°C. This solvent-soluble macromolecular material then underwent thermal cleavage to generate hydrocarbons at higher temperatures. This early generation of bitumen may explain the presence of unusually high amounts of extractable organic matter of macromolecular nature in very immature S-rich sediments.  相似文献   

Thermodynamics of Al/Al avoidance in the ordering of Al/Si tetrahedral framework structures     

Eva R. Myers  Volker Heine  Martin T. Dove 《Physics and Chemistry of Minerals》1998,25(6):457-464

The main driving force behind Al/Si ordering in tetrahedral framework aluminosilicates is nearest-neighbour Al/Al avoidance. Computer simulation is used to explore the direct consequences of such Al/Al avoidance. The main result is that the order-disorder transition temperature T _c falls dramatically as the concentration x of Al in the structure is reduced, and if the only interactions are those associated with nearest-neighbour Al/Al avoidance, T _c becomes zero for x less than some critical value x _c , where x _c =0.31 for the feldspar framework and x _c =0.34 for cordierite. Also a large degree of short range order is found above T _c . Both results differ radically from the standard Bragg-Williams model. Plots of entropy and enthalpy of ordering are given as functions of x and T, which may be used to interpret experimental data or for extrapolation into ranges of x and T inaccessible to experiment. Received: 14 May 1997 / Revised, accepted: 2 June 1997  相似文献   

Venus-intercepting meteoroid streams     

Martin Beech 《Monthly notices of the Royal Astronomical Society》1998,294(2):259-264

This study is motivated by the possibility of determining the large-body meteoroid flux at the orbit of Venus. Towards this end, we attempt to estimate the times at which enhanced meteoric activity might be observed in the planet's atmosphere. While a number of meteoroid streams are identified as satisfying common Earth and Venus intercept conditions, it is not clear from the Earth-observed data if these streams contain large-body meteoroids. A subset of the Taurid Complex objects may produce fireball-rich meteor showers on Venus. A total of 11 short-period, periodic comets and 46 near-Earth asteroids approach the orbit of Venus to within 0.1 au, and these objects may have associated meteoroid streams. Comets 27P/Crommelin and 7P/Pons–Winnecke are identified as candidate parents to possible periodic meteor showers at the orbit of Venus.  相似文献   

The Parkes Southern Pulsar Survey — III. Timing of long-period pulsars     

D'Amico  Stappers  Bailes  Martin  Bell  Lyne  & Manchester 《Monthly notices of the Royal Astronomical Society》1998,297(1):28-40

The Parkes survey of the entire southern sky for millisecond and other low-luminosity pulsars has now been completed. The survey system and initial results were described by Manchester et al. and the final results and population studies are described by Lyne et al. A total of 298 pulsars were detected, including 101 new discoveries of which 17 were millisecond pulsars. Here we report on timing observations at Parkes and Jodrell Bank of the 84 long-period (non-millisecond) pulsars discovered in the survey, including timing solutions for 78 of them. Pulse profiles and arrival times were obtained at several different frequencies over intervals of more than a year, yielding a position, period, period derivative and dispersion measure for each pulsar. Pulse profiles at frequencies near 400 MHz and 600 or 1400 MHz are presented for most of the observed pulsars. Significant timing noise was detected for five pulsars and a glitch was observed in the period of PSR J1123–6259.  相似文献   

Star formation in the circumnuclear environment of NGC 1068     

Richard I. Davies  Hajime Sugai  & Martin J. Ward 《Monthly notices of the Royal Astronomical Society》1998,300(2):388-396

We present near-infrared emission-line images of the circumnuclear ring in NGC 1068. We have measured the Brγ fluxes in a number of star-forming complexes and derived the extinction for each of these by comparison with Hα. We investigate the star-forming histories of these regions and find that a short burst of star formation occurred coevally throughout the ring within the last 30–40 Myr, and perhaps as recently as 4–7 Myr ago. The 1–0 S(1) flux and S(1)/Brγ ratios indicate that as well as fluorescence, shock-excited H₂ emission contributes to the total flux. There is excess H₂ flux to the north-west where the ionization cone crosses the ring, and we show that it is possible that the non-stellar continuum from the Seyfert nucleus which produces the high-excitation lines could also be causing fluorescence at the edges of molecular clouds in the ring. The nuclear 1–0 S(1) is more extended than previously realized but only along the bar's major axis, and we consider mechanisms for its excitation.  相似文献   

Asia-Pacific: New Geographies of the Pacific Rim     

Martin Perry 《New Zealand geographer》1998,54(1):60-61

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Putting the census on the web: lessons from two case studies     

David Martin  James Harris  Jason Sadlert†  Nicholas J Tate† 《Area》1998,30(4):311-320

Summary This paper addresses the digital dissemination of geographically referenced census information in the UK. A number of important weaknesses in the 1991 model of data access are identified, and the possibility of future access to census information via the World Wide Web is then addressed in detail. Two case studies demonstrate the potential to overcome some fundamental weaknesses in earlier access models, including the provision of integrated data and metadata, graphical interfaces to geographical datasets, and an integrated interface and analysis environment.  相似文献   

Climate change, tree species distributions and forest dynamics: A case study in the mixed conifer/northern hardwoods zone of northern Europe   总被引：10，自引：0，他引：10  

Martin T. Sykes  I. Colin Prentice 《Climatic change》1996,34(2):161-177

Three bioclimate variables (growing degree days after budburst, temperature of the coldest month and a moisture index) are used in a model (STASH) to predict potential range limits of north European tree species. CO₂-induced climate warming scenarios cause major changes in these limits. The dominant conifers of the mixed conifer/northern hardwoods zone, Picea abies and Pinus sylvestris, retreat from the south and west while Fagus sylvatica and other temperate hardwoods spread to the north. A gap model (FORSKA 2) is used to simulate the associated transient responses of a forest reserve within this zone. In both dry Pinus- and moist Picea- dominated forest communities, Picea continues to increase while Pinus sooner or later declines. These changes are continuing successional (non-climatic) responses to the cessation of disturbance 150 years ago. Climate warming speeds up the succession, and allows Fagus to establish and increase. The eventual decline of Picea however is delayed due to the persistence of old-growth stands. Picea forests subject to continuing disturbance show a more rapid shift to dominance by Fagus and other temperate hardwoods. Delayed immigration of new species, including Fagus, would favour earlysuccessional species such as Betula pendula and Quercus spp. in a forest with reduced biomass and diversity. The results emphasise the complex and sometimes counter-intuitive nature of transient responses, and the importance of considering disturbance history and potential migration rates when predicting the impacts of rapid climate change on forests.  相似文献   

Environmental variables and their association with faecal coliform and faecal streptococci densities at thirteen Sydney beaches     

Martin Krogh  Lynne Robinson 《Marine pollution bulletin》1996,33(7-12):239-248

Environmental variables and their association with faecal coliform and streptococci densities were investigated at a number of Sydney's metropolitan beaches. High variability in faecal coliform and faecal streptococci densities was observed at most beaches. The ability of the various models to explain the observed variation in faecal coliform or streptococci levels was relatively low, although they did provide an insight into the more influential environmental factors involved. Rainfall has the single most important effect on faecal coliform and streptococci densities at Sydney beaches. Whether this is due to increased stormwater runoff at the beaches, increased discharge through the outfalls (both the deepwater ocean outfalls and the few remaining shoreline outfalls), or a combination of both is unclear and is likely to depend on the individual beach being considered. Elevated levels of faecal coliforms and streptococci are still occasionally observed at some beaches, but these levels are usually not as high nor as frequent as they were prior to commissioning of the deepwater outfalls. The significant associations of current and plume entrapment with faecal coliform and streptococci densities at some Sydney beaches suggest that under certain conditions, effluent from the deepwater ocean outfalls can still influence faecal coliform and streptococci densities at these beaches.  相似文献