Petrogenesis of mafic and associated silicic end-member magmas for calc-alkaline mixed rocks in the Shirataka volcano,NE Japan     

Shiho Hirotani  Masao Ban  Mitsuhiro Nakagawa 《Contributions to Mineralogy and Petrology》2009,157(6):709-734

Eruptive products of the Shirataka volcano (0.9–0.7 Ma) in NE Japan are calc-alkaline andesite–dacite, and are divisible into six petrologic groups (G1–G6). Shirataka rocks possess mafic inclusions—basalt–basaltic andesite, except for G3 and G4. All rocks show mixing and mingling of the mafic and silicic end-members, with trends defined by hosts and inclusions divided into high-Cr and low-Cr types; both types coexist in G1, G2, and G5. Estimated mafic end-members are high-Cr (1120–1170°C, 48–51% SiO₂, olv ± cpx ± plg) and low-Cr type magmas (49–52% SiO₂, cpx ± plg) except for the Sr isotopic composition. In contrast, the silicic end-members of both types have similar petrologic features (790–840°C, 64–70% SiO₂, hbl ± qtz ± px + plg). High-Cr type mafic and corresponding silicic end-members have lower ⁸⁷Sr/⁸⁶Sr ratios than the low-Cr ones in each group. The trace element model calculations suggest that the low-Cr type mafic end-member magma is produced through ca. 20% fractional crystallization (olv ± cpx ± plg) from the high-Cr type one with assimilation of granitoids (r = 0.02–0.05). The silicic magmas are producible through <30% partial remelting of previously emplaced basaltic magma with assimilation of crustal components. The compositional difference between the low-K and medium-K basalts in the Shirataka volcano is mainly attributed to the different degrees of the effect of subduction derived fluid by dehydration of phlogopite. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

A new evolutionary scenario of intermediate-mass star-formation revealed by multi-wavelength observations of OMC-2/3     

Satoko Takahashi  Masao Saito  Shigehisa Takakuwa  Ryohei Kawabe 《Astrophysics and Space Science》2008,313(1-3):165-168

We have performed millimeter- and submilli- meter-wave survey observations using the Nobeyama millimeter array (NMA) and the Atacama Submillimeter Telescope Experiment (ASTE) in one of the nearest intermediate-mass (IM) star-forming regions: Orion Molecular Cloud-2/3 (OMC-2/3). Using the high-resolution capabilities offered by the NMA (∼several arcsec), we observed dust continuum and H¹³CO⁺(1–0) emission in 12 pre- and proto-stellar candidates identified previously in single-dish millimeter observations. We unveiled the evolutionary changes with variations of the morphology and velocity structure of the dense envelopes traced by the H¹³CO⁺(1–0) emission. Furthermore, using the high-sensitivity capabilities offered by the ASTE, we searched for large-scale molecular outflows associated with these pre- and proto-stellar candidates observed with the NMA. As a result of the CO(3–2) observations, we detected six molecular outflows associated with the dense gas envelopes traced by H¹³CO⁺(1–0) and 3.3 mm continuum emission. The estimated CO outflow momentum increases with the evolutionary sequence from early to late type of the protostellar cores. We also found that the 24 μm flux increases as the dense gas evolutionary sequence. We propose that the enhancement of the 24 μm flux is caused by the growth of the cavity (i.e. the CO outflow destroys the envelope) as the evolutionary sequence. Our results show that the dissipation of the dense gas envelope plays an essential role in the evolution of the IM protostars. The extremely high-sensitivity and high-angular resolution offered by ALMA will reveal unprecedented details of the inner ∼50 AU of these protostars, which will provide us a break through in the classic scenario of IM star/disk formation.  相似文献   

Effect of hydrolysed aluminum(III) and chromium(III) cations on the lipophilicity of talc     

E. Kusaka  N. Amano  Y. Nakahiro 《International Journal of Mineral Processing》1997,50(4):243-253

Liquid-liquid extraction and electrokinetic studies show that both the talc particles and the isooctane droplets are affected by the presence of hydrolysable metal species of Al(III) and Cr(III). The inherent lipophilicity of talc is unchanged by the hydroxo complexes of these metal species, while positive shifts in zeta potentials of talc and isooctane take place due partly to the strong adsorption of these hydroxo complexes. In the pH range where the hydroxide precipitates, the talc particles are rendered hydrophillic between the precipitation pH and the point-of-zero charge of the metal hydroxide. This hydrophile-lipophile transition of talc in the isooctane-water system relates to heterocoagulation among talc particles, isooctane droplets and hydroxide precipitates.  相似文献   

The superstructure of plagioclase feldspars     

Yoshiharu Nakajima  Nobuo Morimoto  Masao Kitamura 《Physics and Chemistry of Minerals》1977,1(2):199-212

A modulation function representing the position and density of (Na, Ca) atoms in the superstructure of the e-plagioclase has been derived from the average structures of different plagioclase and a general modulation theory. Based on this function the superstructure of bytownite (An₇₃) has been studied with the single crystal X-ray method. The cell dimensions by Megaw's axes are a=7.946(3)A, b=67.09(2)A, c=12.236(4)A, α=39.03(1)°, β=45.63(1)° and γ=59.63(1)°. Z=18(Na, Ca) Al(Al, Si)Si₂O₈. The initial phase factor of the modulation function for bytownite has been obtained from the intensity data of the satellite reflections. This modulation function indicates a coherent small-scale alternation of the Na-rich and Ca-rich bands in the superstructure. This superstructure has been refined by applying the albite and anorthite structures to the Na-rich and Ca-rich bands, respectively. The change of the superstructure of the e-plagioclase due to the compositional change has been described based on the movements of the satellites in reciprocal space. The direction of the coherent small-scale intergrowth of the anorthite-like and albite-like bands is perpendicular to the t vector. The thickness of the intergrowth is 1/|t|. Both direction and thickness change regularly from An₇₅ to An₂₅.  相似文献   

Exsolved garnet-bearing pyroxene megacrysts from some South African kimberlites     

Ken-Ichiro Aoki  Hirokazu Fujimaki  Masao Kitamura 《Lithos》1980,13(3):269-279

Clinopyroxene and orthopyroxene megacrysts containing garnet lamellae up to 1.2 mm thick as an exsolved phase are found rarely in kimberlites from Frank Smith and Bellsbank. Chemically the clinopyroxenes are characteristically subcalcic, being within the range of 100 Ca/Ca + Mg + Fe = 27 to 36, and the orthopyroxenes are characterized by high Al₂O₃ and Cr₂O₃. Immediately after crystallization during very slow cooling, clinopyroxene and orthopyroxene exsolve wide-spaced orthopyroxene and clinopyroxene phases parallel to (100) of the host phases, respectively, then both host and exsolved phases exsolve garnet lamellae. Topotactic relations between pyroxenes and garnet are determined by X-ray for the first time. Partitioning of major and minor elements among the coexisting clinopyroxene, orthopyroxene and garnet in pyroxene megacrysts is the same as that of the granular-type garnet peridotite xenoliths in Lesotho and South African kimberlies. Mineralogy and chemistry indicate that subcalcic clinopyroxene and orthopyroxene megacrysts contain respectively about 10 and 3 mole % of the garnet molecule in solid solution.  相似文献   

Late Pleistocene and Holocene sea-level change in the Australian region and mantle rheology   总被引：8，自引：0，他引：8  

Masao Nakada  Kurt Lambeck 《Geophysical Journal International》1989,96(3):497-517

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Variations in seawater osmium isotope composition since the last glacial maximum: A case study from the Japan Sea     

Tarun K. Dalai  Katsuhiko Suzuki  Masao Minagawa  Yoshiyuki Nozaki 《Chemical Geology》2005,220(3-4):303-314

Concentrations of Re and Os, and the isotopic composition of Os have been measured in the Japan Sea sediments to assess the response of the Japan Sea to glacial–interglacial climate change and associated weathering fluxes. The osmium concentrations in the sediment samples analyzed vary from 59 to 371 pg/g, and ¹⁸⁷Os/¹⁸⁸Os from 0.935 to 1.042. Only ¹⁸⁷Os/¹⁸⁸Os of sediment samples from dark laminations deposited under suboxic to anoxic conditions and having elevated concentrations of Re and Os, and with ≥ 80% hydrogenous Os are explained in terms of seawater composition. Lower ¹⁸⁷Os/¹⁸⁸Os were observed for sediments deposited during the last glacial maximum (LGM) when planktonic foraminifera from the Japan Sea recorded lighter oxygen isotopic composition. Decrease in dissolved Os fluxes from continents and/or change in the composition of the dissolved load to the Japan Sea are suggested as the driving mechanisms for the observed lower LGM ¹⁸⁷Os/¹⁸⁸Os. The results of this study, coupled with lower ¹⁸⁷Os/¹⁸⁸Os during the last glacial observed at other sites from ocean basins with different lithology and contrasting sediment accumulation rates, suggest that this trend is characteristic of the global oceans.

Data from this study show that the Japan Sea recorded higher ¹⁸⁷Os/¹⁸⁸Os during the current interglacial coinciding with excursions of oxygen isotopic compositions of planktonic foraminifera to heavier values. This is explained in terms of preferential release of ¹⁸⁷Os during deglacial weathering and/or higher continental Os flux driven by warm and wet climate. This study demonstrates that Os isotopic composition of reducing margin sediments has immense potential to track variations in the seawater composition. In addition, ¹⁸⁷Os/¹⁸⁸Os of reducing sediments may be used to draw inferences about local paleoceanographic processes in semi-enclosed basins such as the Japan Sea.  相似文献   

Convective coupling between ductile lower crust and upper mantle, and its tectonic implications   总被引：1，自引：0，他引：1  

Masao Nakada 《Geophysical Journal International》1994,118(3):579-603

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Electron microscopy of clinoenstatite from a boninite and a chondrite     

Masayo Yasuda  Masao Kitamura  Nobuo Morimoto 《Physics and Chemistry of Minerals》1983,9(5):192-196

Clinoenstatite crystals from a boninite and the Yamato-74191 chondrite have been studied with an analytical electron microscope. (100) twins and cracks perpendicular and parallel to the c axis are characteristic of their submicroscopic textures. The frequency in appearance along the c axis and widths of the cracks have been explained by the dimensional change of the c axis in the direct transformation of protoenstatite to clinoenstatite and by the cooling rate around the transformation temperature. The cracks in the crystals from the boninite are filled with fibrous crystals of talc, while those from the chondrite are open or filled with glass in which fine crystals of plagioclase are common.  相似文献   

Axial and equatorial rotations of the Earth's cores associated with the Quaternary ice age     

Masao Nakada 《Physics of the Earth and Planetary Interiors》2006,154(2):113-147

The differential axial and equatorial rotations of both cores associated with the Quaternary glacial cycles were evaluated based on a realistic earth model in density and elastic structures. The rheological model is composed of compressible Maxwell viscoelastic mantle, inviscid outer core and incompressible Maxwell viscoelastic inner core. The present study is, however, preliminary because I assume a rigid rotation for the fluid outer core. In models with no frictional torques at the boundaries of the outer core, the maximum magnitude of the predicted axial rotations of the outer and inner cores amounts to ∼2° year⁻¹ and ∼1° year⁻¹, respectively, but that for the secular equatorial rotations of both cores is ∼0.0001° at most. However, oscillating parts with a period of ∼225 years are predicted in the equatorial rotations for both cores. Then, I evaluated the differential rotations by adopting a time-dependent electromagnetic (EM) torque as a possible coupling mechanism at the core-mantle boundary (CMB) and inner core boundary (ICB). In a realistic radial magnetic field at the CMB estimated from surface magnetic field, the axial and equatorial rotations couple through frictional torques at the CMB, although these rotations decouple for dipole magnetic field model. The differential rotations were evaluated for conductivity models with a conductance of 10⁸ S of the lowermost mantle inferred from studies of nutation and precession of the Earth and decadal variations of length of day (LOD). The secular parts of equatorial rotations are less sensitive to these parameters, but the magnitude for the axial rotations is much smaller than for frictionless model. These models, however, produce oscillating parts in the equatorial rotations of both cores and also in the axial rotations of the whole Earth and outer and inner cores. These oscillations are sensitive to both the magnitude of radial magnetic field at the CMB and the conductivity structure. No sharp isolated spectral peaks are predicted for models with a thin conductive layer (∼200 m) at the bottom of the mantle. In models with a conductive layer of ∼100 km thickness, however, sharp spectral peaks are predicted at periods of ∼225 and ∼25 years for equatorial and axial rotations, respectively, although these depend on the strength of radial magnetic field at the CMB. While the present study is preliminary in modelling the fluid outer core and coupling mechanism at the CMB, the predicted axial rotations of the whole Earth may be important in explaining the observed LOD through interaction between the equatorial and axial rotations.  相似文献