Mantle and crustal processes in the magmatism of the Campania region: inferences from mineralogy, geochemistry, and Sr–Nd–O isotopes of young hybrid volcanics of the Ischia island (South Italy)     

Massimo D’Antonio  Sonia Tonarini  Ilenia Arienzo  Lucia Civetta  Luigi Dallai  Roberto Moretti  Giovanni Orsi  Mariachiara Andria  Alberto Trecalli 《Contributions to Mineralogy and Petrology》2013,165(6):1173-1194

Ischia, one active volcano of the Phlegraean Volcanic District, prone to very high risk, is dominated by a caldera formed 55 ka BP, followed by resurgence of the collapsed area. Over the past 3 ka, the activity extruded evolved potassic magmas; only a few low-energy explosive events were fed by less evolved magmas. A geochemical and Sr–Nd–O isotope investigation has been performed on minerals and glass from products of three of such eruptions, Molara, Vateliero, and Cava Nocelle (<2.6 ka BP). Data document strong mineralogical, geochemical, and isotopic heterogeneities likely resulting from mingling/mixing processes among mafic and felsic magmas that already fed the Ischia volcanism in the past. Detailed study on the most mafic magma has permitted to investigate its origin. The mantle sector below Ischia underwent subduction processes that modified its pristine chemical, isotopic, and redox conditions by addition of ≤1 % of sediment fluids/melts. Similar processes occurred from Southeast to Northwest along the Apennine compressive margin, with addition of up to 2.5 % of sediment-derived material. This is shown by volcanics with poorly variable, typical δ¹⁸O mantle values, and ⁸⁷Sr/⁸⁶Sr progressively increasing toward typical continental crust values. Multiple partial melting of this modified mantle generated distinct primary magmas that occasionally assimilated continental crust, acquiring more ¹⁸O than ⁸⁷Sr. At Ischia, 7 % of Hercynian granodiorite assimilation produced isotopically distinct, K-basaltic to latitic magmas. A SW–NE regional tectonic structure gave these magmas coming from large depth the opportunity to mingle/mix with felsic magmas stagnating in shallower reservoirs, eventually triggering explosive eruptions.  相似文献   

Reclamation influence and background geochemistry of neutral saline soils in the Po River Delta Plain (Northern Italy)     

Dario Di Giuseppe  Barbara Faccini  Micòl Mastrocicco  Nicolò Colombani  Massimo Coltorti 《Environmental Earth Sciences》2014,72(7):2457-2473

Reclaimed neutral saline sulphate soils constitute a large part of the eastern part of Po Plain lowlands, where intensive agricultural activities take place. The knowledge of their geochemical features is essential to develop the best management practices capable to preserve this threatened environment. With this aim, three boreholes were drilled in an agricultural field and a typical reclaimed soil profile has been characterized for major and trace element, pH, electrical conductivity, redox conditions and water-soluble anions and ammonium. Statistical analysis (cluster analysis and principal component analysis) has been used to understand the relationship between elements and grain size. The soil profile is characterized by high salinity and high organic matter contents responsible for high chloride, sulphate, and ammonium concentrations. Heavy metal content is naturally high, since Po Plain sediments are the result of ultramafic rocks erosion; in addition, organic matter tends to concentrate heavy metals by adsorption, mainly in peaty horizons. As a consequence of chemical and zootechnical fertilization, high NO₃ ^? contents have been found in the top soil, thus enhancing the risk of nitrate discharge in the water system, especially in relation to extreme climatic events.  相似文献   

Improved Parameterization of Snow Albedo in WRF + Noah: Methodology Based on a Severe Snow Event on the Tibetan Plateau     

Lian LIU  Massimo MENENTI  Yaoming MA  Weiqiang MA 《大气科学进展》2022,39(7):1079-1102

Snowfall and the subsequent evolution of the snowpack have a large effect on the surface energy balance and water cycle of the Tibetan Plateau (TP). The effects of snow cover can be represented by the WRF coupled with a land surface scheme. The widely used Noah scheme is computationally efficient, but its poor representation of albedo needs considerable improvement. In this study, an improved albedo scheme is developed using a satellite-retrieved albedo that takes snow depth and age into account. Numerical experiments were then conducted to simulate a severe snow event in March 2017. The performance of the coupled WRF/Noah model, which implemented the improved albedo scheme, is compared against the model’s performance using the default Noah albedo scheme and against the coupled WRF/CLM that applied CLM albedo scheme. When the improved albedo scheme is implemented, the albedo overestimation in the southeastern TP is reduced, reducing the RMSE of the air temperature by 0.7°C. The improved albedo scheme also attains the highest correlation between the satellite-derived and the model-estimated albedo, which provides for a realistic representation of both the snow water equivalent (SWE) spatial distribution in the heavy snowbelt (SWE > 6 mm) and the maximum SWE in the eastern TP. The underestimated albedo in the coupled WRF/CLM leads to underestimating the regional maximum SWE and a consequent failure to estimate SWE in the heavy snowbelt accurately. Our study demonstrates the feasibility of improving the Noah albedo scheme and provides a theoretical reference for researchers aiming to improve albedo schemes further.  相似文献   

The research agenda of the European Science Foundation's GISDATA scientific programme     

Massimo Craglia  Ian Masser    Henk Scholten 《International journal of geographical information science》2013,27(5):463-470

Abstract

In January 1993 the European Science Foundation launched a four-year scientific programme on geographical information systems. The programme aims at overcoming the existing fragmentation of GIS research in Europe and addresses three key areas: European-wide data base design, data integration, and social and environmental applications. In each of these areas a number of priorities have been identified which provide the focus of the initiatives and collaborative ventures envisaged by the programme. This article describes the programme's research agenda and sets it in the context of the activities of the European Science Foundation.  相似文献   

Crystal recycling in the steady-state system of the active Stromboli volcano: a 2.5-ka story inferred from in situ Sr-isotope and trace element data     

Lorella Francalanci  Riccardo Avanzinelli  Isabella Nardini  Massimo Tiepolo  Jon P. Davidson  Riccardo Vannucci 《Contributions to Mineralogy and Petrology》2012,163(1):109-131

In situ Sr-isotope data by microdrilling, coupled with major and trace element analyses, have been performed on plagioclase and clinopyroxene from seven samples collected during the 2002–2003 eruptive crisis at Stromboli volcano (Aeolian Islands, Italy). On 28 December 2002, the persistent moderate explosive activity was broken by an effusive event lasting about 7 months. A more violent explosion (paroxysm) occurred on 5 April 2003. Two magma types were erupted, namely a volatile-poor and highly porphyritic magma (HP-magma) poured out as scoria or lava and a volatile-rich, phenocryst-poor magma (LP-magma) found as pumice. LP-magma differs from the HP-magma also for its slightly less-evolved chemistry, the groundmass composition and the lower Sr-isotope ratios. Micro-Sr-isotope data show the presence of zoned minerals in strong isotope disequilibrium, as previously found in products erupted in 1984, 1985 and 1996 AD, with ⁸⁷Sr/⁸⁶Sr values generally decreasing from cores to rims of minerals. Only some outer rims testify for equilibrium with the host groundmass. The internal mineral zones with high Sr-isotope ratios (0.70665–0.70618) are interpreted as ‘antecrysts’, crystallised during the previous activity and recycled in the present-day system since the opening shoshonitic activity of the Recent Period, which occurred at about 2.5 ka ago. This result has implications for the dynamics of the present-day plumbing system of Stromboli at intermediate pressure (about 2–3 km depth) and allows us to propose a model whereby an HP-magma reservoir is directly interconnected at the bottom with a cumulate crystal much reservoir. Efficient mixing between residing HP- and input LP-magmas can occur in this reservoir, due to more similar rheological characteristics of the two magmas than in the conduit, where crystallisation is enhanced by degassing. Antecrysts (and possibly melts) re-enter in the HP-magma reservoir both from the bottom, recycled by ascending LP-magmas crossing the crystal mush, and from the top, recycled by descending degassed and dense HP-magma, residual of the periodic Strombolian explosions at the surface. The isotope variation measured in the groundmasses allows calculating the proportion of the LP-magma entering the shallow HP-magma reservoir at ~20%. From this proportion, we estimate that the total volume of LP-magma input during 2002–2003 closely matches the magma volume erupted in the effusive event, suggesting a steady-state system at broadly constant volume. The comparison with estimates of the LP-magma volume ejected by the paroxysm indicates that the LP-magma amount directly reaching the surface during the 5 April paroxysm is minimal with respect to that entering the system.  相似文献   

Trace element and Pb–B–Li isotope systematics of olivine-hosted melt inclusions: insights into source metasomatism beneath Stromboli (southern Italy)     

Federica?SchiaviEmail author  Katsura?Kobayashi  Eizo?Nakamura  Massimo?Tiepolo  Riccardo?Vannucci 《Contributions to Mineralogy and Petrology》2012,163(6):1011-1031

We studied the elemental and isotopic (Pb, B and Li isotopes) composition of melt inclusions hosted in highly forsteritic (Fo_83–91) olivines that were collected from San Bartolo lava and pumice (ST79p, ST82p and ST531p) samples erupted by Stromboli in historical times. The studied melt inclusions have primitive calcalkaline to shoshonitic basaltic compositions. They cover a compositional range far wider than that exhibited by the whole-rocks and differ in key trace element ratios. San Bartolo melt inclusions are characterized by lower incompatible trace element abundances, higher ratios between fluid-mobile (B, Pb, U and LILE) and less fluid-mobile (REE, Th, HFSE) elements and lower La/Yb ratios relative to the pumice-hosted melt inclusions and pumiceous melts erupted during paroxysmal events. Trace elements, along with different Pb, B and Li isotopic signatures, attest to source heterogeneity on the small scale and provide new insights into subducted components beneath Stromboli. Results of a mixing model suggest that metasomatism of the mantle source of pumice-hosted melt inclusions was driven by solute-rich high-pressure fluids (<20%) expelled from the deep portion of the slab. Heterogeneous Pb isotopic composition together with light δ¹¹B (−8.6 to −13.7‰) and δ⁷Li (+2.3 to −1.7‰) indicates that high-pressure liquids were released in variable proportions from highly dehydrated metabasalts and metasediments. On the other hand, the elemental and isotopic (δ¹¹B ~ −1.9 to −5.9‰) composition of San Bartolo melt inclusions is better explained by the addition of a prevalent aqueous component (~2 to 4%) escaped at shallower depths from sediments and altered basaltic crust in almost equivalent proportions, with a smaller contribution by high-pressure fluids. Owing to the high-angle dip of the subducted cold Ionian slab, aqueous fluids and high-pressure fluids would rise through the mantle wedge and locally superimpose on each other, thus giving origin to variously metasomatized mantle domains.  相似文献   

A two-phase model for fast geomorphic shallow flows   总被引：1，自引：0，他引：1  

Massimo GRECO  Michele IERVOLINO  Angelo LEOPARDI  Andrea VACCA 《国际泥沙研究》2012,27(4):409-425

The paper introduces a 2D shallow water model based on a two-phase formulation for the analysis of fast geomorphic transients occurring in the context of river morphodynamics.Mass and momentum conservation principles are separately imposed for both phases.The model naturally accounts for non-equilibrium solid transport,since neither instantaneous adaptation hypothesis nor any lag equation is employed to represent sediment dynamics.The hyperbolic character of the proposed model is shown to be preserved independently on the flow conditions.Results from numerical simulations of both 1D and 2D test-cases are compared with literature experimental data and with available numerical solutions.  相似文献   

Evaluating TCE Abiotic and Biotic Degradation Pathways in a Permeable Reactive Barrier Using Compound Specific Isotope Analysis     

Paulo Lojkasek‐Lima  Ramon Aravena  Orfan Shouakar‐Stash  Shaun K. Frape  Massimo Marchesi  Stephanie Fiorenza  John Vogan 《Ground Water Monitoring & Remediation》2012,32(4):53-62

A pilot‐scale zero valent iron (ZVI) Permeable Reactive Barrier (PRB) was installed using an azimuth‐controlled ‐vertical hydrofracturing at an industrial facility to treat a chlorinated Volatile Organic Compound (VOC) plume. Following ZVI injection, no significant reduction in concentration was observed to occur with the exception of some multilevel monitoring wells, which also showed high levels of total organic carbon (TOC). These patterns suggested that the zero valent iron was not well distributed in the PRB creating leaky conditions. The geochemical data indicated reducing conditions in these areas where VOC reduction was observed, suggesting that biotic processes, associated to the guar used in the injection of the iron, could be a major mechanism of VOC degradation. Compound‐Specific Isotope Analysis (CSIA) using both carbon and chlorine stable isotopes were used as a complementary tool for evaluating the contribution of abiotic and biotic processes to VOC trends in the vicinity of the PRB. The isotopic data showed enriched isotope values around the PRB compared to the isotope composition of the VOC source confirming that VOC degradation is occurring along the PRB. A batch experiment using site groundwater collected near the VOC source and the ZVI used in the PRB was performed to evaluate the site‐specific abiotic isotopic fractionation patterns. Field isotopic trends, typical of biodegradations were observed at the site and were different from those obtained during the batch abiotic experiment. These differences in isotopic trends combined with changes in VOC concentrations and redox parameters suggested that biotic processes are the predominant pathways involved in the degradation of VOCs in the vicinity of the PRB.  相似文献   

Facies analysis of Pleistocene sediments from the Bannock Basin area: A key to the reconstruction of its tectonic evolution     

Vilia Nolli  Massimo Redaelli  Maria Bianca Cita 《Marine Geology》1991,100(1-4):5-20

Facies analysis was carried out on 21 selected cores from the Bannock area in order to investigate the relationships between sedimentation and tectonism. Bannock Basin is a large, > 3500 m (uncorrected) deep subcircular depression near the deformation front of the Mediterranean Ridge facing the Sirte Abyssal Plain. The basin is divided into several sub-basins aligned along a rim-syncline surrounding a central elevated area (salt dome?). High-density brines and anoxic sediments occupy the deepest part of the depressions.

The facies distribution is controlled by the bottom configuration in that pelagic facies typically occur on plateaus and domes, debris-flow deposits in base-of-slope settings, and turbidites in basinal settings. The facies distribution may therefore be used to reconstruct the evolution of the various parts of the rim-syncline.

Erosional gaps may be related to tectonism or may be features created by the passage of major turbiditic events.

The results of our study of the facies associations, and of the rates of sediment accumulation, indicate that the collapse of the eastern part of the rim-syncline pre-dates the collapse of the western part. The western basins are deeper and larger than the eastern ones and (unlike the latter) are aligned at the foot of a strike-slip fault with a vertical offset of at least 700 m.  相似文献   

The value of technology and of its evolution towards a low carbon economy   总被引：2，自引：1，他引：1  

Massimo Tavoni  Enrica De Cian  Gunnar Luderer  Jan Christoph Steckel  Henri Waisman 《Climatic change》2012,114(1):39-57

This paper assesses the economic value associated with the development of various low-carbon technologies in the context of climate stabilization. We analyze the impact of restrictions on the development of specific mitigation technologies, comparing three integrated assessment models used in the RECIPE comparison exercise. Our results indicate that the diversification of the carbon mitigation portfolio is an important determinant of the feasibility of climate policy. Foregoing specific low carbon technologies raises the cost of achieving the climate policy, though at different rates. CCS and renewables are shown to have the highest value, given their flexibility and wide coverage. The costs associated with technology failure are shown to be related to the role that each technology plays in the stabilization scenario, but also to the expectations about their technological progress. In particular, the costs of restriction of mature technologies can be partly compensated by more innovation and technological advancement.  相似文献