Dual speciation of nitrogen in silicate melts at high pressure and temperature: An experimental study     

Mathieu Roskosz  Bjorn O. Mysen  George D. Cody 《Geochimica et cosmochimica acta》2006,70(11):2902-2918

Solubility and speciation of nitrogen in silicate melts have been investigated between 1400 and 1700 °C and at pressures ranging from 10 to 30 kbar for six different binary alkali and alkaline-earth silicate liquids and a Ca-Mg-alumino silicate. Experiments were performed in a piston-cylinder apparatus. The nitrogen source is silver azide, which breaks down to Ag and molecular N₂ below 300 °C. At high pressure and temperature, the nitrogen content may be as high as 0.7 wt% depending on the melt composition, pressure, and temperature. It increases with T, P and the polymerization state of the liquid. Characterization by Raman spectroscopy and ¹⁵N solid state MAS NMR indicates that nitrogen is not only physically dissolved as N₂ within the melt structure like noble gases, but a fraction of nitrogen interacts strongly with the silicate network. The most likely nitrogen-bearing species that can account for Raman and NMR results is nitrosyl group. Solubility data follow an apparent Henry’s law behavior and are in good agreement with previous studies when the nitrosyl content is low. On the other hand, a significant departure from a Henry’s law behavior is observed for highly depolymerized melts, which contain more nitrosyl than polymerized melts. Possible solubility mechanisms are also discussed. Finally, a multi-variant empirical relation is given to predict the relative content of nitrosyl and molecular nitrogen as a function of P, T, and melt composition and structure. This complex speciation of nitrogen in melts under high pressure may have significant implication concerning crystal-melt partitioning of nitrogen as well as for potential elemental and isotopic fractionation of nitrogen in the deep Earth.  相似文献   

Experimental and numerical investigations of the behaviour of a heat exchanger pile   总被引：1，自引：0，他引：1  

Lyesse Laloui  Mathieu Nuth  Laurent Vulliet 《国际地质力学数值与分析法杂志》2006,30(8):763-781

The geothermal use of concrete geostructures (piles, walls and slabs) is an environmentally friendly way of cooling and heating buildings. With such geothermal structures, it is possible to transfer energy from the ground to fluid‐filled pipes cast in concrete and then to building environments. To improve the knowledge in the field of geothermal structures, the behaviour of a pile subjected to thermo‐mechanical loads is studied in situ. The aim is to study the increased loads on pile due to thermal effects. The maximum thermal increment applied to the pile is on the order of 21°C and the mechanical load reached 1300 kN. Coupled multi‐physical finite element modelling is carried out to simulate the observed experimental results. It is shown that the numerical model is able to reproduce the most significant thermo‐mechanical effects. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

U–U–Th disequilibria and timescale of sedimentary transfers in rivers: Clues from the Gangetic plain rivers     

Franois Chabaux  Mathieu Granet  Eric Pelt  Christian France-Lanord  Valier Galy 《Journal of Geochemical Exploration》2006,88(1-3):373

This study uses ²³⁸U–²³⁴U–²³⁰Th disequilibria in river sediments in order to constrain the transfer times of sediments in alluvial plains of rivers from Himalaya and the Gangetic plain. From the observed distributions we infer sediment transfer times of about 100 ka in the Gangetic plain for rivers taking their source in the Himalayan chain, and longer transfer of about 160–250 ka for foothill-fed rivers. This difference is probably related to the difference in the sediment transport dynamics of these two types of rivers.  相似文献   

Sedimentary provenance of the Late Paleozoic metamorphic basement,south-central Chile: Implications for the evolution of the western margin of Gondwana     

Rurik Romero  Fernando Barra  Mathieu Leisen  Eduardo Salazar  José María González-Jiménez  Martin Reich 《International Geology Review》2020,62(5):598-613

ABSTRACT

U-Pb detrital zircon age patterns are presented for nine samples of metapelites from the metamorphic basement of south-central Chile between 37° and 40°S, along with detrital zircon ages for a sample from the Piedra Santa metamorphic complex and a crystallization age of the Chachil plutonic complex, farther east in Argentina. Two distinct zircon age patterns are identified. One is a pattern with a dominant population of zircons at ca. 470 Ma (Ordovician), a widespread presence of Mesoproterozoic ages (1200 ? 1000 Ma), and a Carboniferous maximum deposition age indicated by the youngest zircon population. The second pattern is drastically different, with a main population of Permian zircons, a 290–250 Ma maximum deposition age, and a minor contribution of Pennsylvanian age zircons. Our results, coupled with previously reported metamorphic ages, show that the patterns reflect the presence of different tectonic blocks separated by the Mocha-Villarrica Fault Zone at 39°S. Metapelites north of this structure have the Ordovician-dominated pattern characteristic of the Western Series of the Paleozoic basement, and those south of the fault show the Permian-dominated pattern observed in the younger high-pressure metapelites from the Bahía Mansa metamorphic complex. The Piedra Santa metamorphic complex also shows the Ordovician-dominated pattern and was intruded by the Chachil plutonic complex dated here at ca. 303 Ma. Therefore, the Piedra Santa complex is interpreted as coeval with the Chilean metamorphic basement. The present dislocation of blocks with different ages is attributed to continental-scale dextral strike-slip tectonics along the Huincul Fault Zone, Argentina, which extends to the west as the Mocha-Villarrica Fault Zone in Chile.  相似文献   

Toward a global coal mining moratorium? A comparative analysis of coal mining policies in the USA,China, India and Australia     

Mathieu Blondeel  Thijs Van de Graaf 《Climatic change》2018,150(1-2):89-101

To stop global warming at well below 2° C, the bulk of the world’s fossil fuel reserves will have to be left in the ground. Coal is the fossil fuel with the greatest proportion that cannot be used, and various advocacy groups are campaigning for a ban on the opening of new coal mines. Recently, both China and the USA implemented temporary moratoria on the approval of new coal mining leases. This article examines whether these coal mining bans reflect the emergence of a global norm to keep coal under the ground. To that end, we review recent coal mining policies in the four largest coal producers and explain them comparatively with a framework based on interests, ideas and institutions. We find that the norm of keeping coal in the ground remains essentially contested. Even in those countries that have introduced some form of a coal mining moratorium, the ban can easily be, or has already been, reversed. To the extent that the norm of keeping coal in the ground has momentum, it is primarily due to non-climate reasons: the Chinese moratorium was mostly an instance of industrial policy (aiming to protect Chinese coal companies and their workers from the overcapacity and low prices that are hitting the industry), while the USA’s lease restrictions were mainly motivated by concerns over fiscal justice. We do not find evidence of norm internalisation, which means that the emerging norm fails to gain much traction amid relevant national actors and other (large) coal producing states. If proponents of a moratorium succeed in framing the issue in non-climate terms, they should have a greater chance of building domestic political coalitions in favour of the norm.  相似文献   

Are opinions expressed in land-use planning documents?     

Eric Kergosien  Bernard Laval  Mathieu Roche 《International journal of geographical information science》2014,28(4):739-762

A great deal of research on information extraction from textual datasets has been performed in specific data contexts, such as movie reviews, commercial product evaluations, campaign speeches, etc. In this paper, we raise the question on how appropriate these methods are for documents related to land-use planning. The kind of information sought concerns the stakeholders, sentiments, geographic information, and everything else related to the territory. However, it is extremely challenging to link sentiments to the three dimensions that constitute geographic information (location, time, and theme). After highlighting the limitations of existing proposals and discussing issues related to textual data, we present a method called OPILAND (OPinion mIning from LAND-use planning documents) designed to semi-automatically mine opinions related to named-entities in specialized contexts. Experiments are conducted on a Thau lagoon dataset (France), and then applied on three datasets that are related to different areas in order to highlight the relevance and the broader applications of our proposal.  相似文献   

Assessing physical vulnerability in large cities exposed to flash floods and debris flows: the case of Arequipa (Peru)     

Jean-Claude Thouret  Susanne Ettinger  Mathieu Guitton  Olivier Santoni  Christina Magill  Kim Martelli  Giulio Zuccaro  Victor Revilla  Juan Antonio Charca  Anita Arguedas 《Natural Hazards》2014,73(3):1771-1815

Understanding the physical vulnerability of buildings and infrastructure to natural hazards is an essential step in risk assessment for large cities. We have interpreted high spatial resolution images, conducted field surveys, and utilized numerical simulations, in order to assess vulnerability across Arequipa, south Peru, close to the active El Misti volcano. The emphasis of this study was on flash floods and volcanic or non-volcanic hyperconcentrated flows, which recur on average every 3.5 years across the city. We utilized a geographic information system to embed vulnerability and hazard maps as a step to calculate risk for buildings and bridges along the Río Chili valley and two tributaries. A survey of ~1,000 buildings from 46 city blocks, different in age, construction materials, and land usage, provided architectural and structural characteristics. A similar survey of twenty bridges across the three valleys was based on structural, hydraulic, and strategic parameters. Interpretation of high spatial resolution (HSR) satellite images, which allows for quick identification of approximately 69 % of the structural building types, effectively supplemented field data collection. Mapping vulnerability has led us to pinpoint strategic areas in case of future destructive floods or flows. Calculated vulnerability is high if we examine structural criteria alone. We further consider physical setting with the most vulnerable city blocks located on the lowermost terraces, perpendicular or oblique to the flow path. Statistical analysis conducted on 3,015 city blocks, considering nine criteria identified from HSR images, indicated that building-type heterogeneity and the shape of the city blocks, along with building and street network density, are the most discriminant parameters for assessing vulnerability.  相似文献