Methane-dominated thermochemical sulphate reduction in the Triassic Feixianguan Formation East Sichuan Basin, China: towards prediction of fatal H₂S concentrations   总被引：2，自引：0，他引：2  

Chunfang Cai  Zengye Xie  Richard H. Worden  Guoyi Hu  Lansheng Wang  Hong He 《Marine and Petroleum Geology》2004,21(10):1265-1279

New sour pools have recently found in the Lower Triassic Feixianguan Fm carbonate reservoirs in the East Sichuan Basin in China with H₂S up to 17.4% by volume. A recent blowout from a well drilled into this formation killed hundreds of people as a result of the percentage concentrations of H₂S. In order to assess the origin of fatal H₂S as well as the cause of petroleum alteration, H₂S concentrations and the isotopes, δ³⁴S and δ¹³C have been collected and measured in gas samples from reservoirs. Anhydrite, pyrite and elemental sulphur δ³⁴S values have been measured for comparison. The high concentrations of H₂S gas are found to occur at depths >3000 m (temperature now at 100 °C) in evaporated platform facies oolitic dolomite or limestone that contains anhydrite nodule occurrence within the reservoirs. Where H₂S concentrations are greater than 10% its δ³⁴S values lie between +12.0 and +13.2‰ CDT. This is within the range of anhydrite δ³⁴S values found within the Feixianguan Fm (+11.0 to +21.7‰; average 15.5±3.5‰ CDT). Thus H₂S must have been generated by thermochemical sulphate reduction (TSR) locally within the reservoirs. Burial history analysis and fluid inclusion data reveal that the temperature at which TSR occurred was greater than about 130–140 °C, suggesting that the present depth-temperature minimum is an artifact of post-TSR uplift. Both methane and ethane were actively involved in TSR since the petroleum became almost totally dry (no alkanes except methane) and methane δ¹³C values become significantly heavier as TSR proceeded. Methane δ¹³C difference thus reflects the extent of TSR. While it is tempting to use a present-day depth control (>3000 m) to predict the distribution of H₂S in the Feixianguan Fm, this is an invalid approach since TSR occurred when the formation was buried some 1000–2000 m deeper than it is at present. The likelihood of differential uplift across the basin means that it is important to develop a basinal understanding of the thermal history of the Feixianguan Fm so that it is possible to determine which parts of the basin have been hotter than 130–140 °C.  相似文献   

计算数据域特征值的两种算法     

洪忠渝 《中国海洋大学学报(自然科学版)》1994,(Z2)

设计两种计算数据域特征值的算法。此特征值通常是用线性反馈移位寄存器（ＬＦ－ＳＲ）组成的特征分析器得到的．在数据已按字节存放和速度要求不高的场合下，本算法将是十分方便和有用的．  相似文献   

Characteristics of Salter's cam for extracting energy from ocean waves     

Arthur E. Mynett  Demetrio D. Serman  Chiang C. Mei 《Applied Ocean Research》1979,1(1):13-20

The performance of Salter's cam as an energy extractor from ocean waves is studied numerically on the basis of linear theory of surface waves and floating bodies. Quantities of engineering interest such as efficiency, induced motion and reaction forces are presented and discussed both for fixed and for partly constrained cam shafts.  相似文献   

虾蟹海产品香味的前体物质的加热变化     

薛长湖  汪贻生  林洪  楼伟凤 《中国海洋大学学报(自然科学版)》1994,(4)

本文研究了虾蟹海产品香味的前体物质在加热前后的变化。实验结果表明：对虾和蟹肌肉中的糖原和不饱和脂肪酸在加热前后含量下降，糖原是Ｍａｉｌｌａｒｄ反应的基础物质．不饱和脂肪酸是虾蟹肌肉香味中羰基化合物的前体物质。虾蟹肌肉中主要积累的核苷酸成分ＡＭＰ在加热后减少，而肌肉提取物中的游离氨基酸和结合氨基酸，特别是疏水氨基酸含量均增加。  相似文献   

可编程序控制器的多机联用     

洪忠渝 《中国海洋大学学报(自然科学版)》1992,(3)

多台可编程序控制器通过输入、输出点的直接连接,传递命令、状态和数据,实现多机联用系统。  相似文献   

环胶州湾公路海上段汽车尾气的环境影响     

杨三才  徐静琦  竺维丽  洪光  吴玉坤 《中国海洋大学学报(自然科学版)》1993,(1)

对类比路段进行连续模拟试验,进行现场调查,给出汽车尾气主要污染物的排污强度,预测了汽车尾气中CO、C_nH_m和NO_x的扩散范围。  相似文献   

Refraction-Diffraction Mathematical Model for Waves With Lateral Energy Transmission Mechanism and Its Verification     

Xu Shikai  Wang Hongchuan Hong Guangwen Engineer  Nanjing Hydraulic Research Institute  Nanjing  . Professor  Research Institute of Coastal  Ocean Engineering  Hohai University  Nanjing 《中国海洋工程》1996,(4)

To solve problems concerning wave elements and wave propagation, an effective way is the wave energy balance equation, which is widely applied in oceanography and ocean dynamics for its simple computation. The present papaer advances wave energy balance equations considering lateral energy transmission and energy loss as the governing equation for the study of wave refraction-diffraction. For the mathematical model, numerical simulation is made by means of difference method, and the result is verified with two examples.  相似文献   

流形上的空间密度聚类算法研究     

刘峰  刘希玉  刘弘 《中国海洋大学学报(自然科学版)》2007,37(4):681-684,626

研究流形上的聚类分析，针对基于密度的空间聚类引入了流形概念，提出1种基于流形的密度聚类算法，该方法将流形的概念与聚类相结合，可以适用于样本为复杂分布的聚类。文中通过实例证明此算法的有效性。  相似文献   

热带西太平洋海洋上层热含量的分布特征及其年际变化的分析   总被引：1，自引：0，他引：1  

白虹  丁宗信  李永祥 《海洋与湖沼》1995,26(2):154-160

选用海面至20℃等温线所处深度水层的平均温度来表征研究海域海洋上层热含量。利用这一特征值，分析1986—1990年期间热带西太平洋边缘海域海洋上层热含量在秋季的分布特征和年际变化。结果表明：（1）热含量呈南高北低分布，在7．5－22．1°N范围内。以130°E断面为代表，热含量的平均递减率为0．179（℃／纬度）；（2）热含量的分布主要取决于环流系统，其等值线因受黑潮和棉兰老海流的影响而由纬向分布转向经向分布。某些区域因受暖涡及冷涡的影响而呈封闭状分布；（3）热含量的年际变化与E1Nino事件存在着很好的相关性，在E1Nino事件发生期间，热含量变得很低，高热含量（大于26．5℃）海区的分布范围明显缩小。  相似文献   

云南程海近500年来湖泊初始生产力的演化   总被引：14，自引：1，他引：14  

吴敬禄  蒋雪中  夏威岚  潘红玺  尹宇 《海洋地质与第四纪地质》2002,22(2):95-98

程海为富营养化封闭湖泊，通过对程海CH01乳沉积物色素分析，定性恢复了近500a来程海湖泊初始生产力演化过程，结果表明，近500a来程海湖泊初始生产力总体上呈现由低到高的上升趋势，其中1700AD前后，1790AD前后是湖泊初始生产力出现变化的界限，另外，色素含量变化揭示研究时期内存在1750AD前后，1930AD前后二次明显暖波动。  相似文献