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101.
In this paper we review the relevant literature and investigate conditions likely to lead to melting of H2O ice, methanol (CH3OH) ice, ethane (C2H6) ice and other volatile ices in cometary nuclei. On the basis of a heat balance model which takes account of volatiles loss, we predict the formation of occasional aqueous and hydrocarbon liquid phases in subsurface regions at heliocentric distances, rh of 1–3 AU, and 5–12 AU, respectively. Low triple-point temperatures and low vapour pressures of C2H6, C3H8, and some higher-order alkanes and alkenes, favour liquid phase formation in cometary bodies at high rh. Microporosity and the formation of a stabilization crust occluding the escape of volatiles facilitate liquid-phase formation. Characteristics of the near-surface which favour subsurface melting include; low effective surface emissivity (at low rh), high amorphous carbon content, average pore sizes of ~10 μm or less, presence of solutes (e.g. CH3OH), mixtures of C2–C6 hydrocarbons (for melting at high rh), diurnal thermal cycling, and slow rotation rate. Applying the principles of soil mechanics, capillary forces are shown to initiate pre-melting phenomena and subsequent melting, which is expected to impart considerable strength of ~104 Pa in partially saturated layers, reducing porosity and permeability, enhancing thermal conductivity and heat transfer. Diurnal thermal cycling is expected to have a marked effect on the composition and distribution of H2O ice in the near-surface leading to frost heave-type phenomena even where little if any true melting occurs. Where melting does take place, capillary suction in the wetted zone has the potential to enhance heat transfer via capillary wetting in a low-gravity environment, and to modify surface topography creating relatively smooth flat-bottomed features, which have a tendency to be located within small depressions. An important aspect of the “wetted layer” model is the prediction that diurnal melt–freeze cycles alter the mixing ratio vs. depth of solutes present, or of other miscible components, largely through a process of fractional crystallization, but also potentially involving frost heave. Wetted layers are potentially durable and can involve significant mass transport of volatile materials in the near-surface, increasing in extent over many rotations of the nucleus prior to and just after perihelion passage, and causing stratification and trapping of the lowest-melting mixtures at depths of several metres. A possible mechanism for cometary outbursts is proposed involving a heat pulse reaching the liquid phase in the deepest wetted zone, leading to supersaturation and triggering the sudden release under pressure of dissolved gases, in particular CO2, CO, CH4 or N2, contained beneath a consolidated near-surface layer. This study indicates that liquid water can persist for long periods of time in the near-surface of some intermediate-sized bodies (102–103 km radius) within protoplanetary discs.  相似文献   
102.
The Helioseismic and Magnetic Imager (HMI) instrument will produce Doppler-velocity and vector-magnetic-field maps of the solar surface, whose accuracy is dependent on a thorough knowledge of the transmission profiles of the components of the HMI optical-filter system. Here we present a series of wavelength-dependence calibration tests, performed on the instrument from 2005 onwards, to obtain these profiles. We obtained the transmittances as a function of wavelength for the tunable and non-tunable filter elements, as well as the variation of these transmittances with temperature and the angle of incidence of rays of light. We also established the presence of fringe patterns produced by interferences inside the blocking filter and the front window, as well as a change in transmitted intensity with the tuning position. This thorough characterization of the HMI-filter system confirmed the very high quality of the instrument, and showed that its properties are well within the required specifications to produce superior data with high spatial and temporal resolution.  相似文献   
103.
Temporal and spatial variability of indoor air volatile organic compound (VOC) concentrations can complicate vapor intrusion (VI) assessment and decision-making. Indicators and tracers (I&T) of VI, such as differential temperature, differential pressure, and indoor radon concentration, are low-cost lines of evidence to support sampling scheduling and interpretation of indoor air VOC sampling results. This study compares peak indoor air chlorinated VOC concentrations and I&T conditions before and during those peak events at five VI sites. The sites differ geographically and in their VI conceptual site models (CSM). Relative to site-specific baseline values, the results show that cold or falling outdoor temperatures, rising cross slab differential pressures, and increasing indoor radon concentrations can predict peak VOC concentrations. However, cold outdoor air temperature was not useful at one site where elevated shallow soil temperature was a better predictor. Correlations of peak VOC concentrations to elevated or rising barometric pressure and low wind speed were also observed with some exceptions. This study shows how the independent variables that control or predict peak indoor air VOC concentrations are specific to building types, climates, and VI CSMs. More I&T measurements at VI sites are needed to identify scenario-specific baseline and peak related I&T conditions to improve decision-making.  相似文献   
104.
The Australian and New Zealand Guidelines for Fresh and Marine Water Quality (ANZECC Guidelines) provide default national guideline values for a wide range of indicators of relevance to the protection of the ecological condition of natural waters. However, the ANZECC Guidelines also place a strong emphasis on the need to develop more locally relevant guidelines. Using a structured framework, this paper explores indicators and regional data sets that can be used to develop more locally relevant guidelines for the Great Barrier Reef World Heritage Area (GBRWHA). The paper focuses on the water quality impacts of adjacent catchments on the GBRWHA with the key stressors addressed being nutrients, sediments and agricultural chemicals. Indicators relevant to these stressors are discussed including both physico-chemical pressure indicators and biological condition indicators. Where adequate data sets are available, guideline values are proposed. Generally, data were much more readily available for physico-chemical pressure indicators than for biological condition indicators. Specifically, guideline values are proposed for the major nutrients nitrogen (N) and phosphorus (P) and for chlorophyll-a. More limited guidelines are proposed for sediment related indicators. For most agricultural chemicals, the ANZECC Guidelines are likely to remain the default of choice for some time but it is noted that there is data in the literature that could be used to develop more locally relevant guidelines.  相似文献   
105.
Analytical solutions for the Ekman layer   总被引:1,自引:0,他引:1  
The PBL equation that governs the transition from the constant-stress surface layer to the geostrophic wind in a neutrally stratified atmosphere for which the eddy viscosityK(z) is assumed to vary smoothly from the surface-layer value U *z (0.4,U *=friction velocity,z=elevation) to the geostrophic asymptoteK GU *d forzd is solved through an expansion in fd/U *1 (f=Coriolis parameter). The resulting solution is separated into Ekman's constant-K solution an inner component that reduces to the classical logarithmic form forzd and isO() relative to the Ekman component forzd. The approximationKU *d is supported by the solution of Nee and Kovasznay's phenomenological transport equation forK(z), which yieldsKU *d exp(–z/d), where is an empirical constant for which observation implies, 1. The parametersA andB in Kazanskii and Monin's similarity relation forG/U * (G=geostrophic velocity) are determined as functions of . The predicted values ofG/U * and the turning angle are in agreement with the observed values for the Leipzig wind profile. The predicted value ofB based on the assumption of asymptotically constantK is 4.5, while that based on the Nee-Kovasznay model is 5.1; these compare with the observed value of 4.7 for the Leipzig profile. A thermal wind correction, an asymptotic solution for arbitraryK(z) and 1, and an exact (unrestricted ) solution forK(z)=U *d[1–exp(–z/d)] are developed in appendices.  相似文献   
106.
107.
Progress has been made in the Pacific region to implement the decisions taken by leaders at the Earth Summit. There has been investment in the environment and in sustainable development initiatives in the Pacific, and island countries have managed to place their concerns and special circumstances clearly on the international agenda. By the very nature of Pacific islands, Agenda 21 and its off-shoot, the Barbados Programme of Action, have influenced ocean and coastal management. However, the extent to which this has changed the fundamental approach to development in islands is less clear. While it may not be possible to determine categorically the state of implementation of Agenda 21 or how far Pacific island countries have gone down the path towards sustainable development, there are some sound indicators of change. This paper examines a number of these indicators of progress to implement Agenda 21 in the Pacific at the national, regional and international levels, and identifies some challenges for the future.  相似文献   
108.
Deposits of the 22.6 ka Okareka Eruption Episode from Tarawera Volcanic Complex record the sequential and simultaneous eruption of three discrete rhyolite magmas following a silicic recharge event related to basaltic intrusion. The episode started with basaltic eruption ( 0.01 km3 magma), and rapidly changed to a plinian eruption involving a moderate temperature (750 °C), cummingtonite-bearing rhyolite magma (T1) with a volume of  0.3 km3. Hybrid basalt/rhyolite clasts demonstrate direct basaltic intrusion that helped trigger the eruption. Crystals, shards and lapilli of two other rhyolite magmas then joined the eruption sequence. They comprise a cooler (720 °C) crystal-rich biotite–hornblende rhyolite magma (T2) ( 0.3 km3), and a hotter (780 °C), crystal-poor, pyroxene–hornblende rhyolite magma (T3) ( 4.5 km3). All mid to late-stage ash units contain various mixtures of T1, T2 and T3 components with a general increase in abundance of T3 and rapid decline of T1 with time. About 4 km3 of T3 magma was extruded as lavas at the end of the episode. Contrasts in melt composition, crystal and volatile contents, and temperatures influenced viscosity and miscibility, and thus limited pre-eruption mixing of the rhyolite magmas. The eruption sequence and the restricted direct basaltic intrusion into only one magma (T1) is consistent with the rhyolites occupying separate melt pods within a large crystal-mush zone. Melt–crystal equilibria and volatile contents in melt inclusions indicate temporary magma storage depths of < 8 km. Each of the magmas display quartz crystals containing melt inclusions that are compositionally highly evolved relative to the accompanying matrix glass, and thus point to a stage of more complete crystallisation. The matrix glass, enriched in Sr and Ti, represents a re-melting event of underlying the crystal pile induced by basaltic intrusion, presumably part of the same event that erupted scoria at the start of the eruption. This recharge rhyolite melt percolated upward and hybridised with the resident melts in each of the three magma pods. The Okareka episode rhyolites contrast with other well-documented rhyolites that are either continuously or discontinuously zoned, or have been homogenised during re-activation to a uniform composition. Rapid basalt dike intrusion to shallow levels appears to have (prematurely?) triggered the Okareka rhyolites into eruption, so that their early ponding in separate melt pods has been recorded before it could be masked by mixing or stratification had amalgamation into a larger body occurred.  相似文献   
109.
The aim of this work was to develop an easy to handle semi-analytical method to estimate the temporal development of emission from a multi-component LNAPL pool considering groundwater recharge. The presented approach allows the estimation of the total mass flux out of an LNAPL pool into the gas and the water phase, the latter including the mass fluxes from groundwater recharge, advection through and diffusion out of the LNAPL zone. Therefore, the known set of constitutive relationships to determine fluid saturation profiles of 2- and 3-phase systems is extended in this work to account for dynamic conditions due to groundwater recharge. The methodology is applied to a kerosene pool at a former military airfield and it is found that the mass flux due to groundwater recharge dominates the aqueous mass flux from the kerosene contaminated zone. A sensitivity study using field parameters shows, that the apparent kerosene thicknesses observed in monitoring wells and the lithology control mass flux into the gas phase, whereas the mass flux into groundwater mainly depends on the groundwater recharge rate. For the kerosene found at the site, source emission into the soil gas is estimated to last longer than the emission into groundwater, the latter varying between less than 100 and 400 years.  相似文献   
110.
Fire and other disturbances of the forests in Mount Rainier National Park   总被引:1,自引:0,他引:1  
The recent history of catastrophic disturbances in forests was reconstructed at Mount Rainier National Park. Basic data were ages of trees based on ring counts of early seral conifer species and maps of age-class boundaries from field work and aerial photographs. Maps illustrate age classes of the forests and show disturbances from fires, snow avalanches, and lahars (volcanic mudflows). Fires are by far the most important major disturbers, followed by snow avalanches and lahars. Fires over 250 ha in size are called fire events. Burns over 1000 ha, which may have been one fire or a series of fires within a short time, are called fire episodes. Important fire events or episodes occurred in the years 1230, 1303, 1403, 1503, 1628, 1688, 1703, 1803, 1825, 1856, 1858, 1872, 1886, 1894, 1930, and 1934 A.D. The largest fire episode was in 1230; it affected approximately 47% of the forests in the park. The majority of the forests are over 350 yr old, and several stands are over 1000 yr old. Stands 350 yr and 100 to 200 yr in age are the most extensive age classes in the park. Three fire frequency indices are compared. None describe fire frequency at Mount Rainier well. Natural fire rotation was estimated at about 434 yr. All but two episodes of major fires since 1300 A.D. correspond well with major droughts reconstructed for locations east of the Cascade Range crest. Impacts of humans on the disturbance regime may have increased the frequency of fire in the 1850–1900 period, followed by a decrease in frequency after 1900. Fuel build-up as a result of fire suppression should have no significant impact on fire frequency, since fires are relatively infrequent and fuels accumulate naturally.  相似文献   
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