Asthenospheric percolation of alkaline melts beneath the St. Paul region (Central Atlantic Ocean)     

Daniele Brunelli  Monique Seyler 《Earth and Planetary Science Letters》2010,289(3-4):393-405

Two peridotite suites collected by submersible in the equatorial Atlantic Ocean (Hekinian et al., 2000) were studied for textures, modes, and in situ major and trace element compositions in pyroxenes. Dive SP12 runs along the immersed flank of the St. Peter and Paul Rocks islets where amphibole-bearing, ultramafic mylonites enriched in alkalies and incompatible elements are exposed (Roden et al., 1984), whereas dive SP03 sampled a small intra-transform spreading centre situated about 370 km east of the St. Peter and Paul Rocks. Both suites are characterized by undeformed, coarse-grained granular textures typical of abyssal peridotites, derived from residual mantle after ～ 15% melting of a DMM source, starting in the garnet stability field. Trace element modelling, textures and lack of mineral zoning indicate that the residual peridotites were percolated, reacted and refertilized by ～ 2.6% partially aggregated melts in the uppermost level of the melting region. This relatively large amount of refertilization is in agreement with the cold and thick lithosphere inferred by previous studies. Freezing of trapped melts occurred as the peridotite entered the conductive layer, resulting in late-stage crystallization of olivine, clinopyroxene, spinel, ± plagioclase. Chondrite-normalized REE patterns in clinopyroxenes from SP03 indicate that they last equilibrated with (ultra-) depleted partial melts. In contrast, REE concentrations in clinopyroxenes from SP12 display U and S shaped LREE-enriched patterns and the calculated compositions of the impregnating melts span the compositional range of the regional basalts, which vary from normal MORB to alkali basalt sometimes modified by chromatographic fractionation with no, or very limited, mineral reaction. Thus the mylonitic band forming the St. Peter and St. Paul Rocks ridge is not a fragment of subcontinental lithospheric mantle left behind during the opening of the Central Atlantic, nor the source of the alkaline basalts as previously suggested. Rather, dive SP12 sampled residual peridotites of normal MORB mantle that were located close to channels transporting alkali basalts. Reacted melts escaping from these channels, infiltrated, and locally equilibrated with, the peridotite matrix by ion exchange reactions. Relicts of the source of the alkaline basalts were not sampled but our study suggests that it was a component of the MORB mantle underlying the St. Paul region.  相似文献   

A new mammalian fauna from the earliest Eocene (Ilerdian) of the Corbières (Southern France): palaeobiogeographical implications     

Bernard Marandat  Sylvain Adnet  Laurent Marivaux  Alain Martinez  Monique Vianey-Liaud  Rodolphe Tabuce 《Swiss Journal of Geoscience》2012,105(3):417-434

A new mammal fauna from the earliest Eocene of Le Clot (Corbières, Southern France) is described. Some taxa identified there, such as Corbarimys hottingeri and Paschatherium plaziati, allow a correlation with the previously described Corbières fauna of Fordones. Moreover, the presence at Le Clot of Lessnessina praecipuus, which is defined in Palette (Provence, Southern France) allows correlating both localities. All three of these localities are referred to the MP7 reference level, even if a direct correlation with the type locality of MP7 (Dormaal, Belgium) is not ascertained. A Southern Europe biochronological sequence is proposed for the beginning of the Eocene: Silveirinha, Fordones/Palette/Le Clot, Rians/Fournes. The diagnosis of a new species of a neoplagiaulacid multituberculate (?Ectypodus riansensis nov. sp.) is proposed. From a compilation of data concerning the earliest Eocene faunas from both Northern Europe and Southern Europe, we conclude that two faunas corresponding to two distinct palaeobiogeographical provinces existed in Western Europe. This faunal disparity, probably related to climatic differences, makes correlations particularly difficult between the two provinces.  相似文献   

The impact of logging on the surrounding flow in a managed forest     

Gengsheng Zhang  Monique Y. Leclerc  Anandakumar Karipot  Henrique F. Duarte  Erich Mursch-Radlgruber  Henry L. Gholz 《Theoretical and Applied Climatology》2011,106(3-4):511-521

The influence of a freshly logged area in a managed pine forest on the flow field is investigated by comparing sodar wind profile data over the forest canopy with the synoptic wind field extracted from North American Regional Reanalysis, National Centers for Environmental Prediction. As a consequence of the pressure gradient arising from the sharp temperature difference between the clearcut and the surrounding uncut forests, the local wind direction over the forest measured with the sodar departs dramatically from the prevailing synoptic wind direction when the latter is transverse to the clearcut-sodar direction. Sodar measurements also indicate systematic strong updrafts during daytime followed by nighttime downdrafts with wind coming from the logged area. This suggests the presence of horizontal advection carrying daytime warm air (or nighttime cool air) from the clearcut to the forested area. This paper also examines the influence of wind velocity, clearcut fetch, and solar radiation on locally generated circulations and advection. The presence of local circulations arising from contrasting neighboring surface characteristics well outside the footprint is of particular relevance for atmospheric flux sites where robust surface?Catmosphere exchange values are sought. This study highlights the high level of circumspection required at the time of identifying locations for flux sites. It also suggests vigilant monitoring of the surrounding landscape during eddy?Cflux measurements particularly in actively managed landscapes.  相似文献   

Sampling strategy and climatic implications of tree-ring stable isotopes on the southeast Tibetan Plateau     

Chunming Shi  Valérie Masson-Delmotte  Camille Risi  Thomas Eglin  Michel Stievenard  Monique Pierre  Xiaochun Wang  Jing Gao  François-Marie Bréon  Qi-Bin Zhang  Valérie Daux 《Earth and Planetary Science Letters》2011,301(1-2):307-316

We explore the potential of tree-ring cellulose δ¹⁸O and δ¹³C records for reconstructing climate variability in the southeast Tibetan Plateau. Our sampling strategy was designed to investigate intra and inter-tree variability, and the effects of the age of tree on δ¹⁸O variation. We show that intra-tree δ¹³C and δ¹⁸O variability is negligible, and inter-tree coherence is sufficient to build robust tree-ring δ¹⁸O or δ¹³C chronologies based on only four trees. There is no evidence of an age effect regarding δ¹⁸O, in contrast with tree-ring width. In our warm and moist sampling site, young tree δ¹³C is not clearly correlated with monthly mean meteorological data. Tree-ring δ¹⁸O appears significantly anti-correlated with summer precipitation amount, regional cloud cover, and relative humidity. Simulations conducted with the ORCHIDEE land surface model confirm the observed contribution of relative humidity to tree cellulose δ¹⁸O, and explain the weak correlation of δ¹³C with climate by the non-linear integration linked with photosynthesis. Altogether, the tree-ring cellulose δ¹⁸O is shown to be a promising proxy to reconstruct regional summer moisture variability prior to the instrumental period.  相似文献   

盐湖丰产元素与Zintl化合物(续完)          下载免费PDF全文

贾永忠  景燕  马军  岳都元  Claude Belin  Monique Tillard 《盐湖研究》2011,19(2):63-72

Zintl化合物是以Edward Zintl命名的化合物,是一类由电正性的碱金属或碱土金属与电负性的13族或14族元素形成的特殊金属间化合物。其价键模式可以是离子键、金属键和共价键共存,其中的准金属可以共价键的形式形成各种形式的离子簇,因而其结构复杂多样。这类化合物的部分阴离子簇不仅具有稳定的笼状、层状和链状结构,并且具有特殊的光、电、磁等性能,使得在半导体、催化、电极材料等方面都有应用的前景和发展潜力。介绍了几个特殊Zintl化合物体系,盐湖丰产元素在Zintl化合物中的作用,指出了含有盐湖丰产元素的Zintl化合物的应用前景和方向。  相似文献   

Mineralogy,chemistry, and grain size composition of recent sediments in the northern Tyrrhenian Sea: Contribution to the study of sediment transport and distribution     

Leonardo Leoni  Franco Sartori  Maurizio Saitta  Vincenzo Damiani  Ornella Ferretti  Monique Viel 《Environmental Geology》1991,17(1):23-46

As a contribution to an environmental study on Tuscany's marine shelf, textural, mineralogical, and chemical characteristics of recent sediments in the northern Tyrrhenian Sea between Elba Island and Livorno have been analyzed. The data provide clear information on sediment sources and movement patterns. The main sediment source appears to be the Cecina River; very subordinate is the contribution of the Fine River. As to sediment movement patterns, the surveyed basin appears to be divided into two subbasins: (1) a greater, southern subbasin, bounded by Tuscany mainland, Elba Island and Elba Ridge, and Capraia Isle, and Vada Shoals; and (2) a smaller, northern subbasin, enclosed between Vada Shoals and Meloria Shoals (off Livorno port).In the former the coarse-grade Cecina River sediments are transported southward along most of the mainland coast by littoral drift and coastal current; a northward flowing countercurrent seems to be active only in the southernmost part. Silts and clays are distributed in concentric belts around basin's central part, being transported mainly by slow circular water movements. In the marginal western zone, very little terrigenous influx is coupled with a high biologic productivity, and biogenic debris sedimentation prevails there.In the northern subbasin the sediment contribution from Fine River is more appreciable. Here the environmental energies are very low and the coarse sediments are restricted to a few small pocket beaches where they are deposited by local creeks. Most of the subbasin area is occupied by sapropelitic muds, again distributed by slow small-scale gyres.  相似文献   

The Gambia River estuary: A reference point for estuarine fish assemblages studies in West Africa   总被引：3，自引：1，他引：3  

Monique Simier  Charline Laurent  Jean-Marc Ecoutin  Jean-Jacques Albaret 《Estuarine, Coastal and Shelf Science》2006,69(3-4):615

The Gambia River is one of the last aquatic ecosystems in West Africa that has not yet been affected by strong environmental changes and human disturbances. In contrast to the neighbouring Casamance and Sine Saloum estuaries, the Gambia estuary is free of major climatic perturbation and remains a “normal” estuary, with a salinity range from freshwater to 39. The present paper aims to study the spatial and seasonal variability of fish assemblages in this estuary in terms of bio-ecological categories and of their relation with some environmental variables. Four surveys were conducted, from June 2001 to April 2002, in order to cover the major hydroclimatic events, at 44 sampling sites along the lower, intermediate and upper zones of the Gambia estuary (up to 220 km). Fish assemblages were sampled using a purse seine net, fish were identified to species level and environmental variables such as water depth, transparency, salinity, temperature and percentage oxygen saturation were measured. The main spatial structure of the fish assemblages and its seasonal changes were first studied using the STATIS-CoA multitable method. The combination of fish assemblages and environmental variables was then analysed using the STATICO method, designed for the simultaneous analysis of paired ecological tables. A total of 67 species were observed, belonging to all bio-ecological categories characterizing West African estuaries. The marine component of the community was largely dominant throughout the estuary, while the freshwater component was permanently observed only in the upstream zone. The main spatial structure was a longitudinal gradient contrasting marine and freshwater affinity assemblages, with strong seasonal variations. The most complete gradient was observed in December, at the beginning of the dry and cool season, while in June, at the end of the dry and warm season, there was the least structured gradient. The role of salinity, always correlated with temperature, was emphasized, while turbidity appeared to be another important factor. Oxygen and depth did not play a major role at the estuary scale. The relative importance of the bio-ecological categories varied according to the season and the distance to sea. Stable fish assemblages were observed in the lower zone at the end of the dry season, in the upper zone during the flood and in the middle zone throughout the year. In some situations, a relative inadequacy between fish assemblages and their environment was noticed. The present study contributes to the definition of the functioning of a “normal” West African estuary, the Gambia estuary, with balanced effects of marine and freshwater influences and the presence of all bio-ecological categories. The Gambia estuary can therefore be considered to be a reference ecosystem for further comparisons with other tropical estuarine ecosystems, subjected to natural or artificial perturbations.  相似文献   

Hydrous olivine alteration on Mars and Earth     

Zoltn Vci  Carl B. Agee  Christopher D. K. Herd  Erin Walton  Oliver Tschauner  Karen Ziegler  Vitali B. Prakapenka  Eran Greenberg  Sylvia Monique‐Thomas 《Meteoritics & planetary science》2020,55(5):1011-1030

Hydrous alteration of olivine macrocrysts in a Martian olivine phyric basalt, NWA 10416, and a terrestrial basalt from southern Colorado are examined using SEM, EPMA, TEM, and µXRD techniques. The olivines in the meteorite contain linear nanotubes of hydrous material, amorphous areas, and fluid dissolution textures quite distinct from alteration identified in other Martian meteorites. Instead, they bear resemblance to terrestrial deuteric alteration features. The presence of the hydrous alteration phase Mg‐laihunite within the olivines has been confirmed by µXRD analysis. The cores of the olivines in both Martian and terrestrial samples are overgrown by unaltered rims whose compositions match those of a separate population of groundmass olivines, suggesting that the core olivines are xenocrysts whose alteration preceded crystallization of the groundmass. The terrestrial sample is linked to deep crustal metasomatism and the “ignimbrite flare‐up” of the Oligocene epoch. The comparison of the two samples suggests the existence of an analogous relatively water‐rich magmatic reservoir on Mars.  相似文献   

Heat flux apportionment to heterogeneous surfaces using flux footprint analysis     

彭谷亮  蔡旭晖  张宏升  李爱国  胡非 《大气科学进展》2008,25(1):107-116

Heat flux data collected from the Baiyangdian Heterogeneous Field Experiment were analyzed using the footprint method. High resolution （25 m） Landsat-5 satellite imaging was used to determine the land cover as one of four surface types： farmland, lake, wetland, or village. Data from two observation sites in September 2005 were used. One site （Wangjiazhai） was characterized by highly heterogeneous surfaces in the central area of the Baiyangdian： lake/wetland. The other site （Xiongxian） was on land with more uniform surface cover. An improved Eulerian analytical flux footprint model was used to determine “source areas” of the heat fluxes measured at towers located at each site from surrounding landscapes of mixed surface types. In relative terms results show that wetland and lake areas generally contributed most to the observed heat flux at Wangjiazhai, while farmland contributed most at Xiongxian. Given the areal distribution of surface type contributions, calculations were made to obtain the magnitudes of the heat flux from lake, wetland and farmland to the total observed flux and apportioned contributions of each surface type to the sensible and latent heat fluxes. Results show that on average the sensible heat flux from wetland and farmland were comparable over the diurnal cycle, while the latent heat flux from farmland was somewhat larger by about 30-50 W m-2 during daytime. The latent and sensible fluxes from the lake source in daytime were about 50 W m-2 and 100 W m-2 less, respectively, than from wetland and farmland. The results are judged reasonable and serve to demonstrate the potential for flux apportionment over heterogeneous surfaces.  相似文献   

Arsenic — a Review. Part II: Oxidation of Arsenic and its Removal in Water Treatment     

Monique Bissen  Fritz H. Frimmel 《洁净——土壤、空气、水》2003,31(2):97-107

In natural waters arsenic normally occurs in the oxidation states +III (arsenite) and +V (arsenate). The removal of As(III) is more difficult than the removal of As(V). Therefore, As(III) has to be oxidized to As(V) prior to its removal. The oxidation in the presence of air or pure oxygen is slow. The oxidation rate can be increased by ozone, chlorine, hypochlorite, chlorine dioxide, or H₂O₂. The oxidation of As(III) is also possible in the presence of manganese oxide coated sands or by advanced oxidation processes. Arsenic can be removed from waters by coprecipitation with Fe(OH)₃, MnO₂ or during water softening. Fixed‐bed filters have successfully been applied for the removal of arsenic.The effectiveness of arsenic removal was tested in the presence of adsorbents such as FeOOH, activated alumina, ferruginous manganese ore, granular activated carbon, or natural zeolites. Other removal technologies are anion exchange, electrocoagulation, and membrane filtration by ultrafiltration, nanofiltration or reverse osmosis.  相似文献