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1.
The Sarliève marsh in the Limagne plain, in the heart of the French Massif Central, functioned as an endorheic lake during the Late Glacial and the Early and Middle Holocene. During the Late Boreal and the Atlantic it experienced drastic lowering of the water level as a result of dry and warm climatic episodes. Then, pre-evaporitic conditions triggered the deposition of sediment rich in organic matter (OM) and in carbonates including dolomite. Fifty-one samples from a ca. 1.8 m sediment core section covering the period were analysed using Rock–Eval pyrolysis and gas chromatography–mass spectrometry (GC–MS). Throughout the interval, the OM content remained notable to high [up to 13.35% total organic carbon (TOC)] and of good quality as indicated by low oxygen index (OI) values (<200 mg CO2 g−1 TOC) and high hydrogen index (HI) values (160–660 mg HC g−1) which, as a rule, increased with increasing TOC content.In contrast to the acid fractions, which sometimes contained notable proportions of n-C16 or n-C18 fatty acids (FAs; analysed as the methyl esters, FAMEs), the neutral fractions were almost devoid of low molecular weight compounds. The latter were probably biodegraded during early diagenesis. Conversely, high molecular weight compounds were abundant in both fractions and were dominated by n-alkanols, n-alkanes, steroids and hopanoids in the neutrals and even numbered FAs and hopanoids in the acid fractions. The hopanoids were dominated by regular bishomohopanoids, accompanied by 2-methylated bishomohopanoids, as well as by unidentified bishomohopanoids with methylation in either the D or E ring. These distributions, typical for bacteria, provide support for previous hypotheses on the contribution of microorganisms to the studied record and for providing conditions for the precipitation and growth of dolomite and other pristine carbonate minerals [Bréheret, J.G., Fourmont, A., Macaire, J.J., Négrel, Ph., 2008. Microbially mediated carbonates in the Holocene lacustrine deposits of the Marais de Sarliève (French Massif Central) testify to the evolution of a restricted environment. Sedimentology 55, 557–578]. The preservation of the compounds was probably ensured by persistent reducing conditions during diagenesis, despite variable climatic conditions and related changes in lake level and sedimentation rate. Comparable distributions of hopanoic acids and hopanols, as well as roughly parallel variation with depth in the corresponding components in both fractions, strongly suggest that all the hopanoids derive from the same microbial precursors, slight shifts in the acid/alcohol ratio being governed by limited changes in redox conditions during early diagenesis.  相似文献   
2.
This work provides five new U–Pb zircon dating and the corresponding Nd isotope data for felsic granulites from the south Itabuna-Salvador-Curaçá Block (ISCB), in the São Francisco Craton, Brazil. Three major sets of felsic granulites can be recognised. The oldest set is tonalitic in composition and of TTG affinity. It is Archaean in age with magmatic zircon cores dated at 2675 ± 11 Ma by LA-ICPMS and up to ca 2.7–2.9 Ga by SHRIMP on an other sample. It exhibits epsilon Nd values between ?8 and ?11 at 2.1 Ga. This Nd signature is similar to that of granulites found in the western Archaean Jequié Block. Cartographically, this set of Archaean terrains represents at least 50% of the granulites in the studied area. The second set corresponds to a Palaeoproterozoic calc-alkaline tonalitic suite with zircon ages from 2019 ± 19 Ma to 2191 ± 10 Ma and epsilon Nd values between ?3 and ?4 at 2.1 Ga, corresponding partially to a newly formed crust. The third set of granulites is also Palaeoproterozoic. It is shoshonitic to monzonitic in composition and synchronous with the high grade metamorphism dated by metamorphic zircons at 2086 ± 7 Ma (average of five samples). The Nd isotope signature for this alkaline set is similar to that of the Palaeoproterozoic calc-alkaline one. Nd isotopes appear to be a very efficient tool to distinguish Archaean from Palaeoproterozoic felsic protoliths in granulitic suites of the Itabuna-Salvador-Curaçá Block (ISCB). Finally, the southern part of the ISCB is composed of a mixture of Archaean and Palaeoproterozoic protoliths, in similar amounts, suggesting that it was probably an active margin between 2.1 and 2.2 Ga located on the eastern border of the Archaean Jequié Block. A major crustal thickening process occurred at ca 2.09 Ga in the ISCB and seems significantly younger towards the west, in the Jequié granulites, where an average of 2056 ± 9 Ma is determined for the high grade event.  相似文献   
3.
Summary. Multiparameter inversions of multimode dispersion data are performed for two large regions: the Pacific Ocean and North America. Anisotropy is taken into account by considering transversely isotropic structures with a vertical axis of symmetry. Two fundamental questions are studied in detail: (1) how to make the inverted models consistent when using different sets of parameters, (2) what is the significance of transversely isotropic inversion for the actual Earth's structure? It is proved that full consistency of the inverted models can be achieved by properly taking into account some a priori informations on the model and it is shown that the use of transversely isotropic models with vertical axis of symmetry does not cause severe limitations when interpreting the data. The models we have obtained are discussed in the light of these investigations. Considering an olivine-rich upper mantle, we make a tentative interpretation of these models in terms of preferred orientation of the a -axis of the crystals in one fixed horizontal direction.  相似文献   
4.
5.
An ESR experimental study of artificial optical bleaching of sedimentary quartz has shown that the aluminum center was maximally bleached after a 6-month illumination equivalent to natural light. This duration seems too long to apply in natural conditions. Nevertheless, the measurement of the ESR intensity of aluminum centers in quartz extracted from modern sediments and deposited in sandy bars shows that the maximum bleaching has effectively been reached.

In order to determine the relationship between the bleaching and the distance covered by a quartz grain in a river, samples were collected along the Creuse River (France) from its spring to about 170 km downstream, where maximum bleaching levels were observed in previous studies. The ESR intensities of the aluminum and titanium centers in quartz were measured, using X-band spectroscopy, before and after artificial bleaching. The difference measured between these sub-samples shows that the maximum bleaching level is obtained in the course of the first kilometer. Hence, the assumption that ESR dating of fluvial sediment is based on the optical bleaching was validated.  相似文献   

6.
Avicennia pollen grains have been discovered in marine facies from the Middle Miocene deltaic series of Châteauredon (southeastern France). Based on the local stratigraphy, an age between 15.8 and 16.5 Ma is proposed for these grains. The age and the transgressive context of the Avicennia bearing-levels are in agreement with the maximum extension of the mangrove known in the western Mediterranean during interval N8–NN4 pro parte, in relation with the Langhian highstand. This mangrove occurrence at 42°N latitude during Middle Miocene is a more northern witness of the mangrove sites known in Languedoc and Provence areas. It also implies a lower climatic gradient than today. To cite this article: J.-J. Châteauneuf et al., C. R. Geoscience 338 (2006).  相似文献   
7.
We present a three-dimensional (3D) SV-wave velocity model of the upper mantle beneath the Antarctic plate constrained by fundamental and higher mode Rayleigh waves recorded at regional distances. The good agreement between our results and previous surface wave studies in the uppermost 200 km of the mantle confirms that despite strong differences in data processing, modern surface wave tomographic techniques allow to produce consistent velocity models, even at regional scale. At greater depths the higher mode information present in our data set allows us to improve the resolution compared to previous regional surface wave studies in Antarctica that were all restricted to the analysis of the fundamental mode. This paper is therefore mostly devoted to the discussion of the deeper part of the model. Our seismic model displays broad domains of anomalously low seismic velocities in the asthenosphere. Moreover, we show that some of these broad, low-velocity regions can be more deeply rooted. The most remarkable new features of our model are vertical low-velocity structures extending from the asthenosphere down to the transition zone beneath the volcanic region of Marie Byrd Land, West Antarctica and a portion of the Pacific-Antarctic Ridge close to the Balleny Islands hotspot. A deep low-velocity anomaly may also exist beneath the Ross Sea hotspot. These vertical structures cannot be explained by vertical smearing of shallow seismic anomalies and synthetic tests show that they are compatible with a structure narrower than 200 km which would have been horizontally smoothed by the tomographic inversion. These deep low-velocity anomalies may favor the existence of several distinct mantle plumes, instead of a large single one, as the origin of volcanism in and around West Antarctica. These hypothetical deep plumes could feed large regions of low seismic velocities in the asthenosphere.  相似文献   
8.
The relationship between the oxygen isotope ratio of mammal tooth enamel and that of drinking water was used to reconstruct changes in the Miocene oxygen isotope ratio of rainfall (meteoric water δ18OMW). These, in turn, are related to climatic parameters (temperature, precipitation and evaporation rate). δ18O values of rhinocerotid teeth from the Aquitaine Basin (southwestern France) suggest a significant climatic change between 17 and 12 Ma, characterized by cooling together with precipitation increase, in agreement with other terrestrial and oceanic records. To cite this article: I. Bentaleb et al., C. R. Geoscience 338 (2006).  相似文献   
9.
VMS deposits of the South Urals developed within the evolving Urals palaeo-ocean between Silurian and Late Devonian times. Arc-continent collision between Baltica and the Magnitogorsk Zone (arc) in the south-western Urals effectively terminated submarine volcanism in the Magnitogorsk Zone with which the bulk of the VMS deposits are associated. The majority of the Urals VMS deposits formed within volcanic-dominated sequences in deep seawater settings. Preservation of macro and micro vent fauna in the sulphide bodies is both testament to the seafloor setting for much of the sulphides but also the exceptional degree of preservation and lack of metamorphic overprint of the deposits and host rocks. The deposits in the Urals have previously been classified in terms of tectonic setting, host rock associations and metal ratios in line with recent tectono-stratigraphic classifications. In addition to these broad classes, it is clear that in a number of the Urals settings, an evolution of the host volcanic stratigraphy is accompanied by an associated change in the metal ratios of the VMS deposits, a situation previously discussed, for example, in the Noranda district of Canada.Two key structural settings are implicated in the South Urals. The first is seen in a preserved marginal allochthon west of the Main Urals Fault where early arc tholeiites host Cu–Zn mineralization in deposits including Yaman Kasy, which is host to the oldest macro vent fauna assembly known to science. The second tectonic setting for the South Urals VMS is the Magnitogorsk arc where study has highlighted the presence of a preserved early forearc assemblage, arc tholeiite to calc-alkaline sequences and rifted arc bimodal tholeiite sequences. The boninitc rocks of the forearc host Cu–(Zn) and Cu–Co VMS deposits, the latter hosted in fragments within the Main Urals Fault Zone (MUFZ) which marks the line of arc-continent collision in Late Devonian times. The arc tholeiites host Cu–Zn deposits with an evolution to more calc-alkaline felsic volcanic sequences matched with a change to Zn–Pb–Cu polymetallic deposits, often gold-rich. Large rifts in the arc sequence are filled by thick bimodal tholeiite sequences, themselves often showing an evolution to a more calc-alkaline nature. These thick bimodal sequences are host to the largest of the Cu–Zn VMS deposits.The exceptional degree of preservation in the Urals has permitted the identification of early seafloor clastic and hydrolytic modification (here termed halmyrolysis sensu lato) to the sulphide assemblages prior to diagenesis and this results in large-scale modification to the primary VMS body, resulting in distinctive morphological and mineralogical sub-types of sulphide body superimposed upon the tectonic association classification.It is proposed that a better classification of seafloor VMS systems is thus achievable using a three stage classification based on (a) tectonic (hence bulk volcanic chemistry) association, (b) local volcanic chemical evolution within a single edifice and (c) seafloor reworking and halmyrolysis.  相似文献   
10.
Mount Bangou, an Eocene volcano (40K–40Ar ages between 44.7 and 43.1 ± 1 Ma) is the oldest dated volcano of the Cameroon Line. In this region, two magmatic series, evolving by fractional crystallization, show transitional affinities that are exceptionally known in this sector. Mineral compositions of basaltic rocks (scarce modal olivine and occurrence of normative hypersthene) as well as geochemical characteristics (low Ba, La, Ta contents and high Y/Nb ratios) are in agreement with this trend. The succession of magmas evolving in time from transitional to more typical alkaline compositions is evidenced in a continental setting. To cite this article: J. Fosso et al., C. R. Geoscience 337 (2005).  相似文献   
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