Stable Cu and Zn isotope ratios as tracers of sources and transport of Cu and Zn in contaminated soil   总被引：7，自引：0，他引：7  

Moritz Bigalke  Stefan Weyer  Jozef Kobza 《Geochimica et cosmochimica acta》2010,74(23):6801-6813

Copper and Zn metals are produced in large quantities for different applications. During Cu production, large amounts of Cu and Zn can be released to the environment. Therefore, the surroundings of Cu smelters are frequently metal-polluted. We determined Cu and Zn concentrations and Cu and Zn stable isotope ratios (δ⁶⁵Cu, δ⁶⁶Zn) in three soils at distances of 1.1, 3.8, and 5.3 km from a Slovak Cu smelter and in smelter wastes (slag, sludge, ash) to trace sources and transport of Cu and Zn in soils. Stable isotope ratios were measured by multicollector inductively coupled plasma mass spectrometry (MC-ICP-MS) in total digests. Soils were heavily contaminated with concentrations up to 8087 μg g⁻¹ Cu and 2084 μg g⁻¹ Zn in the organic horizons. The δ⁶⁵Cu values varied little (−0.12‰ to 0.36‰) in soils and most wastes and therefore no source identification was possible. In soils, Cu became isotopically lighter with increasing depth down to 0.4 m, likely because of equilibrium reactions between dissolved and adsorbed Cu species during transport of smelter-derived Cu through the soil. The δ⁶⁶Zn_IRMM values were isotopically lighter in ash (−0.41‰) and organic horizons (−0.85‰ to −0.47‰) than in bedrock (−0.28‰) and slag (0.18‰) likely mainly because of kinetic fractionation during evaporation and thus allowed for separation of smelter-Zn from native Zn in soil. In particular in the organic horizons large variations in δ⁶⁶Zn values occur, probably caused by biogeochemical fractionation in the soil-plant system. In the mineral horizons, Zn isotopes showed only minor shifts to heavier δ⁶⁶Zn values with depth mainly because of the mixing of smelter-derived Zn and native Zn in the soils. In contrast to Cu, Zn isotope fractionation between dissolved and adsorbed species was probably only a minor driver in producing the observed variations in δ⁶⁶Zn values. Our results demonstrate that metal stable isotope ratios may serve as tracer of sources, vertical dislocation, and biogeochemical behavior in contaminated soil.  相似文献   

Architecture of Upper Cretaceous rhyodacitic hyaloclastite at the polymetallic Madneuli deposit,Lesser Caucasus,Georgia     

Nino Popkhadze  Robert Moritz  Vladimer Gugushvili 《Central European Journal of Geosciences》2014,6(3):308-329

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The effects of vigorous mixing in a convective model of zonal flow on the ice giants     

Jonathan Aurnou  Moritz Heimpel 《Icarus》2007,190(1):110-126

Previous studies have used models of three-dimensional (3D) Boussinesq convection in a rotating spherical shell to explain the zonal flows on the gas giants, Jupiter and Saturn. In this paper we demonstrate that this approach can also generate flow patterns similar to those observed on the ice giants, Uranus and Neptune. The equatorial jets of Uranus and Neptune are often assumed to result from baroclinic cloud layer processes and have been simulated with shallow layer models. Here we show that vigorous, 3D convection in a spherical shell can produce the retrograde (westward) equatorial flows that occur on the ice giants as well as the prograde (eastward) equatorial flows of the gas giants. In our models, the direction of the equatorial jet depends on the ratio of buoyancy to Coriolis forces in the system. In cases where Coriolis forces dominate buoyancy, cylindrical Reynolds stresses drive prograde equatorial jets. However, as buoyancy forces approach and exceed Coriolis forces, the cylindrical nature of the flow is lost and 3D mixing homogenizes the fluid's angular momentum; the equatorial jet reverses direction, while strong prograde jets form in the polar regions. Although the results suggest that conditions involving strong atmospheric mixing are responsible for generating the zonal flows on the ice giants, our present models require roughly 100 and 10 times the internal heat fluxes observed on Uranus and Neptune, respectively.  相似文献   

Timing of igneous accretion,composition, and temporal relation of the Kassandra–Sithonia rift-spreading center within the eastern Vardar suture zone,Northern Greece: insights into Jurassic arc/back-arc systems evolution at the Eurasian plate margin     

Nikolay Bonev  Peter Marchev  Robert Moritz  Petyo Filipov 《International Journal of Earth Sciences》2015,104(7):1837-1864

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Sediment cascades and the entangled relationship between human impact and natural dynamics at the pre-pottery Neolithic site of Göbekli Tepe,Anatolia     

Moritz Nykamp  Fabian Becker  Ricarda Braun  Nadja Pöllath  Daniel Knitter  Joris Peters  Brigitta Schütt 《地球表面变化过程与地形》2021,46(2):430-442

This study presents a meta-analysis of radiocarbon ages for the environs of Göbekli Tepe – one of the oldest monumental structures worldwide – using cumulative probability functions to diachronically assess phases of geomorphodynamic activity as controlled by natural or anthropogenic drivers. We employ sediment cascades as a heuristic framework to study the complex responses of the geomorphological system to various triggers at local to supra-regional scales. Possible triggers include climatic variability as documented by supra-regional hydroclimatic proxy data, regional demographic trends, and local to regional socioeconomic developments such as the emergence of sedentism or the introduction and dispersal of livestock herding. Our results show that phases of intensified geomorphodynamic activity occurred between ca. 7.4–7.0 and 5.8–3.3 ka BP. These phases roughly coincide with phases of population growth in southern Turkey and climatic variations in Turkey and the Levant. The phase between ca. 5.8–3.3 ka BP also corresponds to the time when organized agriculture and the seeder plough were introduced. Also, the identified phases are in agreement with the general trend of varying geomorphodynamic activity in the Eastern Mediterranean as driven by human impact and climatic change. However, neither the Younger Dryas–Holocene transition nor the development of herding during the Pre-Pottery Neolithic left a clear signature. We demonstrate how the different depositional environments in the studied landscape compartments vary with respect to their spatiotemporal coverage and discuss challenges when trying to understand processes that once shaped landscapes of past societies. © 2020 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd  相似文献   

Modelling of sediment supply from torrent catchments in the Western Alps using the sediment contributing area (SCA) approach     

Moritz Altmann  Florian Haas  Tobias Heckmann  Frédéric Liébault  Michael Becht 《地球表面变化过程与地形》2021,46(5):889-906

The production of coarse sediment in mountain landscapes depends mainly on the type and activity of geomorphic processes and topographic and natural conditions (e.g. vegetation cover) of these catchments. The supply of sediment from these slopes to mountain streams and its subsequent transport lead to sediment connectivity, which describes the integrated coupled state of these systems. Studies from the Northern Calcareous Alps show that the size of the sediment contributing area (SCA), a subset of the drainage area that effectively delivers sediment to the channel network, can be used as a predictor of sediment delivery to mountain streams. The SCA concept is delineated on a digital elevation model (DEM) using a set of rules related to the steepness and length of slopes directly adjacent to the channel network, the gradient of the latter and the vegetation cover. The present study investigates the applicability of this concept to the Western Alps to identify geomorphologically active areas and to estimate mean annual sediment yield (SY) in mainly debris-flow-prone catchments. We use a statistical approach that shows a parameter optimisation and a linear regression of SY on SCA extent. We use a dataset of ~25 years of assessed coarse sediment accumulation in 35 sediment retention basins. In the investigated catchments, sediment transport is governed by several factors, mainly by the extent of vegetation-free areas with a minimum slope of 23° that is coupled to the channel network with a very low gradient of the latter. With our improved framework, we can show that the SCA approach can be applied to catchments that are widely distributed, in a large spatial scale (hectare area) and very heterogeneous in their properties. In general, the investigated catchments show high connectivity, resulting in significant correlations between long-term average yield and the size of the SCA.  相似文献   

The influence of enclosing rock type on barite deposits, eastern Pyrenees, Spain: fluid inclusion and isotope (Sr, S, O, C) data     

A. Canals  E. Cardellach  R. Moritz  A. Soler 《Mineralium Deposita》1999,34(2):199-210

The Rocabruna and Coll de Pal barite deposits, located in the eastern Pyrenees of Spain, fill karstic cavities within carbonate rocks of Cambrian and Devonian age, respectively. The deposits contain barite, chalcopyrite, tetrahedrite, pyrite and minor sphalerite and galena with saddle dolomite and quartz as gangue. Fluid inclusion data from Coll de Pal quartz and dolomite indicate that the mineralizing fluid was a polysaline CaCl₂-rich brine, with temperatures between 125 and 150 °C. C and O isotopic compositions of carbonates in both deposits are consistent with a progressive increase in temperature during deposition. The ³⁴S values of barite, which range from 14.2 to 15.9‰ in Coll de Pal, and from 13.9 to 19.3‰ in Rocabruna, together with ⁸⁷Sr/⁸⁶Sr ratios ranging from 0.7118 to 0.7168 in Rocabruna, and from 0.7115 to 0.7136 in Coll de Pal, indicate two different fluid sources. We propose that these deposits formed as a result of mixing between a Ba-rich, sulfate-poor hot fluid, and sulfate-rich solutions of surficial origin. The different Sr isotope ratios in the deposits indicate that the hot Ba-rich fluids involved in each deposit were equilibrated with different rock types (carbonates and shales), in agreement with the geology of the two areas. Received: 22 October 1997 / Accepted: 24 March 1998  相似文献   

Redox gradients at the low oxygen boundary of lakes   总被引：1，自引：0，他引：1  

Mathias K. Kirf  Hans Røy  Moritz Holtappels  Jan P. Fischer  Carsten J. Schubert  Bernhard Wehrli 《Aquatic Sciences - Research Across Boundaries》2015,77(1):81-93

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Book Reviews: Pharmaceuticals in the Environment: Sources,Fate, Effects and Risks. Edited by Klaus Kümmerer     

Moritz Schübler 《洁净——土壤、空气、水》2009,37(7):514-514

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Benthic nutrient fluxes along the Laurentian Channel: Impacts on the N budget of the St. Lawrence marine system     

Benoît Thibodeau  Moritz F. Lehmann  Jacqueline Kowarzyk  Alfonso Mucci  Yves Gélinas  Denis Gilbert  Roxane Maranger  Mohammad Alkhatib 《Estuarine, Coastal and Shelf Science》2010

Water column concentrations and benthic fluxes of dissolved inorganic nitrogen (DIN) and oxygen (DO) were measured in the Gulf of St. Lawrence and the Upper and Lower St. Lawrence Estuary (USLE and LSLE, respectively) to assess the nitrogen (N) budget in the St. Lawrence (SL) system, as well as to elucidate the impact of bottom water hypoxia on fixed-N removal in the LSLE. A severe nitrate deficit, with respect to ambient phosphate concentrations (N*∼−10 μmol L⁻¹), was observed within and in the vicinity of the hypoxic bottom water of the LSLE. Given that DO concentrations in the water column have remained above 50 μmol L⁻¹, nitrate reduction in suboxic sediments, rather than in the water column, is most likely responsible for the removal of fixed N from the SL system. Net nitrate fluxes into the sediments, derived from pore water nitrate concentration gradients, ranged from 190 μmol m⁻² d⁻¹ in the hypoxic western LSLE to 100 μmol m⁻² d⁻¹ in the Gulf. The average total benthic nitrate reduction rate for the Laurentian Channel (LC) is on the order of 690 μmol m⁻² d⁻¹, with coupled nitrification-nitrate reduction accounting for more than 70%. Using average nitrate reduction rates derived from the observed water column nitrate deficit, the annual fixed-N elimination within the three main channels of the Gulf of St. Lawrence and LSLE was estimated at 411 × 10⁶ t N, yielding an almost balanced N budget for the SL marine system.  相似文献