Simple determination of dimethylsulfide (DMS) and dimethylsulfoniopropionate (DMSP) using solid-phase microextraction and gas chromatography-mass spectrometry     

Takushi?NikiEmail author  Taiki?Fujinaga  Mariyo?F.?Watanabe  Junji?Kinoshita 《Journal of Oceanography》2004,60(5):913-917

Solid-phase microextraction (SPME) is a simple, sensitive and less destructive method for the determination of dimethylsulfide (DMS) in seawater. Combined with detection by gas chromatography-mass spectrometry (GC-MS), the method had sufficient sensitivity (minimum detectable concentration of DMS was 0.05 nM), and practical levels of reproducibility (relative standard deviation ≤7%) and linearity (r ² > 0.995) over a wide concentration range (0.5 to 910 nM). The protocol developed was applied to a Sagami Bay water sample to determine concentrations of DMS and DMSP, and in situ DMSP-lyase activity.  相似文献   

Eddy Shedding from the Kuroshio Bend at Luzon Strait   总被引：16，自引：1，他引：16  

Yinglai?JiaEmail author  Qinyu?Liu 《Journal of Oceanography》2004,60(6):1063-1069

TOPEX/POSEDIENT-ERS satellite altimeter data along with the mean state from the Parallel Ocean Climate Model result have been used to investigate the variation of Kuroshio intrusion and eddy shedding at Luzon Strait during 1992–2001. The Kuroshio penetrates into the South China Sea and forms a bend. The Kuroshio bend varies with time, periodically shedding anticyclonic eddies. Criteria of eddy shedding are identified: 1) When the shedding event occurs, there are usually two centers of high Sea Surface Height (SSH) together with negative geostrophic vorticity in the Kuroshio Bend (KB) area. 2) Between the two centers of high SSH there usually exists positive geostrophic vorticity. These criteria have been used to determine the eddy shedding times and locations. The most frequent eddy shedding intervals are 70, 80 and 90 days. In both the winter and summer monsoon period, the most frequent locations are 119.5°E and 120°E, which means that the seasonal variation of eddy shedding location is unclear.  相似文献   

Geodynamics of the deep sedimentary basin of the Caspian Sea region: paragenetic correlation of seismicity and mud volcanism     

Ibrahim?Guliev  Behrouz?PanahiEmail author 《Geo-Marine Letters》2004,24(3):169-176

In this paper we analyze seismic regime and earthquake depth distribution and correlation of seismicity and mud volcanism in the Azerbaijan and the Caspian Sea region. For the present region we have calculated accurate source locations, seismic activity, earthquake repetition and released earthquake energy parameters. It is shown that the active tectonic processes in the region are concentrated within the thick sedimentary cover that we consider as a general source of contemporary stress and a main structural element responsible for the origin of regional earthquakes. The correlation of seismicity and mud volcanism is of paragenetic character.  相似文献   

海南岛博鳌港沉积物的沿岸输送   总被引：19，自引：0，他引：19  

高建华  高抒  陈鹏  葛晨东  朱大奎 《海洋地质与第四纪地质》2002,22(2):41-48

分析了博港沿岸沉积牧粒度参数的沿岸变化，并应用沉积物粒径趋势分析模型（GSTA模型）对沉积物运动趋势进行了分析。GSTA模型结果表明，博鳌港沿岸的泥沙在横向上表现为：万泉河口以北岸段为由海向岸运动，近期处于淤积状态；万泉河口以南岸段即玉带滩大致以NNE走向到NE走向的转折点为界，北部主要是由岸向海运动，是侵蚀岸段，而南部则主要为由海向岸运动，有少量的淤积，博鳌港沿岸泥沙输送在纵向上表现为：万泉河口以北由南向北运动，万泉河口以南，北部是由北向南运动，南部是由南向北运动，其次还运用了经验公式对GSTA结果进行了验证，得到了通过万泉河口南部（玉带滩）3个断面的沿岸漂沙量，其沿岸漂沙方向主要为南北向，以上两种分析方法得出的结果和当地的许多地貌证据基本符合，而GSTA模型在玉带滩北部泥沙纵向输运方向与经验公式计算结果所表现出的一些差异，主要是由于研究时间尺度和所用的资料特征的差异性造成的。  相似文献   

水中矿物油荧光特性实验研究     

夏达英  张士魁  李宝华  王振先  孙培光  史锦珊  尚丽平 《海洋科学进展》2002,20(2):91-98

为了实现现场测量地表水中矿物油含量的全光纤荧光计的研制。采用荧光光谱测量分析方法 ,于 1 999年 1 0月— 2 0 0 0年 5月 ,采集了国内外不同的地区原油和成品油共 2 3种 ,用1 4种不同波长的激发光激励 ,进行荧光光谱特性测量实验研究。同时 ,对不同浓度的矿物油、水混合液也进行了测量实验 ,得出其最低检测浓度为 0 .0 0 5mg/L ;测量了青岛近岸海域表层受油污染海水的含油量为 0 .0 1～ 0 .2 2mg/L ;此外对水中矿物油受激荧光发射原理也作了简述。并对水中矿物油荧光光谱特性、浓度与荧光强度的关系 ,以及为研制现场测量水中矿物油浓度的全光纤荧光计的可能性作出了结论性的意见  相似文献   

影响单位进尺成本的因素及其影响规律研究   总被引：1，自引：0，他引：1  

张伟  王达 《地质科技情报》2008,27(3):93-97

介绍了一种用于分析不同因素对单位进尺成本影响的新方法--偏因素分析方法,该方法可用于在影响因素众多的情况下确定各因素对施工经济性的影响作用;同时介绍了成本影响系数这一新概念,成本影响系数表示了某一因素在一定的条件下对单位进尺成本影响程度的大小.在钻进技术经济研究中采用成本影响系数,可使对影响单位进尺成本因素的对比评价更加方便易行.以一个5 000 m取心钻进项目为例,计算了不同影响因素变化时的单位进尺成本和成本影响系数,最终根据成本影响系数绝对值的大小,对影响单位进尺成本的不同因素进行了评价.  相似文献   

Extension of the solution of Kepler's equation to high eccentricities     

Sandro Da Silva Fernandes 《Celestial Mechanics and Dynamical Astronomy》1994,58(3):297-308

The classic Lagrange's expansion of the solutionE(e, M) of Kepler's equation in powers of eccentricity is extended to highly eccentric orbits, 0.6627 ... <e<1. The solutionE(e, M) is developed in powers of (e–e*), wheree* is a fixed value of the eccentricity. The coefficients of the expansion are given in terms of the derivatives of the Bessel functionsJ _n (ne). The expansion is convergent for values of the eccentricity such that |e–e*|<(e*), where the radius of convergence (e*) is a positive real number, which is calculated numerically.  相似文献   

Fourier analysis of the light curves of eclipsing variables. XIII     

Osman Demircan 《Astrophysics and Space Science》1977,52(1):189-199

New expressions for the fractional loss of light _l ⁰ have been derived in the simple forms of rapidly converging expansions to the series of Chebyshev polynomials, Jacobi polynomials, and Kopal'sJ-integrals. In these expansions, which are a supplement to those given by Kopal (1977b), variablesk andh occur in different products that simplify the numerical computation. The treatment follows the new definition of _l ⁰ which has been recently developed by Kopal (1977a).  相似文献   

Oil-generation kinetics for organic facies with Type-II and -IIS kerogen in the Menilite Shales of the Polish Carpathians     

M.D. Lewan  M.J. Kotarba  D. Wi?c?aw 《Geochimica et cosmochimica acta》2006,70(13):3351-3368

The Menilite Shales (Oligocene) of the Polish Carpathians are the source of low-sulfur oils in the thrust belt and some high-sulfur oils in the Carpathian Foredeep. These oil occurrences indicate that the high-sulfur oils in the Foredeep were generated and expelled before major thrusting and the low-sulfur oils in the thrust belt were generated and expelled during or after major thrusting. Two distinct organic facies have been observed in the Menilite Shales. One organic facies has a high clastic sediment input and contains Type-II kerogen. The other organic facies has a lower clastic sediment input and contains Type-IIS kerogen. Representative samples of both organic facies were used to determine kinetic parameters for immiscible oil generation by isothermal hydrous pyrolysis and S₂ generation by non-isothermal open-system pyrolysis. The derived kinetic parameters showed that timing of S₂ generation was not as different between the Type-IIS and -II kerogen based on open-system pyrolysis as compared with immiscible oil generation based on hydrous pyrolysis. Applying these kinetic parameters to a burial history in the Skole unit showed that some expelled oil would have been generated from the organic facies with Type-IIS kerogen before major thrusting with the hydrous-pyrolysis kinetic parameters but not with the open-system pyrolysis kinetic parameters. The inability of open-system pyrolysis to determine earlier petroleum generation from Type-IIS kerogen is attributed to the large polar-rich bitumen component in S₂ generation, rapid loss of sulfur free-radical initiators in the open system, and diminished radical selectivity and rate constant differences at higher temperatures. Hydrous-pyrolysis kinetic parameters are determined in the presence of water at lower temperatures in a closed system, which allows differentiation of bitumen and oil generation, interaction of free-radical initiators, greater radical selectivity, and more distinguishable rate constants as would occur during natural maturation. Kinetic parameters derived from hydrous pyrolysis show good correlations with one another (compensation effect) and kerogen organic-sulfur contents. These correlations allow for indirect determination of hydrous-pyrolysis kinetic parameters on the basis of the organic-sulfur mole fraction of an immature Type-II or -IIS kerogen.  相似文献   

T -distributed Random Fields: A Parametric Model for Heavy-tailedWell-log Data1     

Jo R?islien  Henning Omre 《Mathematical Geology》2006,38(7):821-849

Histograms of observations from spatial phenomena are often found to be more heavy-tailed than Gaussian distributions, which makes the Gaussian random field model unsuited. A T-distributed random field model with heavy-tailed marginal probability density functions is defined. The model is a generalization of the familiar Student-T distribution, and it may be given a Bayesian interpretation. The increased variability appears cross-realizations, contrary to in-realizations, since all realizations are Gaussian-like with varying variance between realizations. The T-distributed random field model is analytically tractable and the conditional model is developed, which provides algorithms for conditional simulation and prediction, so-called T-kriging. The model compares favourably with most previously defined random field models. The Gaussian random field model appears as a special, limiting case of the T-distributed random field model. The model is particularly useful whenever multiple, sparsely sampled realizations of the random field are available, and is clearly favourable to the Gaussian model in this case. The properties of the T-distributed random field model is demonstrated on well log observations from the Gullfaks field in the North Sea. The predictions correspond to traditional kriging predictions, while the associated prediction variances are more representative, as they are layer specific and include uncertainty caused by using variance estimates.  相似文献