Magnetic spherules in coastal plain sediments,Sullivan's Island,South Carolina,USA     

Pamela L. Taylor  Robert L. Nusbaum  A. Kem Fronabarger  Michael P. Katuna  Neil Summer 《Meteoritics & planetary science》1996,31(1):77-80

Abstract— We extracted black, magnetic spherules from well cuttings of Oligocene sediments in the coastal plain of South Carolina, USA. Three possible origins were considered: industrial, volcanic, and extraterrestrial. An extraterrestrial origin by ablation of parent meteoroid material is proposed, based on the spherule morphologies, the presence of metallic Fe cores in many of the spherules, and the detection of wüstite in some of the oxide rims. Low Ni contents are problematic but may be attributed to the ablation of a low-Ni parental body, such as hexahedrite. The presence of spherules in somewhat clay-like, sandy sediments is unusual, as most magnetic spherules are found in abyssal muds. Based on benthic foraminiferal assemblages and sediment distribution above, within, and below the beds containing spherules, it is unlikely that the spherules were transported from a deep-sea environment.  相似文献   

The lunar farside: The nature of highlands east of Mare Smythii     

Pamela E. Clark  B. Ray Hawke 《Earth, Moon, and Planets》1991,53(2):93-107

Available lunar orbital data were studied in detail to determine the nature and origin of geochemical variation in a portion of the farside highlands east of the Smythii basin. Such data exist for the elements Al, Mg, Fe, Ti, and Th (Clark and Hawke, 1981; Davis, 1980; Metzger et al., 1977). As in our previous studies (Clarke and Hawke, 1981, 1987), averages and ranges of concentrations for these elements are calculated and correlated for photogeologically defined units associated with features such as Babcock, King, Al-Khwarezmi, Langemak, Pasteur, and Sklodowska and with the region as a whole. In addition, comparisons are made between this and other highland regions which have been investigated by other workers in a similar manner (Andre et al., 1977; Haines et al., 1978; Maxwell and Andre, 1981). The region is shown to be distinctively enriched in the anorthositic end-members of the ANT-suite. Anomalies which have been reported for this region (Hawke et al., 1985) are confirmed by this study. An area south of Pasteur shows enrichment in some mafic components, giving evidence for the presence of buried mare basalt, and lending support to the hypothesis that volcanic activity may be fairly widespread even in the farside highlands. The units just southeast of Mare Smythii appear to be geochemically related to the area partly surrounding the Smythii on the west (Clark and Hawke, 1987). Considerable geochemical heterogeneity exists in this area, as in areas of the nearside highlands (Clark and Hawke, 1981, 1982, 1987; Hawke et al., 1985).  相似文献   

Modeling the effects of bond environment on equilibrium iron isotope fractionation in ferric aquo-chloro complexes     

Pamela S. Hill  Edwin A. Schauble 《Geochimica et cosmochimica acta》2008,72(8):1939-1958

Four or five sets of ab initio models, including Unrestricted Hartree Fock (UHF) and hybrid Density Functional Theory (DFT) are calculated for each species in a series of aqueous ferric aquo-chloro complexes: , , , FeCl₃(H₂O)₃, FeCl₃(H₂O)₂, , FeCl₅H₂O²⁻, , ) in order to determine the relative isotopic fractionation among the complexes, to compare the results of different models for the same complexes, to examine factors that influence the magnitude of the isotopic fractionation, and to compare bond-partner-driven fractionation with redox-driven fractionation.Relative to , all models show a nearly linear decrease in ⁵⁶Fe/⁵⁴Fe as the number of Cl⁻ ions per Fe³⁺ ion increases, with slopes of −0.8‰ to −1.0‰ per Cl⁻ at 20 °C. At 20 °C, 1000 ln β (β = ⁵⁶Fe/⁵⁴Fe reduced partition function ratio relative to a dissociated Fe atom) values range from 8.93‰ to 9.73‰ for , 8.04-9.12‰ for , 7.61-8.73‰ for , 7.14-8.25‰ for , and 3.09-4.41‰ for . The fractionation between and ranges from 1.5‰ to 2.6‰, depending on the model; this is comparable in magnitude to fractionation effects due to Fe³⁺/Fe²⁺ redox reactions. β values from the UHF models are consistently higher than those from the hybrid DFT models.Isotopic fractionation is shown to be sensitive to differences in ligand bond stiffness (above), coordination number, bond length, and the frequency of the asymmetric Fe-X stretching vibrational mode, as predicted by previous theoretical studies. Complexes with smaller coordination numbers have higher 1000 ln β (7.46‰, 5.25‰, and 3.48‰ for , ,, respectively, from the B3LYP/6-31G(d) model). Species with the same number of chlorides but fewer waters also show the effect of coordination number on 1000 ln β: (7.46‰ vs. 7.05‰ for FeCl₃(H₂O)₂ vs. FeCl₃(H₂O)₃ and 5.25‰ vs. 4.94‰ for vs. FeCl₅H₂O²⁻ with the B3LYP/6-31G(d) model). As more Fe-Cl bonds substitute for Fe-OH₂ bonds (with a resulting decrease in β), the lengths of the Fe-Cl bonds and the Fe-O bonds increase.Preliminary modeling of shows an Fe³⁺/Fe²⁺ fractionation of 3.2‰ for the B3LYP/6-31G(d) model, in agreement with previous studies. The addition of an explicit outer hydration sphere of 12 H₂O molecules to models of improves agreement with measured vibrational frequencies and bond lengths; 1000 ln β increases by 0.8-1.0‰. An additional hydration sphere around increases 1000 ln β by only 0.1‰.Isotopic fractionations predicted for this simple system imply that ligands present in an aqueous iron environment are potentially important drivers of fractionation, and suggest that significant fractionation effects are likely in other aqueous systems containing sulfides or organic ligands. Fractionation effects due to both speciation and redox must be considered when interpreting iron isotope fractionations in the geological record.  相似文献   

Rates of zinc and trace metal release from dissolving sphalerite at pH 2.0–4.0     

Mark R. Stanton  Pamela A. Gemery-HillWayne C. Shanks III  Cliff D. Taylor 《Applied Geochemistry》2008

High-Fe and low-Fe sphalerite samples were reacted under controlled pH conditions to determine nonoxidative rates of release of Zn and trace metals from the solid-phase. The release (solubilization) of trace metals from dissolving sphalerite to the aqueous phase can be characterized by a kinetic distribution coefficient, (D_tr), which is defined as [(R_tr/X(tr)_Sph)/(R_Zn/X(Zn)_Sph)], where R is the trace metal or Zn release rate, and X is the mole fraction of the trace metal or Zn in sphalerite. This coefficient describes the relationship of the sphalerite dissolution rate to the trace metal mole fraction in the solid and its aqueous concentration. The distribution was used to determine some controls on metal release during the dissolution of sphalerite. Departures from the ideal D_tr of 1.0 suggest that some trace metals may be released via different pathways or that other processes (e.g., adsorption, solubility of trace minerals such as galena) affect the observed concentration of metals.  相似文献   

The Cost(s) of Geospatial Open Data          下载免费PDF全文

Peter A. Johnson  Renee Sieber  Teresa Scassa  Monica Stephens  Pamela Robinson 《Transactions in GIS》2017,21(3):434-445

The provision of open data by governments at all levels has rapidly increased over recent years. Given that one of the dominant motivations for the provision of open data is to generate ‘value’, both economic and civic, there are valid concerns over the costs incurred in this pursuit. Typically, costs of open data are framed as internal to the data providing government. Building on the strong history of GIScience research on data provision via spatial data infrastructures, this article considers both the direct and indirect costs of open data provision, framing four main areas of indirect costs: citizen participation challenges, uneven provision across geography and user types, subsidy of private sector activities, and the creation of inroads for corporate influence on government. These areas of indirect cost lead to the development of critical questions, including constituency, purpose, enablement, protection, and priorities. These questions are posed as a guide to governments that provide open data in addressing the indirect costs of open data.  相似文献   

A commentary on: Effects of tropical deforestation on global and regional atmospheric chemistry     

Peter M. Vitousek  Pamela A. Matson 《Climatic change》1991,19(1-2):159-162

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Restoration of an impounded salt marsh in New England     

Theresa L. Sinicrope  Pamela G. Hine  R. Scott Warren  William A. Niering 《Estuaries and Coasts》1990,13(1):25-30

The restoration of a 20 ha tidal marsh, impounded for 32, yr, in Stonington, Connecticut was studied to document vegetation change 10 yr after the reintroduction of tidal flushing. These data were then compared to a 1976 survey of the same marsh when it was in its freshest state and dominanted byTypha angustifolia. Currently,T. angustifolia remains vigorous only along the upland borders and in the upper reaches of the valley marsh. Live coverage ofT. angustifolia has declined from 74% to 16% and surviving stands are mostly stunted and depauperate. Other brackish species have also been adversely effected, except forPhragmites australis which has increased. In contrast, the salt marsh speciesSpartina alterniflora has dramatically expanded, from <1% to 45% cover over the last decade. Locally, high marsh species have also become established, covering another 20% of the marsh.  相似文献   

Microsomal cytochrome P-450 function in fish evaluated with polyclonal and monoclonal antibodies to cytochrome P-450E from scup (Stenotomus chrysops)     

John J. Stegeman  Bruce R. Woodin  Sang S. Park  Pamela J. Kloepper-Sams  Harry V. Gelboin 《Marine environmental research》1985,17(2-4)

Monooxygenase reactions catalyzed by cytochromes P-450 are paramount in the oxidative metabolism of many xenobiotics, determining both the persistence and effects of numerous types of compounds. Immunological probes are proving useful in evaluating the functions of P-450 isozymes in microsomal preparations from many species. The regulation of specific isozymes by endogenous and exogenous factors can also be evaluated with such probes. Here we describe studies on the activities apparently catalyzed by induced P-450 in fish, evaluated with both polyclonal and monoclonal antibodies to cytochrome P-450E, the apparent major β-naphthoflavone(BNF) or methylcholanthrene(MC)-inducible isozyme purified from scup (S. chrysops) liver.  相似文献   

Toward a new conceptual model for groundwater flow in merokarst systems: Insights from multiple geophysical approaches     

Pamela L. Sullivan  Chi Zhang  Michael Behm  Fan Zhang  G. L. Macpherson 《水文研究》2020,34(24):4697-4711

Merokarst aquifers — relatively thin (<1–2 m) karstified carbonate units interbedded between mudstone, shale, or sandstone — constitute a significant proportion of carbonate terrain and underlie a large portion of the west- and south-central USA, yet few advances have been made in our understanding of porosity development and flow-path generation in these complex systems in decades. Toward this end, we used a multi-geophysical approach at the well-studied Konza Prairie Biological Station (KPBS), a part of the larger Flint Hills (25,734 km²), underlain by thin limestone units (1–2 m thick) interbedded with mudstone/shale units (2–4 m thick), to elucidate hydrologic connectivity and potential controls on known groundwater flow directions. We combined electrical resistivity tomography (ERT), surface and borehole nuclear magnetic resonance (NMR), and ground penetrating radar (GPR) measurements across a low order catchment where over 25 boreholes and groundwater wells sampling perched aquifers could be used to constrain interpretation of lithology, potential flow paths, and permeability. Data revealed that groundwater export may be an unappreciated component of lateral-flow-dominated models used to represent merokarst in that: (a) potentiometric surfaces from two limestone units showed groundwater flows toward a hydrologic depression, opposite the direction of stream flow, in the upstream portion of the catchment, (b) long term measures of groundwater levels revealed a greater variance and overall water storage in this same upstream area compared to wells near the outlet, and (c) ERT and NMR results indicate pronounced lateral heterogeneity within a given unit, suggestive of a greater degree of vertical hydrological connectivity than usually considered for horizontally-layered merokarst. Our data suggest vertical connectivity can shunt water to depth in these “sandwiched” merokarst aquifers, yielding atypical groundwater flow directions and unrealized deep export of weathering solutes and carbon.  相似文献   

Ecohydrological responses to surface flow across borders: Two decades of changes in vegetation greenness and water use in the riparian corridor of the Colorado River delta     

Pamela L. Nagler  Armando Barreto-Muñoz  Sattar Chavoshi Borujeni  Christopher J. Jarchow  Martha M. Gómez-Sapiens  Hamideh Nouri  Stefanie M. Herrmann  Kamel Didan 《水文研究》2020,34(25):4851-4883

Hydrological and bioclimatic processes that lead to drought may stress plants and wildlife, restructure plant community type and architecture, increase monotypic stands and bare soils, facilitate the invasion of non-native plant species and accelerate soil erosion. Our study focuses on the impact of a paucity of Colorado River surface flows from the United States (U.S.) to Mexico. We measured change in riparian plant greenness and water use over the past two decades using remotely sensed measurements of vegetation index (VI), evapotranspiration (ET) and a new annualized phenology assessment metric (PAM) for ET. We measure these long-term (2000–2019) metrics and their short-term (2014–2019) response to an environmental pulse flow in 2014, as prescribed under Minute 319 of the 1944 Water Treaty between the two nations. In subsequent years, small-directed flows were provided to restoration areas under Minute 323. We use 250 m MODIS and 30 m Landsat imagery to evaluate three vegetation indices (NDVI, EVI, EVI2). We select EVI2 to parameterize an optical-based ET algorithm and test the relationship between ET from Landsat and MODIS by regression approaches. Our analyses show significant decreases in VIs and ET for both the 20-year and post-pulse 5-year periods. Over the last 20 years, EVI _Landsat declined 34% (30% by EVI_MODIS) and ET_Landsat-EVI declined 38% (27% by ET_MODIS-EVI), overall ca. 1.61 mm/day or 476 mm/year drop in ET; using PAM ET_Landsat-EVI the drop was from 1130 to 654 mm/year. Over the 5 years since the 2014 pulse flow, EVI_Landsat declined 20% (13% by EVI_MODIS) and ET_Landsat-EVI declined 23% (4% by ET_MODIS-EVI) with a 0.77 mm/day or a 209 mm/year 5-year drop in ET; using PAM ET_Landsat-EVI the drop was from 863 to 654 mm/year. Data and change maps show the pulse flow contributed enough water to slow the rate of loss, but only for the very short-term (1–2 years). These findings are critically important as they suggest further deterioration of biodiversity, wildlife habitat and key ecosystem services due to anthropogenic diversions of water in the U.S. and Mexico and from land clearing, fires and plant-related drought which affect hydrological processes.  相似文献