Analysis of chlorophyll diagenesis—II. Solvent effects on metal incorporation into chlorophyll diagenetic products     

Pamela P. Zelmer  Eugene H. Man 《Organic Geochemistry》1984,7(3-4)

We are attempting to quantify selected transitions in the diagenetic pathway of chlorophyll in deep ocean sediments. To analyze the aromatization from phorbides (less stable) to porphyrins (more stable), we used a model system which closely resembles the compounds identified in oceanic sediments. Kinetic parameters were determined for the incorporation of copper into deoxomesopyropheophorbide a methyl ester (DOMPP) and deoxophylloerythrin methyl ester (DPE) in a series of solvents ranging from highly polar and protic to non-polar and aprotic, representing varying sedimentary environments. In the reaction of copper with these two compounds, the activation parameters for the reaction with DOMPP indicate that DOMPP is more sensitive to the environment than DPE. Also, over the temperature range studied, DOMPP always reacted faster than DPE under similar conditions. These two observations lend support to our previous hypothesis that the phorbide to porphyrin transition includes the metallophorbide as a short-lived intermediate in the reaction sequence.  相似文献   

Analysis of chlorophyll diagenesis—I. Kinetics of the phorbide to porphyrin transition     

Pamela P. Zelmer  Eugene H. Man 《Organic Geochemistry》1983,5(1):43-49

The objective of this project is to quantify selected transitions in the diagenetic pathways of chlorophyll in deep ocean sediments, initially the aromatization from phorbides (unstable) to porphyrins (stable), using a model system which closely resembles the compounds identified in oceanic sediments. We determined the kinetic parameters for the aromatization of deoxomesopyropheophorbide a methyl ester (DOMPP) to deoxophylloerythrin methyl ester (DPE) in the presence of Cu(II) in a series of solvents ranging from highly polar and protic to nonpolar and aprotic, representing varying sedimentary environments. With Cu(II) in ethanol, the aromatization occurs through a pathway which involves a relatively slow initial formation of CuDOMPP, rapid aromatization to CuDPE, and finally an equilibrium reaction in the presence of clay which induces demetalation to form the free base DPE. Based on our model studies, only DOMPP, CuDPE and some DPE would be detected in significant quantities in more polar, protic sedimentary environments on a geologic time scale, although the story might be different with changed environment polarity. Our model studies may ultimately reconcile laboratory observations with those based on DSDP cores which appear to indicate that the diagenetic sequence proceeds from phorbide to free base porphyrin, followed by metalation of the porphyrin.  相似文献   

Current Status and Future Challenges of Weather Radar Polarimetry: Bridging the Gap between Radar Meteorology/Hydrology/Engineering and Numerical Weather Prediction     

Guifu ZHANG  Vivek N.MAHALE  Bryan J.PUTNAM  Youcun QI  Qing CAO  ANDrew D.BYRD  Petar BUKOVCIC  Dusan S.ZRNIC  Jidong GAO  Ming XUE  Youngsun JUNG  Heather D.REEVES  Pamela L.HEINSELMAN  AlexANDer RYZHKOV  Robert D.PALMER  Pengfei ZHANG  Mark WEBER  Greg M.MCFARQUHAR  Berrien MOORE III  Yan ZHANG  Jian ZHANG  J.VIVEKANANDAN  Yasser AL-RASHID  Richard L.ICE  Daniel S.BERKOWITZ  Chong-chi TONG  Caleb FULTON  Richard J.DOVIAK 《大气科学进展》2019,36(6):571-588

After decades of research and development, the WSR-88 D(NEXRAD) network in the United States was upgraded with dual-polarization capability, providing polarimetric radar data(PRD) that have the potential to improve weather observations,quantification, forecasting, and warnings. The weather radar networks in China and other countries are also being upgraded with dual-polarization capability. Now, with radar polarimetry technology having matured, and PRD available both nationally and globally, it is important to understand the current status and future challenges and opportunities. The potential impact of PRD has been limited by their oftentimes subjective and empirical use. More importantly, the community has not begun to regularly derive from PRD the state parameters, such as water mixing ratios and number concentrations, used in numerical weather prediction(NWP) models.In this review, we summarize the current status of weather radar polarimetry, discuss the issues and limitations of PRD usage, and explore potential approaches to more efficiently use PRD for quantitative precipitation estimation and forecasting based on statistical retrieval with physical constraints where prior information is used and observation error is included. This approach aligns the observation-based retrievals favored by the radar meteorology community with the model-based analysis of the NWP community. We also examine the challenges and opportunities of polarimetric phased array radar research and development for future weather observation.  相似文献   

Requirement of endogenous iron for cytotoxicity caused by hydrogen peroxide in Euglena gracilis     

Kimette Radtke  Robert W. Byrnes  Pamela Kerrigan  William E. Antholine  David H. Petering 《Marine environmental research》1992,34(1-4)

It is widely thought that redox-active metals in cells such as iron or copper catalyze the reduction of hydrogen peroxide to toxic hydroxyl radicals or their equivalent. However, this has not been directly demonstrated in vivo. To probe this requirement, the freshwater microorganism Euglena gracilis was used. Its intracellular iron content can be modulated by the concentration of iron in the defined growth medium without effect on the proliferation rate of the cells. E. gracilis contains two large storage pools of cytosolic iron which can be monitored to assess cellular iron status. The toxicity of H₂O₂ in E. gracilis was inversely related to the amount of iron in the extracellular medium. At high levels of external iron, the metal carried out the Fenton reaction with H₂O₂ outside the cell, producing hydroxyl radicals as detected by electron-spin resonance spin-trapping experiments. This reaction reduced the amount of H₂O₂ that could diffuse into cells to cause toxicity. When cells with different intracellular iron content were placed in iron-deficient media, the the toxicity of H₂O₂, measured by inhibition of proliferation, was directly related to the concentration of internal iron. Using cells deficient in iron, this oxidant did not inhibit proliferation at low concentration but was somewhat effective at higher concentrations. Although the iron chelating agents, 1,10-phenanthroline and desferrioxamine, also depressed cytosolic iron, they were cytotoxic to E. gracilis and so could not be used unambiguously to examine the role of intracellular iron in the toxic effects of hydrogen peroxide.  相似文献   

Changes in landuse/landcover patterns and human population growth in the Lake Chivero catchment,Zimbabwe     

Pamela Tendaupenyu  Christopher Hilary Dennis Magadza  Amon Murwira 《国际地球制图》2017,32(7):797-811

The land use and land cover pattern of a region is a consequence of natural and socio-economic factors and their utilization by man in time and space. In this study, we hypothesized that land use and land cover change patterns in the Lake Chivero catchment, Zimbabwe, were related to its human population dynamics. Using nonparametric correlation coefficients (Spearman’s rho, ρ), we found that bareland, cropland and built-up land had positive relations with human population growth of ρ = 0.7, ρ = 0.9 and ρ = 1, respectively. Grassland/shrubland, water and forest, on the other hand, had a negative relationship with human population growth of ρ = ?0.9, ρ = ?0.7 and ρ = ?0.667, respectively. However, these relationships were only significant (p < 0.05) for cropland, grassland/shrubland and built-up land. Human population dynamics in the Lake Chivero catchment could be one of the major drivers of land use and land cover change in the catchment between 1986 and 2014.  相似文献   

Crustal assimilation during turbulent magma ascent (ATA); new isotopic evidence from the Mull Tertiary lava succession,N. W. Scotland     

Andrew C. Kerr  Pamela D. Kempton  Robert N. Thompson 《Contributions to Mineralogy and Petrology》1995,119(2-3):142-154

Assimilation of crustal rocks with concomitant fractional crystallisation (AFC) is a well documented phenomenon in many igneous suites, but geochemical evidence from the Tertiary Mull lava succession suggests that in these magmas crustal contamination occurred by a distinctly different mechanism. Lavas from the lower half of the Mull Plateau group (MPG) can be divided into two broad sub-types; high (>8%) MgO basalts with elevated Ba and K; and lower MgO (<8%) basaltic-hawaiites with lower Ba and K. The lower crust and most of the upper crust beneath Mull is probably of Lewisian age. The Sr-, Nd-and Pb-isotope compositions of local Lewisian crustal samples yield the following ranges: ⁸⁷Sr/⁸⁶Sr=0.71002–0.72348, ¹⁴³Nd/¹⁴⁴Nd=0.51045–0.51058 and ²⁰⁶Pb/²⁰⁴Pb=14.0–14.6. Ten lavas have also been analysed and yield the following ranges: ⁸⁷Sr/⁸⁶Sr=0.7028–0.7042, ¹⁴³Nd/¹⁴⁴Nd=0.51214–0.51230 and ²⁰⁶Pb/²⁰⁴Pb=15.1–17.9. However, within this range, it is predominantly the more primitive mafic compositions, with elevated Mg, Ba and K, that show the lowest Nd- and Pb-, and the highest Sr-isotope values. Modelling of these isotopic results, in conjunction with major and trace element data, show that: (1) contamination by Lewisian lower crustal material does occur; (2) that the process involved was not one of assimilation with concomitant fractional crystallisation (AFC). The proposed contamination process is one whereby the hottest (most MgO rich) magmas have assimilated acidic partial melts of Lewisian lower crust during turbulent ascent (ATA) through thin, poorly connected dyke- and sill-like magma chambers. The chemical composition of the contaminated lavas can be modelled successfully through addition of 5% acidic Lewisian crust to an uncontaminated lava. In contrast, the more evolved magmas — which probably fractionated at sub-crustal levels — were either not hot enough to molt significant amounts of crust, or did not ascend turbulently because of their higher viscosity, and so are less contaminated with crust.  相似文献   

Trust and risk perception of natural hazards: implications for risk preparedness in Chile     

Nicolás C. Bronfman  Pamela C. Cisternas  Esperanza López-Vázquez  Luis A. Cifuentes 《Natural Hazards》2016,81(1):307-327

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Evaluation of the effects of alteration and leaching on Sm–Nd and Lu–Hf systematics in submarine mafic rocks     

Patricia M.E. Thompson  Pamela D. Kempton  Andrew C. Kerr   《Lithos》2008,104(1-4):164-176

Nd and Hf isotope systematics of oceanic basaltic rocks are often assumed to be largely immune to the effects of hydrothermal alteration. We have tested this assumption by comparing Nd and Hf isotope data for acid-leached Cretaceous oceanic basalts from Gorgona and DSDP Leg 15 with unleached data on the same rocks. Hf isotope values and Lu/Hf ratios are relatively unaffected by leaching, but ¹⁴³Nd/¹⁴⁴Nd values of leached samples are significantly higher than those of unleached fractions of the same sample in most cases. Furthermore, the Sm/Nd ratios of the majority of leached samples are 10–40% greater than those of unleached samples. X-ray diffraction studies indicate that selective removal of secondary minerals, such as smectite, during the acid leaching process is responsible for the fractionation of Sm/Nd ratios. These results have implications for interpretation of the Hf–Nd isotope systematics of ancient submarine rocks (older than ~ 50 Ma), as (1) the age-corrected ¹⁴³Nd/¹⁴⁴Nd ratio may not be representative of the primary magmatic signature and (2) the uncertainty of the age-corrected ε_Nd value may exceed the assumed analytical precision.  相似文献   

Magnetotelluric image of the crust and upper mantle in the backarc of the northwestern Argentinean Andes   总被引：2，自引：0，他引：2  

Pamela Lezaeta  Miguel Muñoz  Heinrich Brasse 《Geophysical Journal International》2000,142(3):841-854

Magnetotelluric data from the backarc of the Central Andes in NW Argentinawere re-examined by employing impedance tensor decomposition and 2-D inversion and modelling techniques. The data in the period range of 50–15 000 s were collected on a profile of 220 km length reaching from the Eastern Cordillera across the Santa Barbara System to the Andean foreland of the Argentinean Chaco.
After a dimensionality analysis, data from most sites were treated as regional 2-D. The exception was the eastern section of the profile, where the magnetotelluric transfer functions for periods ≤ 1000 s reflect a 3-D earth. Application of two tensor decomposition schemes yielded a regional strike direction of N–S, which is the azimuth of the Central Andean mountain chains. Several 2-D models were obtained by pseudo- and full 2-D Occam inversion schemes. Special emphasis was placed on the inversion of phase data to reduce the influence of static shifts in the apparent resistivity data. The smooth inversion models all show a good conductor at depth. A final model was then calculated using a finite element forward algorithm.
The most prominent feature of the resulting model is a conductor which rises from depths of 180 km below the Chaco region to 80 km beneath the Santa Barbara System and the Eastern Cordillera. Its interpretation as a rise of the electrical asthenosphere is supported by seismic attenuation studies. Magnetotelluric results, surface heat-flow distribution in the area, and the electrical properties of crustal and mantle rocks suggest that the upper mantle is predominantly ductile beneath the Eastern Cordillera and the western Santa Barbara System. This generally agrees with anelastic seismic attenuation models of the area and is useful in discriminating between models of Q quality factor distribution.  相似文献   

The role of endolithic cyanobacteria in the formation of lithified laminae in Bahamian stromatolites   总被引：5，自引：0，他引：5  

Ian G. Macintyre  Leslie Prufert-Bebout  & R. Pamela Reid 《Sedimentology》2000,47(5):915-921

The microboring activity of endolithic cyanobacteria plays a major role in the formation of the dominant lithified laminae in modern marine stromatolites in the Exuma Cays, Bahamas. These stromatolites are composed primarily of fine-grained carbonate sand that is trapped and bound by the filamentous cyanobacteria Schizothrix sp.. Periodic introduction of coccoid endolithic cyanobacteria Solentia sp. during hiatuses in stromatolite growth associated with very low rates of sedimentation results in the formation of lithified horizons, 200–1000 μm thick. These layers consist of micritized grains that are welded together at point contacts. The micritization is caused by extensive microboring and carbonate precipitation within boreholes concurrent with endolithic activity. Grain welding occurs when boreholes cross from one grain to another at point contacts. Thus, microboring destroys original grain textures but, at the same time, plays a constructional role in stromatolite growth by forming lithified layers of welded grains. These lateral bands of fused carbonate grains help to stabilize and preserve the stromatolite deposits.  相似文献